• Title/Summary/Keyword: 10 mWT

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Preparation of Formed Ceramic materials by Recycling of Aluminium Dross (알루미늄 드로스를 이용한 무기 발포재 제조)

  • 박제신;박형규;장대규
    • Resources Recycling
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    • v.10 no.4
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    • pp.42-47
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    • 2001
  • Recycling of aluminum dross is a significant issue in domestic aluminum industry. In this study, formed ceramic materials were prepared using aluminum dross mixed with feldspar powders to investigate its application as industrial materials and utilization of aluminum dross. In the prepared sample, feldspar was melted at the sintered temperature, and its phase was trans-formed into amorphous, and spinel ($MgA1_2$$O_4$) phase in the dross was remained clearly. Density of the test specimen Increased from 0.91 to 0.65 gr/㎤ and water absorbance decreased from 2.5 to 1.7f% with increasing of sintered time at the sintered temperature $1220^{\circ}C$ with composition of feldspar 55 wt%, dross 40wt% and bentonite 5 wt%. At the same experimental conditions, bending strength of the test specimen was 10.8 MPa, and heat conductivity was 0.34 W/m.K with sintered time 30 minutes.

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Pervaporation Separation of Ethanol-Water Mixtures Using Nylon 4 and Its Blended Membranes (나일론 4와 이의 블렌드 막을 이용한 에탄올-물 혼합물의 투과 증발분리)

  • Rhim, Ji-Won;Huang, Robert Y.M.
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.791-797
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    • 1993
  • The application of the pervaporation process in biotechnology is rapidly growing. A two stage pervaporation process can be applied to the downstream processing of ethanol fermentation. In this paper, the second stage process in which the water-ethanol composition was 50:50 wt.% was investigated in more detail by using Nylon 4 and its blended membranes containing poly(vinyl alcohol) (PVA) and poly(acrylic acid) (PAA). Nylon 4 membranes were tested for compositions at 25, 30, and $35^{\circ}C$. Nylon 4 membranes had a separation factor of 4.18 with a permeability of $0.69kg/m^2hr$ at water-ethanol composition of 50:50 wt.%, while nylon 4-PVA blended membranes crosslinked by 5 Mrad gamma-ray irradiation showed a higher separation factor of 10.56 with permeability $0.55kg/m^2hr$ at the same composition. Nylon 4 also showed a high separation factor 27.8 at the ethanol-water azeotropic composition among the homopolymer membranes.

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High Pressure Phase Behavior in the Binary Polyethylene/Butane and Polyethylene/Dimethyl Ether Systems (이성분 폴리에틸렌/부탄과 폴리에틸렌/디메틸 에테르계의 고압 상거동)

  • Jeon, Nam-Seok;Byun, Hun-Soo
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.761-766
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    • 1999
  • In this paper, high pressure phase behavior in the binary polyethylene/butane and polyethylene/dimethyl ether has been studied. The pressure-temperature diagrams in polyethylene/butane were shown by increasing concentration for molecular weight standards, that is, $M_w=700,\;1000$ and 2000. It is found that the temperature and the pressures go up with increasing in concentrations for each molecular weight, but the latter lower in concentrations over 16 wt % polyethylene. In addition, the phase behaviors for each molecular weights with about 5 wt % polyethylene are shown in pressure-temperature, and pressures increase with increasing in molecular weight($M_w=700,\;1000$, and 2000). The phase behaviors in polyethylene/dimethyl ether are determined according to its molecular weight, and are shown for a range of pressures of 40~280 bar and temperatures of about $120{\sim}220^{\circ}C$. It is shown that in pressure-temperature of polyethylene/dimethyl ether the pressure increases with increasing in polyethylene molecular weight, and the difference in pressure for each molecular weight shows by about 60 bar. The gap in pressure between polyethylene/butane and polyethylene/dimethyl ether system with 5 wt % polyethylene for each molecular weight standards indicates about 25(700), 90(1000), and 100 bar(2000), respectively.

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Fabrication and Characteristic Evaluation of Three-Dimensional Blended PCL (60 wt %)/β-TCP (40 wt %) Scaffold (3 차원 Blended PCL (60 wt %)/β-TCP (40 wt %) 인공지지체의 제작 및 특성 평가)

  • Sa, Min-Woo;Kim, Jong Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.4
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    • pp.371-377
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    • 2014
  • In tissue engineering, a scaffold is a three-dimensional(3D) structure that serves as a template for regeneration the functions of damaged tissues or organs. Among materials for scaffolds, polycaprolactone(PCL) and ${\beta}$-tricalcium phosphate(${\beta}$-TCP) are biodegradable and biocompatible. In this study, we fabricated 3D PCL, blended PCL (60 wt %)/${\beta}$-TCP (40 wt %), and pure ${\beta}$-TCP scaffolds by a multi-head scaffold fabrication system. Scaffolds with a pore size of $600{\pm}20{\mu}m$ was observed by scanning electron microscopy. The effects of 3D PCL, blended PCL (60 wt %)/${\beta}$-TCP (40 wt %) and pure ${\beta}$-TCP scaffolds were analyzed by evaluating their mechanical characteristics. In addition, in an in-vitro study using osteoblast-like saos-2 cells, we confirmed the effects of 3D scaffolds on cellular behaviors such as cell adhesion and proliferation. In summary, the 3D blended PCL (60 wt %)/${\beta}$-TCP (40 wt %) scaffold was found to be suitable for human cancellous bone in terms of its the compressive strength, biocompatibility, and osteoconductivity. Thus, blending PCL and ${\beta}$-TCP could be a promising approach for fabricating 3D scaffolds for effective bone regeneration.

Effect of Grain Growth Inhibitor on Sintering of Nanophase WC-10wt%Co (초미립 WC-l0wt%Co 초경 분말의 소결시 입자 성장 억제제 첨가 효과 연구)

  • 김병기
    • Journal of Powder Materials
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    • v.1 no.2
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    • pp.208-216
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    • 1994
  • A radically new approach to the in situ synthesis of the consituent phases of a composite structure has enabled the production of a new WC/Co materials with an ultrafine microstructure. The process for synthesizing nanophase WC/Co powders consists of spray drying from solution to form a homogeneous precursor powder, and thermochemical conversion of the precursor powder to the nanophase WC/Co powder. Near theoretical density of pure nanophase WC-10 wt%Co has been obtained in only 30 sec at 140$0^{\circ}C$. But WC particles were grown up very rapidly with longer sintering time to get full density. To overcome coarsening of WC particle during sintering, VC, TaC and VC/TaC were used as the grain growth inhibitor with different amount respectively. VC/TaC doped WC-10 wt%Co was shown superior hardness and TRS and microstructure was maintained ultrafine scale (average WC size is less than 0.1 ${\mu}{\textrm}{m}$).

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A comprehensive evaluation of Mg-Ni based alloys radiation shielding features for nuclear protection applications

  • M.I. Sayyed;K.A. Mahmoud;Faras Q. Mohammed;Kawa M. Kaky
    • Nuclear Engineering and Technology
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    • v.56 no.5
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    • pp.1830-1835
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    • 2024
  • The current study aims to study the impacts of the substitution of magnesium with nickel concentrations on physical and γ-ray shielding capacity of magnesium alloys. The density of the magnesium alloys under study is varied from 3.677 g/cm3 to 5.652 g/cm3, with raising the nickel content from 26.7 wt% to 54.8 wt% and reducing the magnesium concentration from 72.6 wt% to 44.2 wt%, respectively. Additionally, the examination of the γ-ray shielding capacity using the Monte Carlo simulation code shows that the substitution of magnesium by nickel content in the magnesium alloys was associated with an enhancement in the γ-ray shielding capacity, where the linear attenuation coefficient for the studied alloys was enhanced by 53.22 %, 52.45 %, and 52.52 % at γ-ray energies of 0.662 MeV, 1.252 MeV, and 1.408 MeV, respectively, with raising the nickel concentration from 26.7 wt% to 54.8 wt%. Simultaneously, the half-value thickness for magnesium alloys was reduced from 2.47 cm to 1.62 cm (at gamma ray energy of 0.662 MeV), from 3.39 cm to 2.22 cm (at gamma ray energy of 1.252 MeV), and from 3.60 cm to 2.36 cm (at gamma ray energy of 1.408 MeV), raising the nickel concentration from 26.7 wt % to 54.8 wt%, respectively. The study shows that the substitution of magnesium for nickel greatly enhanced the radiation shielding capacity of the magnesium alloys.

Effect of Adding of II-Anhydrite and Superplasticizer on the Fluidity of Cement Paste (II형 무수석고 및 고유동화제 첨가가 시멘트 페이스트의 유동성에 미치는 영향)

  • Kim, Jae-Ho;Kim, Do-Su;Lee, Beom-Jae;Rho, Jae-Seong
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.336-341
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    • 1998
  • A comparative study on the effects of mean particle diameter and substitutional ratio of II-anhydrite on the fluidity of cement paste has been conducted. Three different mean particle diameters(4, 14 and $35{\mu}m$) and four different substitution ratios(3, 5, 10, 15wt%) have been tested while the dosage of two superplasticizers - naphtalenic(NSF) and polycarboxylic(NT-2) - has been varied from 0 to 2.0wt%. To investigate the effects of those parameters, the variation in fluidity and apparent viscosity of the cement paste has been observed as a function of the elapsed time. The initial fluidity of the cement paste is more affected by the increase in substitution ratio than by the mean particle size of the II-anhydrite. When the substitution ratio of the II-anhydrite is fixed at 10wt%, addition of 1.0wt% NT-2 improves the fluidity of paste cement more than that for NSF. This case has showed the best improvement of the fluidity in the range of parameters investigated. At the addition of 1.0wt% NT-2, apparent viscosity of the cement paste has been noticeably decreased as substitutional ratio of II-anhydrite increases. It was found that it would be more effective to substitute II-anhydrite at a certain ratio to improve the fluidity of the cement paste, in addition to adding NT-2.

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Measurements of the Thermal Conductivity of Domestic Bentonite for Improving the Physical Performance of Buffer (완충재의 물리적 성능향상을 위한 국내 벤토나이트의 열전도도 측정실험)

  • Kim, Geon-Young;Kim, Seung-Soo;Choi, Jong-Won;Park, Seong-Wan;Bae, Dae-Seok
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.2 s.48
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    • pp.89-98
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    • 2006
  • The thermal conductivities of bentonite blocks with various dry densities (1.6 and $1.8g/cm^3$), water contents (5, 9.4, 15, 20 wt%) and sand contents (0, 10, 20, 30 wt%) were measured in order to investigate the improvement in physical performance of buffer as an engineered barrier. The raw material was domestic bentonite from Oksan mine located in Gyeongju city. The increase in water content was most effective for improving the thermal conductivity. Especiallly, the bentonite blocks with more than 15 wt% of water content showed more than 1.0 W/mK values of thermal conductivity regardless of their dry densities and sand contents. Therefore, if the domestic Oksan bentonite is used as a buffer material, we can suggest that the manufacture of bentonite block having dry density of $1.6g/cm^3$, sand content of $10{\sim}30$ wt% and water content of 15 wt% will be most effective considering the easiness of a manufacturing of bentonite block and the efficiency of an increase in the thermal conductivity.

Dielectric and Piezoelectric Properties of 0.57Pb(Sc1/2Nb1/2)O3-0.43PbTiO3 Ceramics with Dopant Additions (도펀트 첨가에 따른 0.57Pb(Sc1/2Nb1/2)O3-0.43PbTiO3 세라믹스의 유전 및 압전특성)

  • Ji, Seung-Han;Kwon, Sang-Jik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.2
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    • pp.124-129
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    • 2007
  • Dielectric and piezoelectric properties of $0.57Pb(Sc_{1/2}Nb_{1/2})O_{3}-0.43PbTiO_{3}$, which is the morphotropic phase boundary composition for the PSN-PT system, were investigated as a function of $Fe_{2}O_{3},\;Nb_{2}O_{5}\;and\;MnO_{2}$ addition 0 wt% to 0.9 wt%. The maximum dielectric constant of ${\varepsilon}_{33}/{\varepsilon}_{o}=2054$ and the minimum dielectric loss of $tan{\delta}=0.37\;%$ at room temperature were obtained at 0.1 wt% of $Fe_{2}O_{3}$ and 0.5 wt% of $MnO_{2}$ addition, respectively. With addition of 0.5 wt% $Nb_{2}O_{5}$ and $0.5\;wt%\;MnO_{2}$, the electromechanical coupling factor $k_{p}$ and mecanical quality factor $Q_{m}$ were significantly increased, respectively. The maximum electromechanical coupling factor $k_{p}=61.5\;%$ was obtained by addition of $Nb_{2}O_{5}$ and high mechanical quality factor $Q_{m}=919$ was obtained by addition of $MnO_{2}$. The $Q_{m}(=919)$ value is 3.3 times larger than that of non-doped 0.57PSN-0.43PT ceramics.

Change of Soil and Water Temperature on the Different Topography and Irrigation Conditions of Paddy Land (지형(地形)과 관개조건(灌漑條件)에 따른 논의 수온(水溫) 및 지온변화(地溫變化))

  • Kim, Lee Yul;Jo, In Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.1
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    • pp.12-17
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    • 1989
  • Soil and water temperature were evaluated to relate rice growth to topographical chracteristics in paddy soils. Water temperature (WT) and so il temperature (ST) were measured under the various altitudes, slopes and irrigation methods. Temperature fluctuation and growth status in the same field were measured; 1. Air temperature (AT) and ST of 10cm soil depth were decreased with increasing altitude. Difference of its fluctuation in AT, WT and ST of 10cm soil depth in the lapse rate was 0.64, 0.84 and $0.82^{\circ}C$ per 100m elevation, respectively. 2. Maximum WT, in panicle initiation stage, was decreased slowly with increasing altitude whereas minimum WT fallen rapidly. It suggested that the lapse rate of WT was affected by minimum WT. 3. Source of irrigation water and irrigation method affected the WT. WT, ST and rice growth varied with the locations within the same field. 4. Pumping irrigation of artesian well resulted in more fluctuation of WT between irrigation intervals than did the conventional irrigation.

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