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RF and Optical properties of Graphene Oxide

  • Im, Ju-Hwan;Rani, J.R.;Yun, Hyeong-Seo;O, Ju-Yeong;Jeong, Yeong-Mo;Park, Hyeong-Gu;Jeon, Seong-Chan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.68.1-68.1
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    • 2012
  • The best part of graphene is - charge-carriers in it are mass less particles which move in near relativistic speeds. Comparing to other materials, electrons in graphene travel much faster - at speeds of $10^8cm/s$. A graphene sheet is pure enough to ensure that electrons can travel a fair distance before colliding. Electronic devices few nanometers long that would be able to transmit charge at breath taking speeds for a fraction of power compared to present day CMOS transistors. Many researches try to check a possibility to make it a perfect replacement for silicon based devices. Graphene has shown high potential to be used as interconnects in the field of high frequency electrical devices. With all those advantages of graphene, we demonstrate characteristics of electrical and optical properties of graphene such as the effect of graphene geometry on the microwave properties using the measurements of S-parameter in range of 500 MHz - 40 GHz at room temperature condition. We confirm that impedance and resistance decrease with increasing the number of graphene layer and w/L ratio. This result shows proper geometry of graphene to be used as high frequency interconnects. This study also presents the optical properties of graphene oxide (GO), which were deposited in different substrate, or influenced by oxygen plasma, were confirmed using different characterization techniques. 4-6 layers of the polycrystalline GO layers, which were confirmed by High resolution transmission electron microscopy (HRTEM) and electron diffraction analysis, were shown short range order of crystallization by the substrate as well as interlayer effect with an increase in interplanar spacing, which can be attributed to the presence of oxygen functional groups on its layers. X-ray photoelectron Spectroscopy (XPS) and Raman spectroscopy confirms the presence of the $sp^2$ and $sp^3$ hybridization due to the disordered crystal structures of the carbon atoms results from oxidation, and Fourier Transform Infrared spectroscopy (FTIR) and XPS analysis shows the changes in oxygen functional groups with nature of substrate. Moreover, the photoluminescent (PL) peak emission wavelength varies with substrate and the broad energy level distribution produces excitation dependent PL emission in a broad wavelength ranging from 400 to 650 nm. The structural and optical properties of oxygen plasma treated GO films for possible optoelectronic applications were also investigated using various characterization techniques. HRTEM and electron diffraction analysis confirmed that the oxygen plasma treatment results short range order crystallization in GO films with an increase in interplanar spacing, which can be attributed to the presence of oxygen functional groups. In addition, Electron energy loss spectroscopy (EELS) and Raman spectroscopy confirms the presence of the $sp^2$ and $sp^3$ hybridization due to the disordered crystal structures of the carbon atoms results from oxidation and XPS analysis shows that epoxy pairs convert to more stable C=O and O-C=O groups with oxygen plasma treatment. The broad energy level distribution resulting from the broad size distribution of the $sp^2$ clusters produces excitation dependent PL emission in a broad wavelength range from 400 to 650 nm. Our results suggest that substrate influenced, or oxygen treatment GO has higher potential for future optoelectronic devices by its various optical properties and visible PL emission.

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Complex Permeability of 0-3 Polymer Magnetic Composites for Near-Field Communication (근역장 통신용 0-3형 고분자 자성 복합소재의 복소투자율 변화)

  • Nam, Joong-Hee;Lim, Choong Hyuck;Yun, Ji Sun;Jeong, Young-Hun;Cho, Jeong-Ho;Paik, Jong Hoo;Kim, Hyo Tae;Kim, Jong-Hee
    • Journal of the Korean Magnetics Society
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    • v.22 no.6
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    • pp.216-220
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    • 2012
  • Magnetic properties of composite materials consisting of polymer filled with ferromagnetic powders (MnZn ferrite, Fe-Si alloy) were investigated in this study. The volume fraction of magnetic powders as fillers was varied from 70 % to 95 %. This paper presents the fabrication method of polymer magnetic composites in an effort to produce the 0-3 types of MnZn ferrite and FeSi as fillers with a proper complex permeability through the optimization of some experimental parameters. The polymer matrix composites were prepared by mixing the crushed ferrites and flaky FeSi powders homogenously with low-density resins (EPDM, epoxy). The relationships among the manufacturing technology of these materials, their filler volume fraction, as well as their complex permeability were measured and analyzed.

Implementation of Improved Frame Slotted ALOHA Algorithm for Fast Tag Collection in an Active RFID System (고속 태그 수집을 위한 개선된 능동형 RFID 시스템용 프레임 Slotted ALOHA 알고리즘 구현)

  • Kim, Ji-Tae;Kang, Byeong-Gwon;Lee, Kang-Won
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.39B no.9
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    • pp.598-605
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    • 2014
  • In this paper, we suggest a modified slotted ALOHA algorithm for fast tag collection in active RFID system and implement the reader and tag operation using CC2530 chip of Texas Instruments Co. to prove the performance of the proposed algorithm. In the present international standard related with active RFID including ISO/IEC 18000-7 the reader sends sleep command to each tag after successful obtaining tag's information. Meanwhile, in this paper, the tags decide to sleep after checking the second command from the reader resulting in enormously decreased tag collection time. We tested the proposed algorithm with 30 tags over the range of 0-3m and the results showed that the tag collection process was completed in 400msec at average. And 30 tags are collected in one second with 99.7% and the collection rate is 100% in 2m distance between reader and tag. The collection rates are 99.94% and 99.7% for distance 2.5m and 3m, respectively. The average collection rate is 99.91% over all range and it is concluded that the proposed algorithm is enough to apply to real fields.

A Planar Implementation of a Negative Group Delay Circuit (평면 구조의 마이너스 군지연 회로 설계)

  • Jeong, Yong-Chae;Choi, Heung-Jae;Chaudhary, Girdhari;Kim, Chul-Dong;Lim, Jong-Sik
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.3
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    • pp.236-244
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    • 2010
  • In this paper, a planar structure negative group delay circuit(NGDC) is proposed to overcome the limited availability of the component values required for the prototype lumped element(LE) NGDC design. From the prototype LE circuit analysis, general design equations and the conditions to obtain the NGD are derived and illustrated. Then the LE circuit is converted into the planar structure by applying the transmission line resonator(TLR) theory. As a design example, the LE NGDC and the proposed planar structure NGDC are designed and compared. To estimate the commercial applicability, 2-stage reflection type planar NGDC with -5.6 ns of total group delay, -0.2 dB of insertion loss, and 30 MHz of bandwidth together with 0.1 dB and 0.5 ns of the magnitude and group delay flatness, respectively, for Wideband Code Division Multiple Access(WCDMA) downlink band is fabricated and demonstrated. Also, to show the applicability of the proposed NGDC, we have configured a simple signal cancellation loop and obtained good loop suppression performance.

Implementation of Small Size Dual Band PAM using LTCC Substrates (LTCC를 이용한 Small Size Dual Band PAM의 구현)

  • Shin, Yong-Kil;Chung, Hyun-Chul;Lee, Joon-Geun;Kim, Dong-Su;Yoo, Jo-Shua;Yoo, Myong-Jae;Park, Seong-Dae;Lee, Woo-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.357-358
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    • 2005
  • Compact power amplifier modules (PAM) for WCDMA/KPCS and GSM/WCDMA dual-band applications based on multilayer low temperature co-fired ceramic (LTCC) substrates are presented in this paper. The proposed modules are composed of an InGaP/GaAs HBT PAs on top of the LTCC substrates and passive components such as RF chokes and capacitors which are embedded in the substrates. The overall size of the modules is less than 6mm $\times$ 6mm $\times$ 0.8mm. The measured result shows that the PAM delivers a power of 28 dBm with a power added efficiency (PAE) of more than 30 % at KPCS band. The adjacent-channel power ratio (ACPR) at 1.25-MHz and 2.25-MHz offset is -44dBc/30kHz and -60dBc/30kHz, respectively, at 28-dBm output power. Also, the PAM for WCDMA band exhibits an output power of 27 dBm and 32-dB gain at 1.95 GHz with a 3.4-V supply. The adjacent-channel leakage ratio (ACLR) at 5-MHz and 10-MHz offset is -37.5dBc/3.84MHz and -48dBc/3.84MHz, respectively. The measured result of the GSM PAM shows an output power of 33.4 dBm and a power gain of 30.4 dB at 900MHz with a 3.5V supply. The corresponding power added efficiency (PAE) is more than 52.6 %.

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Low-Temperature Sintering and Microwave Dielectric Properties of the $B_2O_3-$ and CuO-added $Ba(Mg_{1/3}Nb_{2/3})O_3$ Ceramics ($B_2O_3$ 와 CuO가 첨가된 $Ba(Mg_{1/3}Nb_{2/3})O_3$ 세라믹스의 저온소결과 마이크로파 유전특성 연구)

  • Lim, Jong-Bong;Son, Jin-Ok;Nahm, Sahn;Yu, Myeong-Jae;Lee, Woo-Sung;Kang, Nam-Kee;Lee, Hwack-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.838-841
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    • 2004
  • [ $B_2O_3$ ] added $Ba(Mg_{1/3}Nb_{2/3})O_3$ (BBMN) ceramics were not sintered below $900^{\circ}C$. However, when CuO was added to the BBMN ceramic, it was sintered even at $850^{\circ}C$. The amount of the $Ba_2B_2O_5$ second phase decreased with the addition of CuO. Therefore, the CuO additive is considered to react with the $B_2O_3$ inhibiting the reaction between $B_2O_3$ and BaO. Moreover, it is suggested that the solid solution of CuO and $B_2O_3$ might be responsible for the decrease of the sintering temperature of the specimens. A dense microstructure without pores was developed with the addition of a small amount of CuO. However, a porous microstructure with large pores was formed when a large amount of CuO was added. The bulk density the dielectric constant $({\varepsilon}_r)$ and the Q-value increased with the addition of CuO but they decreased when a large amount of CuO was added. The variations of those properties are closely related to the variation of the microstructure. The excellent microwave dielectric properties of Qxf=21500 GHz, ${\varepsilon}_r=31$ and temperature coefficient of resonance frequency$({\tau}_f)=21.3\;ppm/^{\circ}C$ were obtained for the $Ba(Mg_{1/3}Nb_{2/3})O_3+2.0\;mol%B_2O_3+10.0$ mol%CuO ceramic sintered at $875^{\circ}C$ for 2h.

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Fabrication and optical characteristics of 50 ㎓ narrow band pass filter for fiber optical communication using dual ion beam sputtering technique (이중 이온빔 스퍼터링 방식을 사용한 채널 간격 50 ㎓ 광통신용 협대역 투과 필터의 제작 및 특성)

  • 김회경;김명진
    • Korean Journal of Optics and Photonics
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    • v.14 no.3
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    • pp.331-337
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    • 2003
  • This paper represents 50 ㎓ narrow band pass filters for fiber optical communication fabricated by dual ion beam sputtering method. We have analyzed the characteristics of the TA$_2$ $O_{5}$ and $SiO_2$ single layers in order to optimize the process conditions for the 50 ㎓ narrow band pass filters, and controlled the film thickness uniformity to less than 0.1 nm deviation by dual peak spike filter pre-deposition. We designed and fabricated 50 ㎓ narrow band pass filters that consist of 216 layers including 4 cavities based on quarter wave optical thickness. Class substrates with high thermal expansion coefficients were used to reduce the film stress. Anti-reflection coating at the rear side of the substrate was also needed to reduce the optical thickness errors of the Optical Monitoring System caused by multiple beam interference between the front side and the rear side of substrate. The optical characteristics of this 50 ㎓ narrow band pass filters are insertion loss of 0.40 ㏈, pass band ripple of 0.20 ㏈, and pass bandwidth at -0.5 ㏈ of 0.20 nm. and isolation bandwidth at -25 ㏈ of 0.6 nm, which satisfy specifications of dense WDM system in fiber optical communications.tions.

A Study on the Wireless Communication Method for Emergency Broadcasting System in Metro Environments (도시철도용 비상방송시스템을 위한 무선통신방식 연구)

  • Jang, Soo-Hyun;Shin, Dae-Kyo;Yoon, Sang-Hun;Jung, Han-Gyun;Jin, Seong-Keun;Lim, Ki-Taeg
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.17 no.6
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    • pp.202-210
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    • 2018
  • Recently, the subway running in metro environments has a problem in securing the safety of passengers due to the failure of announcement in emergency situations such as breakdown, train accidents and power outage in the underground tunnels. Thus, there is a need to develop an emergency broadcasting system that can provide the announcement to all passenger cars in any emergency situations on the railway route. In this paper, the applicability of various wireless communication technologies for the emergency broadcasting system through the measurement campaign was examined in Seoul metropolitan subway. A WAVE(Wireless Access in Vehicular Environments) is communication technology that can use 5.9GHz dedicated frequency band without charge and it is possible to directly communicate between terminals over 200m without the help of additional relay. Especially, it confirms robust communication performance in the various metro environments, and therefore, it is considered to be suitable as a communication method of a radio-connected emergency broadcasting system for urban subway.

Study on the Retrieval of Vertical Air Motion from the Surface-Based and Airborne Cloud Radar (구름레이더를 이용한 대기 공기의 연직속도 추정연구)

  • Jung, Eunsil
    • Atmosphere
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    • v.29 no.1
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    • pp.105-112
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    • 2019
  • Measurements of vertical air motion and microphysics are essential for improving our understanding of convective clouds. In this paper, the author reviews the current research on the retrieval of vertical air motions using the cloud radar. At radar wavelengths of 3 mm (W-band radar; 94-GHz radar; cloud radar), the raindrop backscattering cross-section (${\sigma}b$) varies between successive maxima and minima as a function of the raindrop diameter (D) that are well described by Mie theory. The first Mie minimum in the backscattering cross-section occurs at D~1.68 mm, which translates to a raindrop terminal fall velocity of ${\sim}5.85m\;s^{-1}$ based on the Gunn and Kinzer relationship. Since raindrop diameters often exceed this size, the signal is captured in the radar Doppler spectrum, and thus, the location of the first Mie minimum can be used as a reference for retrieving the vertical air motion. The Mie technique is applied to radar Doppler spectra from the surface-based and airborne, upward pointing W-band radars. The contributions of aircraft motion to the vertical air motion are also described and further the first-order aircraft motion corrected equation is presented. The review also shows that the separate spectral peaks due to the cloud droplets can provide independent validation of the Mie technique retrieved vertical air motion using the cloud droplets as a tracer of vertical air motion.

Microwave Dielectric Properties of (Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 Ceramics ((Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 세라믹스의 마이크로파 유전 특성)

  • Ju Hye Kim;Si Hyun Kim;Eung Soo Kim
    • Korean Journal of Materials Research
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    • v.33 no.8
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    • pp.330-336
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    • 2023
  • The effects of Ni2+ substitution for Mg2+-sites on the microwave dielectric properties of (Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 (0.01 ≤ x ≤ 0.05) (MNTMT) ceramics were investigated. MNTMT ceramics were prepared by conventional solid-state reaction. When the MgO / TiO2 ratio was changed from 1.00 to 1.02, MgTi2O5 was detected as a secondary phase along with the MgTiO3 main phase in the MNTMT specimens sintered at 1,400 ℃ for 4h. For the MNTMT specimens with MgO / TiO2 = 1.07 sintered at 1,400 ℃ for 4h, a single phase of MgTiO3 with an ilmenite structure was obtained from the entire range of compositions. The relative density of all the specimens sintered at 1,400 ℃ for 4h was higher than 95 %. The quality factor (Qf) of the sintered specimens depended strongly on the degree of covalency of the specimens, and the sintered specimens with x = 0.01 showed the maximum Qf value of 489,400 GHz. The dielectric constant (K) decreased with increasing Ni2+ content because Ni2+ had a lower dielectric polarizability (1.23Å3) than Mg2+ (1.32Å3). As Ni2+ content increased, the temperature coefficient of resonant frequency (TCF) improved, from -55.56 to -21.85 ppm/℃, due to the increase in tolerance factor (t) and the lower dielectric constant (K).