• Journal of the Korean Electrochemical Society
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• v.3 no.3
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• pp.141-145
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• 2000

Anodically Polymerized conducting Polypyrrole film electrode was employed to Pick up uranyl ion with the type of Gr/ppy, xylenol orange modified electrode. To have Porous and oriented ppy film, NBR was applied as precoating agent. The rate constant of polymerization was $3.22\times10^{-3}s^{-1}$ which was 1.6 times smaller value than bare graphite surface. The deposited amount of uranyl iou on $1.70Ccm^{-2}$ of ppy was $1.55\times10^{-4}g$. The matrix effect in artificial seawater was $6.8\%$. The polymer film electrode has a diffusion controlled process in conduction, but the modified Gr/ppy, $X.O^{4-}UO^+$ type was influenced on the ion doping and electronic conduction of film itself owing to increasing of impedance. The capacitance of electrical double layer was respectively enhanced to 56 and 130 times in Gr/ppy, $X.O.^{4-}$ and Gr/ppy, $X.O^{4-}UO^+$ than Grippy type electrode.

• Elastomers and Composites
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• v.52 no.3
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• pp.187-193
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• 2017

In this study, the effect of the cure, mechanical properties, and oil resistance of NBR (acrylonitrile-butadiene rubber)/peroxide compounds were investigated for various co-agents. NBR compounds were characterized using a swelling test, a rheometer (MDR), and a compression set test. Mechanical properties were tested with original compounds, heated in air and exposed to the ASTM No.1, IRM 903 oil. NBR compounds were prepared using peroxide as the crosslinking agent. Trimethylolpropane trimethacrylate (TMPTMA), triallyl isocyanurate (TAIC), and 1,2-polybutadiene (HVPBD) were used as co-agents. The NBR compounds containing TMPTMA and HVPBD lowered the scorch time, while the addition of TAIC did not significantly change the scorch time. NBR compounds containing TMPTMA increased the crosslinking density, while the addition of TAIC and HVPBD lowered the crosslinking density. Moreover, the addition of TMPTMA improved the oil resistance of the NBR compound.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.1
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• pp.108-121
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• 1998

Using gas chromatography, the light hydrocarbon emissions were analyzed from SI engine fueled with methane and liquified petroleum gas(LPG), and the effects of fuel and engine operating condition were discussed. For this purpose, 14 species of light hydrocarbon including 1, 3-butadiene were separated, calibrated with standard gas, and measured from undiluted emissions. The brake specific hydrocarbon emission(BSHC) and ozone forming potential(BSO)3 were calculated and discussed with the changes of fuel, engine speed, load, fuel/air equivalence ratio, coolant temperature, and spark timing. As a result, exhaust emission was composed of mainly fuel composed of mainly fuel comp- onent and other olefin components of similar carbon number. The olefin components such as ethylene and propylene determine most of the ozone forming potential. The fraction of fuel component in total hydrocarbon emission was bigger with methane fuel than with LPG fuel. Also fuel fraction increased at high speed or high speed or high temperature of exhaust gas, and to lesser extent with high coolant temperature and retarded spark. However, the effect of equivalence ratio had different tendency according to fuels.

• Applied Biological Chemistry
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• v.48 no.4
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• pp.339-344
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• 2005

Rice blast, which is caused by the fungus Magnaporthe grisea, is one of the most destructive diseases of rice. To identify genes involving in the signal transduction pathways that mediate rice blast resistance, we screened over 2,000 mutant lines of a highly resistant variety RIL260 that were generated by using a DEB (1, 3-Butadiene diepoxide) treatment method. In the mutant population, the frequency of albino plants was 6.7%, indicating that this population has a high frequency of mutations in the genome. The primary screening identified 29 mutant plants that exhibit a complete or partial loss of the resistance to rice blast. Among them, M5465, the most susceptible line, was subsequently examined by DNA gel-blot experiments using DNA molecular markers of Pi5(t) that has been previously identified as a durable resistance locus in RIL260. The result revealed that a large deletion and rearrangement of genomic DNA occurred in the Pi5(t) locus. The results suggest that DEB can be used as an efficient mutagen to induce large scale mutations in the rice genome. The isolated mutants should be useful for elucidating the Pi5(t)-mediated signaling pathways of rice blast resistance.

• Elastomers and Composites
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• v.48 no.3
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• pp.225-231
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• 2013

In this study, we observed the effect of carboxylated SBR latex and zinc oxide on styrene-butadiene-styrene( SBS) composites for improving abrasion and debris. SBS composite, which added only silica, showed poor mechanical properties, NBS abrasion, and debris, caused by strong filler-filler interaction of silica. In case of adding carboxylated SBR latex, mechanical properties, NBS abrasion and debris of SBS composite were improved. Because of carboxyl group of carboxylated SBR latex interacted with silanol group of silica. Both carboxylated SBR latex and zinc oxide were added, SBS composite showed highest mechanical properties, NBS abrasion, and debris by forming ion cluster between carboxylated SBR latex and zinc oxide. By FT-IR analysis, ion clusters were confirmed that observed zinc carboxylated group stretch peak at $1550{\sim}1650cm^{-1}$ range. SBS composite, SC-4, showed excellent mechanical properties ; tensile strength $156kgf/cm^2$, elongation 936%, tear strength 59.4kgf/cm ; and excellent abrasion characteristics ; NBS abrasion 338%. Also, debris of SC-4 was minimized and showed wave-shape in fracture surface.

• Journal of the Korean Chemical Society
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• v.7 no.2
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• pp.128-132
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• 1963

A study has been made on the applicability of gas-liquid partition chromatography to the qualitative and quantitative analysis of complex mixture of gaseous hydrocarbons. While phthalate columns are widely used for this $purpose^9$, they separates neither saturated hydrocarbons from the unsaturated nor n-butane from isobutene or butene-1, therefore combined columns such as phthalate and dimethylsulfolane have been used for the perfect separation of gaseous hydrocarbons. It is shown by this study, however, that hydrocarbons having $C_1$ through $C_4$ can be separated with a 2-meters tetraethyleneglycol dimethylether column except ethane from ethylene, and trans-from cis-2-butene especially operated at $15^{\circ}C$$ using helium as the carrier gas. The column effluents were in order of methane, (ethane, ethylene), propane, propylene, isobutane, n-butane, isobutylene, butene-1, (trans-& cis-2-butene, isopentane), (butadiene-1, 3, n-pentane). Two kinds of liquified petroleum gases in market are analysed qualitatively and quantitatively. The results indicate that use of this 2-meters TEGDE column permits the separation and identification of all the commonly encountered aliphatic gaseous hydrocarbons.

• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.74-81
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• 2021

Silicon (Si) is recognized as a promising anode material for high-energy-density lithium-ion batteries. However, under a condition of electrode comparable to commercial graphite anodes with low binder content and a high electrode density, the practical use of Si is limited due to the huge volume change associated with Si-Li alloying/de-alloying. Here, we report a novel core-shell composite, having a reversible capacity of ~ 500 mAh g-1, by forming a shell composed of a mixture of nano-Si, graphite nanosheets and a pitch carbon on a spherical natural graphite particle. The electrochemical measurements are performed using electrodes with 2 wt % styrene butadiene rubber (SBR) and 2 wt.% carboxymethyl cellulose (CMC) binder in an electrode density of ~ 1.6 g cm-3. The core-shell composites having the reversible capacity of 478 mAh g-1 shows the outstanding capacity retention of 99% after 100 cycles with the initial coulombic efficiency of 90%. The heterostructure of core-shell composites appears to be very effective in buffering the volume change of Si during cycling.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.04a
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• pp.327-338
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• 2011

This study was carried in order to manufacture the high quality coated paper. High quality includes not only properties of coated paper but also final print quality. In this study, new acrylic-styrene emulsion was polymerized in laboratory and compared with styrene-butadiene latex. Low-shear viscosity of coating color was decreased with increasing acrylic-emulsion dosage. WRV was increased with addition and decreased with substitution of acrylic-emulsion. Paper gloss, brightness and whiteness were increased and PPS and opacity was slightly decreased with acrylic-emulsion. Ink gloss was increased with using No. 3 acrylic-emulsion due to lower ink setting properties. However No.1, 2 emulsion shows opposite situation. Surface strength of coated paper was increased with using No. 3 acrylic-emulsion These results indicate that high quality coated paper can be manufactured with using No. 3 acrylic-emulsion.

• Elastomers and Composites
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• v.36 no.1
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• pp.44-51
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• 2001

To see the effect of chemical surface modification, the carbon black surfaces were treated with three types of chemicals (KOH, $H_3PO_4$, and benzene). Vulcanization and mechanical properties of a styrene-butadiene rubber (SBR) were investigated depending on the chemical treatments. The surface free energy increased considerably with the treatments by both the acid (HCB) and base (KCB), but only a slight increase was observed for benzene treatment(BCB). The BCB showed the highest level of the London dispersive component. The vulcanization reaction was found to be faster in the order of KCB-SBR> BCB-SBR> VCB-SBR(virgin) > HCB-SBR. The difference in minimum and maximum torque of rheocurve, representing the degree of crosslinking, was found to be higher for the BCB-SBR compared to those of VCB-SBR, KCB-SBR, and HCB-SBR. The BCB-SBR and KCB-SBR showed the improved tensile and dynamic mechanical properties. A linear relationship was found to exist between the London dispersive component of surface free energy and mechanical properties.

• Applied Chemistry for Engineering
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• v.26 no.2
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• pp.173-177
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• 2015

In this study, effects of both the grafted ABS-g-MAH and the added graphene oxide (GO) on the impact strength of polycarbonate (PC)/poly(acrylonitrile-butadiene-styrene) (ABS) blends were discussed. The PC/ABS blends and PC/ABS/GO composites were fabricated by using twin screw extruder with ABS-g-MAH as a compatibilizer. The ABS-g-MAH was prepared by melting extrusion of ABS and maleic anhydride (MAH) with DCP (dicumyl peroxide) as an initiator using twin screw extruder and the synthesis of ABS-g-MAH was confirmed by the presence of carbonyl group (C=O) peak at $1780cm^{-1}$ of FT-IR spectrum. According to the thermal, rheological, and impact properties of PC/ABS blends, 5 phr (parts per hundred resin) of compatibilizer was chosen as an optimum content for the PC/ABS/GO composites. It was observed that the thermal decomposition of ABS/PC/GO composites increased with GO contents, but there was no significant changes or a decrease in the impact strength. Also the composite fabricated by ABS/GO showed small increase in the impact strength. From the result of the dynamic rheometer to observe the processing properties, the complex viscosities of PC/ABS blend including the compatibilizer increased, but the complex viscosities of composites added GO were not changed.