• Title/Summary/Keyword: 희토류 대체

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Major, Rare-Earth and Trace Geochemistry of Ulleungdo Volcanic Rocks (울릉도 화산암의 주원소, 휘토류 및 미량원소 지구화학)

  • 송용선;박계헌;박맹언
    • The Journal of the Petrological Society of Korea
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    • v.8 no.2
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    • pp.57-70
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    • 1999
  • The volcanic rocks of Ulleungdo reveal very high alkali element abundances and most of them have high K20/Na20 ratios and belong to potassium-series. Ulleungdo volcanics show very wide range of variation in their composition from basalts to trachytic basalt, basaltic trachyandesite, trachyandesite, and finally to trachyte on total alkali-silica diagram. Such a general trend of compositional variation can be explained well by differentiation due to fractional crystallization of various minerals. Olivine, clinopyroxene, plagioclase, ilmenite, and apatite are suggested as the major fractionated minerals. Ulleungdo volcanics show Nb/U and PbICe ratios similar to oceanic volcanics such as MORB and OIB, but significantly different .from volcanic rocks of island arc environments, which suggest that they are not directly related with subduction along the Japanese arc. LREE abundances of Ulleungdo volcanics are highly enriched compared with HREE abundances ((La)N=193-420, (L~)~=7.5-19.5).O nly trachyte-1 show appreciable negative Eu anomalies among various rock types, which suggests significant amount of plagioclase were fractionated. However, trachyte-2, trachyte-3, phonolite, and pumice reveal quite different variation trend of trace and rare earth element abundances from trachyte-1, which suggest that they have originated from different magma batches and have experienced different differentiation processes. A prominent bimodal distribution, thus lacking of intermediate composition, is observed from the Ulleundo volcanics.

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Petrology of the Cretaceous igneous rocks in Gadeog Island, Busan, Korea (부산 가덕도 지역 백악기 화성암류에 대한 암석학적 연구)

  • 고정선;김은희;윤성효
    • The Journal of the Petrological Society of Korea
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    • v.13 no.2
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    • pp.47-63
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    • 2004
  • This study focuses on the petrography and petrochemical characteristics of the volcanic and plutonic rocks in Gadeog island, Busan, Korea. Based on textural and mineralogical characteristics, intermediate volcanic rocks can be divided into andesitic lava flows (porphyritic and massive andesites) and andesitic pyroclastics. Felsic volcanic rocks are composed of rhyolite, rhyolitic welded tuff, and tuff breccia. Plutonic rocks are intruded rhyolite and andesitic rocks, and composed of hornblende granodiorite which contains lots of mafic magma enclaves. Volcanic rocks are composed of andesite, dacite and rhyolite having a range in SiO$_2$ from 59 to 78wt.%. The volcanic rocks belong to the calc-alkaline rock series. Plutonic rocks have a range in SiO$_2$ from 63 to 69wt.%. This compositional variations correspond to those of Cretaceous volcanic and plutonic rocks in the southeastern Gyeongsang basin. The trace element composition and rare earth element patterns of the volcanics, which are characterized by high LREE/HFSE ratios and enrichment in LREE, suggest that they are typical of calc-alkaline volcanic rocks produced in the subduction environment around continental arc. We concluded that volcanic and plutonic rocks in Gadeog Island were evolved from orogenic andesitic magma which was produced by partial melting of the mantle wedge in the subduction environment.

An Analysis of Material Property on Eartherwares Excavated at Auraji site in Jeongseon (정선 아우라지 출토 토기의 재료과학적 특성 분석)

  • Lee, Byeong Hoon
    • Journal of Conservation Science
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    • v.37 no.5
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    • pp.545-556
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    • 2021
  • In this study, we aimed to elucidate the materialistic characteristics of 11 pieces of earthenware belonging to the Neolithic and Bronze Age excavated from Jeongseon Auraji, South Korea. As a result, the chemical composition of earthenwares belonging to the early Bronze Age was distributed in the intermediate area between the Neolithic and Bronze Age earthenwares, but no significant difference was confirmed based on their manufacturing period. Upon comparison, the earthenwares excavated from Jeongseon Auraji site were found to comprise less acidic components than those excavated from Yeongdong, and are characterized by the alkaline components depending on the excavated site. In the rare earth elements distribution pattern, all the analyzed earthenwares exhibited similar pattern, confirming that the raw materials present in the clay were the same. As a result of microstructure analysis, the clay particles and voids were found to be irregularly distributed in the analyzed earthenwares. Neolithic earthenwares exhibited many irregular voids, and an arrangement of aluminosilicate, including feldspar, was observed along with the clay substrate. Furthermore, we confirmed that the empty space in early Bronze Age earthenwares was filled with fine particles and cube crystals. Moreover, the main mineral phase of earthenwares excavated from Jeongseon Auraji exhibited similar composition, and therefore, there was no significant difference in the firing temperature of these earthenwares. The firing temperature of the earthenwares ranged from 750 to 850℃.

Low Dilution Glass Bead Digestion Technique for the Trace Element Analysis of Rock Samples (저희석 유리구 용해법에 의한 암석시료 미량원소 분석법)

  • Park, Chan-Soo;Shin, Hyung-Seon;Oh, Hae-Young;Moon, Jong-Hwa;Cheong, Chang-Sik
    • The Journal of the Petrological Society of Korea
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    • v.20 no.3
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    • pp.161-172
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    • 2011
  • Open beaker digestion method is routinely used as the sample preparation technique for trace element determination of rock samples by inductively coupled plasma mass spectrometry, With this method, however, dissolution of Zr and Hf is not always guaranteed especially when the samples contain refractory minerals. In this study, glass bead digestion technique was compared with conventional open beaker digestion technique for the sample preparation of three USGS rock standards such as AGV-2, BHVO-2, and G-3. Thirty trace elements including rare earth elements were analysed by ICP-MS and ICP-AES. There were no clear differences in analytical results for the AGV-2 and BHVO-2 standards between the two techniques, but Zr, Hf, Y, and middle- to heavy- rare earth element concentrations of the G-3 standard prepared by open beaker digestion technique were significantly lower than the recommended values. This can be attributed to the presence of refractory mineral zircon. On the contrary, all the analytical results of the G-3 standard prepared by glass bead digestion technique were in good agreement with the recommended values, indicating complete dissolution of zircon. The analytical results show that the volatile elements such as Pb and Zn were not lost during the preparation of glass bead. Low dilution glass bead digestion technique described here will be very helpful to enhance precision and accuracy of trace element analysis for geological samples containing refractory minerals.

Development of a Flywheel Energy Storage System using Superconducting Magnetic Bearing (초전도 플라이휠 에너지 저장시스템 개발)

  • 정환명;연제욱;최재호;고창섭
    • The Transactions of the Korean Institute of Power Electronics
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    • v.4 no.5
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    • pp.433-441
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    • 1999
  • This paper presents a S-FES(Superconducting magnetic becuing Flywheel Energy Storage System) for the p purpose of replacing battery used to store the energy. Especially, the design elements of FES, such as the b beming, wheel mateηaI, and power converter, etc., are described. The design and manufacturing techniques of t the controllable IXlwer converter are proposed to generate the sinusoidal output current in the high speed operation and to get the const빠synchronous motor with halbach cuTay of high coesive I\d-Fe-B permanent magnet is used as the driver of F FES. The proposed S-FES system shows the stable rotation characteristics at high speed range about l 10,000[rpm]. To verify the validity of proposed system, the comparative study with the conventional ball b beming s~rstem is proceeded and it is well confirmed with the result of the lower friction losses of S-FES S system.

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Geochemical characteristics of Ogcheon granite in Ogcheon area (옥천화강암의 지구화학적 특성)

  • 윤현수;김대업;박석환
    • The Journal of the Petrological Society of Korea
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    • v.8 no.2
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    • pp.81-91
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    • 1999
  • The area of the study is located in Ogcheon district, middle part of Ogcheon Fold Belt. The area is covered by metasedimentary rocks of Ogcheon Supergroup at northern, eastern and southern part. Jurassic Ogcheon granite which intruded into Ogcheon Supergroup at central part, was intruded by Cretaceous quartz porphyry at western part. The granite consists of quartz, plagioclase, alkali feldspar, biotite, sphene, apatite, epidote, opaque and so on. It is generally characterized by grey to light grey, medium-grained, mafic enclave and partly weak foliation. In terms of geochmical compositions, the granite is felsic, peraluminous, subalkaline and calc-alkaline, and it was differentiated from single granitic magma. It shows parallel LREE enrichment and HREE depletion patterns with 0.84 Eu negative anomaly, which has REE variation trend and anomaly value similar to Jurassic granites in Korea. From charactristics of petrology, mineralogy and geochmistry, it may be interpreted that the Ogcheon granite body was derived from melting of I-type crustal material related to syn-collisional tectonic setting and emplaced more or less rapidly into the Ogcheon Supergroup.

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New and renewable Energy and Critical Raw Materials (신재생에너지와 Critical Raw Materials)

  • Kim, Yujeong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.155-155
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    • 2011
  • 신재생에너지 수요가 확대됨에 따라 신재생에너지 관련 제품에 소요되는 물질에 대한 관심이 확대되고 있다. 이들 물질은 공급리스크가 존재하는 희유금속이 주를 이루고 있다. 본 연구에서는 신재생에너지 등의 high tech 기술 확대로 인한 희유금속의 수요 및 공급을 전망하고 있는 미국의 critical raw material 관리 전략을 살펴보고자 한다. 미국은 2010년 12월 미국 에너지성(DOE : Department of Energy)에서 위기 물질 전략(Critical Materials Strategy)에 관한 리포트를 공표하였다. 클린 에너지 기술 4개 분야(영구자석, 선진 전지, 태양전지 박막, 형광 물질)에서 핵심이 되는 물질(희유금속 등)의 수급 불균형이 일어날 가능성에 대해 조사를 실시하여 리스크 평가하여 단기, 중단기로 구분하여 위기물질을 선정하였다. 클린 에너지 기술 4개 분야에서 핵심이 되는 물질(네오디움, 디스프로슘, 코발트, 리튬, 랜턴, 세륨, 테룰, 인듐, 갈륨, 유로피움, 테르비움, 이트륨)의 12광종 수급을 2025년까지 전망한 결과 전체적으로 단기(2010년~2015년)보다 중기(2015년~2025년)에 공급 부족이 확대한다고 예측되었다. 단기적으로는 인듐이 약간 부족하는 것 외에 디스프로슘과 이트륨에 관해서도 공급 부족할 것으로 예측되었다. 중기적으로는 코발트(전지 기술에 사용)와 유로피움(고효율 조명용의 형광 물질에 사용) 외 대상이 된 다른 모든 물질은 공급 부족이 발생할 것으로 전망되었다. 이를 종합하여 단기적으로는 디스프리슘, 유로피움, 인듐, 테르븀, 네오디움, 이트륨 등이, 중기적으로는 디스프리슘, 유로피움, 테르븀, 네오디움, 이트륨 등이 위기물질(Critical Material)로 분석되었다. 에너지성은 위기물질을 공급원다각화, 대체물질개발, 리유즈, 리사이클링 등을 국제적 파트너와 함께 추진하여 리스크를 관리할 것이며, 2011년까지 최신정보를 구축하여 위기물질 전략을 재설정할 예정이다. 체계적인 위기물질 선정 및 관리전략 등을 참조하고, 신재생에너지기술 변화에 따른 원재료의 중요성 및 리스크 관리현황을 기초로 우리나라에 적합한 위기관리 물질 선정 및 관리가 필요할 것이다.

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Comparison and Torque Analysis for Magnetic Gear with Parallel/Halbach Magnetized PMs according to Design Parameters (평행방향/할박 자화 영구자석을 갖는 마그네틱 기어의 설계변수에 따른 토크특성 해석 및 비교)

  • Hong, Sang-A;Choi, Jang-Young
    • Journal of the Korean Magnetics Society
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    • v.24 no.5
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    • pp.152-159
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    • 2014
  • Magnetic gear can transmit torque without any mechanical contact among rotational parts in rotating mechanical systems. Especially, magnetic gear using rare-earth PMs can be used in variety of industry application because of their great power efficiency. Thus, recent trend shows that magnetic gear can be replaced with common mechanical gear. This paper deals with comparison and torque analysis for magnetic gears with parallel and Halbach magnetization according to various design parameters. Using a two dimensional (2D) finite element (FE) analysis, suitable gear ratio is selected. We performed analysis for magnetically connected inner and outer torque with respect to various design parameters including thickness of inner and outer PM, steel pole angle, segments of Halbach array and magnetization pattern of inner and outer PMs. Finally, we can obtain improved design model having parallel and Halbach magnetization with larger torque, compared with an initial design model.

Magnetostriction of B2-structured FeX (X = Al, Si, Ni, Ga, Ge, and Sn) Alloys: A First-principles Study (B2 구조 FeX(X = Al, Si, Ni, Ga, Ge, Sn) 합금의 자기변형에 대한 제일원리계산)

  • Lee, Sunchul;Odkhuu, Dorj;Kwon, Oryong;Hong, Soon Cheol
    • Journal of the Korean Magnetics Society
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    • v.23 no.4
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    • pp.117-121
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    • 2013
  • In this study we investigated magnetism and magnetostriction of B2-structured FeX (X = Al, Si, Ni, Ga, Ge, and Sn) using a first-principles method, in order to survey the possibility of developing a transition metal based magnetostriction material. The Full-potential Linearized Augmented Plane Wave method was employed for solving the Kohn-Sham equation within the generalized gradient approximation for exchange-correlation interaction between electrons. FeX alloys are stabilized in ferromagnetic states except for the FeSi and FeGe alloys. Magnetostrcition coefficients of FeX (X = Al, Ni, Ga, and Sn) were calculated to be -5, +6, -84, -522ppm, respectively. It is noteworthy that the magnetostriction coefficient (-522ppm) of FeSn is larger than that (+400ppm) of Gafenol.

Application and Type of Magnetic Separator (자력선별장비의 유형과 활용)

  • Lee, Sang-hun;Yang, Injae;Choi, Seungjin;Park, Jayhyun
    • Resources Recycling
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    • v.27 no.6
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    • pp.11-22
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    • 2018
  • Magnetic separators has been used in the mining and the recycling fields in general, and is still applied in wide variety of fields. It is classified into the equipments for separating coarse ferrous scrap from non-ferrous materials and the equipments for concentrating fine ferromagnetic particles below 3mm. Magnetic separation equipments for concentrating fine materials also falls into two categories of low intensity and high intensity magnetic separators. The former is used for ferromagnetic materials but also paramagnetic materials of high magnetic susceptibility, and the latter for paramagnetic materials of lower magnetic susceptibility. Both low and high intensity magnetic separators could be utilized either dry and wet. Recently, the High gradient magnetic separators(HGMS) used in the range of less than 0.7 tesla has been gradually replaced by the magnetic separator made of rare earth permanent magnets commercialized in the 1980s. In addition, the expansion of nanotechnology in terms of synthetic magnetic materials in the environmental and biological fields is expected to contribute positively to the development of magnetic separation technology.