• 제목/요약/키워드: 희석 온도

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열유동 상분리막의 구조연구

  • ;;Douglass, K. Lolyd
    • Membrane Journal
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    • v.1 no.1
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    • pp.13-23
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    • 1991
  • 열유도 상분리법을 이용하여 제조되는 분리막의 구조 변화를 열역학 및 속도론적 관점에서 고찰하였다. Polypropylene과 희석제로서 n-alkanes, n-fatty acids, n,n-bis(2-hydroxyethyl) tallowamine을 model system으로 하였다. 고분자/희석제 system의 상변화의 종류에 따라 다양한 형태의 분리막구조가 얻어졌다. 분리막의 구조에 영향을 미치는 변수로서 고분자/희석제간의 interaction parameter, 희석제의 분자 크기, 용액의 조성, 냉각 조건, 희석제의 결정화 온도 등이며, 각 변수의 역할을 전자현미경을 사용하여 규명하였다. 열유동 상분리법에 의하여 제조된 분리막은 inter-spherulitic 및 intra-spherulitic pore의 이중 구조로 이루어짐을 확인하였다.

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닭 정액의 보존온도 및 희석배율이 수정률에 미치는 영향

  • 김학규;나재천;최철환;장병귀;상병돈;이상진
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2003.11a
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    • pp.107-108
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    • 2003
  • This study was conducted to investigate the effects of dilution rate and stored temperature of semen at 5, 25 and 35$^{\circ}C$ on fertility in liquid rooster semen. At 5$^{\circ}C$ cold temperature, no significant difference were found in sperm mobilities on dilution rate(1:1, 1:3, 1.6) among treatments. Sperm mobility for the conservation of 3 hours at 25∼35$^{\circ}C$ were significantly higher for 1:3 and 1:6 dilution rate(semen:diluent) groups than for 1:1 dilution rate group(P<0.05). In Fertility results after artificial insemination with the conservation of 3 hours at 5∼25$^{\circ}C$ temperature, no significant difference were found in fertility on dilution rate among treatments. Fertilities after artificial insemination with the conservation of 3 hours at 35$^{\circ}C$ were significantly higher for 1.3 and 1:6 dilution rate(semen:diluent) groups than for 1:1 dilution rate group(P<0.05).

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Effects of Reactive Diluents on the Curing Behavior of Epoxy Resin (에폭시 수지의 경화 거동에 미치는 반응성 희석제의 영향)

  • Kim, Wan-Young;Lee, Dai-Soo;Kim, Hyung-Soon;Kim, Jung-Gee
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.1030-1035
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    • 1994
  • Curing behavior and glass transition temperatures of epoxy resins into which reactive diluents were added to control processability were investigated. Heat of cure generated of the epoxy resin was reduced with butyl glycidyl ether(BGE) and phenyl glycidyl ether(PGE) contents. $T_g$ of the resin was decreased with the amount of reactive diluents and it was attributed to increased molecular weight between crosslink points. Cure kinetics of the resins was studied employing autocatalytic reaction model and found that reaction constants decreased as the contents of reactive diluent was increased.

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A Study on Efficiency of Boar Semen Extender KpA for Swine AI Aspects of Storage Temperature and pH Change (돼지 인공수정용 국산 희석액 KpA 의 효용성에 관한 연구 : 보존온도와 pH 변화 측면)

  • 정구민;김선의;신영수;김인철;이장희;임경순
    • Korean Journal of Animal Reproduction
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    • v.23 no.3
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    • pp.257-262
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    • 1999
  • This study was carried out to evaluate the effect of pH and storage temperature on the viability of boar sperm diluted with extender KpA for swine artificial insemination. The results obtained in this experiment were summarized as follows : 1. The viability of boar sperm diluted with KpA was higher than that with BTS during storage and especially more than 60% of sperm viability in KpA was maintained through 6 days. The pH values of all extenders were kept during storage of semens following dilution. 2. The sperm diluted with acidic (pH 6.3~6.8) or alkalic (pH 7.8~8.0) KpA and stored at 4$^{\circ}C$ or 37$^{\circ}C$ were more sensitive in viability than that with neutral pH (6.8~7.3) and at 17$^{\circ}C$ storage. But pH values of all conditions were not increased rapidly. Especially acidic and alkalic diluents were more stable in pH after dilution. Conclusively, extender pH and storage temperature was the important factors for sperm viability. The KpA setting up around neutral pH was the optimal boar semen extender for maintaining liquid semen at 17$^{\circ}C$.

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Study on the Preservation of Liquid Boar Semen with $\textrm{BF}_5$ and Butschwiler Diluents (희석액 $\textrm{BF}_5$ 엔오투와 Butschwiler를 이용한 돼지 액상정액 보존에 관한 연구)

  • 천용민;박창식;서길웅;이규승
    • Journal of Embryo Transfer
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    • v.11 no.2
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    • pp.159-166
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    • 1996
  • 본 연구는 돼지 액상정액을 인공수정용 100ml 플라스틱 병에 보존하면서 BF5희석액과 Butschwiler 희석액 간에 보존 온도별 차이를 조사하고, BF5 희석액에서의 글리세롤 농도의 효과를 조사하여 돼지 액상정액을 좀더 장기간 사용할 수 있는 방법을 찾고자 실시하였다. 돼지 액상정액을 5$^{\circ}C$ 냉장고에 보존하면서 조사한 바에 의하면, 37$^{\circ}C$에서 0.5 및 2시간 배양후의 정자운동성은 전체 보존기간동안 BF5 희석액이 Butschwiler 희석액보다 유의하게 (P<0.05) 높게 나타났고, 정상첨체비율은 두 희석액간에 차이가 없었다. 돼지 액상정액을 15$^{\circ}C$에 보존하면서 조사한 바에 의하면, 3일부터 7일 보존시 까지 정자운동성과 정상첨체비율에 있어서 Butschwiler 희석액이 BF5 희석액보다 유의하데 높게 나타났다. BF5 희석액을 이용한 돼지 액상정액의 글리세롤 농도의 효과에 있어서는 최종 글리세롤 농도가 0, 2, 3, 및 5% 보다 1%일 때 가장 높은 정자운동성과 정상첨체비율을 나타내었다. 분만율, 복당 생존자돈수 그리고 출생시 평균 생시체중은 BF5 희석애과 Butschwiler 희석액간에 차이가 없었다. 이상의 연구 결과를 종합해 볼 때 BF5 희석액을 5$^{\circ}C$에서 Butschwiler 희석액은 15$^{\circ}C$에서 6-7일 동안 돼지 액상정액을 보존할 수 있었다.

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Combustion Performance Test of Syngas Gas in a Model Gas Turbine Combustor - Part 2 : NOx/CO emission Characteristics, Temperature Characteristics and Flame Structures (모델 가스터빈 연소기에서 합성가스 연소성능시험 - Part 2 : NOx/CO 배출특성, 온도특성, 화염구조)

  • Lee, Min Chul;Yoon, Jisu;Joo, Seong Pil;Yoon, Youngbin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.8
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    • pp.639-648
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    • 2013
  • This paper describes on the NOx/CO emission characteristics, temperature characteristics and flame structures when firing coal derived synthetic gas especially for gases of Buggenum and Taean IGCC. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Nitrogen addition caused decrement in adiabatic flame temperature, thus resulting in the NOx reduction. At low heat input condition, nitrogen dilution raised the CO emission dramatically due to incomplete combustion. These NOx reduction and CO arising phenomena were observed at certain flame temperature of $1500^{\circ}C$ and $1250^{\circ}C$, respectively. As increasing nitrogen dilution, adiabatic flame temperature and combustor liner temperature were decreased and singular points were detected due to change in flame structure such as flame lifting. From the results, the effect of nitrogen dilution on the NOx/CO and flame structure was examined, and the test data will be utilized as a reference to achieve optimal operating condition of the Taean IGCC demonstration plant.

Experimental Investigations of the Characteristics of the Length Variation of Kerosene-Oxygen Laminar Diffusion Flames (등유-산소 층류 확산화염의 길이 변화 특성에 관한 실험적 연구)

  • Lee, Soo-Han;Lee, Jong won;Park, Seul Hyun
    • Fire Science and Engineering
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    • v.32 no.6
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    • pp.22-27
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    • 2018
  • The flame length in coaxial diffusion flame configurations was investigated when the kerosene fuel flow rate, temperature of the oxidizer stream, and inert gas concentrations in the oxidizer stream were varied. The diffusion flame was photographed using a Schlieren camera under each of the experimental conditions and the obtained images were then digitized to measure the flame length. The measured flame lengths were proportional to the kerosene fuel flow rate and increased with increasing temperature of the oxidizer stream. In addition, increases in the inert gas concentration in the oxidizer stream resulted in stretching of the flame. In particular, the flame was further elongated in the oxidizer steam diluted with helium gas. Inert substitutions in the oxidizer stream that can adjust the viscous drag are believed to be one of the important mechanisms that affect the length of the coaxial diffusion flames.

Performance Analysis of IGCC Gas Turbine Considering Turbine Operation Condition Change due to Modulation of Nitrogen Dilution (질소희석량 조절에 따른 터빈 운전조건 변화를 고려한 IGCC 용 가스터빈의 성능분석)

  • Kim, Chang Min;Kang, Do Won;Kim, Tong Seop
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.11
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    • pp.1023-1029
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    • 2013
  • The integration between a gas turbine and an air separation unit (ASU) is important in IGCC plants. The portion of ASU air extracted from the gas turbine and the degree of nitrogen supply from the ASU to the gas turbine side are important operating parameters. Their effect on the gas turbine performance and operability should be considered in a wide ambient temperature range. In this study, appropriate nitrogen dilution rate and turbine inlet temperature that satisfy the two limitations of turbine blade temperature and maximum allowable power output were predicted. The air integration was set at zero. The simulation showed that the power output increases and turbine blade temperature decreases as the nitrogen dilution increases. The maximum allowable power output can be obtained under medium and low ambient temperature ranges. Under a high ambient temperature range, the achievable power is less than the maximum power.

Effect of substrate temperature and hydrogen dilution on solid-phase crystallization of plasma-enhanced chemical vapor deposited amorphous silicon films (PECVD로 증착된 a-Si박막의 고상결정화에 있어서 기판 온도 및 수소희석의 효과)

  • 이정근
    • Journal of the Korean Vacuum Society
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    • v.7 no.1
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    • pp.29-34
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    • 1998
  • The solid-phase crystallization (SPC) of plasma-enhanced chemical vapor depsoited (PECVD) amorphous silicon (a-Si) films ha s been investigated by x-ray diffraction (XRD). The a-Si films were prepared on Si (100) wafers using $SiH_4$ gas and without $H_2$ dilution at the substrate temperatures between $120^{\circ}C$ and $380^{\circ}C$, and than annealed at $600^{\circ}C$ for crystallization. The annealed samples exhibited (111), (220), and (311) XRD peaks with preferential orientation of (111). The XRD peak intensities increased as the substrate temperature decreased, and the $H_2$dilution suppressed the solid-phase crystallization. The average grain size estimated by XRD analysis for the (111) texture has increased from about 10 nm to about 30 nm, as the substrate temperature decreased. The deposition rate also increased with the decreasing substrate temperature and the grain size was closely dependent on the deposition rate of the films. The grain size enhancement was attributed to an increase of the structural disorder of the Si network.

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A Basic Study on Physical Method for Preventing Recombination of Gas Product from the Decomposition of Ammonium Carbamate (암모니움 카바메이트 분해 시 생성된 가스의 재결합 방지를 위한 물리적 방법의 기초연구)

  • Chun, Minwoo;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.10
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    • pp.639-647
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    • 2017
  • This basic study is focused on the physically removal method of carbon dioxide from the decomposition of ammonium carbarmate to prevent the recombination of ammonium salts. A basic visual experimental set-up was designed and constructed to observe the recombination phenomena from the proper composition of ammonia gas, carbon dioxide gas, and compressed air dilution gas. To quantify the recombination phenomena, a simple device was designed to measure the weight change under severe cases for three different tube sizes. The temperature and pressure in the visual tube and the volumetric flow rates of the nitrogen dilution gas were studied and the conditions to avoid recombination were analyzed according to mean free path theory. Diffusivity values based on the Chapman-Enskog theory were calculated from the experimental data. These value may serve as an index for the prevention of recombination.