• Title/Summary/Keyword: 흑연소재

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Zr based metallic glass thin films for corrosion protection of the metallic bipolar plate in PEM fuel cell (금속계 연료전지 분리판의 내식특성 향상을 위한 Zr기 비정질 박막 합성기술)

  • Seon, Ju-Hyeon;Mun, Gyeong-Il;Sin, Seung-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.19-20
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    • 2014
  • 연료전지 스택을 구성하는 핵심 부품 중 하나인 분리판(Bipolar plate)은 반응 연료인 수소와 산소를 분리하여 셀(cell)의 전면적에 균일하게 분배, 공급, 배기 및 전기화학반응에 의해 생성된 전류를 수집하며, 높은 가스밀폐성, 전기전도성 및 내식성이 요구된다. 분리판 소재로는 흑연, 고분자-탄소 복합체 및 금속 등이 사용되고 있으며, 이중 연료전지 스택의 부피, 무게 및 제조비용 감소를 위하여 금속분리판이 주목받고 있다. 그러나 금속분리판의 경우 연료전지 작동환경에서 부식반응에 의한 이온 용출로 인해 전극촉매나 고분자전해질막의 오염을 유발할 수 있다는 단점이 있어 최근 금속계 분리판의 코팅을 통하여 분리판의 내식특성 및 전기적 특성을 향상시키는 연구가 활발히 진행되고 있다.

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A Study on the Thermal Response Characteristics of Carbon/Carbon Composites for Nozzle Throat Insert (노즐목 적용 탄소/탄소 복합재료의 열반응 특성 연구)

  • Ham Hee-Cheol
    • Journal of the Korean Society of Propulsion Engineers
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    • v.10 no.1
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    • pp.30-37
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    • 2006
  • A thermal resistance estimation of carbon/carbon composites used as the nozzle throat insert of solid rocket motor was performed using TPEM motor. Three types of TPEM motor and two types of propellant were employed. The ablation rate is higher for the higher chamber pressure and also higher for the higher concentration of oxidizing species in combustion gas, but it is lower for the higher material density.

Crystal growth of ring-shaped SiC polycrystal via physical vapor transport method (PVT 방법에 의한 링 모양의 SiC 다결정 성장)

  • Park, Jin-Yong;Kim, Jeong-Hui;Kim, Woo-Yeon;Park, Mi-Seon;Jang, Yeon-Suk;Jung, Eun-Jin;Kang, Jin-Ki;Lee, Won-Jae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.5
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    • pp.163-167
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    • 2020
  • Ring-shaped SiC (Silicon carbide) polycrystals used as an inner material in semiconductor etching equipment was manufactured using the PVT (Physical Vapor Transport) method. A graphite cylinder structure was placed inside the graphite crucible to grow a ring-shaped SiC polycrystal by the PVT method. The crystal polytype of grown crystal were analyzed using a Raman and an UVF (Ultra Violet Fluorescence) analysis. And the microstructure and components of SiC crystal were identified by a SEM (Scanning Electron Microscope) and EDS (Energy Disruptive Spectroscopy) analyses. The grain size and growth rate of SiC polycrystals fabricated by this method was varied with temperature variation in the initial stage of growth process.

Study of Lithium Ion Capacitors Using Carbonaceous Electrode Utilized for Anode in Lithium Ion Batteries (이차전지 음극용 탄소 전극을 이용한 리튬이온 커패시터 연구)

  • Oh, Rye-Gyeong;Hong, Jung-Eui;Yang, Won-Geun;Ryu, Kwang-Sun
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.489-493
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    • 2013
  • The most common carbonaceous anode materials of lithium ion batteries (natural graphite, artificial graphite, hard carbon, and mesocarbon microbeads) were utilized as an electrode in lithium ion capacitors. It could be able to enhance the energy density of capacitors due to the intercalation of lithium ion. In this work, the properties of capacitors using the symmetric electrode were measured by organizing coin cell typed capacitors. Also, we made other capacitors having pre-intercalated lithium ions at one side of the electrode. The results of electrochemical measurements for these capacitors show that the storage capacitance was appeared. In other words, if the migration of lithium ions is supplied continuously in the electrolytes, lithium ions can be diffused into the carbonaceous materials. And it results in the improvement of capacitance compared to only using symmetric carbonaceous electrodes. Also, we conducted the same measurement with graphene oxide having a the large specific area in the same condition. Herein, we recognized that the large specific area is extremely important for supercapacitors.

Convergent Study of Personalized Modeling and 5-Axis Machining Technology Using Patellofemoral Bone DICOM Image (넙다리무릎뼈 의료용 디지털 영상 및 통신 표준 영상을 이용한 맞춤형 모델링과 5축 가공기술의 융합적 연구)

  • Yoon, Jae-Ho;Kim, Hyeong-Gyun
    • Journal of the Korea Convergence Society
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    • v.9 no.11
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    • pp.137-143
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    • 2018
  • DICOM images of patellofemoral bones were converted into a stereolithography file, and a Unigraphics CAD program was used to create a CAD modeling in which there exists point, line and facet information. The modeling extraction of joint facets was performed by linking two adjacent points into lines in the stereolithography file by using the Unigraphics rapid spacing function and then linking the lines into facets to complete the entire modeling. This modeling extraction was performed based on the anatomical knowledge of joint facet directions. As a result, a personalized space modeling and solid modeling were produced for the joint facets of patellofemoral bones. This was followed by a CAM control computing operation of solid modeling on graphite materials and 5-axis machining of patellofemoral bones. That is the description of a method for a personalized implant modeling by using DICOM images of patellofemoral bones.

A Study of Wear Behavior for Sealing Graphite at Elevated Temperature (씰링 그라파이트의 고온 마모 거동에 관한 연구)

  • Kim, Yeonwook;Kim, Jaehoon;Yang, Hoyoung;Park, Sunghan;Lee, Hwankyu;Kim, Bumkeun;Lee, Seungbum;Kwak, Jaesu
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.5
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    • pp.113-120
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    • 2013
  • Graphite is commonly used as a solid lubricant leading to low friction coefficient and abrasion. In this study, wear behavior of sealing graphite(HK-6) at elevated temperature was evaluated. Reciprocating wear test was carried out as wear occurred graphite as a seal(HK-6) is positioned between the liner and driving shaft. Variables which are temperature, sliding speed and contact load are set. This study suggest optimized environment conditions through the wear properties of graphite.

A Study on the Electrical and Physical Properties of Cement Mortar used Carbon Material Industrial by-product (탄소소재 산업부산물을 사용한 시멘트 모르타르의 전기·물리적 특성 연구)

  • Jo, Jeong-Hoon;Kim, Nam-Il;Lee, Young-Jun;Seo, Sung-Kwan;Chu, Yong-Sik
    • Resources Recycling
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    • v.30 no.6
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    • pp.19-27
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    • 2021
  • Electrically conductive mortar used in industrial carbon material byproducts was manufactured and analyzed in this study. The contents of the carbon material and mixed water were controlled, and the distance between electrodes was set to 0.42 m and 0.88 m. The carbon material was graphite with a layered structure. The carbon material was used as fine powder and aggregate substitutes according to particle size. The average particle sizes of each materials were 18.4㎛ and 546.1 ㎛ and the electrical conductivities were 62.3 S/m and 32.5 S/m, respectively. To maintain similar mortar flow in each sample, the water content was increased with increasing carbon material, and accordingly, the porosity showed an increasing trend. When electrode distance of the mortar (week 6) was 0.42 m, the voltage-current values were 342 V-1.48 A (S20) and 349 V-1.44 A (S30). For electrode distance of 0.88 m, these values were 513 V-0.98 A (S20) and 500 V-1.01 A (S30). The exothermic properties improved with increasing carbon material content and decreasing electrode distance.

Electricity Generation and Microbial Community variation in Microbial Fuel Cell with various Electrode Combinations. (다양한 탄소전극조합에 따른 미생물 연료전지의 전기발생량 및 미생물 군집변화)

  • Kwon, Jae-Hyeong;Choi, Soo-Jung;Cha, Jae-Hwan;Kim, Hyo-Soo;Kim, Ye-Jin;Yu, Jae-Cheul;Kim, Chan-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.1
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    • pp.87-96
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    • 2010
  • The electrode material is one of the factors affecting the power production of microbial fuel cell. In this study, effects of carbon electrode material, thickness and configuration on the power density, biofilm formation and microbial community diversity of microbial fuel cell were investigated. To optimize the anode-cathode electrode assembly, seven lab-scale reactors which had various carbon electrode constructions were operated in continuous mode. Under the steady state condition, the electrode combination of graphite felt (6 mm) with hole showed the highest cell voltage of 238 mV and the coulombic efficiency of 37%. As a result of SEM analysis, the bacteria growing on surface of knitted type of carbon cloth and graphite felt electrode ncreased significantly. The change of dominant species between seeding sludge and biofilm on the surface of anode electrode, microbial analysis with PCR-DGGE showed that the dominant species of seeding sludge are quite different from those of biofilm on the surface of each anode electrode. Especially Geobacter sp., a well known electrochemical bacteria, was found as the dominant species of the electrode combination with graphite felt.

Investigation of Regraphitization during Cam Shaft Remelting (캠 샤프트 재용융 처리시 재흑연화 현상에 관한 연구)

  • Oh, Young-Kun;Kim, Gwang-Soo;Koh, Jin-Hyun
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.648-652
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    • 1998
  • TIG remelting was performed to harden the surface of automobile earn shaft. Multipass remelting was conducted in longitudinal direction under argon gas atmosphere. The microstructure of as-east earn shaft was gray iron which consisted of flake graphite and pearlitic matrix. The remelted area had microstructue of both fine pearlite and ledeburite structure that consisted of globular austenite and $Fe_3C$. Hardness for as-cast earn shaft had HRc 25~28, however it increased at remelted area to HRc 53~55. Black line was found at heat affected zone next to the fusion line, that is remelt area of previous pass, during multipass remelting. Black line was identified as graphite, which was transformed from $Fe_3C$. in the ledeburite structure. It is observed that all graphites were nucleated at $Fe_3C$. and matrix interface. High density energy laser remelting process was also applied to verify whether black line could be eliminated. However, black line was still existed as observed in TIG remelting process. Regraphitization was simulated on the ledeburitic structure specimen using Gleeble 1500 with conditions of 1100 and 100$0^{\circ}C$ for 0.5, I, 3, 5 and 1Osee. From the fact that graphite was formed even at the simulation condition of 100$0^{\circ}C$ for 0.5sec, it is seen that regraphitization is an inevitable phenomenon generated whatever processes used during multipass overlap remelting.

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Vanadium-doped semi-insulating SiC single crystal growth by using porous graphite (다공성 흑연 소재를 이용한 바나듐 도핑된 반절연 SiC 단결정 성장의 특성 연구)

  • Lee, Dong-Hun;Kim, Hwang-Ju;Kim, Young-Gon;Choi, Su-Hun;Park, Mi-Seon;Jang, Yeon-Suk;Lee, Won-Jae;Jung, Kwang-Hee;Kim, Tae-Hee;Choi, Yi-Sik
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.6
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    • pp.215-219
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    • 2016
  • Vanadium-doped SiC crystals have been grown by using a porous graphite inner crucible filled with vanadium carbide (VC) and by using a porous graphite plate and SiC + VC powders, respectively. Semi-insulating SiC crystals were grown onto the 6H-SiC seed crystals by PVT (Physical Vapor Transport) method. The grown crystals were indicated to be 6H-SiC polytype by XRD. As result of SIMS analysis, vanadium-rich precipitates were observed when the vanadium concentration was relatively higher than the maximum solubility of vanadium ($3-5{\times}10^{17}cm^{-3}$) in vanadium-doped SiC crystals, which resulted in degradation of crystal quality.