• Title/Summary/Keyword: 황 회수

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Proposal of New Correction Factors for New and Renewable Energy Sources in Public Building (공공건축물에 적용되는 신·재생에너지원의 새로운 보정계수 제안)

  • Kim, Yun-Ho;Park, Yun-Ha;Won, An-Na;Hwang, Jung-Ha
    • Journal of the Korean Solar Energy Society
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    • v.36 no.6
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    • pp.13-24
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    • 2016
  • The government introduced a mandatory installation system of new & renewable energy for public building to meet the target of greenhouse gas reduction and also suggest a correction factor for new renewable energy to expand the installation of various new & renewable energy systems. The introduction of correction factors, however, was followed by the reduction of installation size of new & renewable energy sources. Assuming that it was caused by a correction factor for each new renewable energy source calculated by the initial costs, this study proposed a new correction factor approach based on payback periods to reflect the technology element in the calculation process of correction factors additionally. The application results of new correction factors show that it was possible to do complex calculations including the economic and technological aspects to select a new & renewable energy system and that the installation size was also enlarged.

Application of Pervaporation Membrane Process in Petrochemical Industry (석유화학공업에서의 투과증발막의 응용)

  • Nam, Sang-Yong
    • Membrane Journal
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    • v.17 no.1
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    • pp.1-13
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    • 2007
  • Pervaporation process using membrane is newly emerging energy saying and cost effect process instead of distillation process. Especially, in pertrochemical industry, pervaporation process is a strong candidate to substitute the conventional energy consuming processes because that petrochemical industry has much energy consuming separation processes, many azeotrope mixtures to separate and needs to compact space to install new process units. Aromatic/aliphatic separation including benzene/cyclohexane mixture, olefin/paraffin separation, xylene isomer separation, reactive monomer recovery and sulfur compound removal from gasoline have been inversitigated for the application of pervaporation membrane process by many researchers and are under commercializing.

A Study on Spectroscopic Analysis by using Raman Spectrometer of Multi-Guest Mixed Hydrates Containing $SF_6$ (Raman Spectroscopy를 이용한 $SF_6$ 혼합 하이드레이트의 분광학적 해석에 관한 연구)

  • Shin, H.J.;Moon, D.H.;Kim, M.C.;Kim, Y.S.;Seo, Y.W.;Lee, G.W.
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.223-225
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    • 2008
  • 하이드레이트는 저온.고압에서 저분자량의 게스트(guest)가 호스트(host)인 물분자 속에 포획되어 만들어지는데 일련의 과정은 물리적 반응을 통해 생성된다.본 연구에서는$CO_2$보다 지구온난화지수(Global Warming Potential)가 23,900배 높은 $SF_6$의 회수 및 정제기술로써 하이드레이트화를 이용하는 신기술 개발의 일환으로 분광학적 접근을 통해 $SF_6$ 혼합 하이드레이트의 정성 및 정량분석을 수행하였다. Raman Shift 분석 결과 $SF_6$$770cm^{-1}$에서 $v_1$ 진동주파수를 확인함으로써 하이드레이트 내 $SF_6$가 안정적으로 포집됨을 확인하였고 혼합가스 내 $SF_6$ 농도별로 만들어진 샘플의 Raman Shift를 통해서 $SF_6$의 하이드레이트 전환율을 가늠할 수 있었다.

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Application of An Energy-Efficient Distillation System using Three Columns to Hexane Process (3기의 증류탑을 이용한 에너지 절약형 증류탑의 헥산공정에의 응용)

  • Kim, Young-Han;Hwang, Kyu-Suk
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.39-46
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    • 2005
  • Though a fully thermally coupled distillation column-an energy efficient distillation system-consumes less energy, it is not widely implemented in practice due to its operational difficulty. A 3-column distillation system having improved operability is proposed here, and its energy saving performance and application related issues are investigated from the implementation result to a practical hexane process. When an energy integration is employed, the proposed system requires 18% less energy than a conventional 2-column system, which is found from the HYSYS simulation. Though more control loops than the 2-column system are required, the proposed system has better controllability of product compositions and the pressure control of the system is easier.

Effects of Coagulant Concentration and Phytic Acid Addition on the Contents of Ca and P and Rheological Property of Soybean Curd (응고제 양 및 Phytic acid 첨가가 두부의 칼슘, 인 함량과 물성에 미치는 효과)

  • Park, Chan-Kyeong;Hwang, In-Kyeong
    • Korean Journal of Food Science and Technology
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    • v.26 no.4
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    • pp.355-358
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    • 1994
  • The effect of concentration of coagulant and addition of phytic acid on physico-chemical properties of soybean curd was investigated. The results showed that the maximum protein yield in soybean curds was obtained with 0.029N Ca and the bound calcium per protein molecule significantly increased as the level of calcium increased. The highest precipitation of phytic acid occured at 0.029N Ca. When phytic acid was added to soybean milk during soybean curd preparation, the weight of soybean curd increased. The hardness of soybean curd was remarkably reduced by the increase of phytic acid level.

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Study of Research and Development for Seasoning Oil as Red Pepper Seed Oil Substituted: Manufacturing of oil soluble natural black pigment from Gardenia and Kaoliang (고추씨 기름 대체 향미유 개발에 관한 연구: 치자, 고량을 이용한 유용성 천연 검정색소의 제조)

  • 구본순;김덕숙
    • Food Science and Preservation
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    • v.11 no.1
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    • pp.42-46
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    • 2004
  • Each pigments were obtained by ethyl alcohol extraction method, blue and yellow pigment from Gardenia as well as dark brown pigment from Kaoliang. Concentration of these pigments are all 60 Brix, the extraction yields were 0.68, 1.97, 0.63 %(w/w), respectively. Oil soluble natural black pigment (OSNBP) was composed of soybean oil, water, emulsifier, Gardenia blue and yellow, Kaoliang dark brown etc. Blending ratio of these was 8: 22: 42: 10: 15: 13 (w/w), this mixture was carried out homogenized. Solubility of this OSNBP in soybean oil was appeared the maximum level at about 30∼40$^{\circ}C$ range. OSNBP solubilized black oil was not reseparated at below 20$^{\circ}C$.

Characteristics of Microwave Leaching for the Removal of Bi, As from the Sulfide Mineral Concentrate (황화광물정광으로부터 Bi, As 제거를 위한 마이크로웨이브 용출 특성)

  • On, Hyun-Sung;Togtokhmaa, B.;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.3
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    • pp.137-147
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    • 2018
  • The aim of this study was to leach penalty elements, such as Bi and As, effectively through microwave leaching of a gold concentrate sample containing penalty elements with nitric acid solution. For this purpose, the time effect of microwave leaching, nitric acid concentration effect, and sample addition effect in a microwave were examined. The experiment, demonstrated that the leaching rate of penalty elements increased as microwave leaching time and nitric acid concentration increased and concentration addition decreased. When a microwave heating experiment was carried out on the concentrate and ore minerals, Bi was removed by as much as 90%, and the phase of arsenopyrite was transformed in the order of arsenopyrite (FeAsS), pyrrhotite (FeS), and hematite ($Fe_2O_3$). When the X-ray diffraction (XRD) analysis was carried out with solid residue, elemental sulfur and anglesite were identified. The intensity of the XRD peaks of elemental sulfur and anglesite increased, and the peaks were sharper when the microwave leaching time was 12 min instead of 1 min, the nitric acid concentration was 4 M in rather than 0.5 M, and the concentration addition was 30 g rather than 5 g. This was probably because more elemental sulfur and anglesite were generated in the leaching solution as the leaching efficiency increased. Bi can be leached as valuable elements in the leaching solution through microwave leaching processes while they are released to the environment through a microwave heating processes.

Separation of $SF_6$ from $SF_6/N_2$ Mixtures Using Polymeric Membranes (고분자 분리막을 이용하여 $SF_6/N_2$ 혼합 기체에서 $SF_6$ 분리)

  • Ko, Young-deok;Lee, Hyung-Keun;Hong, Seong-Uk
    • Membrane Journal
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    • v.22 no.1
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    • pp.72-76
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    • 2012
  • $SF_6$ has an extremely high global worming potential (GWP). Therefore, there has been an effort to reduce the use of $SF_6$ and its emission into atmosphere. One possible solution for minimizing the use of $SF_6$ in electrical equipments is utilization of gas mixtures such as $SF_6/N_2$. The $SF_6$ concentration in the gas mixture varies from 10 to 60%. However, when the apparatus is repaired or dismantled, we have to recover $SF_6$ from the gas mixture. Since the boiling point of $SF_6$is low (${\sim}-60^{\circ}C$), the liquefaction method is difficult to apply. One possible alternative is the membrane separation technology. In this study, we investigated the $SF_6$ and $N_2$ permeation properties of 5 polymeric membranes. For example, permeability of $N_2$ in BOPP membrane at $25^{\circ}C$was 0.19 barrer, whereas that of $SF_6$ was only 0.0012 barrer, resulting in the selectivity of 158. An upper bound for $SF_6/N_2$ gas pair was suggested for the first time with n = -1.33 and k = 160 (barrer).

Application of Macroporous Diatomaceous Earth Column for Residue Analysis of Insecticide Endosulfan in Herbal Medicines (한약재 중 살충제 Endosulfan의 잔류분석을 위한 Macroporous Diatomaceous Earth 컬럼 적용)

  • Hwang, Jeong-In;Jeon, Young-Hwan;Kim, Hyo-Young;Kim, Ji-Hwan;Lee, Yoon-Jeong;Park, Ju-Young;Kim, Do-Hoon;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.30 no.1
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    • pp.60-67
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    • 2011
  • BACKGROUND: Because dried herbal medicines have many active ingredients, it is not easy to determine the residue amount after extraction, partition and clean up of pesticides from them. Especially, liquid-liquid partition method is consuming many times and solvents. Macroporous diatomaceous earth(MDE) column was used to replace the separatory funnel for liquid-liquid extraction with dichloromethane to analyze the endosulfan and its metabolite. METHODS AND RESULTS: The residue analysis method using MDE column instead of liquid-liquid partition for determining insecticide endosulfan and its metabolite in 4 dried herbal medicines was developed by GC/MS. As a result, the recovery rates of the pesticides in 4 herbal medicines were ranged from 80.3 to 93.5% for ${\alpha}$-endosulfan, from 81.0 to 100.3% for ${\beta}$-endosulfan and from 80.6 to 95.6% for endosulfan sulfate, respectively. The coefficients of variation for triplicate were ranged from 1.1 to 3.4%. CONCLUSION: The improved methods are more ecofriendly, safer, faster and less laborious than conventional method by KFDA.

Adsorption/Desorption Characteristics of Vanadium from Ammonium Metavanadate using Anion Exchange Resin (음(陰)이온교환수지(交換樹脂)를 이용한 Ammonium Metavanadate로부터 바나듐 흡탈착(吸脫着) 특성(特性))

  • Jeon, Jong Hyuk;Kim, Young Hun;Hwang, In Sung;Lee, Jin Young;Kim, Joon Soo;Han, Choon
    • Resources Recycling
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    • v.22 no.1
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    • pp.55-63
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    • 2013
  • Considering considerable contents of vanadium and tungsten in spent SCR DeNOx catalysts, separation and recovery of those metals are required. In this respect, commercial anion exchange resin (MP600) was employed to recover vanadium from the synthetic solution of ammonium metavanadate. Experimental results indicated that vanadium exist as anion under the acidic condition (pH 2 ~ 6) and adsorbed on the resin. Although the adsorption rate was increased with temperature, the maximum amount of adsorption was not affected by temperature. Desorption took place under either strong acidic (less than pH 1) or strong caustic (higher than pH 13) condition. However, desorption seldom took place under moderate conditions (pH 3~11). Furthermore, adsorption equilibrium results agreed well with Freundlich isotherm and pseudo-second-order reactions. And, adsorption energy was evaluated using Dubinin-Radushkevich and Temkin isotherm.