• Journal of the Korea Institute of Building Construction
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• v.9 no.1
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• pp.81-87
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• 2009

The purpose of this study is to investigate the sulfate attack resistance of concrete using the EAF(electric arc furnace) Slag as fine aggregate. In order to figure out the effects of magnesium sulfate solution on the durability of concrete using the EAF Slag as fine aggregate, the experiments for the immerging test in the 10% magnesium sulfate solution was executed by selecting factors such as aging processes, replacement ratio(0, 10, 20, 30, 50%), and duration of immerging. The specimens were made with various EAF slag replacements for fine aggregates and with W/C ratio fixed 0.45. compressive strength and S.D.F(Sulfate Deterioration Factor), weight change, and SEM(Scanning Electron Microscope) were tested. From the test results, EAF slag aggregate treated with accelerated aging is better than treated with air aging. The compressive strength and resistance to the sulfate attack is slightly improved with an increase in the EAF slag aggregate treated with accelerated aging replacement for aggregate.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.122-123
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• 2016

Sulfate anion which cause concrete degradation is affected on marine structures. There are two of control method concrete degradation which is arisen by sulfate anion. Cementitious materials prevent permeation of sulfate anion and water-binder ratio increase to improve watertightness. But, those methods are passive. So, this study is developing new materials which prevent actively concrete degradation on sulfate anion.

• Journal of the Korea Institute of Building Construction
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• v.22 no.6
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• pp.663-672
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• 2022

The purpose of this study is to evaluate the magnesium sulfate resistance of a geopolymer mixed with rice husk powder. General concrete, silica fume mixed concrete, and binary blended geopolymer were selected as comparison targets to confirm the magnesium sulfate resistance, and sulfate deterioration was calculated using the compressive strengths with ages. In addition, the weight change rate and the relative dynamic coefficient of the geopolymer were comparatively analyzed, and the degree of etteringite formation was confirmed using X-ray diffraction analysis. the experiment, the geopolymer mixed with 10% rice husk powder showed 10.8% higher compressive strength than concrete with silica fume when submerged for 56 days. Also, the geopolymer mixed with rice husk powder showed a small weight change rate of 0.9 to 1.45%. composition after immersion in magnesium sulfate through X-ray diffraction analysis, it was observed that a small amount of ettringite was dispersed in the geopolymer containing rice husk powder. Thus, there is a high correlation with the corrosion resistance of magnesium sulfate

• The Science & Technology
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• v.35 no.4 s.395
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• pp.28-29
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• 2002

한양대 토목공학과 문한영교수는 건설재료 중에서 가장 많이 사용되는 콘크리트 재료를 재료공학적 측면에서 연구를 계속하고 있는 과학자이다. 문교수는 지난해 '시멘트 경화체의 황산염 침식 저항성 평가'라는 제목의 논문을 발표하여 과학기술 우수논문상을 받기도 했다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.2
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• pp.94-101
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• 2016

This paper presents an investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(0, 30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0) and initial curing temperatures($23^{\circ}C$ and $70^{\circ}C$). The tests involved immersions for a period of 6 months into 10% solutions of sodium sulfate and magnesium sulfate. The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, as higher GGBFS replace ratio or Ms shown higher compressive strengths on 28 days. In case of immersed in 10% sodium sulfate solution, the samples shows increase in long-term strength. However, for samples immersed in magnesium sulfate solutions, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$); the gypsum increased up to 6 months continuously.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.221-224
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• 2006

This paper reports a study carried out to investigate sulfate attack caused by cation type(sodium, magnesium) accompanying $SO_4^{2-}$ ions in sulfate solutions. The sulfate attack of mortar specimens was evaluate using the visual appearance, compressive strength loss and expansion. In addition, at the end of 360 days, the products of sulfate attack and the mechanism of attack were investigated through x-ray diffraction.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.112.1-112.1
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• 2011

쌀을 주식으로 하는 우리나라의 여건상 연간 추정치로 싸라기 약 12만톤, 미강 약 49만톤, 왕겨 약 79만톤의 벼 도정 부산물이 발생하고 있다. 본 연구에서는 벼 도정 부산물 중 비식량 자원인 왕겨를 대상으로 고효율 효소 당화를 위한 바이오매스 전처리 방법을 탐색하였다. 왕겨 원시료의 초기 조성은 셀룰로스 34.5%, 헤미셀룰로스 20.5%, 리그닌 25.3%, 회분 14.6%로 나타났는데, 억새 등 초본계 바이오매스와 비교하여 특이하게 높은 성분은 회분으로 이는 벼에 대한 규산질 비료의 시용에서 기인한 것이다. 바이오매스 전처리에 많이 사용되는 암모니아, 희황산 용매와 규산염에 침식성을 가지는 가성소다 용매를 이용하여 각 용매별 단독 및 알칼리-산 복합 처리 하였을 때 효소 가수분해 효율, 고상시료 성분변화 등을 상호 비교하였다. 예비실험을 통하여 암모니아 처리조건은 15%(w/w) $150^{\circ}C$ 20분, 가성소다 처리조건은 1.5%(w/w) $150^{\circ}C$ 20분, 희황산 처리조건은 1.0%(w/w) $150^{\circ}C$ 10분으로 설정하였다. 암모니아 단독, 희황산 단독, 암모니아-희황산 복합 처리 시료의 효소 가수분해 효율은 각각 37.8%, 39.1%, 42.8%로 약 40%선에서 큰 차이가 없었다. 반면 가성소다 단독, 가성소다-희황산 복합 처리시료의 효소 가수분해 효율은 각각 62.7%, 82.8%로 나타나 앞선 3가지 처리방법 대비 50%, 100%에 가까운 효소 가수분해 효율 향상을 보였다. 이 때 전처리 고상시료의 성분 변화를 살펴보면 회분 함량에서 큰 차이를 보였는데 암모니아 단독, 가성소다 단독, 희황산 단독, 암모니아-희황산 복합, 가성소다-희황산 복합 처리에서 각각 47.8%, 77.1%, 43.5%, 55.8%, 94.7%의 회분 성분 기각률(rejection rate)을 나타냈다. 이는 왕겨 효소 가수분해 효율의 최대 저해요인이 회분임을 추정할 수 있다. 왕겨 전처리 알칼리 용매는 암모니아보다 가성소다가 더 효과적이었고 희황산 복합 처리시 그 효과가 크게 상승하였다. 따라서 규산염(회분) 함량이 높은 바이오매스는 고온 고압 조건에서 가성소다 용액으로 처리한 후 그 고상분을 희황산 용액으로 복합 처리하는 시스템이 효소 당화 증진에 매우 유리함을 확인하였다.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.217-220
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• 2006

This paper describes a study undertaken to determine the effect of ground calcium carbonate(GCC) cement mortar with respect to sulfate attack. It were investigated visual appearance and expansion of cement mortars with GCC immersed in artificial solution of 5% sodium sulfate during 510days. According to increasing replacement of GCC, the expansion ratio was comparatively superior to GCC0 mortar specimen. The test results indicated that cement mortars with GCC was benefit the resistance of sulfate attack due to micro filler effect.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.527-530
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• 2005

Shotcrete have become a deterioration which is used in the underground such as groundwater and soil in sulfate ion. Sulfate attack on concrete structures in service is not widespread, and the amount of laboratory-based research seems. to be disproportionately large. In this study, immersion test using $Na_2SO_4$ solution($1,2,5\%$) was performed to evalute the resistance of shotcrete. From the results of the immersion test for 112 days of exposure. In order to understand the deterioration mechanism due to seawater attack, test using scanning electron microscopy(SEM) analysis and X-ray diffraction showed that the deterioration mechanism due to sulfate attack in shotcrete.

• Journal of the Korea Concrete Institute
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• v.12 no.5
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• pp.141-151
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• 2000

Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.