• Title/Summary/Keyword: 활성 산소종

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Nanostructure Control of PtNiN/C Catalysts for Oxygen Reduction Reaction by Regulating Displacement Rate of Precursor (전구체 치환 속도 조절을 통한 산소환원반응용 PtNiN/C 촉매의 나노구조 제어)

  • Dong-gun Kim;Seongseop Kim;Sung Jong Yoo;Pil Kim
    • Clean Technology
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    • v.30 no.1
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    • pp.55-61
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    • 2024
  • Efforts are actively underway to address the issues related to the high cost of Pt-based catalysts for oxygen reduction reactions by designing high-performance Pt-based alloys through the control of their nanostructures. In this study, a method was proposed to control the nanostructure of Pt-based alloys, either hollow or core-shell, by adjusting the pH of the solution during the galvanic replacement reaction between the carbon-supported nickel-nickel nitride composite and the Pt ions. The physical characteristics, including the state, quantity, and morphology of the metal particles under different preparation conditions, were evaluated through X-ray diffraction, transmission electron microscopy, and inductively coupled plasma. When the prepared catalysts were employed for the oxygen reduction reaction, they exhibited an improvement in area specific-activity compared to a commercial Pt/C, with a 1.7 and 1.9-fold enhancement for the hollow and core-shell structured catalysts, respectively.

Effect of Plants Extracts on Lipid Peroxidation of Rat Brain Tissue Induced by Reactive Oxygen Species (활성산소에 의해 유도된 흰쥐 뇌조직의 지질산화에 대한 식물체 추출물의 효과)

  • Kim, Seok-Joong;Han, Dae-Seok
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.976-982
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    • 2005
  • Abilities of various edible plants and natural antioxidants to protect brain against oxidative damages were evaluated using brain homogenate of perfused Sprague-Dawley rat. Oxidative damage, expressed as lipid peroxidation (LPO), indicating total quantity of malondialdehyde and 4-hydroxyalkenal, increased from 4.1 to 6.9nmol/mg protein by treatment of $2.5{\mu}M$ ferrous sulfate and 7.5mM hydrogen peroxide as source of reactive oxygen species (ROS) on brain homogenate for 10min at $37^{\circ}C$ Mallow(88%) in leafy vegetables, small potato (93%) in root vegetables, green red pepper (76%) in fruit vegetables, and avocado (96%) in fruits showed highest LPO inhibition capacities. Ability of mushrooms decreased in order of nameko, shiitake, pine mushroom, oyster mushroom, and new type pine mushroom. Among natural antioxidants tested, (+)catechin (91%), (-)epigallocatechin gallate (85%), (-)epicatechin gallate (83%), and kaempferol(83%) showed high LPO inhibition capacities.

신품종소개 - 항산화 성분이 풍부한 건강기능성 메수수 '동안메'

  • Kim, Jeo-In
    • 농업기술회보
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    • v.50 no.2
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    • pp.39-39
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    • 2013
  • 수수는 폴리페놀, 플라보노이드 등 다양한 기능성 성분이 많이 함유하고 있어 몸속 활성산소를 막는 항산화 효과와 더불어 고지혈증 예방, 항비만 및 항당뇨 등 주요 생활습관병에 우수한 건강기능성 식품으로 주목받고 있다. 하지만 재래종자는 유전적으로 순도가 높지 못해 쓰러짐에 약하고 수량이 낮아 품종개선이 필요했다. 이에 따라 농촌진흥청에서는 쓰러짐에 강하고 수량이 많은 메수수 '동안메'를 2012년에 육성하였다.

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Antioxidative Activities and Nitrite Scavenging Abilities of Extracts from Ulmus devidiana (느릅나무 추출물의 항산화 효과 및 아질산염 소거능)

  • 이영주;한준표
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.5
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    • pp.893-899
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    • 2000
  • To measure antioxidative activities, the various extracts from Ulmus devidiana were examined in oil emulsion. Water, ethanol, methanol and butanol were used as extract solutions. The activity oxygen species ($H_2O_2,-OH,\;KO_2$) bound the extracts for antioxidative activities were excellent. The extracts bound $Fe^{2+}$ ion and $Cu^{2+}$ ion showed effective antioxidative activities and strong chelating effects. The concentration of $Fe^{2+}$ ion and total ion in ethanol and methanol extracts from Ulmus devidiana root parts (Chinese) were higher than those of the other products. The highest superoxide dismutase-like activities showed butanol extracts from Ulmus devidiana root parts (Chinese) and water extracts from Ulmus devidiana bark parts (Korean). Electron donating abilities and nitric scavenging abilities of ethanol, methanol and butanol extracts were higher than those of water extracts. The nitrite scavenging abilities also reached the maximum at pH 1.2 and the minium at pH 6.0.

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An Optimization of Synthesis Method for High-temperature Water-gas Shift Reaction over Cu-CeO2-MgO Catalyst (고온수성가스전이반응 적용을 위한 Cu-CeO2-MgO 촉매의 제조방법 최적화)

  • I-Jeong Jeon;Chang-Hyeon Kim;Jae-Oh Shim
    • Clean Technology
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    • v.29 no.4
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    • pp.321-326
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    • 2023
  • Recently, there has been a growing interest in clean hydrogen energy that does not emit carbon dioxide during combustion due to the increasing focus on carbon neutral. Research related to hydrogen production continues, and in this study, we applied waste-derived synthesis gas to the water-gas shift reaction to simultaneously treat waste and produce high-purity hydrogen. To enhance catalytic activity in the high-temperature water-gas shift (HT-WGS) reaction, magnesium was used as a support material alongside cerium. Cu-CeO2-MgO catalysts were synthesized, with copper acting as the active component for the HT-WGS reaction. A study on the catalytic activity based on the preparation method was conducted, and the Cu-CeO2-MgO catalyst prepared by impregnation method exhibited the highest activity in the HT-WGS reaction. The observed superior performance of the Cu-CeO2-MgO catalyst prepared through the impregnation method can be attributed to its significantly higher oxygen storage capacity and amount of active Cu species.

A Study on CH4-SCR Reaction Characteristics of Mg-added Composite Alumina Pt Catalysts (Mg이 첨가된 복합 알루미나 Pt촉매의 CH4-SCR 반응특성에 관한 연구)

  • Won, Jong Min;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.87-94
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    • 2017
  • In this study, a catalyst based on $Pt/Al_2O_3$ supported on Mg was prepared by a wet impregnation method to investigate the $CH_4-SCR$ reaction characteristics of various alumina supports. Alumina supported on $Pt/Al_2O_3$ catalyst was converted to an $Al_2O_3$ composite, and when Mg was added, oxygen species of the active metal Pt were controlled due to electrophobic characteristics. Oxygen-controlled Pt used as a reducing agent inhibited the oxidation of $CH_4$ to $CO_2$. The addition of Mg also promoted the adsorption of NO species and the conversion of NO to $NO_2$ due to the NOx storage property on the catalyst surface.

Study on the distribution of marine bacteria and the consumption of oxygen in Wonmun bay (원문만의 해양세균분포와 산소소모량에 관한 연구)

  • PARK Young-Tae;LEE Won-Jae;PARK Joo-Suck;LEE Pil_Yong;KIM Hak-Gyoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.5
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    • pp.303-314
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    • 1991
  • Hypoxic bottom $(\leq2.0ml/l),\;40\%\;oxygen\;saturation)$ is formed in the semi-closed Wonmun bay during summer and autumn early. This study was carried out to know seasonal distribution of marine bacteria and the role of marine bacteria for forming the hypoxic bottom at Wonmun bay during summer and autumn early, 1990. During the study periods, 170 bacterial strains were isolated from sea water and sediment. Viable cell counts were ranged between $10^5-10^7\;cells/ml$. The dominant species were Acinetobacter spp. in spring, Flavobacerium spp. in summer, Pseudomonas spp. in autumn, Serratia spp. in winter. Because ETSA(Electron Transport System Activity) reveals potential consumption of oxygen in the aquatic microorganisms, the ETSA was used as potential consumption of oxygen in this study. The potential consumption of oxygen was in the range of $232.4-637.5{\mu}l/O_2/l/day$ by marine organism and $142.6-432.4{\mu}l/O_2/l/day$ by marine bacteria during the study periods. The ratio of potential oxygen consumption of marine bacteria to total marine microorganism was 0.54. The potential consumption of oxygen by marine bacteria closely related with the number of viable cells. Consequently, bacteria play an important role to form Hypoxic bottom at marine environment.

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Antioxidative Effect and Melanogenesis of Nelumbo nucifera Stamen Extract on Cultured Human Skin Melanoma Cells Injured by Hydrogen Peroxide (연꽃수술추출물이 과산화수소로 손상된 배양 인체피부흑색종세포에 대한 항산화효과 및 멜라닌화에 미치는 영향)

  • Kim, Myoung-Seoup;Park, Yun-Jum;Sohn, Young-Woo
    • Korean Journal of Plant Resources
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    • v.23 no.2
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    • pp.145-150
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    • 2010
  • To examine the antioxidative effect and melanogenesis of Nelumbo nucifera stamen (NNS) extract on hydrogen peroxide $H_2O_2$ induced cytotoxicity in cultured human skin melanoma cells (SK-MEL-3), cell adhesion activity (CAA), tyrosinase inhibitory activity and total amount of melanin synthesis were measured by colorimetric assay. In this study, $H_2O_2$ significantly decreased CAA, and $CAA_{50}$ value of $H_2O_2$ was determined at 30 uM. In the antioxidative effect, NNS extract increased cell adhesion activity which was decreased by $H_2O_2$ induced cytotoxicity, and also, tyrosinase activity and total amount of melanin were decreased by NNS extract. These results suggested that $H_2O_2$ was highly toxic on cultured human skin melanoma cells and NNS extract showed the antioxidative and inhibitory effect of melanogenesis by the increased CAA, and the decresed tyrosinase activity and total amount of melanin synthesis.

Effects of Extracts of Five Species of Korean Native Forest Plants on Lipid Accumulation and Reactive Oxygen Species Production during Differentiation of 3T3-L1 Preadipocytes (3T3-L1 세포분화 중 지방축적 및 활성산소종 생성에 대한 국내 산림자원 5종 추출물의 효과)

  • Choi, Sun-Il;Lee, Jong Seok;Lee, Sarah;Lee, Hye Jin;Yeo, Joohong;Cho, Bong-Yeon;Lee, Jin-Ha;Kim, Jae-Min;Jung, Tae-Dong;Choi, Seung-Hyun;Kim, Jong-Yea;Kang, Suk-Nam;Lee, Ok-Hwan
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.4
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    • pp.523-528
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    • 2017
  • This study investigate the effects of extracts of five species of Korean native forest plants on lipid accumulation and reactive oxygen species (ROS) production during the differentiation of 3T3-L1 cells. Our results show that Korean native forest plants extracts significantly reduced lipid accumulation and ROS production during adipogenesis in 3T3-L1 cells. Especially, Rubus coreanus Miq. was most effective in the inhibition of lipid accumulation and ROS production at a concentration of $100{\mu}g/mL$. Moreover, Rubus coreanus Miq. extracts significantly inhibited adipocyte differentiation, which is dependent on down-regulation of peroxisome proliferator-activated receptor gamma, CCAAT/enhancer-binding protein alpha, and adipocyte-specific fatty acid binding protein, a key adipogenic transcription factor. Therefore, these results suggest that Rubus coreanus Miq. might be a valuable source of bioactive compounds with anti-adipogenic activity.

Antioxidant Activity of Ethanolic Extract from Germinated Giant Embryonic Rices (발아 거대배아미 에탄올 추출물의 항산화 활성)

  • Kang, Mi-Young;Kim, Sul-Yi;Koh, Hee-Jong;Nam, Seok-Hyun
    • Applied Biological Chemistry
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    • v.47 no.3
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    • pp.293-299
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    • 2004
  • Antioxidant activity of ethanolic extract of two giant embryonic rices, Nampung giant embryonic rice and Hwachung giant embryonic rice, were investigated mainly focusing on their ability to inhibit lipid peroxidation and scavenge reactive oxygen species in comparison with those of general rice. The results showed that germination process increased reducing power, inhibitory activity on lipid peroxidation and scavenging ability either on superoxide or hydroxyl radicals. Among the cultivars tested, increase in antioxidative action was found to be most prominent for Hwachung giant embryonic rice cultivar. For scavenging of superoxide radicals, the extract from Nampung giant embryonic rice has the most potent activity, however, increasing rate of scavenging activity by germination process was also found to be the greatest for Hwachung giant embryonic rice. We found that the scavenging mechanism for superoxide radicals was attributed to the direct scavenging of the radicals. The scavenging of hydroxyl radicals, the most toxic oxygen radical to biological system, by the rice extracts were also examined, and the results showed that either overall activity or the increasing rate of the activity to scavenge hydroxyl radicals by germination process was the greatest for Hwachung giant embryonic rice. Moreover, the results suggested that the scavenging action to hydroxyl radicals might be mediated by direct quenching of the radicals, not by chelating $Fe^{2+}$. Further studies showed that the antioxidant action of the rice extracts tested in vitro was also operative for suppressing ROS production induced in TPA-stimulated HL-60 cells.