• Korean Journal of Fisheries and Aquatic Sciences
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• v.10 no.4
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• pp.213-220
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• 1977

In this study, physical and chemical properties of sea water were investigated qualitatively from the data measured by means of the conductive method as described in the previous paper. The activation energy, ${\Delta}E$, calculated from the suggested equation describing the electrical conductive property of sea water was about 3.0 to 4.0 Kcal/mole at a given pressure and concentration. The average values of the activation volume change, ${\Delta}V$, over the pressure 1 to 1,200 bars decreased from -1.30 to $-0.27\;cm^3/mole$ as the temperature increased from 10 to $25^{\circ}C$.

• Journal of the Korean Chemical Society
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• v.30 no.3
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• pp.307-311
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• 1986

The rates of hydrolysis of the complex, $trans^-[Cr(en)_2F(H_2O)]^{2+}$, have been investigated using spectrophotometric method at various temperatures and pressure. Temperature was 30${\circ}C$ to 50${\circ}C$ and pressure was varied up to 1500bar. The rate constant measured at 30${\circ}C$ is $2.632{\times}10^{-5}sec^{-1}$. The rate constants are decrease with increasing pressure at constants temperature. Activation volume and other activation parameters are calculated from these rate constants. The activation volumes are all positive and lie in the limited range 0.447 ∼ 3.152$cm^3$/mol and the activation entropies are small values. From the results, it was found that this reaction was endothermic and enthalphy controlled reaction in the experimental temperature.

• Proceedings of the Korean Magnestics Society Conference
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• 2002.04a
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• pp.72-73
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• 2002

No Abstract, See Full Text

• Proceedings of the Korean Magnestics Society Conference
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• 2001.04a
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• pp.106-107
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• 2001

• Journal of Environmental Impact Assessment
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• v.29 no.3
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• pp.198-209
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• 2020

In this study, electrospun nanofibers made of PAN (polyacrylonitrile) were activated through a physical method to obtain an optimized pore structure. In particular, to enhance the surface alkalinity, the activated carbon fibers (ANFs) were impregnated with tetraethylenepentamine (TEPA) with the aid of HNO₃. Then, the low level (3,000 ppm) CO₂ adsorption capacity for each ANF sample was evaluated. The specific surface area of ANFs increased from 308.4 ㎡/g to 839.4 ㎡/g and the total pore volume increased from 7.882 ㎤/g to 27.50 ㎤/g. Although the TEPA impregnation reduced the specific surface area and pore volume of the ANFs due to blocking of micropores, the HNO₃ pre-oxidation enhanced the amino groups tethered, increasing the amine content from 6.42% to 17.19%, and finally, increased the adsorption capacity of CO₂. This study showed that the sample 60-ANF-HNO₃-TEPA, which was activated for 60 minutes and was impregnated with HNO₃ and TEPA, had the best adsorption capacity for low level (0.3%) CO₂ (in a binary mixture with N₂).

• Korean Journal of Food Science and Technology
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• v.21 no.2
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• pp.313-319
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• 1989

Hydration Properties of Olchal(Japonica type) and Hankangchalbyeo $(J{\times}I\;type)$ waxy rices at soaking temperatures of $4-40^{\circ}C$ were examined. The water uptake rate constant of Olchal was greater than that for Hankangchalbyeo. Volume increase rate during hydration of Olchal was faster. The rate constants of hardness decrease during hydration were similar between the two varieties. The Z-value and $Q_{10}$ were $39.7^{\circ}C$ and 1.78, respectively.

• Journal of the Korean Chemical Society
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• v.31 no.5
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• pp.413-418
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• 1987

Rates of the reaction for p-nitro benzyl chloride, benzyl chloride and p-methyl benzyl chloride with pyridine in methanol solvent have been measured by an electric conductivity method at 40$^{\circ}$C and 50$^{\circ}$C under various pressures (1∼2000bar). Pseudo first-order rate constants and second-order rate constants were determined. Rates of these reactions were increased in the order p-NO$_2$ < p-H < p-CH$_3$ and increased with temperature, pressure and concentration of pyridine. From those rate constants, the activation parameters were evaluated. The activation volume and the activation compressibility coefficient are both negative values, but the activation enthalpy is positive and the activation entropy is large negative value. From the evaluation of the ground state and transition state which was resulted from substituents and pressure, it was found that this reaction proceeds through S$_N$2 reaction, and S$_N$2 fashion is slightly disappeared as pressure increases.

• Journal of the Korean Chemical Society
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• v.41 no.9
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• pp.443-448
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• 1997

Kinetics for the solvolyses of acyl chlorides and alkyl chlorides in hydroxylic solvent mixtures have been measured by conductometric method at various temperatures and pressures. The activation parameters (${\Delta}V^{\neq},\; {\Delta}H^{\neq},\; {\Delta}S^{\neq}$) were estimated from the rate constants. The reactivities of these reactions were also estimated from the correlation of the activation volumes with the activation entropies.

• Korean Journal of Food Science and Technology
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• v.21 no.2
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• pp.289-293
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• 1989

During soaking of soybeans in water at $4^{\circ}C{\sim}98^{\circ}C$, the volume gain of soybeans held a linear relation with the square root of soaking time regardless of soaking temperatures and showed a highly positive correlation with weight gain, which indicated that the volume increase of soybeans was basically due to the diffusion of water. The activation energies for the volume increase were changed at $40^{\circ}C$. The log time to reach a fixed moisture content showed a linear relation with the soaking temperature during soaking of soybeans at $4^{\circ}C-60^{\circ}C$. The z-value to reach 50% hydration was $50^{\circ}C-55^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.37 no.12
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• pp.1159-1164
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• 2000

페롭스카이트 구조를 갖는 E $r_{1-x}$S $r_{x}$Cr $O_{3-y}$ 계에서 x=0.0, 0.05, 0.1, 0.2인 비화학양론적 화합물 고용체를 1573 K 대기압 하에서 제조하였다. X-선 회절분석을 통하여 제조된 모든 계들이 등방정계 단일상을 형성하였고, 또한 반지름이 큰 S $r^{2+}$를 doping 시켜줌에 따라 격자상수 및 환산부피가 증가됨을 알 수 있었으며, 단위 세포의 부피는 직선성을 보이며 증가하였다. TG-DTA에 따른 열분석 결과 Sr이 치환되지 않은 계에서는 상전이가 발생하는 반면, x값이 0.05 이상인 계들은 고온영역에 이르기까지 등방정계에서 마름모정계로의 상전이가 억제되었다. 전자현미경을 통하여 치환된 Sr의 몰비에 따른 시료들이 미세구조를 관찰하였고, d.c 전도도 측정을 통하여 다결정성 시료계들이 가지는 전도도의 온도 의존성으로부터 구한 활성화 에너지는 0.17 eV였다.다.