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Preparation of 40 wt.% Ag-coated Cu Particles with Thick Ag Shells and Suppression of Defects in the Particles (두꺼운 Ag shell이 형성되는 40 wt.% Ag 코팅 Cu 입자의 제조 및 입자 내 결함 억제)

  • Choi, Eun Byeol;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.4
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    • pp.65-71
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    • 2017
  • To prepare the Cu-based filler material indicating enhanced oxidation resistance property and Ag content, Ag-coated Cu particles was fabricated by Ag plating of 40 wt % on the spherical Cu particles with an average size of $2{\mu}m$ and their oxidation behavior was also evaluated. In the case that ethylenediaminetetraacetic acid was used alone, the fabricated particles frequently showed broken structures such as delamination at Ag shell/core Cu interface and hollow structure that are induced by excessive galvanic displacement reaction. As a result, fraction of defect particles increased up to 19.88% after the Ag plating of 40 wt.%. However, the fraction in the 40 wt.% Ag-coated Cu particles decreased to 9.01% and relatively smooth surface and dense microstructure in the Ag shell were also observed with additional usage of hydroquinone as a complexing agent. Ag-coated Cu particles having the enhanced microstructure did not show any weight increase by oxidation for exposure to air at $160^{\circ}C$ for 2 h, indicating increased oxidation resistance property.

Effect of CeO2 Addition on De-CH4 and NOx Performance (CH4와 NOx 저감 성능에 관한 CeO2 첨가의 영향)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.9
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    • pp.473-479
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    • 2017
  • Due to environmental pollution, hazards of the human body, and global warning, changes in the power train of automobiles are intensifying, and the market forelectronic vehicles is rising. Also, in order to meet the stricter emission regulations forautomobiles with internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is increasing gradually. The objective of this study is to investigate the effectsfrom additive ceric oxide ($CeO_2$) loading amounts to improve the methane ($CH_4$) and nitric oxide (NOx) abatement ability of the natural gas oxidation catalysts(NGOC) reducing toxic gases emitted from compressed natural gas (CNG) buses. Three kinds of NGOC were prepared under the following conditions: fresh and $700^{\circ}C$ for 12hr thermal aging, and the reduction performance of toxic gases was evaluated. Fresh $1Pt-3Pd-1Rh-3MgO-6CeO_2/(Al+Z)$ NGOC containing 6wt% $CeO_2$ had the highest dispersivity of palladium (Pd) with high selectivity to $CH_4$ and improved harmful gas reduction performance. The NGOC with 6wt% $CeO_2$ loaded the least decreased in the dispersivity of the noble metal, and showed the highest reduction of harmful gases due to the thermal durability of $CeO_2$.

Electrochemical Performance of Hollow Silicon/Carbon Anode Materials for Lithium Ion Battery (리튬이차전지용 Hollow Silicon/Carbon 음극소재의 전기화학적 성능)

  • Jung, Min Ji;Lee, Jong Dae
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.444-448
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    • 2016
  • Hollow silicon/carbon (H-Si/C) composites as anode materials for lithium ion batteries were investigated to overcome the large volume expansion. H-Si/C composites were prepared as follows; hollow $SiO_2\;(H-SiO_2)$ was prepared by adding $NaBH_4$ to $SiO_2$ synthesized using $st{\ddot{o}}ber$ method followed by magnesiothermic reduction and carbonization of phenolic resin. The H-Si/C composites were analyzed by XRD, SEM, BET and EDX. To improve the capacity and cycle performance, the electrochemical characteristics of H-Si/C composites synthesized with various $NaBH_4$ contents were investigated by charge/discharge, cycle, cyclic voltammetry and impedance tests. The coin cell using H-Si/C composite ($SiO_2:NaBH_4=1:1$ in weight) in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC : DMC : EMC = 1 : 1 : 1 vol%) has better capacity (1459 mAh/g) than those of other composition coin cells. It is found that the coin cell ($SiO_2:NaBH_4=1:1$ in weight) has an excellent capacity retention from 2nd cycle to 40th cycle.

A Study of Utilizing Brand Touch Point of Corporate Museum : In terms of the Market-Driving Brand and Consumer Insight (기업박물관의 브랜드 접점 활용연구 : 브랜드 시장주도와 소비자 인사이트 관점에서)

  • Kim, Eun-Jeong;Chang, Dong-Ryun;Hong, Sung-Min
    • Archives of design research
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    • v.20 no.3 s.71
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    • pp.163-178
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    • 2007
  • The importance of brands as well as the consumers' emotional & cultural desire have increased. In the meantime, the companies have made efforts to create their positive brand images through the support of Mecenat using culture or social return. In addition, they made ceaseless efforts to provide consumers with a cultural space by building up brand service areas as part of their purpose. However, the rapidly increasing brand service spaces have not really appealed to consumers. In order to become a competitive and powerful brand in the severe brand market, it is necessary to enhance the brand image and to let the brand be considered as a culture and the lifestyle of consumers. In order to do so, the companies have to establish their market-driving strategies by creating new products or new market. To do so, it is important for them to figure out consumers' inner desire through the touch point with consumers. This study attempted to suggest a method of using a corporate museum as a space that could meet all of the said elements at a time. Through the route of a corporate museum, the companies would be able to study their future directions by looking back their history and they could be reborn as culture brands. Therefore, this study suggested that the corporate museum could be a space for culture and education as well as a brand space and could play a positive role in the companies; in this process, the study could grope for consumers' inner desire with its touch point where companies and consumers would meet and its utilization of brand market-driving strategy as a test marketing strategy observing consumers' responses.

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Purification and Properties of Alkaline Protease from Streptomyce sp. YSA-130 (Streptomyces sp. YSA-130이 생산하는 Alkaline Protease의 정제 및 특성)

  • 윤성우;이강표;유주현;신철수;오두환
    • Microbiology and Biotechnology Letters
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    • v.17 no.4
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    • pp.358-364
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    • 1989
  • A crystalline alkaline pretense- producing Streptomyce sp. YSA-130 was isolated from soil in alkaline medium(pH 10.5). The optimum culture condition of Streptomyce sp. YSA-130 for the production of alkaline protease was as follows; 2.0% soluble starch, 1.0% soytone, 0.3% $K_2$HPO$_4$, 0.02% MgSO$_4$.7$H_2O$, 0.8% Na$_2$CO$_3$, pH 10.5, 3$0^{\circ}C$, and 12 hr. The alkaline pretense from the culture broth of Streptomyce sp. YSA-130 was purified about 24 folds by ammonium sulfate precipitation , dialysis, DEAE-cellulose ion exchange chromatography, gel filtration on Sephadex G-15 and crystallization. Optimum temperature and pH of purified enzyme were 6$0^{\circ}C$, and 11.5. Temperature and pH stability of purified enzyme were 5$0^{\circ}C$, and 5.5-12.0. Calcium ion was effective to stabilize the enzyme at higher temperature. The molecular weight of the purified enzyme was approximately 30,000. The purified enzyme was inactivated by diisopropyl flurophosphate(DFP) but not affected by metal ion, EDTA, sulfhydryl reagent and stable detergent.

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Changes on the Components of Salted Eggplants during Storage (저장방법에 따른 절임 가지(시키부품종)의 성분 변화)

  • Nam Hak-Sik;Kim Nam-Woo;Um Young-Chul;Shin Seung-Ryeul
    • Food Science and Preservation
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    • v.11 no.3
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    • pp.293-298
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    • 2004
  • This study was carried out to investigate the changes on the components of salted eggplant(shikibu) during storage. The contents of total and reducing sugars were decreased during storage, and the tendency of decrease was lower in the salted eggplants of vacuum packing storage than in the salted eggplants of rice bran immersion storage. The contents of acetic and malic acid were higher than other organic acids. The content of acetic acid was increased during storage, but malic acid was decrease. The major amino acid were valine, leucine, aspartic acid, glutamic acid. The content of essential amino acids was increased during storage. Aspartic acid, alanine, cystine and proline were high content of free amino acids. The contents of phosphoserine, taurine, Y-aminoisobutyric acid and hydroxyproline were higher than others. Posphoserine content was decreased during storage, but Y-aminoisobutyric acid was increased to 5 times of fresh eggplant at 20 days of storage.

Studies on Improved Carbon Cathode Performance in High Rate $Li/SOCl_2$ Cell (고율 방전용 $Li/SOCl_2$ 전지의 카본 양극 개선에 관한 연구)

  • 최정자;조성백;박희숙
    • Journal of the Korean Ceramic Society
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    • v.34 no.3
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    • pp.225-232
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    • 1997
  • The performance characteristics of high rate discharge LiSOCl2 cells are highly affected by carbon cathode. During the cell discharge, SOCl2 reduction takes place at the porous carbon cathode, resulting in the precipitation of reaction products, mainly LiCl, within the pores of the substrate. This leads to eventual passivation of the cathode surface and resulting cell failure. To improve the cathode performance, we ex-amined discharge reactions of cathodes (half-cell, 50 mA/$\textrm{cm}^2$ constant current) with various surface density and thickness. The carbon cathode with the optimum capacity for our application is surface density 0.04 g/$\textrm{cm}^2$ and thickness 1.4mm carbon. The carbon cathode with surface density 0.04g/$\textrm{cm}^2$ and thickness 1.4 mm exhibits decreased polarization, increased discharge duration time and capacity (Ah/$\textrm{cm}^2$) as compared with that with surface density 0.04g/$\textrm{cm}^2$ and thickness 0.8mm. The porosities analyses on the two carbon cathodes show that total pore volume of the carbon cathode with thickness 1.4 mm is larger than that with thickness 0.8mm. The increased volume of mesopores (0.05$\mu$m~0.5$\mu$m) and macropores(>0.5$\mu$m) is ob-served with the carbon cathode with thickness 1.4mm as compared with that with thickness 0.8mm, which can be related with the observed capacity increase. We observed LiCl crystals, cubic crystallites and fused, plate-like aggregates, and some elemental S as discharge products by EDS and XRD.

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Changes in Components of Salted Eggplants (Chukyang) during Storage (축양품종 염절임 가지의 저장중의 성분 변화)

  • Nam, Hak-Sik;Kim, Nam-Woo;Shin, Seung-Ryeul
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.1
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    • pp.120-125
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    • 2005
  • This study was carried out to investigate the changes in components of salted eggplant (chukyang) during storage. The contents of total and reducing sugar were decreased during storage, and the tendency was lower in the salted eggplants of vacuum packing storage than in the salted eggplants of rice bran immersion storage. The organic acids of salted eggplants were acetic acid, citric acid, lactic acid, and malic acid. And acetic and malic acid contents were much higher than the others. The content of acetic acid was increased during storage, but malic acid was decreased. Major amino acids of eggplants were valine, aspartic acid, glutamic acid, glycine, and alanine. The content of total amino acid was 1,488.18 mg/100 g in eggplant packed vacuum film at 20 days of storage, and higher than those in fresh eggplant. The content of total amino acid in eggplant immersed in wet rice bran was 745.42 mg/100 g at 20 days of storage, and decreased during storage. The contents of aspartic acid, alanine, cystine, and proline in free amino acids of salted eggplants were higher than other amino acids. The contents of phosphoserine, taurine, ${\gamma}$ -aminoisobutyric acid and hydroxyproline were higher than others. Posphoserine content was decreased during storage, but ${\gamma}$ -aminoisobutyric acid content was increased during storage.

Chemical Compounds and Biological Activity of Phellinus baumii (상황버섯의 화학성분 및 생리활성 효과)

  • Shon, Mi-Yae;Seo, Kwon-Il;Choi, Sun-Young;Sung, Nak-Ju;Lee, Sang-Won;Park, Seok-Kyu
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.5
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    • pp.524-529
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    • 2006
  • Chemical compounds, hydrogen peroxide and nitrite-scavenging activities of Phellinus baumii (PB) were investigated to expand the utilization of PB as functional food material. Total mineral contents of PB was 534.3 mg% and potassium was the highest content being 224 mg%. Total and reducing sugars were 56.2% and 9.8%, respectively The contents of free amino acids (FAAs) were in a range of $16.9{\sim}765.5mg%$ with the major FAAs of phenylalanine, aspartic acid, glutamic acid, leucine, serine and valine. The contents of total phenolic compounds in methanol and hot water extracts of PB were 33.3 and 20.7 mg/100 mL, respectively and were higher than those of other solvent extracts. Hydrogen peroxide-scavenging activity (80%) of methanol extract at $10{\mu}g/mL$ for 30 min was similar to tocopherol (83.1%) as control. Nitrite-scavenging activity of extracts of methanol and hot water at 500 mg/mL and pH 1.2 were 57.3% and 51.8%, respectively and then their effects were increased by lowering pH. The present results showed that the methanol and water extracts of Phellinus baumii exhibited strong hydrogen peroxide and nitrite-scavenging activities.

Development and Validation of Urea- SCR Control-Oriented Model for NOX and NH3 Slip Reduction (NOX 및 NH3 Slip 저감을 위한 Urea-SCR 제어기반 모델 개발 및 검증)

  • Lee, Seung Geun;Lee, Seang Wock;Kang, Yeonsik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.1
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    • pp.1-9
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    • 2015
  • To satisfy stricter $NO_X$ emission regulations for light- and heavy-duty diesel vehicles, a control algorithm needs to be developed based on a selective catalytic reaction (SCR) dynamics model for chemical reactions. This paper presents the development and validation of a SCR dynamics model through test rig experiments and MATLAB simulations. A nonlinear state space model is proposed based on the mass conservation law of chemical reactions in the SCR dynamics model. Experiments were performed on a test rig to evaluate the effects of the $NO_X$ and $NH_3$ concentrations, gas temperature, and space velocity on the $NO_X$ conversion efficiency for the urea-SCR system. The parameter values of the proposed SCR model were identified using the experimental datasets. Finally, a control-oriented model for an SCR system was developed and validated from the experimental data in a MATLAB simulation. The results of this study should contribute toward developing a closed-loop control strategy for $NO_X$ and $NH_3$ slip reduction in the urea-SCR system for an actual engine test bench.