• Title/Summary/Keyword: 확산이중층

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The Change in Geotechnical Properties of the Deposited Clay Contaminated by Leachate from Waste Disposals (침출수로 오염된 퇴적점토의 역학적 특성변화)

  • Ha, Kwang-Hyun;Lee, Sang-Eun
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.3
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    • pp.43-54
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    • 2006
  • In this paper, the uniaxial, triaxial compression tests and consolidation tests on the clay sample substituted initial pore water for pollutant were performed to evaluate the change in geotechnical properties of the contaminated clay. The contaminant transport analysis on embankment type landfill using the MT3D model was also performed to evaluate the extent of transport and diffusion. There was tendency that strength, compressibility and permeability has increased with the increase in the concentration of NaCl solution. The increase in the strength and compressibility of sample saturated with leachate was higher than samples saturated with NaCl solution, but in the permeability coefficient was lower. As the result of contaminant transport analysis, the predicted concentration was in high with the increase in the initial concentration of $Cl^-$ ion and increased in a non-linear form. The transportation distance calculated with use of regression equation between the distance from contaminant source and the concentration of $Cl^-$ ion was increased with the increase in the initial concentration.

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A Study on the Electrical Properties of Cobalt Policide Gate (코발트 폴리사이드 게이트의 전기적 특성에 관한 연구)

  • Jeong, Yeon-Sil;Gu, Bon-Cheol;Bae, Gyu-Sik
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1117-1122
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    • 1999
  • Amorphous Si and Co/Ti bilayers were sequentially evaporated onto 5- 10nm thick $\textrm{CoSi}_{2}$ and rapidly thermal-annealed(RTA) to form Co-polycide electrodes. Then, MOS capacitors were fabricated by doping poly-Si using SADS method. The C-V and leakage-current characteristics of the capacitors depending upon the RTA conditions were measured to study the effects of thermal stability of $\textrm{CoSi}_{2}$ and dopant redistribution on electrical properties of Co -polycide gates. Capacitors RTAed at $700^{\circ}C$ for 60-80 sec., showed excellent C-V and leakage-current characteristics due to degenate doping of poly-Si layers. But for longer time or at higher temperature, their electrical properties were degraeded due to $\textrm{CoSi}_{2}$ decomposition and subsequent Co diffusion. When making Co-polycide gate electrodes by SADS, not only degenerate doping of poly-Si layer. but also suppression of have been shown to be very critical.

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Modeling of Acid/Base Buffer Capacity of soils (토양의 산/염기 완충능의 모델링)

  • 김건하
    • Journal of Korea Soil Environment Society
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    • v.3 no.3
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    • pp.3-10
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    • 1998
  • Acid/Base buffer capacity of soil is very important in prediction of contaminant transport for its direct impact on pH change of the system composed of soil-contaminant-water, In this research, diffuse double layer theory as well as two layer electrostatic adsorption model are applied to develop a theoretical model of buffer capacity of soil. Model application procedures are presented as well. Buffer capacity of Georgia kaolinite and Milwhite kaolinite was measured by acid-base titration. Model prediction and experimental results are compared.

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Development of BiPbSrCaCuO Superconductor by Diffusion of Dual-Layer Sample (이중층 시료에서 확산에 의한 BiPbSrCaCuO 초전도체 개발)

  • 최성환;박성진;유현수;강형곤;한병성
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.5
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    • pp.795-801
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    • 1994
  • The BiPbSrCaCuO superconductor was fabricated by diffusion of The dual layer composed of SrS12TCaS11TCuS12TOS1xT in upper layer and BiS12TPbSI0.3TCuS12TOS1yT in lower layer, and varified growh-mechanism of BiPbSrCaCuO superconducting phase. And, we produced optimum conditions of spread volume and each stage of sintering time were upper layer:Lower layer=1:0.2, 1:0.4, 1:0.6 and 24hr., 120hr., 210hr. From the result, the optimum conditions are spread volume(Upper layer:Lower layer=1:0.6), sintering time(210hrs.) at 820$^{\circ}C$.The BiPbSrCaCuO superconductor, fabricated optimum condition, showed zero resistance at critical temperature of 70k.

A Study on the Formation fo Epitaxial $CoSi_2$ Thin Film using Co/Ti Bilayer (Co/Ti이중박막을 이용한 $CoSi_2$에피박막형성에 관한 연구)

  • Kim, Jong-Ryeol;Bae, Gyu-Sik;Park, Yun-Baek;Jo, Yun-Seong
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.81-89
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    • 1994
  • Ti film of lOnm thickness and Co film of 18nm thickness were sequentially e-heam evaporated onto Si (100) substrates. Metal deposited samples were rapidly thermal-annt.aled(KTA) in thr N1 en vironment a t $900^{\circ}C$ for 20 sec. to induce the reversal of metal bilayer, so that $CoSi_{2}$ thin films could be formed. The sheet resistance measured by the 4-point probe was 3.9 $\Omega /\square$This valur was maintained with increase in annealing time upto 150 seconds, showing high thermal stab~lity. Thc XRII spectra idrn tified the silicide film formed on the Si substrate as a $CoSi_{2}$ epitaxial layer. The SKM microgr;iphs showed smooth surface, and the cross-sectional TKM pictures revealed that the layer formed on the Si substrate were composed of two Co-Ti-Si alloy layers and 70nm thick $CoSi_{2}$ epl-layer. The AES analysis indicated that the native oxide on Si subs~rate was removed by TI ar the beginning of the RTA, and Ihcn that Co diffused to clean surface of Si substrate so that epitaxial $CoSi_{2}$ film could bt, formed. In thc rasp of KTA at $700^{\circ}C$. 20sec. followed by $900^{\circ}C$, 20sec., the thin film showed lower sheet resistance, but rough surface and interface owing to $CoSi_{2}$ crystal growth. The application scheme of this $CoSi_{2}$ epilayer to VLSI devices and the thermodynarnic/kinetic mechan~sms of the $CoSi_{2}$ epi-layer formation through the reversal of Co/Ti bdayer were discussed.

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Thermal Cycle Reliabilties and Cracking Characteristics of Electroplated Cr/Ni-P Coatings (전해 Cr/Ni-P 도금막의 열 사이클 신뢰성 및 균열거동 분석)

  • Lee, Jina;Son, Kirak;Lee, Kyu Hwan;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.4
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    • pp.133-140
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    • 2019
  • The effects of thermal cycle conditions on the bonding strength and crack propagation behaviors in electroplated Cr/electroplated Ni-P coatings were systematically evaluated. 1st heat treatment was performed at 500℃ for 3 hours after electroplating Ni-P, and then, 2nd heat treatment was performed at 750℃ for 6 hours after electroplating Cr. The measured bonding strength by ASTM C633 were around 25.6 MPa before thermal cycling, while it increased to 47.6 MPa, after 1,000 cycles. Increasing thermal cycles led to dominant fail mode with cohesive failure inside adhesive, which seemed to be closely related to the increasing bonding strength possibly not only due to higher Cr surface roughness, but also to penetrated channeling crack density. Also, increasing density of penetrated channeling cracks in electroplating Cr layer led to slightly stronger bonding strength due to mechanical interlocking effects of adhesive inside channeling cracks.

fabrication of Self-Aligned Mo2N/MO-Gate MOSFET and Its Characteristics (자기 정렬된 Mo2N/Mo 게이트 MOSFET의 제조 및 특성)

  • 김진섭;이종현
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.21 no.6
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    • pp.34-41
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    • 1984
  • MOEN/MO double layer which is to be used It)r the RMOS (refractory metal oxide semiconductor) gate material has been fabricated by means of low temperature reactive sputtering in N2 and Ar mixture. Good Mo2N film was obtained in the volumetric mixture of Ar:N2=95:5. The sheet resistance of the fabricated Mo7N film was about 1.20 - 1.28 ohms/square, which is about an order of magnitude lower than that of polysilicon film, and this would enable to improve the operational speed of devices fabricated with this material. When PSG (phosphorus silicate glass) was used as impurity diffusion source for the source and drain of the RMOSFET in the N2 atmosphere at about 110$0^{\circ}C$, the Mo2N was reduced to Mo resulting in much smaller sheet resistance of about 0.38 ohm/square. The threshold voltage of the RMOSFET fabricated in our experiment was - 1.5 V, and both depletion and enhancement mode RMOSFETs could be obtained.

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Phase Asymmetry Effect on Vesicle Fusion Induced by Phospholipase D (인지질분해효소D에 의해 유도된 소낭 융합에 대한 상 비대칭의 영향)

  • Park, Jin-Won
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.672-676
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    • 2015
  • Spherical phospholipid bilayers, vesicles, were formed with respect to phase of each layer via a double emulsion technique. The conversion of phosphatidylcholine (PC) to phosphatidic acid (PA) at the outer layer, caused by phospholipase D (PLD), induced a curvature change in the vesicles, which eventually led them to fuse each other. The effect of the lipid layer physical-properties on the PLD-induced vesicle fusion was investigated using the fluorescence intensity change. 8-Aminonaphthalene-1,3,6-trisulfonic acid disodium salt(ANTS) and p-Xylene-bis(N-pyridinium bromide)(DPX) were encapsulated in the vesicles, respectively, for the quantification of the fusion. The fluorescence scale was calibrated with the fluorescence of a 1/1 mixture of ANTS and DPX vesicles in NaCl buffer taken as 100% fluorescence (0% fusion) and the vesicles containing both ANTS and DPX as 0% fluorescence (100% fusion), considering the leakage into the medium studied directly in a separate experiment using vesicles containing both ANTS and DPX. It was observed that the fusion occurred to the liquid-phase of the inner layer only. The fusion behaviors were very similar for both solid and liquid of the outer layer. However, the leakage was faster for the solid-phase outer-layer than the liquid-phase outer-layer. The difference in the leakage seems to be caused by the lipid concentration and the lateral diffusivity in the layer.

A Study on the Fire Spread through Curtain Wall System with Fire Simulations (FDS) (화재 시뮬레이션(FDS)을 이용한 커튼월 구조의 화재 확산에 관한 연구)

  • Song, Young-Joo;Gu, Seon-Hwan;Kim, Hyun-Jin;Park, Deuk-Jin;Park, Jeong-Min
    • Fire Science and Engineering
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    • v.26 no.6
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    • pp.31-37
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    • 2012
  • In this study, the fire risk of the curtain wall structure was compared with a general structure among the double envelope structure using a fire simulation program. To this end, a fire-story building curtain wall was modeled as virtual using the PyroSim based on a fire simulation program (FDS). And then, the fires occurred in the model, divided by curtain wall non-applied model and applied model, in the same structure and place. To identify the fire characteristics, smoke behavior characteristics, viewing distance, and volume fractions of CO and $CO_2$ were comparative analyzed. As a result, it was identified that the curtain wall applied model quickly filled with smoke from the top floor to under the floor compared to the curtain wall non-applied model. From this study, the fire risk of curtain wall structure was evaluated in detail using the fire simulations.

Recent International Cooperations and Response Strategies to Arrest Global Warming (지구온난화에 관한 최근의 국제동향과 대응책)

  • 주수영;김용석
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.1
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    • pp.73-80
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    • 1991
  • 인류가 산업발전 등으로 인해 석유등 화석연료를 사용함에 따라 대기오염은 날로 악화되어 1952년 런던스모그 같은 참사를 맞이하였고 이에 각국은 이러한 대기 오염물질을 저감하기 위하여 노력한 결과 대기 오염물질은 낮아지고 있으나 이에 반해 이산화탄소 배출량 증가에 따른 지구 온난화 현상과 오존층 파괴는 지역적인 환경문제에서 번세계적인 환경문제로 확산 전개되고 있다. 특히 산업혁명후 화석연료의 급격한 사용증가로 인한 이산화탄소 배출량 증가는 지구를 온나화시키고 수십년 후에는 환경에 심각한 영향을 주게 되는 것은 의심할 여지가 없는 것으로 이는 지구환경문제 중에서 금회 최대의 과제로 대두되게 되었다. 이에 따라 1985년 UNEP 관리 이사회를 필두로 "지구환경보전에 관한 동경회의", "대기오염 및 기후변동에 관한 노드윅 회의", "백악관회의", "휴스톤 Summit" 등에서 이 문제가 거론되기 시작하여 '90. 8월에는 스웨덴에서 온난화에 대한 과학적 인식과 대책의 메카니즘을 정하기 위한 IPCC 4차 회의가 각국 대표들이 참석한 가운데 정치, 경제, 과학의 문제로 등장하여 우리생활의 근본을 좌우할 다각적인 논의가 진행된 바 있다. 또한 미국, 영국, 일본 등 선진국들의 정상이 모이는 G7 회담 등에서 논의되고 있는 것들 중 정치적인 문제를 제외하고는 환경문제를 가장 많이 다룬다는 외신보도를 우리는 여러번 접한바 있다. 현재 국제적 환경문제로 가장 관심이 집중되고 있는 문제 중 몇가지를 소개하면 우선 <몬트리올의 정서에 의한 오존층 보호>를 들 수 있겠고, 최근 국제 협약 제정을 추진하고 있는 "지구온난화 방지에 관한 기후협약" 그리고 유해폐기물의 국제교역에 관한 "바젤협약"과 함께 새로이 제기된 "생물학적 다양성 협약"등이 거론되고 있으며, 이에 덧붙여 미국의 "자동차배출가스 규제"도 우리나라 산업에 큰 영향을 미칠 것으로 판단된다. 본 논문은 이중 대기와 관련된 오존층 보호와 지구온난화 대책에 대한 국제회의 등에서 현재까지 논의되었거나 토의될 내용에 대하여 기술하고 특히 금년부터 집중적으로 국제협상이 진행될 지구온난화 문제에 대한 최근의 국제동향 우리나라의 입장을 기술하고자 한다.

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