• Journal of the Korean Chemical Society
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• v.48 no.3
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• pp.273-282
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• 2004

The synthetic technology of improved polyaluminiumchloride (IPAC) similar to characteristics of PACS was established with minimum expense for modifying existing production line. The conditions for activating silicate was studied before the synthesis of IPAC, and the IPAC was synthesised with raw materials such as aluminumhydroxide and concentrated hydrochloric acid, followed by adding activated silicate and alginate. The specification of product, chemical structure, and coagulating properties were tested by using specification testing method, instrumental analytical method, and Jar tester, respectively. As a result, the product, IPAC, contained aluminium oxide content more than 17%, and no precipitation was shown at all while the IPAC solution was preserved, and the larger floc and faster coagulation were represented compared to existing PAC under the same conditions. It was suggested that these synthetic technology could be applied to the existing production line for producing PAC without approximately cost raising factor because of adding sulfuric acid-activated silicate instead of sodium sulfate.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.542-547
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• 1998

Polyamine type polymer flocculants were synthesized and their characterization, viscosity and flocculation studies were conducted. In order to increase the molecular weight of polyamine flocculant which was prepared by polycondensation reaction from dimethylamine and epichlorohydrin, a small amount of 1,6-hexanediamine was employed. The incorporation of 1,6-hexanediamine up to 5.5 mole % replacing corresponding part of dimethylamine gave a branched type polyamine sample with increased intrinsic viscosity ([${\eta}$]=0.46 in 1 wt % aqueous NaCl solution). The amount of 1,6-hexanediamine above 5.5 mole %, however, resulted in gelation during polymerization. Utilizing raw water from Maegok potable water treatment plant, it was found that the addition of polyamine flocculant at a concentration of 1 mg/L level could reduce the amount of polyaluminum chloride (PAC) inorganic flocculant by half (15 mg/L). It was also observed that the incoporation of polyamine flocculant at 1 mg/L level was effective in the higher pH raw water, while PAC inorganic flocculating agent alone was not effective.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.325-326
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• 2006

현 화학플랜트에서 사용되고 있는 ABS 수지 응집 공정의 경우 교반기 내부의 불균일한 유동분포와 유동메커니즘의 문제점은 공정 제품의 생산성을 저하 시키는 원인으로 작용하고 있다. 그러나 우수한 성능의 산업용 교반기를 설계하기 위해선 반드시 교반성능에 영향을 미치는 다양한 내부의 유동특성의 정량적인 실험 데이터 확보가 필요하나, 3차원적 비정상 특성을 나타내는 복잡한 구조의 내부 유동특성에 관한 정량적 해석은 현재까지도 상당한 어려운 문제로 남아있다. 이에 이런 문제점을 개선하여 생산성을 향상시키기 위해서는 PIV 기법을 이용한 교반기 내부의 유동분포와 유동메커니즘을 규명하여 교반기 내부의 최적화된 유동을 형성시키는 임펠러의 형상을 개발하고자 한다.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.4
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• pp.463-474
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• 2010

In this study, chemical coagulation conditions for treating combined sewer overflow(CSO) occurred during rainy season were evaluated by jar tests with aluminum sulfate[$Al_2(SO_4)_3{\cdot}17H_2O$] and ferric chloride[$FeCl_3{\cdot}6H_2O$]. The raw domestic sewage sampled from the primary sedimentation tank at a local sewage treatment plant was filtered through $150{\mu}m$ sieve before using. Point of zero charge(PZC) for various dose of aluminum sulfate occurred at pH 5.8-6.5, while for ferric chloride occurred at pH 5.3-6.0 in term of streaming current(SC) values. Charge neutralization ability of aluminum sulfate was bigger than that of ferric chloride. Optimum pH and dose of aluminum sulfate and ferric chloride were 6.2, 0.438mM and 5.8, 0.925mM, respectively. Removal efficiencies of TCOD, turbidity, SS and TP were 75, 97, 95, 96% with aluminum sulfate and 74, 96, 98, 99% with ferric chloride at their optimum coagulation conditions. More efficient removal of SS, TP and small particles was possible with ferric chloride at optimum coagulation conditions. Both SC values and COD removal started to increase where soluble phosphorus was completely removed.

• Journal of Wetlands Research
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• v.14 no.4
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• pp.629-635
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• 2012

This study was conducted to evaluate the removal behaviors of DOM(dissolved organic matter) and phosphorus in eutrophic lake water by coagulation process with PAC(powdered activated carbon). It was observed that the removal characteristic of soluble matter was different from that of dissolved one, and the removal of DOM was effected by both pH and coagulant dosage. It was founded that PAC could increase the removal efficiency by an adsorption of DOM in coagulation process. A formation of soluble and colloidal matters resulted in the degradation of phosphorus removal efficiency in a chemical precipitation process. The phosphorus removal efficiency could be enhanced by an absorption of colloidal matter and dissolved complex with PAC addition. In addition, the PAC addition caused the increase of floc density in coagulation process, that led to the rise of sedimentation rate, and resulted in a significant improvement of solid-liquid separation efficiency.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.6
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• pp.613-619
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• 2006

The objectives of this research are to evaluate the effect of membrane materials, particulate matter and membrane pore size on permeate flux. It was shown that the removal efficiency of high MW organic matter more than 10 kDa was lower than that of low MW organic matter for $MIEX^{(R)}$ process. For the change of permeate flux by the pretreatment process, $MIEX^{(R)}+UF$ process showed high removal efficiency of organic matter as compared with coagulation+UF processes, but high reduction rate of permeate flux was presented through the reduction of removal efficiency of high MW organic matter. The pretreatment of the raw water significantly reduced the fouling of the hydrophilic membrane, but did not decrease the flux reduction of the hydrophobic membrane. Flux decline on MF process increased due to the pore clogging, while the permeate flux decline of UF process decreased due to the formation of cake layer. It was shown that particle matter was not effect on MIEX+membrane process. But, for coagulation+membrane process, particle matter was important factor on permeate flux.

• Korean Journal of Food Science and Technology
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• v.27 no.3
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• pp.318-323
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• 1995

To improve wastewater treatment in a confectionery factory and to optimize chemical coagulation process, this study was performed. $COD_{Mn}$ and total solid of untreated wastewater were $200{\sim}820ppm\;and\;860{\sim}1350ppm$, respectively. Composition of total solid was sugar 40%, protein 10%, hexane-soluble 20%, and ash 30%. Turbidity at 650 nm and the amount of suspended solid (SS) showed correlation, thus turbidity could be used for the on-line measurement of SS. The most effective combination of coagulants for the removal of $COD_{Mn}$ and SS was that of $Al_2(SO_4)_3\;and\;Ca(OH)_2$. The optimal concentration of $Al_2(SO_4)_3\;and\;Ca(OH)_2$ was 480 ppm and 200 ppm, respectively. Optimal retention time of wastewater for $Al_2(SO_4)_3$ addition $Ca(OH)_2$ addition : flocculation was 2 : 2 : 10 min. Multiple treatment of $Al_2(SO_4)_3:Ca(OH)_2$ overcame coagulation inhibition by gelatin and detergent, and addition of microbial sludge reduced it.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.257-264
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• 2006

This study investigated the effects of hybrid process(chemical coagulation, Fenton oxidation and ceramic UF(ultrafiltration)) on COD and color removals of commercial reactive dyestuffs. In the case of chemical coagulation, the optimal concentrations of $Fe^{3+}$ coagulant for COD and color removals of RB49(reactive blue 49) and RY84(reactive yellow 84) were determined according to the different coagulant dose at the optimal pH. They were 2.78 mM(pH 7) in RB49 and 1.85 mM(pH 6) in RY84, respectively. In the case of Fenton oxidation, the optimal concentrations of $Fe^{3+}\;and\;H_2O_2$ were obtained. Optimal $[Fe^{2+}]:[H_2O_2]$ molar ratio of COD and color removals of RB49 and RY84 were 4.41:5.73 mM and 1.15:0.81 mM, respectively. In the case of ceramic UF, the flux and rejection of supernatant after Fenton oxidation were investigated. After ceramic UF for 9 hr, the average flux of RB49 and RY84 solutions were $53.4L/m^2hr\;and\;67.4L/m^2hr$ at 1 bar, respectively. In addition, the permeate flux increased and the average flux recovery were 98.5-99.9%(RB49) and 91.0-97.3%(RY84) according to adopting off-line cleaning(5% $H_2SO_4$). Finally, COD and color removals were 91.6-95.7% and 99.8% by hybrid process, respectively.

• Korean Chemical Engineering Research
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• v.44 no.5
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• pp.547-554
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• 2006

The overall objective of this research was to find out the role of rapid mixing conditions in the species of hydrolyzed Al(III) formed by Al(III) coagulants and to evaluate the distribution of hydrolyzed Al(III) species by coagulant dose and coagulation pH. When an Al(III) salt was added to water, monomeric Al(III), polymeric Al(III), precipitate Al(III) was formed by Al(III) hydrolysis. The method of hydrolyzed Al(III) species characterization analysis was based on timed spectrophotometer with ferron as a color developing reagent. The hydrolytic species were divided into monomer, polymer, precipitate from the reaction kinetics. And then, the color intensity for monomeric Al(III) was read 3 min after mixing. With standard Al solution containing monomeric Al(III) only, the Al-ferron color intensity slightly increased with until about 3 min. During the rapid mixing period, for purewater, formation of dissolved Al(III) (monomer and polymer) was similar to rapid mixing condition, but for raw water, the species of Al(III) hydrolysis showed different result. During the rapid mixing period, for high coagulant dose, Al-ferron reaction increases rapidly. The kinetic constants, Ka and Kb, derived from Al-ferron reaction. The kinetic constants followed very well the defined tendencies for coagulation condition. For pure water, when the rapid mixing time increased, the kinetic constants, Ka and Kb showed lower values. Also, for raw water, when the rapid mixing time increased, the kinetic constants, Ka and Kb showed lower values.

• Proceedings of the Membrane Society of Korea Conference
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• 1998.10a
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• pp.127-129
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• 1998

국내 산업폐수 발생량 중 소량이지만 오염도가 높고 난분해성이 다량 함유되어 있는 염료폐수는 일반적인 응집침전 + 생물학적처리로는 폐수 방류기준치인 COD_{MN} 100ppm이하로 처리하기가 불가능하다. 따라서 S화학에서는 방류수 수질 기준을 만족시키기 위하여 생물학적 처리 후단에 3차 처리로서 분말 활성탄 설비와 같은 고도처리설비를 도입하여 운전하고 있으나 운전비가 과다하고, 분말활성탄의 주입시 미분의 비산으로 인하여 주위시설에 영향을 미치는 것으로 나타났다. S화학에서는 활성탄처리설비의 문제점을 해결하고 폐수를 공업용수로 재활용하기 위해 일일 $1500m^3$의 폐수 중 $750m^3$에 고도처리설비인 역삼투설비를 적용하였다.