• Title/Summary/Keyword: 화학적 도구

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QMS를 이용한 플라즈마 공정 진단

  • Ju, Jeong-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.92-92
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    • 2016
  • 전기방전의 기본적인 특성을 가지고 있는 플라즈마를 이용하여 재료를 가공하는 증착, 식각, 표면처리 공정에 있어서 플라즈마 내의 전자 충돌 반응에 의한 이온, 라디칼의 생성과 재료 표면의 반응을 분석하는 도구로써 분압 측정은 일반적인 화학 조성 분석에 기원한 오랜 역사를 가지고 있다. 1 amu 정도의 분해능을 가지고 있고 크기가 30 cm 정도에 불과한 사중극자 질량 분석기는 적절한 질량 스캔 시간과 넓은 이온 전류 측정 범위를 가지므로 소형 차등 배기 시스템과 조합하면 1 mTorr 영역의 스퍼터링 시스템에서 1 Torr 영역의 PECVD/PEALD 시스템 진단에도 쉽게 적용이 가능하다. Inficon사의 CPM-300과 Pfeiffer사의 Prisma80을 이용한 플라즈마 식각 공정 분석 결과를 보면 동위원소까지 분석이 가능하다. 또한 전자충돌 이온화 에너지를 조절하여 m/q(질량전하비율)가 중첩되는 경우의 해석도 가능하다. 다중 오리피스를 갖는 compact design의 밸브 블록을 이용한 설계에서는 line-of-sight 입사가 불가능하여 이온 전류를 분석할 수 없다는 단점이 있으나 표준 가스를 이용한 정량화 등의 큰 장점들이 있다. 최근 이루어진 연구의 내용으로는 유도 결합 플라즈마 장치에서 전도성 메쉬를 이용한 라디칼 거동 관찰을 위해서 두 대의 CPM-300을 메쉬 전 후에 설치하여 라디칼의 양 변화를 전류 프로브와 같이 사용하여 조사하였다.

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Review on the Computer Simulation Tools for Polymeric Membrane Researches (고분자 분리막 연구를 위한 전산모사 도구 소개)

  • Choi, Chan Hee;Park, Chi Hoon
    • Membrane Journal
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    • v.30 no.4
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    • pp.242-251
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    • 2020
  • Computer simulation tools mainly used for polymer materials and polymeric membranes are divided into various fields depending on the size of the object to be simulated and the time to be simulated. The computer simulations introduced in this review are classified into three categories: Quantum mechanics (QM), molecular dynamics (MD), and mesoscale modeling, which are mainly used in computational material chemistry. The computer simulation used in polymer research has different research target for each kind of computational simulation. Quantum mechanics deals with microscopic phenomena such as molecules, atoms, and electrons to study small-sized phenomena, molecular dynamics calculates the movement of atoms and molecules calculated by Newton's equation of motion when a potential or force of is given, and mesoscale simulation is a study to determine macroscopically by reducing the computation time with large molecules by forming beads by grouping atoms together. In this review, various computer simulation programs mainly used for polymers and polymeric membranes divided into the three types classified above will be introduced according to each feature and field of use.

Convergence Study on Unmet Demand and Influencing Factors in Advanced Cancer Patients Receiving Conventional Chemotherapy (고식적 항암화학요법 받는 진행성 암환자의 미충족 요구와 영향요인에 대한 융합적 연구)

  • Youm, Myeong-Ja;Park, Jeong Sook
    • Journal of the Korea Convergence Society
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    • v.11 no.11
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    • pp.433-441
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    • 2020
  • This study was attempted to use as basic data for developing a nursing intervention program suitable for terminal cancer patients by analyzing the unmet needs of advanced cancer patients receiving palliative chemotherapy and identifying the influencing factors. The subject of the study consisted of 71 patients with advanced cancer who were admitted to a university hospital and received palliative chemotherapy, and the research tool used CNAT (Comprehensive Needs Assessment tool in Cancer) developed by Shin et al., and data analysis was an independent sample. It was analyzed by t-test, ANOVA and multiple regression analysis. As a result of the study, the medical staff's area was the highest at 2.34 ± 0.63 out of 4 points, followed by psychological problems (2.09 ± 0.53) and information education (1.69 ± 0.45). Factors influencing unmet needs include educational background (β=.207, p=.047), thoughts on death (β=-.269, p=.018), diagnosis (β=-.283, p=. 013). Based on the results of this study, it is necessary to consider the needs of the medical staff in advanced cancer patients, provide psychological support, and consider ways to meet the needs according to academic background and diagnosis.

The Infection Control of Dental Impressions (치과용 인상체의 감염 관리)

  • Lee, Jin-Han
    • Journal of Dental Rehabilitation and Applied Science
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    • v.29 no.2
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    • pp.183-193
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    • 2013
  • The characteristics of dental treatment makes the dental staff frequently contact with patient directly. Also the daily use of high-handpieces, sharp instruments, and needles often causes bleeding on oral cavity. Therefore, the risk of cross transmission grows up. The pathogen from dental practice could spread on not only the practice itself but also the dental laboratory with contaminated impressions and prosthesis. Dental clinic staffs (dentists, dental hygienists and dental technicians) should recognize all the patients have a possibility of cross contamination, and try to prevent the transmission of infection by proper infection control. In this study, we review the articles about disinfection methods and chemical infection agents used for dental impressions, and try to figure out the suitable and effective infection control system of dental impressions.

An Investigation on Pre-service Chemistry Teachers’ Difficulties in Practice of Inquiry-based Experiment (문제 해결 중심 탐구실험에서 예비 화학교사들이 경험한 어려움에 대한 연구)

  • Baek, Jongho;Choi, Chui Im;Jeong, Dae Hong
    • Journal of the Korean Chemical Society
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    • v.59 no.5
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    • pp.434-444
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    • 2015
  • Inquiry-based experiments provide opportunities to understand scientific knowledge and acquire nature of science. In this study, the difficulties which pre-service teachers experienced in inquiry-based experiment class were investigated and analyzed. Twenty-two pre-service teachers attended course designed as ‘ill-structured inquiry’ for 13 weeks, and researchers investigated their difficulties by questionnaires and interview. They showed difficulties mostly in designing experiment and interpretation and also in understanding inquiry purpose, lack of prior knowledge, confidence in inquiry performance, and understanding of experimental instruments and facilities. As a result, it is necessary to provide opportunities to engage in inquiries and environments to properly instruct pre-service teachers the inquiry ability in college of education.

Determination of Main Factors Affecting the Electrodialysis of Succinate by Using Design of Experiment Method (실험계획법을 이용한 숙신산염 탈염의 주요 공정변수 결정)

  • Shin, Seunghan;Chang, Eugene;Lee, Do-Hoon;Kim, Sangyong
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.179-184
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    • 2008
  • The separation and purification of succinate are necessary for the succinic acid production by a fermentation process. Among the purification processes, desalination of succinate is inevitable. In this work, electrodialysis was selected as a desalination method and its operating parameters affecting the degree of desalination and energy consumption were examined. Commercialized electrodialysis apparatus was used in this work and its optimum operating parameters were determined by using design of experiment (DOE) method. Voltage, concentration of succinate, and pH were selected as main parameters. Among them, voltage seemed to be the most important one. The final conversion of succinate to succinic acid was calculated when the operating parameters were optimized. Finally, the effect of impurities, such as corn steep oil, yeast extract, and dextrose on the electrodialysis efficiency was also studied.

Study on Attitude of Science Gifted and Talented Middle School Students toward Science (중학교 과학 영재 학생의 과학 관련 태도에 관한 연구)

  • So, Keum-Hyun;Shim, Kew-Cheol;Lee, Hyun-Uk;Chang, Nam-Kee
    • Journal of The Korean Association For Science Education
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    • v.20 no.1
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    • pp.166-173
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    • 2000
  • Purpose of this study is to investigate on the attitude toward science of science gifted and talented(G/T) middle school students. The inventory instrument used for study was a revision of TOSRA which consisted of six domains. Subjects were 131 students who had entered into Center for Science G/T Education, Seoul National University in 1999. This center is composed of five divisions: mathematics, physics, chemistry, biology, and earth science. There was no difference between genders totally, but the attitude level of male was higher than that of female in 'career interest in science' domain. Compared among domains, while the attitude score toward leisure interest in science' was the highest, 'normality of scientist' was the lowest. Whereas the attitude level was no difference among divisions except chemistry, that of chemistry division was higher than mathematics in 'adoption of scientific attitudes' domain. Thus, it is needed to provide social and national encouragement for superior science G/T students as well as to develope special programs for them so as to achieve their dreams and to contribute to scientific development of nations.

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Rare Earth Elements of Atmospheric Particulates (PM2.5) in Northeast Asia: Beijing and Gwangju (동북아시아 초미세먼지의 희토류 원소 특성 비교: 북경과 광주)

  • Jeong, Seok;Lee, Jiyeong;Park, Sanghee;Yang, Minjune;Chang, Hyejung;Ryu, Jong-Sik
    • Korean Journal of Remote Sensing
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    • v.38 no.5_3
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    • pp.863-872
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    • 2022
  • Rare earth elements (REEs) have been used as one of power tracers for understanding geological and environmental changes due to their similar physico-chemical properties. In this study, we investigated the characteristics of rare earth elements in atmospheric particulates(PM2.5) collected in Beijing and Gwangju during January 2018. The total concentrations of REEs in the Beijing samples were about 16X higher than those in Gwangju samples, and both samples are enriched in light REE than heavy REE, up to 8-10 times. The Post Archean Australian Shale (PAAS)-normalized pattern showed that both samples are enriched in Eu, Tb, and Er, and displayed positive Eu but negative Ce anomalies. The elemental correlations indicate that both samples originated from China desert and Loess plateau as well as cities surrounding Beijing. This study suggests that REEs in PM2.5 can be used as a powerful proxy of revealing the difference between China and Korea, and provide basic information on the source and transport of PM2.5.

Actin Affinities of Recombinant α-Tropomyosins That Residues 276 or 277 in the Carboxyl Terminal Region are Individually Substituted to a Cysteine Residue (α-트로포마이오신의 276 또는 277 아미노산 잔기가 단일 시스테인 잔기로 치환된 돌연변이 트로포마이오신의 액틴친화력)

  • Kim, Don-Kyu;Cho, Young-Joon
    • Journal of Life Science
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    • v.19 no.5
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    • pp.573-580
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    • 2009
  • It has been previously reported that the carboxyl terminal residues 276 and 277 of ${\alpha}$-tropomyosin are important for actin affinity. In order to investigate actin affinities of these two residues of skeletal (HA) and smooth (QT) muscle ${\alpha}$-tropomyosins, a series of mutant tropomyosins were constructed in which residues at either 276 or 277 were individually replaced with a cysteine residue for chemical modification. These mutants were overexpressed in E. coli as unacetylated and Ala-Ser (AS) dipeptide fusion forms. While actin affinities of unacetylated tropomyosins were considerably low, those of AS/TMs were remarkably higher than those of corresponding unacetylated tropomyosins. However, actin affinities of AS/TM24 (QC) and AS/TM29 (HC) were dramatically lower than those of other AS/TMs and were close to those of unacetylated tropomyosins. In addition, actin affinities of unacetylated TM24 (QC) and TM29 (HC) failed to be restored in the presence of troponin, unlike unacetylated TM10 (HA) and TM23 (CA). These results indicated that the presence of a cysteine residue at 277 caused a drastic decrease in actin affinity, and also that the residue 277 is important for actin affinity of ${\alpha}$-tropomyosin. Since TM23 (CA) showed high actin affinity, it may serve as a valuable tool for chemical modification studies for investigating the interaction of the carboxyl terminal residues of ${\alpha}$-tropomyosin with actin and/or troponin.

Quality Characteristics of Potato and Sweet Potato Peeled by Different Methods (박피방법에 따른 감자 및 고구마의 초기 품질 비교)

  • Jeong Jin-Woong;Park Kee-Jai;Jeong Seong-Weon;Sung Jung-Min
    • Food Science and Preservation
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    • v.13 no.4
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    • pp.438-444
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    • 2006
  • This study was carried out to obtain fundamental data such as peeling efficiency and quality of potatoes and sweet potatoes peeled by hand, machine and alkali(NaOH). The weight loss by peeling was influenced by peeling methods. Weight losses by rotational brushing-type peeler showed the lowest value, 7.9% in potato, and 7.3% in sweet potato. Any significant differences in moisture content were not found in potatoes and sweet potatoes by peeling methods. The pH of potatoes and sweet potatoes just after peeling were 5.8-6.8 and 6.23-6.63, and decreased somewhat until 3 hrs after peeling. Hardness of potatoes and sweet potatoes peeled by hand with fruit knife were better than that of others. Depending upon the peeling method used the color and color differences undergo some changes in their color and browning. Color difference value of peeled potatoes by hand with a technical tools, and by mechanical peeler such as rotational cutting-type peeler and rotational brushing-type peeler showed just slightly. In particular, changes of rotor differences value of potatoes and sweet potatoes peeled by dipping with 10% NaOH solution at $100^{\circ}C$ was the highest in the samples peeled by NaOH.