• Title/Summary/Keyword: 화학의 해

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Utilization and Quantitative Analysis Method of Available Phosphorus in Soils for Nak-Dong Rice (낙동(洛東)벼의 토양중(土壤中) 유효인산(有效燐酸) 이용(利用)과 그 정량방법(定量方法))

  • Kim, Yong Joo;Kim, Jin Ho;Park, Woo Churl
    • Current Research on Agriculture and Life Sciences
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    • v.5
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    • pp.59-67
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    • 1987
  • The pot experiment was conducted using soils with varying contents of available phosphorus to select the reasonable method for determination of the available phosphorus content in soils for Nak-Dong rice cultivation. On a basis of the responses to the phosphorus tertilizer applied, the linear correlation coefficients by Bray No.1, Bray No.2, Lancaster, North Carolina and Olsen methods were 0.887, 0.868, 0.879, 0.952 and 0.911 for Nak-Dong rice yield, respectively. Of the methods tested, North Carolina method was the most suitable for determining, the phosphorus content in soils for Nak-Dong rice. The phosphorus application promoted the growth of Nak-Dong rice in pots for culm, tiller number, available stem and grain number per ear. Based on this experiment it could be presumed that the recommanded quantity of phosphorus fertilizer should attain to 5kg per 10a to promote the growth of Nak-Dong rice in A-soil and 10kg per 10a in B -, C - and D-soil. The results from the pot experiment will be somewhat different from those from the field experiment. Therefore, field experiment should be carried out for further information.

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The Survey of regional and seasonal characteristics of water quality in Nakdong river (낙동강 수계의 지역적.시기별 수질 특성 조사)

  • Kim, Joon-Keun;Kang, Sang-Jae;Seo, Sang-Hyun;Park, Woo-Churl
    • Current Research on Agriculture and Life Sciences
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    • v.16
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    • pp.75-83
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    • 1998
  • The purpose of this survey was to investigate the regional and seasonal characteristics of a water system and to obtain basic information of a water system at Andong bridge, Nakdan bridge, Kangjung, Waekwan bridge and Koryung bridge along Nakdong River. We surveyed the water quality in the Nakdong River for 2 years from Jan. 1996 to Dec. 1997. The results summarized were follows; 1) The pH in the Nakdong River on the basic of 2 years average were 6.5-8.6. 2) The DO, the COD and the BOD were low level in summer and high level in winter, respectively. 3) The suspended solids(SS) contents was high especially in summer. 4) The T-P and the T-N contents were higher than the lower level of nitrogen and phosphorous for algae growth and the contents were high especially in winter. 5) The $NH_4{^+}$-N and $NO_3{^-}$-N were also observed to be quite high.

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Petrology of the Cretaceous igneous rocks in Gadeog Island, Busan, Korea (부산 가덕도 지역 백악기 화성암류에 대한 암석학적 연구)

  • 고정선;김은희;윤성효
    • The Journal of the Petrological Society of Korea
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    • v.13 no.2
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    • pp.47-63
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    • 2004
  • This study focuses on the petrography and petrochemical characteristics of the volcanic and plutonic rocks in Gadeog island, Busan, Korea. Based on textural and mineralogical characteristics, intermediate volcanic rocks can be divided into andesitic lava flows (porphyritic and massive andesites) and andesitic pyroclastics. Felsic volcanic rocks are composed of rhyolite, rhyolitic welded tuff, and tuff breccia. Plutonic rocks are intruded rhyolite and andesitic rocks, and composed of hornblende granodiorite which contains lots of mafic magma enclaves. Volcanic rocks are composed of andesite, dacite and rhyolite having a range in SiO$_2$ from 59 to 78wt.%. The volcanic rocks belong to the calc-alkaline rock series. Plutonic rocks have a range in SiO$_2$ from 63 to 69wt.%. This compositional variations correspond to those of Cretaceous volcanic and plutonic rocks in the southeastern Gyeongsang basin. The trace element composition and rare earth element patterns of the volcanics, which are characterized by high LREE/HFSE ratios and enrichment in LREE, suggest that they are typical of calc-alkaline volcanic rocks produced in the subduction environment around continental arc. We concluded that volcanic and plutonic rocks in Gadeog Island were evolved from orogenic andesitic magma which was produced by partial melting of the mantle wedge in the subduction environment.

Analysis the Use of Concrete Fine Aggregates of Coal Gasification Slag (콘크리트용 잔골재로서 석탄가스화 용융슬래그(CGS)의 활용성 분석)

  • Park, Kyung-Taek;Han, Min-Cheol;Hyun, Seung-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.101-108
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    • 2019
  • This study is analysis of the utilization as a concrete fine aggregate on CGS, a by-product of Integrated coal gasification combined cycle(IGCC). That is, in KS F 2527 "Concrete aggregate," properties of 1~12times to CGS were evaluated, focusing on quality items corresponding to natural aggregate sand(NS) and melted slag aggregate sand(MS). As a result, the distribution of grain shape, safety and expansion were all satisfied with KS standards by physical properties, but the quality was unstable at 7~12times of water absorption ratio and absolute dry density. The particle size distribution was unstable due to asymmetry distribution of coarse particles, and particles were too thick for 7~12times. The passing ratio of 0.08mm sieve was also out of the KS standard at part factor of 7~12times, but chloride content, clay contents, coal and lignite were all satisfactory. Meanwhile, chemical composition was satisfactory except for $SO_3$ in 1~6times, and content and amount of harmful substances were all within the specified value except for F in 7~12times. As a result of SEM analysis, the surface quality and porosity were 7~12times more than 1~6times, and it was the quality was degraded. Therefore, it is necessary to reduce the quality deviation by using separate measures in order to utilize it as concrete aggregate in the future, and if it is premixed with fine quality aggregate, it will contribute positively to solve aggregate supply shortage and utilize circulation resources.

A Study on the Utilization of potential heat sources for Heat Pumps to District Heating System in Urban (도시 내 지역난방 Heat Pump용 잠재열원 이용에 관한 연구)

  • Oh, Kwang Min;Kim, Lae Hyun
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.841-855
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    • 2018
  • The purpose of this study is to estimate the available potential heat source for heat pump in the district heating supply area in the city. Unused energy potentials were estimated and integrated based on open source based data. In particular, geographical spatial analysis of recoverable heat energy density and heat demand in the heat source area of large retailers and public sauna facilities in the DH network located in the southern part of the metropolitan area (Pyeongtaek-si) was conducted. As a result of the study, the DH network area had a total potential energy of 1,741.7 toe/year for the two heat sources of large retailers and public saunas. It is estimated that 1,006.9 toe/year, which is 57.8% of the total, can be linked to the district heating. The large retailers showed a positive correlation with the floor area and energy use of 0.4937. The recoverable energy intensity was estimated to be $0.0017toe/m^2$ per unit area and $0.0069tCO_2/m^2$ for greenhouse gas emissions. In addition, public saunas were analyzed by comparing the empirical case with the theoretical calculation, and it was estimated that energy conservation estimate of 80% was $0.0315toe/m^2$ per bath area and $0.1183tCO_2/m^2$ for greenhouse gas emissions. The total potential energy amount of this area was positively correlated with the heat demand of apartment house by administrative district, and it was confirmed that it had a relatively high potential energy especially in traffic and commercial center.

The Research of Layout Optimization for LNG Liquefaction Plant to Save the Capital Expenditures (LNG 액화 플랜트 배치 최적화를 통한 투자비 절감에 관한 연구)

  • Yang, Jin Seok;Lee, Chang Jun
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.51-57
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    • 2019
  • A plant layout problem has a large impact on the overall construction cost of a plant. When determining a plant layout, various constraints associating with safety, environment, sufficient maintenance area, passages for workers, etc have to be considered together. In general plant layout problems, the main goal is to minimize the length of piping connecting equipments as satisfying various constraints. Since the process may suffer from the heat and friction loss, the piping length between equipments should be shorter. This problem can be represented by the mathematical formulation and the optimal solutions can be investigated by an optimization solver. General researches have overlooked many constraints such as maintenance spaces and safety distances between equipments. And, previous researches have tested benchmark processes. What the lack of general researches is that there is no realistic comparison. In this study, the plant layout of a real industrial C3MR (Propane precooling Mixed Refrigerant) process is studied. A MILP (Mixed Integer Linear Programming) including various constraints is developed. To avoid the violation of constraints, penalty functions are introduced. However, conventional optimization solvers handling the derivatives of an objective functions can not solve this problem due to the complexities of equations. Therefore, the PSO (Particle Swarm Optimization), which investigate an optimal solutions without differential equations, is selected to solve this problem. The results show that a proposed method contributes to saving the capital expenditures.

Material Properties of Soil and Potteries Excavated From Ra-No.19 Site of Pung-nap Mudcastle (풍납토성 라-19호 출토 토양과 토기의 재료학적 특성)

  • Heo, Jun Su;Kim, Jo Yoon;Han, Ji Sun;Kim, Su Kyoung;Lee, Han Hyoung;Moon, Eun Jung;Yoo, Young Mi;Han, Min Su;Seo, Min Seok
    • Korean Journal of Heritage: History & Science
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    • v.45 no.3
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    • pp.194-211
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    • 2012
  • Pung-nap mudcastle has brought wide attention to archaeologists since scientific studies were carried out on the various types of building sites and excavated potteries related to A period of Baekje Kindom when it sat Hansung as the capital. It is identified that clay from Ra-No.19 site of Pung-Nap mudcastle has different from compositions that of residential soil. From archaeological point of view, it is believed that the the soil was a source material for potteries due to the appropriate viscosity and inclusions. Mineralogical and geochemical studies show that the compositions between the source material and randomly chosen two potteries from the same site are similar. Behavior pattern classification of major, trace and rare elements provides also very similar result. Artificial specimen has been made at different temperature in order to estimate firing temperature of the potteries by means of various kinds of instrumental application. As a result of the study, it is believed that the firing temperature of the red and brown pottery was $550{\sim}600^{\circ}C$ and $900{\sim}1,000^{\circ}C$ respectively.

Analysis of the Performance of the Employment Support Field by the Government Specialization Project (정부 특성화 사업에 따른 취업지원분야 사업성과 분석)

  • Kim, Hak Yong
    • Journal of Industrial Convergence
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    • v.17 no.2
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    • pp.29-34
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    • 2019
  • The purpose of this study is to analyze the achievements of employment support by the government support specialization project. The data used in this study are based on the comparison of 5 - year employment support field and the operation results of the program until 2014-2018. The results of the study are as follows. First, the overall employment rate of the university has been continuously increased. Especially, the employment rate of the specialization department has been higher than the employment rate of the non - specialization department. Second, as a result of the analysis of the employment capacity strengthening index and the learning capacity strengthening index, it showed a steady increase in each year and contributed to the cultivation of customized talents required by the local society and the national industry. Third, as a result of analyzing the satisfaction of students who are business users, it was confirmed that the business reflecting the demands of the consumers was realized. Fourth, the continuous improvement of the business and the reflux have made the infrastructure of the employment support project more advanced and the system of supporting employment of the university systematically established. In conclusion, the result of the employment support project according to the specialization program showed excellent results and it is necessary to complement theses results when establishing related business plan in the future.

Assessment of Damage for the Three­Storied Stone Pagoda of Bulguksa Temple in Gyeongju (경주 불국사 삼층석탑(석가탑)의 손상도 평가)

  • Lee, Gemma
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.9
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    • pp.299-305
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    • 2019
  • As the damage factors of the three­storey stone pagoda of the Bulguksa Temple in Gyeongju could cause a reduction in the historical and artistic value and accelerate the deterioration of the stone, an appropriate solution is needed. The aim of stone conservation is to conserve the original shape and convey originality from the ancestors to their descendants. This procedure includes a record of the condition, being available in the future. In particular, the damage assessment could be used in conservational research, educational data, conservational treatment, and preventive data. As a result of quantitative damage assessment, biological damage indicated 159 %, chemical damage 114 %, and physical damage 16 %. The west direction revealed 95 % because of the amount of sunshine, moisture, and expansion of rock. Complex factors and high range damage were observed on the foundation and body of the pagoda. Since the top of pagoda was restored in the 1970s, the state presented a good condition. By doing this, the number of organisms could be reduced by cleaning and the physical damage could be minimized by bonding. On the other hand, continuous monitoring will be needed because there is a possibility of reforming the damage in the future.

Adsorption Characteristics of Brilliant Green by Coconut Based Activated Carbon : Equilibrium, Kinetic and Thermodynamic Parameter Studies (야자계 입상 활성탄에 의한 brilliant green의 흡착 특성 : 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.25 no.3
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    • pp.198-205
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    • 2019
  • The adsorption equilibrium, kinetic, and thermodynamic parameters of brilliant green adsorbed by coconut based granular activated carbon were determined from various initial concentrations ($300{\sim}500mg\;L^{-1}$), contact time (1 ~ 12 h), and adsorption temperature (303 ~ 323 K) through batch experiments. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Harkins-Jura, and Elovich isotherm models. The estimated Langmuir dimensionless separation factor ($R_L=0.018{\sim}0.040$) and Freundlich constant ($n^{-1}=0.176{\sim}0.206$) show that adsorption of brilliant green by activated carbon is an effective treatment process. Adsorption heat constants ($B=12.43{\sim}17.15J\;mol^{-1}$) estimated by the Temkin equation corresponded to physical adsorption. The isothermal parameter ($A_{HJ}$) by the Harkins-Jura equation showed that the heterogeneous pore distribution increased with increasing temperature. The maximum adsorption capacity by the Elovich equation was found to be much smaller than the experimental value. The adsorption process was best described by the pseudo second order model, and intraparticle diffusion was a rate limiting step in the adsorption process. The intraparticle diffusion rate constant increased because the dye activity increased with increases in the initial concentration. Also, as the initial concentration increased, the influence of the boundary layer also increased. Negative Gibbs free energy ($-10.3{\sim}-11.4kJ\;mol^{-1}$), positive enthalpy change ($18.63kJ\;mol^{-1}$), and activation energy ($26.28kJ\;mol^{-1}$) indicate respectively that the adsorption process is spontaneous, endothermic, and physical adsorption.