• Title/Summary/Keyword: 화학설

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A Study on the Formation of Hydrous Ferric Oxide from Ferrous Sulfate (黃酸第一鐵로부터 含水酸化鐵生成에 關한 硏究)

  • Sung Joo Kyung;Suhl Soo Duk;Whang Yong Kil
    • Journal of the Korean Chemical Society
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    • v.19 no.2
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    • pp.142-146
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    • 1975
  • The formation of iron oxide hydroxide in a ferrous sulfate was studied in different contents of iron in the solution at a temperature range of 90 to $100^{\circ}C$ under 1${\sim}$3 atmospheres. The Mohr's salt thus formed was hydrolyzed under 1 to 3 atmospheres, in 14 to 72 g/l of iron content in the solution pH 3 or 6 for two hours at 90 to $100^{\circ}C$. The results obtained was as follows; 1) In Mohr's salt solution, as the iron content was increased, with decreasing the concentration of hydrogen ion, the yield of iron oxide hydroxide was gradually increased. 2) When iron content in Mohr's salt solution was 42.81 g/l, 91.5% of iron was recovered in the form of $\alpha$-goethite similar to yellow grade of natural goethite. 3) When $\alpha$-goethite obtained was calcined of $500^{\circ}C$, it was turned into ${\alpha}$-ferric oxide with a redish brown colour.

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A Study on Accident Response Guidelines for Hazardous Materials(HAZMAT) Transport Vehicle (유해화학물질 수송용 차량의 사고 대응 가이드라인에 관한 연구)

  • Seol, Ji Woo;Yong, Jong Won;Chae, Chung-Keun;Tae, Chan Ho;Ko, Jae Wook
    • Journal of the Korean Institute of Gas
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    • v.19 no.5
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    • pp.87-97
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    • 2015
  • Accidents of HAZMAT transport vehicle are generally dealt by unskilled firefighters. As a result, firefighters became 2nd victims of accidents in some case because of this reason, and it is required to prepare an accident response guidelines against HAZMAT transport vehicle accidents. In this study, risk assessment methods and making methods of guidelines were investigated to make accident response guidelines of HAZMAT transport vehicle accidents. and It identifies hazards and combines with guideword for making guideline items. At last, we determine criteria or detailed methods by referring survey regulations and existed methods.

Study on the Vanadium Redox Flow Battery using Cation Exchange Membrane and Ammonium Metavanadate (메타바나듐산암모늄과 양이온교환막을 활용한 바나듐 레독스 흐름전지에 관한 연구)

  • Jung, Bo-Young;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.31 no.4
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    • pp.262-267
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    • 2021
  • The electrochemical performance of all vanadium redox flow battery (VRFB) using an electrolyte prepared from ammonium metavanadate and a cation exchange membrane (Nafion117) was evaluated. The electrochemical performance of VRFB was measured at a current density of 60 mA/cm2. The average current efficiency of VRFB using the electrolyte prepared from ammonium metavanadate was 94.9%, the average voltage efficiency was 82.2%, and the average energy efficiency was 78.0%. In addition, it was confirmed that the efficiencies of VRFB using the electrolyte prepared from ammonium metavanadate had almost the same value as the efficiencies of VRFB using the electrolyte prepared with vanadyl sulfate (VOSO4).

The development of PEMFC cathode using polyol method with directly grown CNT on carbon paper (Carbon paper에 직접적으로 생산한 CNT를 polyol 방법으로 Pt deposition하여 PEMFC cathode 개발)

  • Ok, Jinhee;Altalsukh, Dorjgotov;Rhee, Junki;Park, Sangsun;Shul, Yonggun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.84.1-84.1
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    • 2010
  • Since the discovery of the carbon nanotube(CNTs), they have attracted much attention because of unique properties that may impact many fields of science and technology. The considerable properties of CNTs include high surface area, outstanding thermal, electrical conductivity and mechanical stability. However, uniform deposition of Pt nanoparticles on carbon surface remains inaccessible territory because of the inert carbon surface. In this study, we prepared directly oriented CNTs on carbon paper as a catalyst support in cathode electrode. carbon surface was functionalized using aryl diazonium salt for increasing adhesion of Ni particles which is precursor for growing CNTs. For fabricate electrode, CNTs on carbon paper were grown by chemical vapor deposition using Ni catalyst and Pt nanoparticles were deposited on CNTs oriented carbon paper by polyol method. The performance was measured using Proton electrolyte Membrane Fuel Cell(PEMFC). The structure and morphology of the Pt nanoparticles on CNTs were characterized by Scanning electron Microscopy(SEM) and Transmission electron Microscopy (TEM). The average diameter of Pt nanoparticles was 3nm.

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The performance evaluation of the separator for PEMFCs (고분자 전해질막 연료전지 분리판 성능평가)

  • Hwang Ho-Jung;Yang Tae-Hyun;Yoon Young-Gi;Lee Won-Yong;Shul Yong-Gun;Kim Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.288-290
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    • 2005
  • 고분자전해질 연료전지는 자동차, 분산전원 및 이동전원 등에 대한 차세대 에너지원으로 채택 가능성이 높아지고 있다. 고분자전해질 연료전지 시스템의 상용화를 위한 가장 큰 걸림돌 중 한 가지로 가격문제를 들 수 있는데, 연료전지 스택이 전체 가격의 약 $50\%$를 차지하고 있다. 또한 스택을 구성하는 요소 중 분리판의 가격 비중은 약 $30\%$를 차지하고 있어, 분리판의 생산단가 저감은 연료전지의 상용화를 위해 반드시 해결해야 될 문제이다. 본 연구에서는 탄소를 재료로 하는 분리판에 대한 연구를 수행하였으며, 압축성형방식으로 제작된 다양한 복합재료 분리판 및 흑연 분리판에 대한 기계적 강도, 물리적 특성, 화학적 안정성을 조사하였으며, 가흑 운전 시 분리판내에 함유되어있는 고분자 성분의 침출에 의한 연료전지의 성능변화가 발생하는지 확인하였으며 이에 대한 단위전지의 성능평가를 수행하였다. 이러한 결과를 토대로 최적의 압축성형 복합체 분리판 제작 방향을 제시하고, 보다 신뢰성 있는 분리판 성능평가 기준을 확립하고자 하였다.

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Knowledge of Modern housing of the Textbooks for Physiology and Hygiene in Korea 1894-1910 (생리 및 위생분야 교과용도서의 근대적 주거지식(1894-1910))

  • Kim, Myung-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.5
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    • pp.1328-1333
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    • 2008
  • The new knowledge in the textbooks for Physiology and Hygiene in Korea 1905-1910 was focused on the problems of hygiene. Lighting, ventilation, dryness were proposed as main conditions fer hygienic housing, for which management and planning methods were explained. This knowledge was taught as 'scientific' or 'modern' knowledge based on the physiological theory and air property, thereafter the conditions were placed as important conditions of modern housing.

Biochar for soil carbon sequestration (토양탄소격리를 위한 바이오차)

  • Woo, Seung Han
    • Clean Technology
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    • v.19 no.3
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    • pp.201-211
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    • 2013
  • Biochar is charred materials generated during pyrolysis processes in the absence of oxygen using biomass, resulting in high carbon contents. In recent years, biochar has attracted more increasingly due to its potential role in carbon sequestration, renewable energy, waste management, soil amendment for agricultural use, and environmental remediation. Since biochar has a long-term stability in soil for thousands of years, biochar can be carbon negative compared to carbon-neutral biomass energy that decomposes eventually. Moreover, when biochar is applied to soil, crop production can be largely improved due to its high pH and its superior ability to retain water and nutrients. This paper review the research trends of biochar including the principles of carbon sequestration by biochar, its physico-chemical properties, and its applications on agricultural and environmental area.

Reaction Kinetics of Carbon Dioxide and Glycidyl Methacrylate using a Ionic Liquid Catalyst of Imidazole Immobilized on MCM41 (MCM41에 담지된 Imidazole 촉매에 의한 Glycidyl Methacrylate와 이산화탄소의 반응속도론)

  • Son, Young-Sik;Park, Moon-Ki;Kim, Gun-Woo;Park, Sang-Wook
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.410-417
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    • 2009
  • Carbon dioxide was absorbed into GMA solution in a stirred flat cell using mesoporous catalyst Imidazole-CP-MS41, which was synthesized by CP-MCM41 with imidazole. Experiments were carried out at a batch-type absorber with different conditions, varying reaction temperature, concentration of GMA, solvent but maintaining 50 rpm of agitation speed and 2 g of catalyst. Absorption rate of $CO_2$ was used to obtain the kinetics based on the film theory using zwitterion mechanism with 2 elementary reaction and the kinetics were correlated with the solubility parameter of the solvents.

The design and Manufacture of Laser Induced Fluorescence Spectroscope Using the High Resolution Charge Coupled Device (고정밀 전하결합장치를 이용한 레이저유도 형광분광기의 설계 및 제작)

  • Kim, Ki-Jun;Lee, Hoo-Seol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.2
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    • pp.129-133
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    • 2005
  • It is very important to use the charge coupled devices (CCDs) in spectrometry because we can study the molecular energy level, molecular structure, absorption or emission, intermolecular reaction, weakly bound molecular energy, photochemistry, fluorescence and photodynamic therapy (PDT). CCD is very essential to study the molecular structure and medical engineering combining laser spectroscopy in the modem physicsal and chemistry. Therefore, this study has designed and manufactured the electromagnetic spectrometry with CCD and then analyzed the printed electronic circuit. In the yesterday, CCD was thought to be used in only broadcasting system. But nowadays, it is used by industrial demand in observations, instrumentations and robotics as the industry develop.

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A Performance characteristics of Pt/C Electrode prepared by Hot Pressing Method (Hot Pressing법에 의해 제조된 Pt/C 전극의 성능특성)

  • 김진수;서동우;설용건;이태희
    • Journal of Energy Engineering
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    • v.1 no.1
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    • pp.58-65
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    • 1992
  • Pt loaded porous carbon Pt/C electrode was prepared by hot pressing process to enhance the electrode performance in PAFC (phosphoric acid fuel cell). By changing the hot pressing conditions and PTFE contents, Pt/C electrodes were prepared and the electrochemical characteristics of oxygen reduction and unit-cell performance were evaluated. The optimum condition of hot press to make electrode is 360$^{\circ}C$ and 10 kg/$\textrm{cm}^2$. Maximum performance was obtained at 30 wt% PTFE content in the catalyst layer with 80% utilization of platinum clusters. Unit-cell performance of hot pressed Pt/C electrode was 200 mA/$\textrm{cm}^2$ at 700 ㎷ and stable performance was maintained more than 200 hr.

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