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Reaction Kinetics of Carbon Dioxide and Glycidyl Methacrylate using a Ionic Liquid Catalyst of Imidazole Immobilized on MCM41  

Son, Young-Sik (Division of Chemical Engineering, Pusan National University)
Park, Moon-Ki (Department of Pharmaceutical Engineering, Daegu Haany University)
Kim, Gun-Woo (Business Environment Improvement Division, Busan-Ulsan Regional Office of Small and Medium Business Administration)
Park, Sang-Wook (Division of Chemical Engineering, Pusan National University)
Publication Information
Korean Chemical Engineering Research / v.47, no.4, 2009 , pp. 410-417 More about this Journal
Abstract
Carbon dioxide was absorbed into GMA solution in a stirred flat cell using mesoporous catalyst Imidazole-CP-MS41, which was synthesized by CP-MCM41 with imidazole. Experiments were carried out at a batch-type absorber with different conditions, varying reaction temperature, concentration of GMA, solvent but maintaining 50 rpm of agitation speed and 2 g of catalyst. Absorption rate of $CO_2$ was used to obtain the kinetics based on the film theory using zwitterion mechanism with 2 elementary reaction and the kinetics were correlated with the solubility parameter of the solvents.
Keywords
Imidazole; Carbon Dioxide; Absorption; Ionic Liquid;
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Times Cited By KSCI : 3  (Citation Analysis)
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