• Journal of the Korea Organic Resources Recycling Association
• /
• v.23 no.4
• /
• pp.86-94
• /
• 2015

Torrefaction is a thermochemical process proceeded at the temperature around $250^{\circ}C$ in an inert gas condition. By torrefaction, the hemicellulose portions contained in biomass are broken down to change into the volatile gas which is removed from biomass eventually. The main purpose of biomass torrefaction is to improve the energy density of the biomass to minimize the transport energy consumption, though the flammability can be elevated for transportation. In this study two types of solid biomass fuel, waste wood and rice straw, were torrefied at various temperature range from $200^{\circ}C$ to $300^{\circ}C$ to evaluate the torrefied biomass characteristics. In addition torrefied biomass were tested to evaluate the combustion characteristics using TGA (Thermogravimetric Analysis). After the torrefaction of biomass, the C/H (carbon to hydrogen ratio) and C/O (carbon to oxygen ratio) were measured for aquisition of bio-stability as well as combustion pattern. Generally C/H ratio implies the soot formation during combustion, and the C/O ratio for bio-stability. By torrefaction temperature at $300^{\circ}C$, C/H ratio and C/O ratio were increased by two times for C/H and three times for C/O. The torrefied biomass showed similar TGA pattern to coal compared to pure biomass; that is, less mass decrease at lower temperature range for torrefied biomass than the pure biomass.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.26 no.1
• /
• pp.22-30
• /
• 2020

In March 2016, a 6.67-ton fishing boat capsized owing to the loss of stability during crane operations. Capsizing occurs when a boat or ship is flipped over (or turned upside down) for reason other than accidents caused by collisions, contact, stranding, fire or explosion. Over the past nine years (2010-2018), capsize accidents have accounted for 2.34 % of all marine accidents and are gradually increasing. The loss of stability from improper shipping is the main cause of most capsizes, especially for small fishing vessels weighing 10 tons. According to the Fishing Vessel Act, small fishing vessels weighing less than a ton are exempted from inspections on stability and load cranes. This study analyzes the issue cited as the reason for the capsizing of the small fishing boat in Goseong, namely, the reduction of restoring moment due to increased weight of the crane. Fishing boats with similar loading conditions were modeled on the basis of re-determination, and their stability before and after the accident was assumed. The fishing boats with heavier cranes were found to be at higher risk of capsizing owing to the reduction of the restoring moment and the angle of deck immersion. Under standard loading conditions, the stability moments of fishing vessels are lesser during fishing, compared to when they depart from or arrive at the port.

• Korean Chemical Engineering Research
• /
• v.46 no.2
• /
• pp.376-382
• /
• 2008

There are many accidents such as fire and explosion in laboratories that have caused a great loss to lives and property in spite of the effort to the enhancement of laboratory safety level for years. Development of laboratory safety management system is a necessary to improve safety level because the accidents of similar types have periodically occurred in laboratories. The laboratory safety management system may reduce many accidents and a serious loss in laboratory. In this study, we summarized major items for a risk management and safety improvement based on the analysis results of various accidents in the laboratories. And then the laboratory safety management system was developed containing a laboratory safety management manual, a laboratory management system, a education management system, a MSDS (material safety data sheet) management system and a laboratory safety audit system. It may have a potential application for the laboratory safety management in the chemical laboratories.

• Korean Chemical Engineering Research
• /
• v.48 no.6
• /
• pp.717-724
• /
• 2010

The flash point is one of the most important physical properties used to determine the potential for fire and explosion hazards of flammable liquids. Despite the needs of the experimental flash point data for the design and construction of chemical plants, there is often a significant gap between the demands for the data and their availability. This study have built and compared two models of partial least squares(PLS) and support vector machine(SVM) to predict the experimental flash points of 893 organic compounds out of DIPPR 801. As the independent variables of the models, 65 functional groups were chosen based on the group contribution method that was oriented from the assumption that each fragment of a molecule contributes a certain amount to the value of its physical property, and the logarithm of molecular weight was added. The prediction errors calculated from cross-validation were employed to determine the optimal parameters of two models. And, an optimization technique should be used to get three parameters of SVM model. This work adopted particle swarm optimization that is one of heuristic optimization methods. As the selection of training data can affect the prediction performance, 100 data sets of randomly selected data were generated and tested. The PLS and SVM results of the average absolute errors for the whole data range from 13.86 K to 14.55 K and 7.44 K to 10.26 K, respectively, indicating that the predictive ability of the SVM is much superior than PLS.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.27 no.2
• /
• pp.71-78
• /
• 2014

There is a big risk of bullet impact because military rotorcraft is run in the battle environment. Due to the bullet impact, the rapid increase of the internal pressure can cause the internal explosion or fire of fuel cell. It can be a deadly damage on the survivability of crews. Then, fuel cell of military rotorcraft should be designed taking into account the extreme situation. As the design factor of fuel cell, the internal fluid pressure, structural stress and bullet kinetic energy can be considered. The verification test by real object is the best way to obtain these design data. But, it is a big burden due to huge cost and long-term preparation efforts and the failure of verification test can result in serious delay of a entire development plan. Thus, at the early design stage, the various numerical simulations test is needed to reduce the risk of trial-and-error together with prediction of the design data. In the present study, the bullet impact numerical simulation based on SPH(smoothed particle hydrodynamic) is conducted with the commercial package, LS-DYNA. Then, the resulting equivalent stress, internal pressure and bullet's kinetic energy are evaluated in detail to examine the possibility to obtain the configuration design data of the fuel cell.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.23 no.2
• /
• pp.168-176
• /
• 2017

HNS accidents involve large-scale fires and explosions, causing numerous human casualties and extreme environmental pollution in the surrounding area. The widespread diffusion of effects should be prevented through rapid decision making. In this study, a high-quality, standardized, and digitized HNS accident databases has been generated based on the HNS standard code proposed. Furthermore, the HNS Accident Tracking System (HATS) was applied and implemented to allow for systematic integration management and sharing. In addition, statistical analysis was performed on 76 cases of domestic HNS accident data collected over 23 years using HATS. In Korea, an average of 3.3 HNS accidents occurred each year and major HNS accident factors were Springs (41 %), Aprons (51 %), Chemical Carriers (49 %), Crew's Fault (45 %) and Xylenes (12 %). (The number in parentheses is the percentage of HNS accident factors for each HNS accident classification)

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.25 no.7
• /
• pp.936-944
• /
• 2019

Submarines, which have been called an invisible force, are strategic underwater weapon systems that perform missions such as anti-surface warfare, anti-submarine warfare, and high payoff target strikes with the advantage of underwater covertness. A submarine should be able to withstand the hydrostatic pressure of the deep sea. In this respect, the submarine pressure hull, as the main structural system to resist the external pressure corresponding to the submerged depth, should ensure the survivability from hazards and threats such as leakage, fires, shock, explosion, etc. To do this, the initial scantling of the submarine pressure hull must be calculated appropriately in the concept design phase. The shape of the aft transition ring varies according to its connection with the submarine aft end conical structure, pressure hull cylindrical part, and non-pressure hull of the submarine; the design of the aft transition ring should not only take into account stress flow and connectivity but also the cost increase due to the increased man-hours of its complex geometry. Therefore, trade-off studies based on the four different shapes of the aft transition ring are carried out considering both the review of the structural strength through nonlinear finite element analysis (FEA) and economic feasibility by reviewing the estimations of the manufacturing working days and material costs. Finally, the most rational structural aft transition ring shape for a submarine amongst four reviewed types was proposed.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.30 no.2
• /
• pp.165-175
• /
• 2024

Hydrogen is being touted as one of the energy sources to combat the climate change crisis. However, hydrogen can leak into enclosed spaces, rise to the ceiling, accumulate, and cause fires and explosions if it encounters an ignition source. In particular, ships that transport hydrogen or use it as a fuel comprise multiple enclosed spaces. Therefore, the dif usion characteristics within these spaces must be understood to ensure the safe use of hydrogen. The purpose of this study is to experimentally determine the diffusion characteristics of helium, which has similar properties to hydrogen, in a closed space on board a ship, and to determine the change in the oxygen concentration along the leakage direction as the air change per hour(ACH) increases to 25, 30, 35, 40, and 45 through CFD simulation. The study, results revealed that the oxygen concentration reduction rate was 2% for leakage in the -z direction and 1% for leakage in the +x and +z directions, and the ventilation time was 15 min 30 s for leakage in the -z direction, 7 min for leakage in the +x direction, and 9 min for leakage in the +z direction, showing that differences existed in the oxygen concentration and ventilation time depending on the leakage direction. In addition, no significant difference was observed in the rate of oxygen concentration reduction and ventilation time in all leakage directions from the ACH of 35 and above in the experimental space. Therefore, because the oxygen concentration and ventilation time were not improved by increasing the ACH, 35 was noted as the optimal ACH in this experimental environment.

• Journal of Science Education
• /
• v.34 no.2
• /
• pp.291-305
• /
• 2010

The aim of this study was to survey the perceptions of the elementary school teachers on the smallscale chemistry(SSC) following its training session. The teachers participating in the survey were 266 teachers in the Gyeongnam province. They were given a questionnaire that focused on the nine areas of the SSC: Needs for the teacher training and its application, its benefits, issues of safety and danger as well as treatment of environmental pollution, its economic efficiency and the development of investigative skills. The designed questionnaire was checked by an authority, and the responses to each question were tallied and analyzed. The results are as follows. The biggest problems of the traditional experimental methods as rated by the teachers were, in the order of importance, the preparation time, the legal liability of teachers for the safety and accidents, financial issues, disposal of the experimental wastes and the lack of relevant data. Since most of the teachers had not experienced the SSC lab programs in the field, they responded positively to the questions of need for its introduction and training. The implementation of the experimental SSC lab programs should proceed in the following order: introduction into the textbook, teacher training program, after-school education and the invitation of instructors. The most useful materials for the SSC program were CDs, videos, books and various printed materials, in that order. The responses regarding benefits of the SSC program included its simplicity, convenience, time savings, diversity, qualitative and quantitative aspects, integration into the regular class and use of toys. In particular, the teachers mentioned the increased safety due to the small amount of experimental reagents needed and the durability of plastic instruments. The familarity from the use of everyday tools as well as easy access to and the low-cost of the instruments were other important benefits. The teachers in general rated the educational content of the program highly, but many also found it to be average. Some pointed out the lack of sufficient discussion due to the individual or pair groupings as a potential shortcoming. The potential for development of problem solving ability and improvement of skills was rated positively. The number of teacher who rated the development of creativity positively was just over the half. As for the area of improving investigative skills, many found its assessment difficult and confusing because of the lack of its systemic definition and categorization. Based on the findings of this study, I would like to recommend the application and a wider dissemination of the small-scale chemistry lab program into the elementary school science curriculum.