• Title/Summary/Keyword: 혼합속도

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Effect of Zine Oxide Size and Oxygen Pressure on the Magnetic Properties of (Ni, Zn) Ferrite Powders Prepared by Self-propagating High Temperature Synthesis (ZnO의 입도와 산소압이 고온연소합성법으로 제조된 Ni-Zn Ferrite 분말의 자기적 특성에 미치는 영향)

  • Choi, Yong;Cho, Nam-Ihn;Hahn, Y.D.
    • Journal of the Korean Magnetics Society
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    • v.9 no.2
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    • pp.78-84
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    • 1999
  • $(Ni, Zn)Fe_2O_4$ powders were prepared through self-propagating high temperature synthesis reaction and the effects of initial zinc oxide powder size and oxygen pressure on the magnetic properties of the final combustion products were studied. The ferrite powders were combustion synthesized with iron, iron oxide, nickel oxide, and zinc oxide powders under various oxygen pressures of 0.5~10 atmosphere after blended in n-hexane solution for 5 minutes with a spex mill, followed by dried at 120 $^{\circ}C$ in vacuum for 24 hours. The maximum combustion temperature and propagating rate were about 1250 $^{\circ}C$ and 9.8 mm/sec under the tap density, which were decreased with decreasing ZnO size and oxygen pressure. The final product had porous microstructure with spinel peaks in X-ray spectra. As the ZnO particle size in the reactant powders and oxygen pressure during the combustion reaction increase, coercive force, maximum magnetization, residual magnetization, squareness ratio were changed from 1324 Oe, 43.88 emu/g, 1.27 emu/g, 0.00034 emu/gOe, 37.8$^{\circ}C$ to 11.83 Oe, 68.87 emu/g, 1.23 emu/g, 0.00280 emu/gOe, 43.9 $^{\circ}C$ and 7.99 Oe, 75.84 emu/g, 0.791 emu/g, 0.001937 emu/gOe, 53.8 $^{\circ}C$ respectively. Considering the apparent activation energy changes with oxygen pressure, the combustion reaction significantly depended on initial oxygen pressure and ZnO particle size.

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Absorption Characteristics of Carbon Dioxide by Water-lean Diethylenetriamine Absorbents Mixed with Physical Solvents (물리 흡수제를 포함한 디에틸렌트리아민(Diethylenetriamine) 저수계 흡수제에서의 이산화탄소 흡수 특성)

  • Lee, Hwa Young;Seok, Chang Hwan;You, Jong-Kyun;Hong, Yeon Ki
    • Clean Technology
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    • v.24 no.1
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    • pp.50-54
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    • 2018
  • In this work, N-methyl-2-pyrrolidone (NMP) was added into diethylenetriamine (DETA) aqueous solution for high $CO_2$ loading via phase splitting of absorbents during $CO_2$ absorption. Immiscible two phases were formed in the range of more than 30 wt% of NMP in 2 M DETA + NMP + water absorbents because of low solubility of DETA-carbamate in NMP solution. As the composition of NMP in the absorbents increased, the difference of $CO_2$ loading between each phase increased and the volume of bottom phase decreased. In $CO_2$ absorption in packed column by 2 M DETA + NMP + water absorbents, the absorption rate decreased in the range of more than 40 wt% of NMP. It is due to the increasing of mass transfer resistance in liquid film of absorbents at the high concentration of NMP. DETA + NMP + water absorbent is expected as the promising one for reducing the regeneration energy of absorbents according to volume reduction of $CO_2-rich$ phase.

A Study on Capillary Gas-Liquid Chromatographic Determination of Diosgenin in Costus Speciosus (모세관 기체-액체 크로마토그래피에 의한 Costus Speciosus 중 Diosgenin의 정량에 관한 연구)

  • Taek Jae Kim;Cha Kee Surk;Kim Young Sang
    • Journal of the Korean Chemical Society
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    • v.30 no.4
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    • pp.369-376
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    • 1986
  • Diosgenin in an Indonesian Costus speciosus was determined by capillary gas-liquid chromatography (GLC). The experimental conditions for the hydrolysis, extraction and acetylation of the diosgenin, and the determination by GLC were investigated. 0.20g of dried sample powder was refluxed in the solution of 3N HCI and xylene at 95∼100${\circ}C$ for 4 hours and the xylene layer was separated. The residue evaporated the xylene was refluxed in 20 : 80 acetic anhydride-pyridine for 30 minutes and the diosgenin acetate was extracted with diethyl ether. Dehydrated with anhydrous $Na_2SO_4$ and evaporated the ether, the residue was dissolved in 5.00ml of n-hexane and injected into GLC. Capillary column of SE-30 25m ${\times}$ 0. 33mm was installed in GLC and the column temperature was increased from 180${\circ}$ to 270${\circ}C$ at rate of 10${\circ}C$/min. The flow rate of carrier gas $N_2$ was 2ml/min and FID was used to detect. The analytical result of the diosgenin was 0.281% and relative standard deviation of 5 measures was 1.8%.

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A Study on the Hydrolysis of p-Nitrophenyl Carboxylates by Micellar Surfactants Catalysts Involving Histidyl Residue (히스티딜기등을 포함하는 미셀성 계면활성제를 촉매로 사용한 파라니트로페닐 에스테르의 가수분해반응에 관한 연구)

  • Won Fae Koo;Choon Pyo Hong
    • Journal of the Korean Chemical Society
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    • v.33 no.1
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    • pp.3-10
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    • 1989
  • In order to obtain a clue in understanding enzymatic hydrolysis in which the His-Cys moieties of papain protease is involved, we prepared cationic peptide-sufactants bearing histidyl, cysteinyl, and both histydyl and cysteinyl residues. Their catalytic efficiency toward the hydrolysis of PNPL were investigated in comicellar phases formed with $N^{+}C_{2}CysC_{12}$, $N^{+}C_{2}HisC_{12}$, $N^{+}C_{2}HisCysC_{12}$ increased markedly in the same order compared with that of $N^{+}C_{2}AlaC_{12}$. The markedly increased catalytic effects are attributed to the imidazole groups of $N^{+}C_{2}HisC_{12}$ and the thiol groups of $N^{+}C_{2}CysC_{12}$, and the large catalytic efficiency of $N^{+}C_{2}HisCysC_{12}$, is considered due to the interaction of the imidazole and the thiol groups. In order to investigate catalytic activities, rate constants for the functional groups, km* and dissociation constants, pKa have been determined. The results showed that $k^{\ast}_m$ and pKa of the imidazole groups were $7.91{\times}10^{-4}S^{-1}$ and 6.49, and those of the thiol groups were $6.00{\times}10^{-4}S^{-1}$ and 10.50. The catalytic effects of comicellar systems on the hydrolysis of p-nitrophenyl esters has increased according to the increasing size of the alkyl carbon number. Therefore, the catalytic effects have been increasing by the interaction of micellar hydrophobic parts and substrates as well as action of the functional groups.

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Development of an Unmanned Conveyor Belt Recovery Skimmer for Floating Marine Debris and High Viscosity Oil (무인 컨베이어 벨트식 부유쓰레기 및 고점도유 회수장비 개발 연구)

  • Han, Sang-goo;Lee, Won-ju;Jang, Se-hyun;Choi, Jae-hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.2
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    • pp.208-215
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    • 2017
  • When persistent oil, such as crude oil or Bunker C oil, is spilled at sea, viscosity increases through the weathering process. Equipment that can collect this oil when mixed with floating marine debris is very limited. In this study, devices that can be attached to the outside of existing oil skimmers have been applied to the inside of the main body, to develop an unmanned conveyor belt type floating marine debris and high viscosity oil recovery skimmer, which is composed of a conveyor belt, a sweeper with a forced inflow device, and a collection tank equipped with a buoyant body. The resulting skimmer was operated at a speed of 1.2 knots at a distance of 30 m in a sea area test. It was stable when moving laterally in any direction. An oil recovery performance test was conducted using a portable storage tank, and oil was recovered from a minimum of $7.8k{\ell}/h$ to a maximum of $23.3k{\ell}/h$. Moreover, recovery of $7.7k{\ell}/h$ was obtained in a wave water tank test with floating marine debris such as PET bottles and oil mixed. If the equipment developed in this study was used in the field for oil pollution accidents, it could be expected to contribute to improved response capability. We believe our equipment could be used in further studies to improvement the performance of existing portable oil skimmers.

Preparation and Characterization of Bead Type Superabsorbent Resin (비드형 고흡수성 수지의 제조 및 특성연구)

  • Ahn, Kyo Duck;Yoon, Minjoong
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.760-766
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    • 2014
  • Bead type super-absorbent resins to be used for release-control were prepared by modification of the inverse suspension polymerization, and their physical properties were characterized. Acrylic acid and acrylamide were used as monomers, and N,N-methylenebisacrylamide was used as crosslinker, controlling the viscosity of monomer solution by adding hydroxyethylcellulose (HEC). SEM studies of the synthesized beads verified that the bead surfaces had many pores with their diameters of several tens nm. The bead sizes were in the range of $500{\sim}3000{\mu}m$, depending on the viscosity of the monomer solution. Both absorbent amount and absorbent rate of the beads were inversely proportional to the bead size, and the maximum water absorbent amount of 1 g beads was determined to be ca. 170~200 g for 5 hrs. The absorbent rate was also dependent on pH change of the aqueous solution, exhibiting the maximum rate in pH ranging from 5 to 11. The absorbent rate decreased as the concentration of salt (NaCl and $MgCl_2$) or ethanol and ethylene glycol increased. Release time of the water absorbed into the bead resins was 700 hrs, confirming the usefulness of the resin for the good release-control materials.

Understanding the Viscoelastic Properties and Surface Characterization of woodflour-Polypropylene Composites (목분-폴리프로필렌 복합재의 점탄성적 성질과 표면특성)

  • Son, Jungil;Gardner, Douglas J.
    • Journal of Adhesion and Interface
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    • v.3 no.4
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    • pp.1-9
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    • 2002
  • The main goal of this study was to analyze the effect of process additives, i.e. maleated polypropylene (MAPP), and nucleating agent on the viscoelastic properties of different types of extruded polypropylene-wood plastic composites manufactured from either PP homopolymer, high crystallinity PP or PP impact copolymer using dynamic mechanical thermal analysis. And also, the esterification reaction between wood flour and maleated polypropylene, and its role in determining the mechanical properties of wood flour-polypropylene composites was investigated. The wood plastic composites were manufactured using 60% pine wood flour and 40% polypropylene on a Davis-Standard $Woodtruder^{TM}$. Dynamic mechanical thermal properties, polymer damping peaks(than ${\delta}$), storage modulus (E') and loss modulus (E") were measured using a dynamic mechanical thermal analyzer. XPS (X-ray Photoelectron Spectroscopy), also known as ESCA (Electron Spectroscopy for Chemical Analysis) study of wood flour treated with MAPP was performed to obtain information on the chemical nature of wood fiber before and after treatment. To analyze the effect of frequency on the dynamic mechanical properties of the various composites, DMA tests were performed over a temperature range of -20 to $100^{\circ}C$, at four different frequencies (1, 5, 10 and 25 Hz), and at a heating rate of $5^{\circ}C/min$. From these results, the activation energy of the various composite was measured using an Arrhenius relationship to investigate the effect of maleated PP and nucleating agent on the measurement of the interphase between the wood and plastic of the extruded polypropylene wood plastic composites.

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Extraction Conditions and Green Index of Green Pigments from Discolored Garlic (녹변된 마늘의 색소 추출 조건과 Green Index)

  • Hwang, Jin-Bong;Ha, Jae-Ho;Shin, Dong-Bin;Park, Wan-Soo;Nahmgung, Bae;Lee, Young-Chun
    • Korean Journal of Food Science and Technology
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    • v.37 no.4
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    • pp.678-684
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    • 2005
  • Extraction conditions, spectrometric, and sensory properties of pigment extracts from green discolored garlic (GDG) were studied for development of green index to evaluate degree of green discoloration of garlic. GDG pigments were extracted using polar solvents, such as methanol, ethanol, and water. Methanol with 1% HCl resulted in highest extraction of green pigments. Extraction of pigments was affected by temperature, and extracted pigments were partially destroyed at high temperatures. Optimum conditions for extraction of green pigments were $20^{\circ}C$ for 30 min. Because green pigments are unstable at room temperature, and no method has been reported to evaluate degree of green discoloration of garlic, color chart was designed by mixing varying amounts of control and GDG. High correlation was observed between sensory scores and "a" value of color chart samples (y=-3.465x - 11.676) with $R^2$ of 0.993. Green index (GI) was developed based on linear regression equation between sensory scores and "a" values. Sensory panel recognized green discoloration of garlic at $GI{\geq}3.0$. GI developed in this study could be utilized to evaluate degree of green discoloration of garlic during cold storage and distribution of garlic.

Phase Behavior and Morphological Studies of Polysulfone Membranes; The Effect of Alcohols Used as a Non-solvent Coagulant (비용매 알코올 응고조를 이용한 폴리술폰 막의 상전이 거동 및 모폴로지 특성 연구)

  • Park Byung Gil;Kong Sung-Ho;Nam Sang Yong
    • Membrane Journal
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    • v.15 no.4
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    • pp.272-280
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    • 2005
  • In this study, asymmetric polysulfone membranes were prepared by the phase inversion method and the casting solutions were containing N-methyl-2-pyrrolidone (NMP) as a solvent. Deionized water and various alcohols(methanol, ethanol, and propanol) were used as a coagulation medium in preparing asymmetric polysulfone membranes. This study investigates the effect of alcohol coagulants having different solubility parameters as a pore-former on the construction of porous structures and their pure water permeation properties. Asymmetric polysulfone membranes immersed in the pure alcohol coagulation bath solution showed the typical sponge-like structures and the reduced water permeability as compared with those of polysulfone membranes precipitated in the pure water coagulation bath solution. In the water/alcohol mixtures, asymmetric polysulfone membranes showed the finger-like structures with the sponge-like structures. Therefore, the sponge-like structure of polysulfone membrane was formed under the delayed demixing systems while the porosity of membrane was decreased significantly. The water permeability of polysulfone membrane precipitated in the pure water coagulant showed 164 [$L/m^2hr$] at 14.7 psi. In case of polysulfone membranes prepared in the pure methanol and ethanol coagulant, they showed the water permeability of 56 and 30 [$L/m^2hr$], respectively.

Effects of Carbon Substrates on Exopolysaccharide Production by Enterobacter sp. (Enterobacter sp. 의 다당 생산에 미치는 탄소원 기질의 영향)

  • Lee Ju-Ha;Lee Shin-Young
    • KSBB Journal
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    • v.20 no.1 s.90
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    • pp.26-33
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    • 2005
  • The effects of carbon sources for exopolysaccharide production during batch cultivation of an Enterobacter sp. isolated from the composter were investigated. The highest amount of exopolysaccharide was obtained when lactose was used as carbon source. Lactose in medium was converted into glucose and galactose. Glucose was metabolized fast and was completely consumed, but about $20\%$ of lactose was accumulated as galactose. On the other hand, enzyme activity was about $350\~450$ unit with the increase of lactose concentration. Thus, it was considered that the exopolysaccharide might be produced in the course of that lactose was hydrolyzed into glucose and galactose by $\beta-galactosidase$ with respect to that enzyme activity on lactose hydrolysis was accorded to the exopolysaccharide production. When glucose and galactose were added to lactose medium, respectively, it could be considered that glucose was as a repressor and galactose was as a inducer for $\beta-galactosidase$ synthesis even though the mechanisms were not elucidated. The increase of lactose concentration was almost ineffective to the specific growth rate $(0.133\~0.151\;hr^[-1})$ but showed the difference in the biomass content. The higher carbon source concentration, the more residual sugar remained. It was assumed that the optimum lactose concentration for exopolysaccharide production was $30\~70g/L.$ On the other hand, it was considered that the nitrogen acted as growth limiting nutrients to the cell growth. In the cases of 30 and 70 g/L of the fixed carbon concentrations, the increase of the nitrogen sources concentration caused a remarkable increase within the range of $0.059\~0.225\;hr^{-1}$ and $0.141\~0.237hr^{-1}$ of the specific growth rate, respectively, while there was no significant difference in biomass.