• Title/Summary/Keyword: 혼합물점도

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Durability Evaluation of a Buried Expansion Joint of Buried Folding Lattice Type (BFL형의 매설형 신축이음장치의 내구성 평가)

  • Jwa, Yong-Hyun;Park, Sang-Yeol;Kim, Seok-Hyun
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.9-20
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    • 2011
  • Most of domestic expansion joint system was applied by exposed expansion joint system. There are cases where it is damaged by driving. As the result noise and impact happened, and the social cost due to frequent repair works is increasing. So based on the Asphalt Plug Joint(APJ) system that applied in the United States and Europe, new buried expansion joint system was lately developed a system of Buried Folding Lattice Joint(BFLJ) that changed substructure. In this research, we have tested for durability and flexibility performance of buried expansion joint system that based on the type of asphalt mixture. Also we have evaluated for durability of BFLJ system against vehicle load using accelerated pavement testing. As a result of the experiment, the developed BFLJ system gives high flexibility performance and resolves transformation concentration along the joint section more than APJ system. Also it could be seen that the BFLJ system could overcome the disadvantages of APJ and prevent early damage. Because surface deflection of BFLJ system against vehicle load was measured low, and sub system in the buried expansion joint system was not damaged against vehicle load.

Rheological Properties and Cure Kinetics of Cycloaliphatic/DGEBA Epoxy Blend System Initiated by Cationic Latent Curing Agent (잠재성 경화제를 이용한 Cycloaliphatic/DGEBA계 에폭시 블렌드 시스템의 유변학적 특성 및 경화 동력학)

  • 곽근호;박수진;이재락;김영근
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.227-233
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    • 1998
  • The effects of 1 mol% N-benzylpyrazinium hexafluoroantimonate(BPH) as a thermal latent initiator and blend compositions composed of cycloaliphatic and DGEBA epoxies were investigated in the rheological properties and cure kinetics. Latent properties were performed by measurement of the conversion as a function of reaction time using isothermal DSC at $150^{\circ}C$ and $50^{\circ}C$ Rheological properties of the blend systems were investigated in terms of isothermal experiments using a rheometer. The gelation time was obtained from the evaluation of storage modulus (G'), loss modulus (G") and damping factor (tan$\delta$)). Cross-linking activation energy ($E_c$) was also determined from the Arrhenius equation based on gel time and curing temperature. As a result, the gel time and cross-linking activation energy increased with increasing DGEBA composition. The cure activation energies ($E_a$) were obtained by Kissinger method using dynamic DSC thermograms. In this work, the cure activation energy decreased with increasing CAE concentration, which might be resulted from the short repeat units, simple side-groups and viscosity of reaction media.edia.

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Study for Mechanical Strength according to Thickness of Specimen in the Ceramic Injection Molding Process (세라믹 사출공정에서 시편의 두께에 따른 기계적 강성 연구)

  • Kim, Jinho;Hong, Seokmoo;Hwang, Jihoon;Lee, Jongchan;Kim, Naksoo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3396-3402
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    • 2014
  • The importance of shape design for strength is highly regarded when applied to thin plate products in Ceramic Injection Molding (CIM), such as cases for electronic goods. This study analyzed the characteristics of the mechanical strength of CIM product by measuring the flexural strength and elastic modulus through a 3-point bending test according to the thickness of a thin plate test piece prepared by CIM. The specimen with a thickness of 0.48mm required a 82.9~94.5N fracture load, whereas a 1.0mm thick test piece required 233.6~345.8N. The increase in thickness by 0.5mm resulted in a 3-fold increase in the fracture load, whereas the elastic modulus decreased by 20%. The thicker the specimen, the lower relative density and surface hardness of the specimen. This is because the thicker the specimen, the lower the powder fraction of the ceramic mixture, and the material properties partially change after sintering.

Acrylamide Polymerization on ceramic Powders(I) : The Process Control of Si2N4 Gelcasting by Polymerization of Acrylamicde (세라믹분체 표면에서 아크릴아마이드 중합(제1보) : 아마이드 고분자중합에 의한 질화규소 겔캐스팅 공정제어)

  • 류병환;김은영;이재도
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.178-185
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    • 1999
  • For the process control of silicon nitride gelcasting, the composition effect of acryamide system on the viscosity of slip and mechanical property of gelcast green body were investigated. The slip was prepared by ball milling of silicon nitride suspension prepared with acrylamide monomer and polyelectrolyte dispersant after premixing them by attritor. The slip mixed with initiator was vacuum deaired and cast into molds, and then polymerized. The consolidated green body was obtained by drying the gelated slip. The viscosity measument and the diametral compression test was done to evaluate the rheological behaviro of slip and mechanical property of gelcast body, respectively. Experimental results showed that the high solid loading of silicon nitride slip was obtained up to 46 vol% with a low viscosity. The mechanical property of gelcast body mainly increased with increasing the concentration of monomer. The gelcast body was machinable above the ∼3 MPa of tensile strength. The relative density of pressured-sintered body was 98.5% at 1760$^{\circ}C$, 3 h.

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Determination of Valid Dynamic Stability in Wheel Tracking Test of Asphalt Concretes (아스팔트 콘크리트 반복주행 시험에서의 동적안정도 정립에 관한 연구)

  • Kim, K.W.;Kim, J.E.;Kim, B.C.;Doh, Y.S.
    • International Journal of Highway Engineering
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    • v.6 no.3 s.21
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    • pp.37-46
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    • 2004
  • This study was performed to establish valid methodology for determining dynamic stability(DS) of deformation-cycle curve which is obtained through wheel tracking(WT) test, the most widely used method for forecast of rutting tendency of asphalt mixture. Existing Korean and Japanese methods for DS are unrealistic and do not really reflect characteristics of rut resistance of asphalt concretes especially when the slope of deformation-cycle curve is stabilized at the end. It was proved that the new DS developed in this study reflected rut resistance characteristics better than existing methods. It is especially effective to distinguish the mixtures with high DR(depth of rut) but stable slope at the end of curve from the mixture with lower DR and continuous slope. The field evaluation must be followed to prove whether the mixture which shows a high DS value this method perform well in the filed.

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Effects of Salts on the Partition of Proteins in Poly (ethylene glycol)-Dextran Aqueous Two Phase System (Poly(ethylene glycol)-dextran 수용액 2상계에서 단백질 분획계수에 미치는 금속염의 효과)

  • Lee, Sam-Pin;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.146-150
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    • 1987
  • The effects of pH and added salts on the partition coefficients of proteins in a polyethylene glycol)-dextran aqueous two-phase system were investigated. The partition coefficients attained the lowest value at the isoelectric point of proteins in an equal volume aqueous two-phase system containing 5% PEG and 9.5% dextran in 5 mM phosphate buffer solution. The coefficients increased dramatically at pH 11; BSA which had highest effective hydrophobicity marked 50-fold increase, while ${\beta}-lactoglobulin$ and ovalbumin which had low hydrophobicity 10-fold increase, respectively. The effect of added salts varied with the pH. The partition coefficient increased by the addition of salt at pH 3.0 but decreased drastically at pH 7.0. The partition coefficient increased in the order of added Li < Na < K at pH 3.0 and decreased in the order of added Li < Na < K at pH 11.0.

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Analysis of Oil Species of Illegally Disposed Oil (무단 투기 유류에 대한 유종 해석)

  • Lim, Young-Kwan;Lee, Eun-Yul;Seong, Sang-Rae;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.664-668
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    • 2016
  • The contamination in soil, underground water and river environment became serious due to illegal waste dumping. In this study, our research group analyzed the oil species of illegally disposed oils from J City. After pretreating the mixture of oil, water and solid phases to obtain homogeneous phase components, the physical property analysis, atom analysis, and gas chromatography were performed. From the results showing 11.8% of oxygen content, $-6^{\circ}C$ of pour point and chromatogram pattern. the contaminated oil was identified as a vegetable one. High performance liquid chromatography (HPLC) analysis was also performed in order to know what kind of vegetable oil was, and the ratio of LLO, OOL and POL was found to be high indicating that the disposed oil is majorly the used soybean oil with some vegetable oil mixtures. This study can be used for identifying contaminators for oils from the illegal waste dumping.

A Study on Physical Properties of Epoxy Resin Filled with Surface-treated Silica: I. Surface-treating of Silica and Properties of Mixtures (표면처리된 실리카를 충전한 에폭시 수지계의 물성에 관한 연구 I. 실리카의 표면처리 및 혼합 물성)

  • Hong, Suk-Pyo;Choi, Sang-Goo
    • Applied Chemistry for Engineering
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    • v.1 no.1
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    • pp.63-72
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    • 1990
  • Surface of crystalline silica was sequentially reacted with silane(A 187), liquid rubber(CTBNx8) and vinyl monomer(AA, MMA, 2-HEA, GMA) in existance of amines(TEA, CTMAB, BETAC) or peroxide(BPO). By mixing it with epoxy resin at a ratio 0~36%(volume %) of total component, liquid properties of mixtures was investigated experimentally. i) Coating ratio depended on quantity and sorts of catalyst. ii) Total coating of 2.5~5.8% was attained by using 0.1~2.0% of catalyst. iii) Treated surfaces represented each different features in according to sorts of treatment. iv) Silane/rubber or silane/rubber/vinyl represented lower viscosity and settling than non-treated or silane-treated.

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Effects of Added Corn Starches and Hydrocolloids on the Characteristics of Mungbean Starch and the Mook(Starch Gel) (옥수수 전분과 Hydrocolloids 첨가가 녹두 전분 및 묵의 특성에 미치는 영향)

  • Park, Ok-Jin;Kim, Kwang-Ok
    • Korean Journal of Food Science and Technology
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    • v.20 no.4
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    • pp.618-624
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    • 1988
  • This study was conducted to observe the effects of partial replacement of mungbean starch(MB) with dent(DT) or cross-linked(CL) corn starches, and of added hydrocolloids on the characteristics of mungbean starch and the mook. The replacement with CL caused less changes compared to that with DT in phase transition enthalpy of MB measured with defferential scanning calorimeter. The viscosity of MB paste cooled to $50^{\circ}C$ after heating was also affected less with CL than with DT. The addition of hydrocolloids to mixed starches of MB and CL did not affect initial viscosity increase but resulted in marked increase in viscosity at later stage of heating. Mixed monks with CL were more similar to MB monks than those with DT. Hydrocolloids added to MB-CL mixture further decreased the gap between monks with and without CL.

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Influence of Amine Base Dispersing Agent on Properties of Silica Filled Rubber Compounds (아민계 분산제가 실리카 고무배합물의 물성에 미치는 영향)

  • Park, Sung-Soo;Kil, Sang-Gyu;Jang, Byung-Man;Song, Ki-Chan;Kim, Su-Kyung
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.503-511
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    • 2001
  • Present silica dispersing agents are based mainly on fatty acid derivatives of Zn, K and mixture of fatty acid and metallic soaps are used to increase activity. The viscosity of silica filled rubber is lowered by Zn-K soap type silica dispersing agent, thus fluidity of hydrocarbon chains and processibility is improved. Silica dispersing agent should not exert an influence on chracteristics of vulcanization. But scorch and curing time is shortened by Zn-K soap type silica dispersing agent. A newly developed silica dispersing agent, which is a nonmetal type agent, reduced the viscosity and hardness of silica compounding rubber, and the highly increased degree of dispersion of silica is caused by interaction of silica and rubber. Also it did not affect the curing characteristics and scorch stability of silica compounding rubber.

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