• Title/Summary/Keyword: 혼합금속복합재료

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Fabrication and Characteristics of $Al_2O_{3p}$/AC8A Composites by Pressureless Infiltration Process (무가압함침법에 의한 $Al_2O_{3p}$/AC8A 복합재료의 제조 및 특성)

  • 김재동;고성위;정해용
    • Composites Research
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    • v.13 no.6
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    • pp.1-8
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    • 2000
  • The fabrication Process of $Al_2O_{3p}$/AC8A composites by pressureless infiltration technique and the effects of additive Mg content and volume fraction of particulate reinforcement on mechanical and wear properties were investigated. It was found that the bending strength decreased with increasing volume fraction of $Al_2O_{3p}$ particles. Whereas hardness increased with volume fraction of $Al_2O_{3p}$ particles. The decrement of strength in case of high volume fraction of $Al_2O_{3p}$ particles was attributed to high porosity level. In terms of additive Mg content, $Al_2O_{3p}$/AC8A composites containing around 5~7wt% of additive Mg indicated the highest strength, and hardness values increased with additive Mg contents. Wear resistance of AC8A alloy were improved by reinforcement of $Al_2O_{3p}$ particles especially at high sliding velocity. Wear property of $Al_2O_{3p}$/AC8A composites and AC8A alloy exhibited different aspects. $Al_2O_{3p}$/AC8A composites indicated more wear loss than AC8A alloy at slow velocity region. However a transition point of wear loss was found at middle velocity region which shows the minimum wear loss and wear loss at high velocity region exhibited almost same value as at slow velocity region, whereas wear loss of AC8A alloy almost linearly increased with sliding velocity. It was found that $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 20% exhibited abrasive wear surface regardless of sliding velocity and $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 40% showed slightly adhesive wear surface at low sliding velocity, and it progressed to severe wear as increasing the sliding velocity.

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Fabrication of Al2O3/Fe-Ni Nanocomposites by Pressureless Sintering and their Magnetic Properties (상압소결에 의한 Al2O3/Fe-Ni 나노복합재료의 제조 및 자기적 특징)

  • Lee, Hong-Jae;Jeong, Young-Keun;NamKung, Seok;Oh, Sung-Tag;Lee, Jai-Sung
    • Journal of the Korean Ceramic Society
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    • v.39 no.8
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    • pp.769-774
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    • 2002
  • The powder mixture in which Fe-Ni alloy particles of 20 nm were homogeneously dispersed on $Al_2O_3$ particle surfaces was prepared by hydrogen reduction of $Al_2O_3$ and metal oxide powders. $Al_2O_3$/Fe-Ni nanocomposites fabricated by pressureless sintering were only composed of $Al_2O_3$ and ${gamma}$-Fe-Ni phases and achieved over 98% of the theoretical density at the sintering temperature above $1350^{\circ}C$. The highest strength and toughness of the composites were 574 MPa and 3.9 MP$a{\cdot}m1/2$, respectively. These values were about 20% higher than these of monolithic $Al_2O_3$ sintered at the same conditions. Nanocomposites showed ferromagnetic properties and coercive force was increased with decrease of the average particle size of dispersions.

Hybrid Carbon Nanomaterials for Electromagnetic Interference Shielding (전자파 차폐용 하이브리드 탄소나노물질)

  • Lee, Si-Hwa;Oh, Il-Kwon
    • Composites Research
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    • v.29 no.4
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    • pp.138-144
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    • 2016
  • Recently, electromagnetic interference (EMI) shielding materials have been extensively developed and significantly considered to protect electronic systems from harmful electromagnetic waves. Although, metal-based materials show high electrical conductivity and EMI shielding effectiveness, they have several challenging problems such as high density and corrosion. Carbon-based materials have been acclaimed as alternative EMI materials due to light weight, high mechanical properties, resistance to corrosion and excellent electrical conductivity. Here, we introduce 1-phase and 2-phase carbon materials as well as 3-phase hybrid carbon materials. The 3-phase hybrid carbon materials composed of metal nanoparticles, carbon nanotubes and graphene can be used as a promising EMI shielding material.

Mechanical Properties of Aminosilane-Treated Wood Flour/PVC/Nanoclay Composites (아미노실란으로 개질된 목분/PVC/나노점토 복합재의 기계적 특성)

  • Park, Sol-Mon;Kim, Dae-Su
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.573-578
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    • 2012
  • In general, most physical properties of wood/polyvinyl chloride (PVC) composites are lower than those of corresponding neat PVC resin because of poor interfacial adhesion between the hydrophilic wood flour and hydrophobic PVC. Therefore, in this study, we treated wood flour with three aminosilanes to improve wood/PVC interfacial adhesion strength, and eco-friendly wood/PVC/nanoclay composites were prepared by melt blending the aminosilane-treated wood flour, a heavy metal free PVC compound, and a type of nanoclay. The effects of treating wood flour with the aminosilanes and adding the nanoclay on the mechanical properties of the composites were investigated. Mechanical properties of the composites were investigated by universal testing machine (UTM), izod impact tester, dynamic mechanical analyzer (DMA), and thermomechanical analyzer (TMA). The tensile properties of the composites with the aminosilane-treated wood flour were considerably higher than those of the composites with neat wood flour. Furthermore, a small amount of the nanoclay improved mechanical properties of the composites. The performance of the wood/PVC composites was considerably improved by using the aminosilane-treated wood flour and the nanoclay.

Improvement for Shielding Effectiveness of EMI Shield Layers using Conformal Spray Coating Scheme (콘포멀 스프레이 코팅으로 형성한 EMI 차단막의 차폐효과 개선)

  • Hur, Jung;Lee, Won-Hui
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.18 no.6
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    • pp.107-112
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    • 2018
  • Shielding effectiveness (SE) improvement with EMI shield layers fabricated by conformal spray coating system was studied. Silver or Nickel powder filled acrylic resin were sprayed on the samples. We compared the performance with the viscosity of 400 cPs and 100 cPs cases. The thickness range of the coating layer was 20 to 50 um for the silver, 60 to 120 um for the nickel. The shielding effectiveness was measured by ASTM D4935 using coaxial type TEM-cell. The silver-filled resin showed much better performance than that of the nickel-filled resin. The shielding effectiveness increased almost proportional to the thickness of the coating layers until being saturated around 63 dB for the silver-layer or around 34 dB for the nickel-layer. The best performance measured in this study was the shielding effectiveness of 63 dB with $35{\mu}m-thick$ of silver-layer.

Vibration Analysis of the Rotating Hybrid Cylindrical Shells Laminated with Metal and Composite (회전하는 금속복합재료 혼합적층 원통쉘의 진동해석)

  • Lee, Young-Sin;Kim, Young-Wann
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.3
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    • pp.968-977
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    • 1996
  • The linear/nonlinear vibration response of the rotating hybrid cylindrical shell with simply supported boundary condition is studied. The Ritz-Galerkin method is applied to obtain the nonlinear frequency equation, which excludes in-plane and rotatory inertia but includes bending stretching coupling terms. The bifurcation phenomena for the linear frequency and the frequency ratio(nonlinear/linear frequency ratio) are presented. The hybrid cylindrical shells are composed of composite(GFRP, CFRP) metal(aluminium, steel) with symmetric and antisymmetric stacking sequence. The effects of the Coriolis and centrifugal force are considered The results also present the effects of length-to- radies ratio, radius-to-thickness ratio, the circumferential wave number, the stacking sequence, the material property, the initial excitation amplitude and the rotating speed. The present linear frequency results are compared with those of the available literature.

Zinc Based Anode Materials and Its Application to Lithium Ion Rechargeable Batteries (아연복합산화물 음극활물질과 리튬이차전지 특성)

  • Hwang, Min Ji;Lee, Won Jae;Doh, Chil Hoon;Son, Yeong Guk
    • Journal of the Korean Electrochemical Society
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    • v.16 no.2
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    • pp.85-90
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    • 2013
  • Graphite is a commercial anode material to have the specific capacity of 372 mAh/g and the true density of 2.2 g/ml. Many effort had been pouring to find out the better material than graphite. Good candidates are silicon, tin, etc. Zinc is also a plausible candidate to have the specific capacity of 412 mAh/g and the true density of 7.14 g/ml. In this study, the Zn based anode material including indium and nickel as minor additives was synthesised. In order to get the homogeneouly mixed Zn-In-Ni composite material, the sol-gel method was used. The anode prepared by Zn-In-Ni composite material has the $1^{st}$ specific capacity of 910 mAh/g. Through prolonged charge-discharge cycling, the specific capacities were reduced to 365 (at $31^{st}$ cycle) and 378 mAh/g (at $62^{th}$ cycle). The $1^{st}$ Ah efficiency was 45% and Ah efficiencies were exhibited at the prolonged cycle.

Effective Equivalent Finite Element Model for Impact Limiter of Nuclear Spent Fuel Shipping Cask made of Sandwich Composites Panels (사용후 핵연료 수송용기 샌드위치 복합재 충격완충체의 유효등가 유한요소 모델 제시)

  • Kang, Seung-Gu;Im, Jae-Moon;Shin, Kwang-Bok;Choi, Woo-Suk
    • Composites Research
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    • v.28 no.2
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    • pp.58-64
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    • 2015
  • The purpose of this paper is to suggest the effective equivalent finite element model for the impact limiter of a nuclear spent fuel shipping cask made of sandwich composite panels. The sandwich composite panels were composed of a metallic facesheet and a core material made of urethane foam, balsa wood and red wood, respectively. The effective equivalent finite element model for the impact limiter was proposed by comparing the results of low-velocity impact test of sandwich panels. An explicit finite element analysis based on LS-DYNA 3D was done in this study. The results showed that the solid elements were recommended to model the facesheet and core of sandwich panels for impact limiter compared to combination modeling method, in which the layered shell element for facesheet and solid element for core material are used. In particular, the solid element for balsa and red wood core materials should be modeled by the element elimination approach.

Effects of Drying Agents on the Drying and Calcination in Synthesis of Mullite by Sol-Gel Process (졸-겔법에 의한 mullite합성시 건조 첨가제가 건조 및 소성에 미치는 영향)

  • Hahm, Yeong-Min;Hong, Young-Ho;Choi, Seung-Il
    • Applied Chemistry for Engineering
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    • v.4 no.3
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    • pp.497-504
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    • 1993
  • The effect of DCCA (Drying Control Chemical Additives) on the drying of gel was investigated in order to determine an optimum drying condition of mullite precursor through sol-gel process. Aluminium sec-butoxide was synthesized from aluminium foil and then mullite powders were synthesized from Tetra-ethyl-ortho-silicate (TEOS) and the aluminium sec-butoxide. N, N-dimethyl formamide (DMF), Glycerol, 1, 4-Dioxane, and Oxalic acid were used as DCCA. Mullite powders that were calcined at 200, 900, 1100, and $1250^{\circ}C$ for 2hr were analysed by XRD, TG-DTA, FT-IR, and SEM in order to investigate structural change and characteristics of calcined powders. The results of this work showed that the drying time of gel was reduced to about half in the presence of 0.1mol DMF compared with the absence of DCCA and also calcined powders were obtained without remarkable structural change despite of the addition of DCCA.

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Fabrication of $YBa_{2}Cu_{3}O_{7-x}$-Ag Composite Superconductors by Pyrophoric Synthetic Method (발화합성법에 의한 $YBa_{2}Cu_{3}O_{7-x}$-Ag 복합 초전도체 제조)

  • Yang, Seok-U;Kim, Chan-Jung;Hong, Gye-Won;Sin, Hyeong-Sik
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1082-1089
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    • 1998
  • To obtain fine dispersion of Ag particles in $YBa_2$$Cu_3$$O_{7-y}$ (123) superconductors, 123 samples were made by pyrophoric synthetic method using malic acid and the subsequent solid- state reaction. As the pyrophoric synthetic powder was used as a precursor material, fine 123 powder of submicron size was produced in a short reaction time. The added $Ag_2$O was converted to metallic Ag during Pyrophoric reaction and it accelerated both the formation of 123 phase and the grain growth via the enhanced mass transfer. The Ag particles of the sample sintered using the pyrephoric synthetic powder were more finely dispersed in the 123 matrix, compared to those of the sample sintered using the mechanically mixed powder, attributing to the improvement of the superconducting properties.

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