• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.7
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• pp.829-835
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• 2016

An excess in the nutrients such as nitrogen and phosphate leads to a phenomenon called eutrophication. In order to avoid this, numerous methods have been used to remove excess nutrients in the water. In this study, the use of a chemical method was assessed through the formation of magnesium ammonium phosphate. The difference in the removal efficiency of seawater and sea salt solution as primary sources of $Mg^{2+}$ ions and $Ca^{2+}$ ions for the formation of magnesium ammonium phosphate (MAP) and hydroxyapatite (HAP) respectively, were observed, taking into account the changes in pH and concentration. The results showed that seawater removed about 90 % phosphate and less than 50 % ammonia in sewage water condition, whereas the sea salt solution removed almost 90 % phosphate and 70 % ammonia in solution at pH 9 and 10 mM concentration of sea salt which further increases as the optimum ${Mg/PO_4}^{3-}$, ${NH_4}^+$ ratio reaches 2. The difference in the removal efficiency of seawater and sea salt was due to the fact that the set-ups were prepared in different conditions. This study suggests that both seawater and sea salt can be used to remove nutrients from the water. The relatively higher removal of phosphate can be explained by the formation of HAP from free $Ca^{2+}$ ions initially present in seawater and sea salt solution.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.151-154
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• 2004

본 논문에서는 국내의 서-남해 연안지역에서 광범위하게 발생하고 있는 해수침투의 확산방지를 위하여 해수침투보호구역이라는 개념을 소개한다. 해수침투보호구역을 설정하기 위해서는 해당 지역 해수침투대의 고분해능 염분농도분포가 필요하며 이와 같은 염분농도분포도는 물리탐사 기술로 작성이 가능하다. 전남 영광지역에서 물리탐사 기술로 작성한 해수침투대의 고분해능 염분농도 분포도는 시험시추 결과, 매우 신뢰성이 높았으며 염분농도의 공간적인 분포도에서 해수침투로 인한 지하수 개발 제한지역, 보호구역 등에 대한 설정이 가능하였다. 향후, 해수침투의 확산방지와 지속적인 지하수의 개발이 가능한 해수침투보호구역설정에 대한 후속적인 조치가 필요할 것으로 판단된다.

• Korean Journal of Environmental Biology
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• v.35 no.3
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• pp.373-379
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• 2017

Juvenile Paralichthys olivaceus (mean length $19.8{\pm}2.6cm$, mean weight $97.8{\pm}15.8g$) were exposed for 96 hours to different nitrate concentrations of 0, 62.5, 125, 250, 500, 1,000, and $1,500mg\;L^{-1}$ in biofloc and 0, 62.5, 125, 250, 500, and $1,000mg\;L^{-1}$ in seawater. Median lethal concentration values ($LC_{50}$, the concentration at which 50% of mortality occurred after 96 hours of exposure) of nitrate to P. olivaceus in biofloc and seawater were 1,226 and $597mg\;NO_3L^{-1}$ (P<0.05), respectively, revealing a higher toxicity of nitrate to P. olivaceus in seawater than in biofloc. In hematological parameters, hematocrit level in P. olivaceus exposed to nitrate was significantly increased only at a concentration of $1,000mg\;L^{-1}$ in biofloc and at concentrations higher than $250mg\;L^{-1}$ in seawater, but no significant changes in hemoglobin were found in biofloc and seawater. In plasma parameters, aspartate aminotransferase (AST) and alanine aminotransminase (ALT) were significantly increased by nitrate exposure in biofloc and seawater, but no significant changes in alkaline phosphatase (ALP) were found in biofloc and seawater. Results of this study indicate that nitrate exposure to P. olivaceus have a lethal toxic effect and alter hematological and plasma constituents of flatfish P. olivaceus. Given relatively lower toxicity of nitrate in biofloc than in seawater, the use of biofloc in aquaculture may reduce potential toxic effect caused by nitrate in feces and feed residue.

• Journal of Korea Water Resources Association
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• v.49 no.5
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• pp.431-438
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• 2016

Large energy consumption is one of the main weaknesses of RO desalination. A new method is proposed to reduce the energy consumption of RO desalination which depends on the salinity of the feedwater. Low salinity feedwater can be obtained using groundwater wells which extracts both fresh groundwater and subsurface sea water. Subsurface feedwater is advantageous in overcoming other problems associated with surface seawater intakes. Salinities of groundwater depend on a number of factors. In this work a new simulation-optimization model is proposed to identify well locations and pumping rates with would provide the required design flow rate with the minimum salinity. When groundwater is developed in a coastal area, the saltwater wedge advances inland and may contaminate existing groundwater wells, which must be prevented. The model can protect existing wells while developing minimum salinity feedwater. Examples are provided to demonstrate the usage of the model.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.532-535
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• 2003

새만금 방조제를 통하여 새만금호로 유입되는 해수 침출수량과 새만금 방조제 내부에서의 해수와 담수 사이의 상호작용 등에 대한 연구를 수행하였다. 본 연구에는, 밀도 차이에 의한 흐름을 고려한 지하수 흐름 지배 방정식과 염류의 분산 및 이송 지배 방정식을 결합시킨 수치해석 모델이 이용되었다. 밀도류를 고려한 경우에는 밀도류를 고려하지 않았을 경우보다 해수 침출량은 다르지 않았으나, 해수 침출면의 길이가 축소되고 유속이 증가하였다. 부정류상태의 해수-담수 경계면은 정류 상태의 결과와 매우 달랐으며, 해수 침출면이 방조제의 하부가 아닌 상부에 존재함을 보였다.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.2-2
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• 2020

해안 지역은 종종 도시화, 인구 증가 및 환경 오염으로 인해 해안대수층의 지하수의 염도가 증가하는 현상인 해수침투가 발생한다. 본 연구는 국내 제주도 해안대수층을 대상으로 GIS 기법을 이용한 수리지질학적 변수의 지수화 방식으로 해안대수층의 해수침투 취약성 평가를 적용하였고 국내 해수침투 특성을 더욱 명확하게 반영할 수 있도록 취약성 평가 방식을 개선하고자 하였다. 취약성 평가를 수행하기 위해 대수층 특성, 수리전도도 특성, 지하수위, 해안으로부터의 거리, 염도분포, 대수층 깊이 등의 자료를 확보하여 취약성 평가의 주요 인자로 활용하였으며 특히 다년간에 걸친 국내 해수침투 관측망 관측 자료를 사용한 것을 특징으로 한다. 취약성 평가 인자 중 지하수위를 지수화 하는 과정에서 지하수위의 평가 구간 범위를 개선하였고, 염도 적용 방식을 해수침투 관측망 데이터 유형인 전기전도도를 이용한 새로운 평가 구간 범위를 설정하였다. 연구 결과 기존에 해수침투가 발생했던 지역에서의 취약성 지수가 높게 나타났으며 취약성 평가의 개선 작업 결과에 의해 지속적인 지하수위 하강이 발생하고 계절적 요인으로 해수침투가 발생하는 지역에서 취약 지수의 증가세를 더욱 선명하게 구분할 수 있었다.

• Korean Journal of Environmental Biology
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• v.17 no.4
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• pp.427-438
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• 1999

Differential growth of Ulva pertusa Kjellman was observed in response to different photon irradiances and seawater. Growth rate of U. pertusa cultivated in the seawater collected from the East Sea was significantly higher than that in the seawater collected from the Yellow Sea. Optimal growth was found at $100{\mu} molm^{-2} s^{-1}$ in both cases. Chlorophyll contents of U. pertusa grown in the east sea water were higher than that cultivated in the west sea water at irradiances lower than $60{\mu} molm^{-2} s^{-1}$. At irradiances higher than $100{\mu} molm^{-2} s^{-1}$, there was no difference in chlorophyll content in between the two different sea waters with tendency that pigmentation decreased with increasing photon irradiances. Nitrate concentration in the west sea water was 2-fold higher than that in the east sea water, while phosphorus concentrations (0.03 ppm) were similar. Concentrations of $Cu^{2+}$ and $Pb^{2+}$ were 0.004 and 0.003 ppm respectively which are far below environmental standard concentrations (0.02 ppm for $Cu^{2+}$ and 0.1 ppm for $Pb^{2+}$). Taking those data into account, we have done laboratory investigations into the effects of inorganic nutrients and heavy metals on U. pertusa. As nitrate concentration increased from 0.5 to 5 ppm, growth rate of U. pertusa increased, but different concentrations of phosphorus did not cause any differential effect. On the other hand, chlorophyll contents increased with increasing phosphorus concentrations. Copper of U. pertusa be toxic decreased the growth and pigmentation as the concentration increased, whereas lead showed no such effect. Concentrations of $Cu^{2+}$ employed in the present study were much higher than those in ambient seawater. Intermittent soaring of $Cu^{2+}$ level as observed in natural seawater could, however, seriously damage the growth behaviour of U. pertusa.

• Journal of Navigation and Port Research
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• v.26 no.5
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• pp.571-575
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• 2002

An immersion-type on-line refractometer useful for the in-situ measurement of salinity and temperature of sea water is developed, and its performance is examined by applying the refractometer to known salt solution having salt concentration between 2 and 4 % similar to practical sea water salinity. Since refractive index and temperature are measured simultaneously, it is possible to compensate the effect of temperature for fast and direct measurement. The outcome of salinity measurement for the different concentrations of salt solution indicates that the device is suitable for the salinity measurement by yielding stable and reproducible reading.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.5
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• pp.407-412
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• 2014

A new apparatus for seawater desalination, based on the principle of gas hydrates, is suggested. The equipment continuously produces and pelletizes gas hydrates by a squeezing operation in a dual cylinder unit, which is able to extract pure hydrate pellets from the seawater-containing reactor. Desalination efficiency for each dissolved ion from seawater samples was tested by inductively coupled plasma atomic emission spectroscopy (ICP-AES) and ion chromatography (IC) analysis. This study demonstrates that the suggested method and the stated apparatus may solve the difficulty of separating hydrate crystals from concentrated brine solutions, and therefore may be applied to improve the efficiency of existing desalination processes.

• Economic and Environmental Geology
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• v.45 no.3
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• pp.317-333
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• 2012

The Yeongweol Group is a Lower Paleozoic mixed carbonate-siliciclastic sequence in the Taebaeksan Basin of Korea, and consists of five lithologic formations: Sambangsan, Machari, Wagok, Mungok, and Yeongheung in ascending order. Sequence stratigraphic interpretation of the group indicates that initial flooding in the Yeongweol area of the Taebaeksan Basin resulted in basal siliciclastic-dominated sequences of the Sambangsan Formation during the Middle Cambrian. The accelerated sea-level rise in the late Middle to early Late Cambrian generated a mixed carbonate-siliciclastic slope or deep ramp sequence of shale, grainstone and breccia intercalations, representing the lower part of the Machari Formation. The continued rise of sea level in the Late Cambrian made substantial accommodation space and activated subtidal carbonate factory, forming carbonate-dominated subtidal platform sequence in the middle and upper parts of the Machari Formation. The overlying Wagok Formation might originally be a ramp carbonate sequence of subtidal ribbon carbonates and marls with conglomerates, deposited during the normal rise of relative sea level in the late Late Cambrian. The formation was affected by unstable dolomitization shortly after the deposition during the relative sea-level fall in the latest Cambrian or earliest Ordovician. Subsequently, it was extensively dolomitized under the deep burial diagenetic condition. During the Early Ordovician (Tremadocian), global transgression (viz. Sauk) was continued, and subtidal ramp deposition was sustained in the Yeongweol platform, forming the Mungok Formation. The formation is overlain by the peritidal carbonates of the Yeongheung Formation, and is stacked by cyclic sedimentation during the Early to Middle Ordovician (Arenigian to Caradocian). The lithologic change from subtidal ramp to peritidal facies is preserved at the uppermost part of the Mungok Formation. The transition between Sauk and Tippecanoe sequences is recognized within the middle part of the Yeongheung Formation as a minimum accommodation zone. The global eustatic fall in the earliest Middle Ordovician and the ensuing rise of relative sea level during the Darrwillian to Caradocian produced broadly-prograding peritidal carbonates of shallowing-upward cyclic successions within the Yeongheung Formation. The reconstructed relative sea-level curve of the Yeongweol platform is very similar to that of the Taebaek platform. This reveals that the Yeongweol platform experienced same tectonic movements with the Taebaek platform, and consequently that both platform sequences might be located in a body or somewhere separately in the margin of the North China platform. The significant differences in lithologic and stratigraphic successions imply that the Yeongweol platform was much far from the Taebaek platform and not associated with the Taebaek platform as a single depositional system. The Yeongweol platform was probably located in relatively open shallow marine environments, whereas the Taebaek platform was a part of the restricted embayments. During the late Paleozoic to early Mesozoic amalgamations of the Korean massifs, the Yeongweol platform was probably pushed against the Taebaek platform by the complex movement, forming fragmented platform sequences of the Taebaeksan Basin.