• Title/Summary/Keyword: 합성율

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Synthesis of Melamine Phosphate-Polyurethane Composite Foam Blown by Water and Characterization of Its Thermal Properties (H2O로 발포된 멜라민포스페이트-폴리우레탄폼 복합체 합성과 열적 특성 분석)

  • Park, Kyeong-Kyu;Lee, Sang-Ho
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.441-448
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    • 2014
  • Polyurethane/melamine phosphate composite foam (MP-PUF) was prepared from poly(adipate)diol/melamine phosphate composite (f=2), polyether-polyol (f=4.6), and PMDI (f=2.5). The thermal properties of MP-PUF such as morphology, closed-cell content, thermal conductivity, and thermal stabilities were characterized. Water was used as a blowing agent, and the composition of melamine phosphate (MP) was maintained at $1.43{\pm}0.3wt%$ of MP-PUF. As the content of water increased, the thermal conductivity of pure polyurethane foam (PUF) decreased, whereas the thermal conductivity of MP-PUF increased. The thermal stabilities of the PUF and the MP-PUF were maximized at 5 php $H_2O$, and then decreased at the higher $H_2O$ contents. The thermal stabilities of MP-PUF were greatly enhanced due to the synergetic effect of MP and urea, which was generated during the blowing process. The temperature of 50% residual mass of MP-PUF increased to $370{\sim}450^{\circ}C$ and the temperature of 30% residual mass exceeded over $700^{\circ}C$. Compared to the PUF, the temperature of 50% residual mass and 30% residual mass were higher than 25 and $70^{\circ}C$, respectively.

Production of Solar Fuel by Plasma Oxidation Destruction-Carbon Material Gasification Conversion (플라즈마 산화분해-탄화물 가스화 전환에 의한 태양연료 생산)

  • Song, Hee Gaen;Chun, Young Nam
    • Clean Technology
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    • v.26 no.1
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    • pp.72-78
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    • 2020
  • The use of fossil fuel and biogas production causes air pollution and climate change problems. Research endeavors continue to focus on converting methane and carbon dioxide, which are the major causes of climate change, into quality energy sources. In this study, a novel plasma-carbon converter was proposed to convert biogas into high quality gas, which is linked to photovoltaic and wind power and which poses a problem on generating electric power continuously. The characteristics of conversion and gas production were investigated to find a possibility for biogas conversion, involving parametric tests according to the change in the main influence variables, such as O2/C ratio, total gas feed rate, and CO2/CH4 ratio. A higher O2/C ratio gave higher conversions of methane and carbon dioxide. Total gas feed rate showed maximum conversion at a certain specified value. When CO2/CH4 feed ratio was decreased, both conversions increased. As a result, the production of solar fuel by plasma oxidation destruction-carbon material gasification conversion, which was newly suggested in this study, could be known as a possibly useful technology. When O2/C ratio was 0.8 and CO2/CH4 was 0.67 while the total gas supply was at 40 L min-1 (VHSV = 1.37), the maximum conversions of carbon dioxide and methane were achieved. The results gave the highest production for hydrogen and carbon dioxide which were high-quality fuel.

Consolidation Behavior of Agricultural Reservoir under Embankment on Soft Ground (연약지반상(軟弱地盤上)에 축조(築造)된 농업용저수지(農業用貯水池) 제체의 압밀거동(壓密擧動))

  • Oh, Beom-Hwan;Lee, Dal-Won;Eam, Sung-Hoon
    • Korean Journal of Agricultural Science
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    • v.29 no.2
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    • pp.53-66
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    • 2002
  • This study was performed to evaluation the consolidation behavior of agricultural reservoir in the very soft ground. The final settlement prediction methods by Terzaghi, Hyperbolic and Asaoka methods were used to compare with the degree of consolidation estimated by exess pore water pressure. The dissipated excess pore water pressure during embankment construction and peak excess pore water pressure on the completed embankment were suggested for the estimation of the degree of consolidation. It was concluded that the degree of consolidation estimated from dissipated excess pore water pressure was more reliable than that from the peak excess pore water pressure. The stability methods for agricultural reservoir was used to compare and analyze with various condition by limit equilibrium method.

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Lactic acid Production from Hydrolysate of Pretreated Cellulosic Biomass by Lactobacillus rhamnosus (전처리된 섬유소계 바이오매스로부터 Lactic acid생산)

  • Ahn, Su Jin;Cayetano, Roent Dune;Kim, Tae Hyun;Kim, Jun Seok
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.1-5
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    • 2015
  • Lactic acid, the most widely occurring hydroxy-carboxylic acid, has traditionally been used as food, cosmetic, pharmaceutical, and chemical industries. Even though it has tremendous potential for large scale production and use in a wide variety of applications, high cost lactic acid materials are primarily problems. Lactic acid can be obtained on either by fermentation or chemical synthesis. In recent years, the fermentation approach has become more successful because of the increasing market demand for naturally produced lactic acid. Generally, lactic acid was produced from pure starch or from glucose. As an alternative, biomass which is the most abundant renewable resources on earth have been considered for conversion to readily utilizable hydrolysate. In this study, we conducted the fermentation method to produce L(+)-lactic acid production from pretreated hydrolysate was investigated by Lactobacillus rhamnosus ATCC 10863. The hydrolysate was obtained from pretreatment process of biomass using Ammonia percolation process (AP) followed by enzymatic hydrolysis. In order to effectively enhance lactic acid conversion and product yield, controlled medium, temperature, glucose concentration was conducted under pure glucose conditions. The optimum conditions of lactic acid production was investigated and compared with those of hydrolysate.

A Unified ARIA-AES Cryptographic Processor Supporting Four Modes of Operation and 128/256-bit Key Lengths (4가지 운영모드와 128/256-비트 키 길이를 지원하는 ARIA-AES 통합 암호 프로세서)

  • Kim, Ki-Bbeum;Shin, Kyung-Wook
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.21 no.4
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    • pp.795-803
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    • 2017
  • This paper describes a dual-standard cryptographic processor that efficiently integrates two block ciphers ARIA and AES into a unified hardware. The ARIA-AES crypto-processor was designed to support 128-b and 256-b key sizes, as well as four modes of operation including ECB, CBC, OFB, and CTR. Based on the common characteristics of ARIA and AES algorithms, our design was optimized by sharing hardware resources in substitution layer and in diffusion layer. It has on-the-fly key scheduler to process consecutive blocks of plaintext/ciphertext without reloading key. The ARIA-AES crypto-processor that was implemented with a $0.18{\mu}m$ CMOS cell library occupies 54,658 gate equivalents (GEs), and it can operate up to 95 MHz clock frequency. The estimated throughputs at 80 MHz clock frequency are 787 Mbps, 602 Mbps for ARIA with key size of 128-b, 256-b, respectively. In AES mode, it has throughputs of 930 Mbps, 682 Mbps for key size of 128-b, 256-b, respectively. The dual-standard crypto-processor was verified by FPGA implementation using Virtex5 device.

Flexural Strength of PHC Pile Reinforced with Infilled Concrete, Transverse and Longitudinal Reinforcements (내부충전 콘크리트와 횡보강 및 축방향 철근으로 보강된 PHC 말뚝의 휨강도)

  • Bang, Jin-Wook;Hyun, Jung-Hwan;Lee, Bang-Yeon;Lee, Seung-Soo;Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.25 no.1
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    • pp.91-98
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    • 2013
  • The pre-tensioned spun high strength concrete (PHC) pile has poor load carrying capacity in shear and flexure, while showing excellent axial load bearing capacity. The purpose of this study is to evaluate the flexural performance of the concrete-infilled composite PHC (ICP) pile which is the PHC pile reinforced with infilled concrete, transverse and longitudinal reinforcement for the improvement of shear and flexural load carrying capacity. The ICP pile specimen was designed to make allowable axial compression and bending moment higher load bearing capacity than those determined through the investigation of abutment design cases. The allowable axial compression and bending moment of the ICP pile was obtained using the program developed for calculating the axial compression - bending moment interaction. Then, ICP pile specimens were manufactured and flexural tests were performed. From the test results, it was found that the maximum bending moment of the ICP pile was approximately 45% higher than that of the PHC pile and the safety factor of ICP pile design was about 4.5 when the allowable bending moment was determined to be 25% of the flexural strength.

The Analysis and Design of Advanced Neurofuzzy Polynomial Networks (고급 뉴로퍼지 다항식 네트워크의 해석과 설계)

  • Park, Byeong-Jun;O, Seong-Gwon
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.39 no.3
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    • pp.18-31
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    • 2002
  • In this study, we introduce a concept of advanced neurofuzzy polynomial networks(ANFPN), a hybrid modeling architecture combining neurofuzzy networks(NFN) and polynomial neural networks(PNN). These networks are highly nonlinear rule-based models. The development of the ANFPN dwells on the technologies of Computational Intelligence(Cl), namely fuzzy sets, neural networks and genetic algorithms. NFN contributes to the formation of the premise part of the rule-based structure of the ANFPN. The consequence part of the ANFPN is designed using PNN. At the premise part of the ANFPN, NFN uses both the simplified fuzzy inference and error back-propagation learning rule. The parameters of the membership functions, learning rates and momentum coefficients are adjusted with the use of genetic optimization. As the consequence structure of ANFPN, PNN is a flexible network architecture whose structure(topology) is developed through learning. In particular, the number of layers and nodes of the PNN are not fixed in advance but is generated in a dynamic way. In this study, we introduce two kinds of ANFPN architectures, namely the basic and the modified one. Here the basic and the modified architecture depend on the number of input variables and the order of polynomial in each layer of PNN structure. Owing to the specific features of two combined architectures, it is possible to consider the nonlinear characteristics of process system and to obtain the better output performance with superb predictive ability. The availability and feasibility of the ANFPN are discussed and illustrated with the aid of two representative numerical examples. The results show that the proposed ANFPN can produce the model with higher accuracy and predictive ability than any other method presented previously.

A Study on Reliability Based Design Criteria for the Steel Highway Bridge (강도로교(鋼道路橋)의 신뢰성(信賴性) 설계규준(設計規準)에 관한 연구(硏究))

  • Cho, Hyo Nam;Kim, Woo Seok;Lee, Cheung Bin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.5 no.1
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    • pp.43-53
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    • 1985
  • This study proposes a reliability based design criteria for the steel bridge (H-beam, plate-girder and composite-beam), which is most common type of steel bridge, and also proposes the theoretical bases of nominal safety factors as well as load and rasistance factors based on the reliability theory. Major 2nd moment reliability analysis and design theories including both Cornell's MFOSM (Mean First Order 2nd Moment) Methods and Lind-Hasofer's AFOSM(Advanced First Order 2nd Moment) Methods are summarized and compared, and it has been found that Lind-Hasofer's approximate and an approximate Log-normal type reliability formula are well suited for the proposed reliability study. A target reliability index (${\beta}_0=3.5$) is selected as an optimal value considering our practice based on the calibration with the safety pravisions of the current steel bridge design code. Galambo's theory is used for the derivation of the algorithm for the evaluation of uncertainties associated with resistences by LRFD Format and SGST Format, whereas the magnitude of the uncertainties associated with load effects are chosen primarily by considering our level of practice. It may be concluded that the proposed LRFD reliability based design provisions for the steel highway bridge give more rational design than the current standard code for steel highway bridge.

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Enhanced Production of Astaxanthin in Paracoccus haeundaensis Strain by Physical and Chemical Mutagenesis (물리·화학적 돌연변이 유도를 통한 Paracoccus haeundaensis의 astaxanthin 생산량 증대)

  • Seo, Yong Bae;Jeong, Tae Hyug;Choi, Seong Seok;Lim, Han Kyu;Kim, Gun-Do
    • Journal of Life Science
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    • v.27 no.3
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    • pp.339-345
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    • 2017
  • Carotenoids are natural lipid-soluble pigments, which are produced primarily by bacteria, algae, and plants. Many studies have focused on the identification, production, and utilization of natural sources of astaxanthin from algae, yeast, and crustacean byproducts as an alternative to the synthetic pigment, which is mostly used today. The aim of the present study was to identify a mutant of Paracoccus haeundaensis by exposure to UV and ethyl methanesulfonate (EMS). The mutant was then exposed to nutrient stress conditions to isolate an astaxanthin-hyperproducing strain, followed by characterization of the mutant. The survival rate decreased in accordance with an increase in the UV exposure time and an increase in the EMS concentration. A mutant of the original P. haeundaensis strain was identified that showed hyperproduction of astaxanthin following exposure to UV irradiation (20 min) and EMS treatment (0.4 M concentration). The optimal culture conditions for the PUE mutant were $25^{\circ}C$, pH 7-8, and 3% NaCl. The effects of various carbon and nitrogen sources on the growth and astaxanthin production of PUE were examined. The addition of 1% raffinose and 3% potassium nitrate influenced cell growth and astaxanthin production. The selected mutant exhibited an increase of 1.58 folds in astaxanthin content compared to initial wild type strain. A genetically stable mutant strain obtained using mutagen (UV irradiation and EMS treatment) may be a suitable candidate for further industrial scale production of astaxanthin.

Immobilization of Late Transition Metal Catalyst on the Amino-functionalized Silica and Its Norbornene Polymerization (아미노-기능화된 실리카 위 후전이 금속 촉매 담지 및 이를 이용한 노보넨 중합)

  • Pacia, Rose Mardie P.;Kim, So Hui;Lee, Jeong Suk;Ko, Young Soo
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.313-318
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    • 2016
  • In this study, an amorphous silica was functionalized with aminosilane, N-[(3-trimethoxysilyl)propyl]ethylenediamine (2NS) and the late transition metal catalysts including ($(DME)NiBr_2$ and $PdCl_2$(COD)) were subsequently immobilized on the functionalized amorphous silica for norbornene polymerization. Effects of the polymerization temperature, polymerization time, Al/Ni molar ratio, and type of co-catalyst on norbornene polymerization were investigated. Unsupported late transition metal catalysts did not show any activities for norbornene polymerization. However, the $SiO_2$/2NS/Ni catayst with MAO system, with increasing polymerization temperature, increased the polymerization activity and decreased the molecular weight of the polynorbornene (PNB). Furthermore, the catalyst when increasing polymerization temperature caused the decrease in both the polymerization activity and molecular weight of PNB. This confirmed that the stability of $SiO_2$/2NS/Ni at a high temperature was greater than that of $SiO_2$/2NS/Pd. Also the longer polymerization time resulted in the higher conversion of norbornene for both catalysts. When the Al : Ni molar ratio was 1000 : 1, the highest activity (15.3 kg-PNB/($({\mu}mol-Ni^*hr$)) but lowest molecular weight ($M_n$ = 124,000 g/mol) of PNB were achieved. Also $SiO_2$/2NS/Ni catalyst with borate/TEAL resulted in diminishing the polymerization activity and molecular weight of PNB with increasing the polymerization temperature.