• Composites Research
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• v.16 no.2
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• pp.62-67
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• 2003

Interfacial properties and damage sensing for the carbon fiber/epoxy-amine terminated (AT)-polyetherimide (PEI) composite were performed using microdroplet test and electrical resistance measurements. As AT-PEI content increased, the fracture toughness of epoxy-AT-PEI matrix increased, and interfacial shear strength (IFSS) increased due to the improved fracture toughness by energy absorption mechanisms of AT-PEI phase. The microdroplet in the carbon fiber/neat epoxy composite showed brittle microfailure mode. At 15 phr AT-PEI content ductile microfailure mode appeared because of improved fracture toughness. After curing, the change in electrical resistance $\Delta\textrm{R}$) with increasing AT-PEI content increased gradually because of thermal shrinkage. Under cyclic stress, in the neat epoxy case the reaching time until same stress was faster and their slope was higher than those of 15 phr AT-PEI. The result obtained from electrical resistance measurements under curing process and reversible stress/strain was correspondence well with matrix toughness properties.

• Composites Research
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• v.15 no.1
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• pp.21-31
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• 2002

To overcome the disadvantages of conventional excavation technology various trenchless (or excavation free, or no-dig) repair-reinforcement technologies have been developed and tried. But trenchless technologies so far developed have some drawbacks such as high cost and inconvenience of operation. In this study, a repairing-reinforcing process for underground pipes with glass fiber fabric polymer composites using VARTM (Vacuum Assisted Resin Transfer Molding) has been developed. The developed process requires shorter operation time and lower cost with smaller and simpler operating equipments than those of the conventional trenchless technologies. For the reliable operation of the developed method, a simple method to apply pressure and vacuum to the reinforcement was devised and flexible mold technology was tried. Also, resin filling and cure status during RTM process were monitored with a commercial dielectrometry cure monitoring system, LACOMCURE. From the investigation, it has been found that the developed repairing-reinforcing technology with appropriate process variables and on-line cure monitoring has many advantages over conventional methods.

• Resources Recycling
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• v.18 no.4
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• pp.52-61
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• 2009

Purpose of this research is deducing optimum pretreatment method of electric arc furnace slag from comparing and investigating the properties of electric arc furnace slag and electric arc furnace slag concrete by existing pretreatment method and surface pretreatment method being used by this research. Besides, as the surface pretreatment method, the method of naturally drying for 6 hours after impregnating with an inorganic type silica solution for 1 day was used. From the results, comparing the hot water treatment method, surface treatment method being used by this research is more effective. Therefore, it is judged that surface treatment method is more effective in the decrease of expansibility of electric arc furnace slag and practical use.

• Applied Chemistry for Engineering
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• v.17 no.5
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• pp.539-546
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• 2006

A study on the polymerization of polyethylenedioxythiophene (PEDOT) and the carbonization process of a separator was carred out in order to apply conductive polymer PEDOT to the winding typed aluminum condenser as a solid electrolyte and a negative electrode. PEDOT was polymerized with ethylenedioxythiophene (EDOT) as a monomer and ferric-p-toluenesulfonate as an oxidizing agent. The separator of condenser element was carbonized to control its fibrous tissue for the purpose of making it easy to impregnate the PEDOT solution into the microporous etched pit of aluminum foil by preventing separator from concentrating the PEDOT solution on itself. The characteristics of condenser such as capacitance, dissipation factor, equivalent series resistance, and thermal resistance depended on a carbonization temperature and a carbonization time. It was found that a thickness and a density of the used separator were major parameters of carbonization process and the characteristics of condenser were affected by these parameters.

• Polymer(Korea)
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• v.32 no.3
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• pp.213-218
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• 2008

About 17% of historical properties in Korea were made of stones and most of them are exposed to weathering, as such that discoloring, cracking, and shattering occur from physical, chemical, mechanical, and biological effects due to outdoor placement. Proper treatments for conservation are necessary to prevent the weathering damage and to retain the original shape of stones. MMA, an acrylic monomer having low viscosity can be impregnated deep inside stones by consecutive compression and decompression process in a pressurized vessel. After the polymerization of MMA impregnate, the space inside of the stone was filled with PMMA. It is expected that water repellent and weather resistant properties will be improved because of the improved bonding of constituent materials in stones. In this study, moisture absorption, chemical resistance, and mechanical property of two domestic granites were examined after treating them with MMA for the purpose of determining the conservation value of this method that was possibly useful to the conservation of stone cultural assets.

• Membrane Journal
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• v.22 no.1
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• pp.54-61
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• 2012

To separate and recover of VOCs, supporting membranes using PEI were prepared by phase separation method and it was coated with PDMS to prepare PEI-PDMS hollow composite membrane. To investigate characteristic of prepared membrane, pure gas permeability was measured using oxygen and nitrogen, the stage cut and permeance property with feed concentration were evaluated using xylene, ethyl benzene, toluene and cyclohexane. Also, to check solvent resistance on VOCs, stress-strain property of membrane with immersion time in solvent were measured by DMA. The permeance value of $O_2$ and $N_2$ showed 63 GPU and 30 GPU respectively. Permeated VOCs concentration was decreased with increasing stage cut. But, conversely, recovery efficiency that was increased with increasing stage cut. As a result of DMA test, the stress and strain were 11.93 MPa and 13.52%, respectively.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.458-466
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• 2023

Structures in our surroundings deteriorate over time due to environmental and chemical factors, resulting in a decrease in their performance. The primary causes of degradation in concrete structures are carbonation, salt damage, and freeze-thaw cycles. Various maintenance methods exist to address these degradation issues. However, research and technological development for existing maintenance methods have been ongoing, but the accuracy and effectiveness of repair materials and techniques have not been extensively validated. Therefore, in this study, we conducted a material performance evaluation of various manufacturers' repair materials. Based on this evaluation, we applied corrosion inhibitors and epoxy, which are the methods most closely related to crack repair, to assess the durability performance against carbonation, salt damage, and freeze-thaw cycles. The results show approximately a two-fold performance improvement against carbonation and salt damage, and a 5% enhancement in repair performance against freeze-thaw cycles. Thus, it is considered effective in preventing rebar corrosion when appropriate maintenance is carried out according to environmental and chemical factors during structural repairs.

• Composites Research
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• v.37 no.1
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• pp.15-20
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• 2024

Since the residual stress of hydrogen tank is directly related to durability, it is very important to reduce it for safety. Type II~IV hydrogen tank are manufactured by the filament winding method, in which the fiber is impregnated with resin and wound around the liner. Residual stress in composite is affected by curing conditions and fiber tension etc. In this study, the effect of curing conditions on residual stress was analyzed when manufacturing a Type III hydrogen tank using carbon fiber filament winding process. First, the curing behavior of the epoxy resin was analyzed using a differential scanning calorimetry. Through this, the curing temperature was set to 140℃. During the same curing time, the specimens were cured under 2-stage curing condition that reached 140℃ earlier and a 4-stage curing condition that reached 140℃ later, respectively. After curing, the residual stress of the composite material was measured by the ring slitting method, and the experimental values were compared with numerical values. It was confirmed that there was a significant difference in residual stress according to the optimization of curing conditions.

• The Korean Journal of Rheology
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• v.11 no.1
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• pp.34-43
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• 1999

Flow-induced voids during resin impregnation and poor fiber wetting have known to be highly detrimental to the performance of composite parts manufactured by resin transfer molding(RTM) process. In this study, in order to overcome these serious problems encountered in RTM, the effects of surface modification by using silane coupling agent as a surface modifier on the flow characteristics, the wetting between resin and fiber, and void content were investigated. For the experiments of microscopic flow visualization and curing in a beam mold, glass fiber mats having plain weaving structure and epoxy resin were used. Modifying the fiber surface was found to result in a significant decrease of dynamic contact angle between resin and fiber and increase of wicking rate. Therefore, it was confirmed that the surface modification employed in this study could improve the wettability of reinforcing fibers as well as micro flow behavior. In addition, It was revealed that high temperature and low penetration rate of the resin are more favorable processing conditions to reduce the dynamic contact angle. However, surface modified fiber mat was found to have lower permeability than the unmodified one, which may be explained in terms of the decrease of contact time between resin and fiber owing to improvement of wetting. It was also exhibited that surface modification had a significant influence on void formation in RTM process, resulting in a decrease of overall void content due to the improvement of wetting in cured composite parts.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.11
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• pp.634-640
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• 2020

Failure analysis and heat-resistant were performed for an electric fuel pump that is installed in the fuel tank to transfer fuel to the engine of combat vehicles. The fuel pump with a DC motor was disassembled and inspected to determine the cause of failure. The failure phenomenon was classified into three categories based on observations of the inside of the housing: burnt winding, quick brush abrasion, and fuel leak into the pump. Based on the inspection results, it was estimated that overheating was the main cause of failure. The thermal test was conducted under the no-load condition in 24 hours, and the thermal sensor was installed on the stator surface and the brush holder to check the possibility of damage to the winding due to overheating. When the ambient temperature of the fuel pump was set to 68 ℃, the stator temperature increased to 135.9 ℃, and the winding of the motor was almost damaged. The test results confirmed the lack of heat resistance of fuel pump windings, and suggested that the type F of insulation class (below 155 ℃) of the windings and varnish should be replaced with type C or higher that can be used above 180 ℃.