• Title/Summary/Keyword: 함침도

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Preparation and Properties of Moisture-absorbing Film Impregnated with Polyacrylic Acid Partial Sodium Salt Material (폴리아크릴산 나트륨 염이 함침된 흡수성 고분자 복합 필름의 제조 및 특성 연구)

  • Lee, Youn Suk;Choi, Hong Yeol;Park, Insik
    • Korean Chemical Engineering Research
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    • v.52 no.4
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    • pp.530-537
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    • 2014
  • Moisture is a major factor causing the deteriorative physical change, microbial growth, and chemical reaction of the products. In this study, the moisture absorbing composite films have been prepared with moisture absorbing material of polyacrylic acid partial sodium salt (PAPSS) impregnated on LLDPE polymer for the functional packaging applications. The results showed that PAPSS impregnated film illustrated uniformly dispersed PAPSS particles in the LLDPE polymer matrix. The transparency of the PAPSS impregnated film decreased slightly at higher PAPSS concentrations. An increase in the PAPSS content for moisture-absorbing films showed a similar decrease in tensile strength, percent elongation at break, and tear strength. Their values of films impregnated with PAPSS of 0.5, 1, and 2% showed no significant difference. Meanwhile, 4% PAPSS films significantly decreased the values of mechanical properties compared to the films impregnated with different PAPSS levels. Values of the oxygen permeability and water vapor permeability for PAPSS impregnated films decreased significantly with greater PAPSS. The results indicate that 4% PAPSS impregnated in LLDPE films had high affinity of moisture absorbencies compared to the other films. The mathematical equation that best described the moisture sorption isotherm of each film sample was the GAB equation at $25^{\circ}C$. The crystallization and melting temperatures of PAPSS films were influenced by the addition of PAPSS material, but showed good thermal stability.

Conservation Treatment of Sand Stone by Pressurized Impregnation with Acrylic Materials (아크릴계 보존처리제를 이용한 사암의 가압함침 보존처리)

  • Kim, Youn-Cheol;Kim, Sa-Duk;Kim, Hyung-Joong
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.395-401
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    • 2011
  • After pressurized impregnation treatment, which has been proposed as an effective conservation method for stone cultural property, was executed with methyl metacrylate (MMA), MMA-butyl acrylate (PMB73) mixture and MMA-vinyl trimethoxy silane (PMV5) co-monomer mixture, the physical-chemical properties on the sand stone and the granite impregnated were evaluated. Compared to the case of granite, the impregnation ratios of sand stone showed larger values in the range of 3.2 to 3.7 wt% and these were increased up to 32% when the decompression process was applied to autoclave. The physical properties of sand stone such as anti-moisture property, flexural strength, impact property and ultrasonic velocity were also higher values than those of granite, which can be interpreted by high impregnation ratio resulted in many void within sand stone. The impact failure energy was 1.22 J for PMMA, 1.84 J for PMB73, and 2.8 J for PMV5, respectively. Since the inorganic affinity of treatment agent is more effective than the molecular structure of acrylic agent, PMV5 improved inorganic property indicates the optimum impact property.

Carbon-nanotube-based Spacer Fabric Pressure Sensors for Biological Signal Monitoring and the Evaluation of Sensing Capabilities (생체신호 모니터링을 위한 CNT 기반 스페이서 직물 압력센서 구현 및 센싱 능력 평가)

  • Yun, Ha-yeong;Kim, Sang-Un;Kim, Joo-Yong
    • Science of Emotion and Sensibility
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    • v.24 no.2
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    • pp.65-74
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    • 2021
  • With recent innovations in the ICT industry, the demand for wearable sensing devices to recognize and respond to biological signals has increased. In this study, a three-dimensional (3D) spacer fabric was embedded in a single-wall carbon nanotube (SWCNT) dispersive solution through a simple penetration process to develop a monolayer piezoresistive pressure sensor. To induce electrical conductivity in the 3D spacer fabric, samples were immersed in the SWCNT dispersive solution and dried. To determine the electrical properties of the impregnated specimen, a universal testing machine and multimeter were used to measure the resistance of the pressure change. Moreover, to examine the changes in the electrical properties of the sensor, its performance was evaluated by varying the concentration, number of penetrations, and thickness of the specimen. Samples that penetrated twice in the SWCNT distributed solution of 0.1 wt% showed the best performance as sensors. The 7-mm thick sensors showed the highest GF, and the 13-mm thick sensors showed the widest operating range. This study confirms the effectiveness of the simple process of fabricating smart textile sensors comprising 3D spacer fabrics and the excellent performance of the sensors.

Effect of Coagulating Nonsolvent on Impregnation of Inorganic Fluor in the PSF Membranes Prepared by Phase Inversion (상반전 폴리설폰 막에 무기 fluor의 함침에 있어 침지용 비용매가 미치는 영향)

  • 한명진;남석태
    • Membrane Journal
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    • v.11 no.2
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    • pp.89-95
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    • 2001
  • Polysulfone membranes containing an inorganic fluor, cerium activated yttrium silicate (CA Y5), were prepared via the phase inversion technique. The casting solutions with the fluor' were solidified to result in a membrane by using two different nonsolvent coagulants, water and isopropanol. In the process, the fluor worked as a monitioring agent for investigating the characteristics of the phase inversiun process. On the initial contact with water as nonsolvent, the induction of rapid polymer collapse results.in the entrapment of the fluor in the formed membrane structure. Impregnated fluor is dispersed in the polymer structure rather than being enveloped by polymer molecules. In comparison, the fluor is localized in the cell-like structure of membrane, as the cast solution film is cuagulated by immersion into a isopropanol bath.

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Fabrication of ceramic fibre composite and improvement of its property (세라믹 섬유 복합체의 제조 및 물성 향상)

  • 김법진;신재혁;신동우;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.2
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    • pp.203-212
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    • 1996
  • Applicability of SiC coating through CVD process and PCS(polycarbosilane) impregnation for the oxidation resistance and mechanical properties of C/C composite was studied. The SiC layer coated by CVD was deposited uniformly on the C/C composite, whereas the SiC converted from PCS impregnation wetted around individual carbon fiber. The PCS-impregnated C/C composite exhibited a significant increase of bending strength in comparison with as received C/C composite. This increase in the mechanical property could be attributed to the high bonding strength between fibers due to an impregnated SiC phase. The PCS-impregnated C/C showed 25% improvement in density, 3.5 times higher MOR and 2.8 times higher oxidation resistance compared to the as-received C/C. The increments due to PCS impregnation were more effective than CVD process.

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Promotion effect of Ce on coke resistance over Ni-based catalyst in combined steam and carbon dioxide reforming of methane (메탄의 수증기-이산화탄소 복합개질 반응에서 니켈 촉매의 탄소침적 저항성에대한 Ce 증진효과)

  • Koo, Kee-Young;Roh, Hyun-Seog;Jung, Un-Ho;Yoon, Wang-Lai
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.208-208
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    • 2009
  • 메탄의 수증기-이산화탄소 복합개질반응에서 니켈 촉매의 탄소 침적 저항성에대한 Ce 증진 효과를 살펴보기 위해, Ni-Ce/${\alpha}-Al_2O_3$ 촉매를 제조하였다. Ce/Ni 비율 변화에 따른 촉매 비표면적, Ni 입자 분산도 및 촉매 활성 변화를 살펴보았고, Ce 첨가량을 최적화 할 수 있었다. Ce/Ni 비율 증가에 따라 NiO 결정크기가 감소하고 표면적과 Ni 분산도는 증가하였다. 특히, Ce/Ni=0.5 첨가 시, 촉매는 가장 넓은 비표면적과 Ni 분산도를 가졌으며, 우수한 촉매 활성 및 높은 탄소 침적 저항성을 보였다. 또한, 본 연구에서는 Ni과 Ce 담지 방법에 따른 Ni 분산도 향상과 Ni과 Ce간의 접촉 면적 극대화를 통한 활성산소 공급 향상에 대한 영향을 함께 살펴보았다. Ni과 Ce를 동시 함침법과 연속 함침법으로 담지하여 비교한 결과, 동시 함침법으로 제조한 Ni-Ce/${\alpha}-Al_2O_3$ (Ce/Ni=0.5) 촉매가 가장 우수한 촉매 성능 및 높은 탄소 침적 저항성을 보였다. 이는 동시 함침법으로 고분산된 Ni 입자와 담체간의 강한 상호작용 형성과 원활한 활성 산소 공급에 기인한 것이다.

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A Study on Characteristics of Concrete Impregnated with the Inorganic Surface Penetration Agents (무기계 표면침투제 용액으로 함침한 콘크리트의 특성 연구)

  • Bae, Ju-Seong;Kim, Hyeok-Jung;Park, Gook-Jun;Han, Jong-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.1
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    • pp.71-77
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    • 2010
  • The concrete structure's durability and integrity is reduced owing to various deterioration phenomena. Therefore, it is important to prevent the deterioration phenomena. This study inquired into the various experimental results of specimens with different dilution concentration and impregnation time by the each solution to present the economic and efficient using method of the inorganic surface penetration agents. As a results, the reasonable dilution concentration and impregnation time of colloidal silica solutions are 15% and 5 minute and for the sodium alumina silicate solutions are 17% and 10 second.

Resin Content and Dimensional Rise in Board Impregnated with Phenol Resin for Making Woodceramics - Effect of Steam Injection Time - (우드세라믹 제조용 석탄산수지 함침보드의 수지 함침율과 치수 증가율 - 증기분사 시간의 영향 -)

  • Oh, Seung-Won
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.2
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    • pp.158-164
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    • 2002
  • The properties of new porous carbon materials "Woodceramics" are affected by the characteristics of raw boards. To investigate of density profile and resin contents in impregnated boards, control board and 3 types of steam-injected boards were made by steam injection time, The wood species used for manufacturing boards was Sugi(Cryptomeria japonica). The results are as follows: 1) The density gradient of board after 10 minutes steam injection was the smallest and non-steamed board was largest. 2) The resin content and dimensional rise decreased with increase of board density, and were the largest in board after 10minutes steam injection but there was little difference between boards after 5 and 10 minutes steam injection.

Preparation of an Inorganic Scintillator Loaded Film for the Measurement of Surface Contamination and its Performance Test (표면오염 측정용 무기섬광 함침 필름의 제조 및 성능 평가)

  • 서범경;이근우;임난주;박진호;한명진
    • Journal of Energy Engineering
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    • v.13 no.2
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    • pp.93-100
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    • 2004
  • The smear media possible to sampling and radiation detection was prepared and evaluated for the surface contamination using indirect method. The films were made by impregnating Cerium Activated Yttrium Silicate (CAYS) in a polysulfone membrane. The membranes used solution as a dimethylformamide (DMF) and methylene chloride (MC), polysulfone as a polymer matrix and CAYS as a inorganic scintillator. The proximity membranes were prepared with single- and double-layered structure. The solidified methods were immersion to the nonsolvent bath such at water and ethanol and solvent evaporation. The measurement of the photon produced by interaction with radiation and inorganic scintillator used a photomultiflier tube (PMT), amplifier, and counter. In the comparison with the low background alpha/beta counter, the counter rate using inorganic scintillator proximity membrane for the $\^$14/C surface contamination was about 50%. Also. the $^3$H counting results revealed that the prepared membranes were efficient to monitor the surface contaminated with the low energy be-ray emitter nuclides.