• Title/Summary/Keyword: 한국화학연구원

Search Result 1,252, Processing Time 0.023 seconds

Synthesis and Characterization of Phosphorus Polyurethanes Using Phosphorus Polyols (인계 폴리올을 이용한 난연성 폴리우레탄의 합성 및 특성 분석)

  • Kim, Taeyoon;Kim, Yong Gap;Lim, Chung-Sun;Seo, Bongkuk;Lee, Wonjoo
    • Journal of Adhesion and Interface
    • /
    • v.20 no.2
    • /
    • pp.61-65
    • /
    • 2019
  • In this study, phosphorus polyols, having a molecular weight of 880 to 1,560 g/mol, were synthesized by reacting phenylphosphonic dichloride (PPDC), allylphosphonic dichloride (APDC), and ethylene glycol (EG) in solvent, to enhance flame retardance of polyurethane. Phosphorus polyurethanes were polymerized using the synthesized phosphorus polyols, polycarbonate diol (PCD), and 4,4'-diphenylmethane diisocyanate (MDI) by a melt polymerization method. As increasing phosphorus contents of the phosphorus polyurethanes, we observed that the remaining char amount increased. This tendency was also confirmed in the following UL-94V test. We found that when the synthesized phosphorus polyols were applied, the resulting phosphorus polyurethanes show UL-94V0 grade at above 0.5 wt% phosphorus contents.

Quantitative analysis of phosphorus by HERETIC-NMR method (HERETIC-NMR법을 이용한 인의 정량분석)

  • Lim, Heon-Sung;Park, Chan-Jo;Lee, Sueg-Geun
    • Analytical Science and Technology
    • /
    • v.21 no.5
    • /
    • pp.438-441
    • /
    • 2008
  • We have developed an alternative to the internal chemical reference based on a calibrated reference signal which is not a real NMR line but an electronically produced signal (HERETIC) and determined the phosphorus concentration using this method. The area ratio of HERETIC and sample peaks obtained from the standard samples was used to measure the concentrations of different samples directly. The analysis of phosphorus by this method showed the excellent linear regression coefficient ($R^2=0.9999$) for the concentration range from 20 ppm to 500 ppm with HERETIC peak as reference.

Modified LOGIT(MLOGIT) Transformation: Prediction of $IC_{50}$ Value from Two Arbitrary Concentration Data

  • 유성은;차옥자
    • Bulletin of the Korean Chemical Society
    • /
    • v.16 no.2
    • /
    • pp.110-112
    • /
    • 1995
  • A LOGIT transformation is a method to estimate IC50 values with two arbitrary concentration data when complete dose response curves(DRCs) are not available. We propose a modified LOGIT transformation (MLOGIT) which predicts IC50 values more accurately than the conventional LOGIT method.

Synthesis and Characterization of Water-borne Pressure Sensitive Adhesives Polymerized using Styrenated Phenol Type Surfactants (스티렌페놀계 계면활성제 기반 친환경 수계 점착제 합성 및 특성 분석)

  • Song, Young Kyu;Lee, Sang-Ho;Park, Young Il;Kim, Jin Chul
    • Journal of Adhesion and Interface
    • /
    • v.21 no.4
    • /
    • pp.156-161
    • /
    • 2020
  • Waterborne pressure sensitive adhesives (PSA) has been received much attentions from both academia and industries as an environmental friendly-technology because it can significantly reduce use of hazardous organic volatile solvents. However, in the process of the mass production of waterborne PSAs, hazardous phenol type amphiphilic compounds have essentially been used as surfactants for the emulsion polymerization. For the reason, tremendous research efforts have been made to develop environment-friendly organic surfactant which can replace the phenol type surfactants. In this study, we verify the potential of a new class of surfactants based on the styrenated phenol derivatives as an alternative to the phenol type surfactants.

Chemical Constituents from the Fruit Bodies of Tricholoma matsutake (송이(Tricholoma matsutake) 자실체의 화학성분)

  • Lee, Hak-Ju;Choi, Yun-Jeong;Ka, Kang-Hyeon;Bak, Won-Chul
    • Journal of the Korean Wood Science and Technology
    • /
    • v.31 no.4
    • /
    • pp.63-70
    • /
    • 2003
  • One alkaloid derivatives, one amide and two steroids were isolated from the fruit bodies of Tricholoma matsutake. The structures were determinded as adenosine, methyl trans-cinnamate, ergosterol and ergosta-4, 6, 8 (14), 22-tetraen-3-one, respectively, on the basis of spectroscopic data.