• Title/Summary/Keyword: 피넨

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Characterization of Fragrances from Lilac Blossom by Gas Chromatography-Mass Spectrometry (GC-MS에 의한 라일락 꽃 향기 분석)

  • Kim, Nam-Sun;Lee, Dong-Sun
    • Analytical Science and Technology
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    • v.17 no.1
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    • pp.85-89
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    • 2004
  • Fragrance components of lilac (Syringa vulgaris) blossom have been characterized in this paper. The accurate characterization of fragrances collected from lilac blossom was carried out by solid-phase trapping-solvent extraction and gas chromatography-ion trap mass spectrometry. According to lilac species, the chemical compositions were significantly different. Benzaldehyde, phenylacetaldehyde, and ${\alpha}$-farnesene were found as the predominant component of white lilac blossom whereas benzaldehyde, ${\alpha}$-pinene, and ocimene were those of pale purple lilac. The enantiomeric analysis of ${\alpha}$-pinene in lilac blossom was found in the form of ( ).

Change of Physical Property of Rubber Compound by Terpene Modified Phenolic Resin Structure (테르펜 개질 페놀 수지 구조에 따른 배합고무 물성 변화)

  • Kim, Kun Ok;Kim, Do-Heyoung;Song, Yo Soon
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.310-316
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    • 2020
  • Terpene-modified phenolic resins were used to improve the tires wet traction related to the driving safety and also rolling resistance related to fuel efficiency. In this work, alpha-pinene, beta pinene, and delta limonene resins, which constitute different basic structures of terpene-modified phenolic resins, were individually added to the tread compounds of tires and their physical properties were compared with those of the alkyl phenol resin compounds. Alkyl phenolic resins showed no significant difference in tangent delta from terpene-modified phenolic resins at 0 ℃, which is related to wet traction, but showed higher tangent delta at 80 ℃, which is related to rolling resistance, indicating smaller fuel efficiency improvement effects. Among the terpene-modified phenolic resins, beta pinene one showed improved wet traction and fuel efficiency compared to those of other resins. Delta limonene resin showed the best wet traction improvement effect, and alkyl phenolic resins showed relatively high tensile strength and abrasion property. All terpene-modified resins exhibited better rolling resistance than those of alkyl phenolic ones so that they can be said to have better fuel efficiency improvement effects and also to improve other properties compared to those of blanks. Terpene-modified phenolic resins could be used when mixing tire compounds referring to the properties of the phenolic resins revealed in this work, which could result in preparing compounds with improved wet traction and rolling resistance.

환경친화성 천연세정제의 유화특성에 관한 연구

  • Jeong, Gap-Seop;Na, Seok-Eun;An, Dae-Myeong
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.05a
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    • pp.319-321
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    • 2005
  • 음이온계와 양이온계의 계면활성제를 사용하여 천연세정성분인 리모넨의 유화특성을 고찰한 결과 두 계열 모두 만족할 만한 결과를 나타내지 못하였고, 교반속도는 1500 rpm이상에서는 영향이 거의 없었으며, 유화온도는 상온에서도 가능할 것으로 판단된다. 유사한 구조와 물성을 가지는 리모넨과 ${\sigma}$-피넨을 비교한 결과 리모넨이 우수한 것으로 나타났으며 무독성인 IPA를 첨가한 경우가 첨가하지 않은 것보다 양호한 결과를 얻었다.

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Aroma Components and Antioxidant Activities of Pure Rosemary Essential Oil Goods Produced in Different Countries (순수 로즈마리 정유제품의 생산국별 향기성분과 항산화 활력)

  • Woo, Jin-Ho;Mok, Min-Gyun;Han, Koh-Woon;Lee, Sang-Yong;Park, Kuen-Woo
    • Horticultural Science & Technology
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    • v.28 no.4
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    • pp.696-700
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    • 2010
  • Thirty-one units of pure rosemary essential oil (EO) in domestic and foreign distribution markets were collected. Aromatic components of these samples were analyzed and antioxidant activity was measured. As the result, major aromatic components were identified such as ${\alpha}$-pinene, camphene, ${\beta}$-pinene, 1.8-cineole, verbenone and borneol. Major components of rosemary EO were different according to countries. Essential oil from France had good quality. Essential oil cultivated and extracted in South Korea had more content than the collected essential oil in components of ${\alpha}$-pinene and camphene. Only 16% of the total 31 unit samples satisfied the content of 9 ingredients presented by ISO. The quality of EDA was shown as 4.8-96.0%, remarkable differences per specimen. A total of 31 units, only 13% of EO showed more than 60% antioxidant activity. Difference of antioxidant activity did not correspond with specific component. Essential oil from Swiss had high antioxidant activity.

Development of a Layered Nanocomposite Containing α-pinene to Treat Scuticociliatosis Caused by Miamiensis avidus (알파-피넨(alpha-pinene)이 함유된 스카티카증 치료용 나노복합체 개발 및 Miamiensis avidus에 대한 살충 효과)

  • Jung, Chul-Yeon;Lee, Sukkyoung;Yoon, Joo-Young;Han, Yang-Su;Lee, Jehee
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.51 no.1
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    • pp.15-22
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    • 2018
  • Alpha-pinene is an organic compound that possesses antibiotic and anti-parasitic activities. In this study, we developed a layered nanocomposite to combat against Miamiensis avidus which causes scuticociliatosis in the olive flounder Paralichthys olivaceus. We used a solid-solid reaction to develop the layered nanocomposite, incorporating-pinene ($C_{10}H_{16}$) into organically modified montmorillonite. We used cetyltrimethylammonium cations as the interlayered modifier for the adsorption of hydrophobic pinene molecules. The X-ray diffraction patterns of the nanocomposite structure showed that the basal spacing increased from $9.6{\AA}$ to $30.4{\AA}$. Interestingly, the fraction of ${\alpha}$-pinene released remained constant for a long period of time (228 h) due to the layered nature of the nanocomposite. Additionally, optical microscopic images of the treated scuticociliatids revealed that their cells were lysed, and this effect increased with the increasing concertration of ${\alpha}$-pinene. Histopathological assessment of ${\alpha}$-pinene nanocomposite-treated olive flounder gills revealed no significant morphological changes, even at the highest concentration of the ${\alpha}$-pinene. The nanocomposite has several advantages, including easy handling, high solubility, low toxicity, and the easy formulation of granules or powder, which improve the pesticidal activity of ${\alpha}$-pinene. Collectively, our results suggest that ${\alpha}$-pinene nanocomposite may be a useful treatment against scuticociliatosis.

Development of Primary Standard Gas Mixtures for Monitoring Monoterpenes (α-pinene, 3-carene, R-(+)-limonene, 1,8-cineole) Ambient Levels (at 2 nmol/mol) (대기 중 모노테르펜 (α-피넨, 3-카렌, R-리모넨, 1,8-시네올) 측정을 위한 혼합표준가스개발)

  • Kang, Ji Hwan;Kim, Mi Eon;Kim, Young Doo;Rhee, Young Woo;Lee, Sangil
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.3
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    • pp.320-328
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    • 2016
  • Among biogenic volatile organic compounds (BVOCs) in the natural ecosystem, monoterpenes, along with isoprene, play important roles in atmospheric chemistry and make significant impacts on air pollution and climate change, especially due to their contribution to secondary organic aerosol production and photochemical ozone formation. It is essential to measure monoterpene concentrations accurately for understanding their oxidation processes, emission processes and estimation, and interactions between biosphere and atmosphere. Thus, traceable calibration standards are crucial for the accurate measurement of monoterpenes at ambient levels. However, there are limited information about developing calibrations standards for monoterpenes in pressured cylinders. This study describes about developing primary standard gas mixtures (PSMs) for monoterpenes at about 2 nmol/mol, near ambient levels. The micro-gravimetric method was applied to prepare monoterpene (${\alpha}$-pinene, 3-carene, R-(+)-limonene, 1,8-cineole) PSMs at $10{\mu}mol/mol$ and then the PSMs were further diluted to 2 nmol/mol level. To select an optimal cylinder for the development of monoterpene PSMs, three different kinds of cylinders were used for the preparation and were evaluated for uncertainty sources including long-term stability. Results showed that aluminum cylinders with a special internal surface treatment (Experis) had little adsorption loss on the cylinder internal surface and good long-term stability compared to two other cylinder types with no treatment and a special treatment (Aculife). Results from uncertainty estimation suggested that monoterpene PSMs can be prepared in pressured cylinders with a special treatment (Experis) at 2 nmol/mol level with an uncertainty of less than 4%.

Insecticidal Activity of Chinese Honeysuckle, Quisqualis indica Extracts against Scale Insects (사군자추출물의 깍지벌레류에 대한 살충활성)

  • Song, Jin Sun;Lee, Chae Min;Choi, Young Hwa;Lee, Dong Woon
    • The Korean Journal of Pesticide Science
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    • v.18 no.2
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    • pp.104-114
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    • 2014
  • Scale insects heavily damaged many agricultural crops and trees in urban and forest areas. This study was conducted to carry out alternative control methods for environmentally friendly control of scale insects. Hot water extract of Quisquali indica produced high mortality against the black pine bast scale, Matsucoccus thunbergianae in previously experiment. Methanol extract obtained from fruit of Q. indica was successively fractionated using hexane, chloroform, ethyl acetate, buthanol and water which were examined by exposing for their insecticidal activity against four Cocoidea species (Eriococcus lagerstroemiae, Ceroplastes japonicus, Crisicoccus pini and Planococcus citri) in laboratory. Hexane fraction gave the highest insecticidal activity against scale insect pest. GC-mass analysis confirmed that the main compounds of Q. indica were alpha-pinene, methyl palmitate, eugenol, methyl myristate, phthalic acid mono(2-ethylhexyl)ester and palmitic acid. Among those compounds, ${\alpha}$-pinene was included 10 hexane subfractions. $LC_{50}$ of ${\alpha}$-pinene was 0.0114 ppm against 2nd instar of E. lagerstroemiae. These results suggest that Q. indica extracts might be used as an alternative control agent of scale insects.

Field Bioassay for Longhorn Pine Sawyer Beetle Monochamus alternatus (Coleoptera: Cerambycidae) in Korea Based on Aggregation Pheromone 2-(Undecyloxy)ethanol (집합페로몬 2-(Undecyloxy)ethanol을 이용한 솔수염하늘소 유인 실험)

  • Lee, Sung-Min;Hong, Do Kyung;Park, Jongseong;Lee, Jinho;Jang, Sei-Heon;Lee, ChangWoo
    • Journal of Life Science
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    • v.25 no.12
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    • pp.1445-1449
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    • 2015
  • The pinewood nematode Bursaphelenchus xylophilus (Nematoda: Parasitaphelenchidae) poses a serious threat to pine forests in Europe and East Asia, leading to a debilitating pine wilt disease. Infected pine trees in Korea are generally fumigated or crushed to small wood chips after felling. Although pine wilt disease often recurs in pest management sites, there are no adequate means to monitor the effectiveness of pest control measures in those sites. Recently, a male-produced aggregation pheromone, 2-(undecyloxy)ethanol, was shown to be useful for attracting several Monochamus species, which are vectors for the pinewood nematodes. In this study, we investigated the abilities of 2-(undecyloxy)ethanol at three different doses (175, 350, and 700 mg), as well as host plant volatiles (α-pinene and ethanol), to attract M. alternatus (Coleoptera: Cerambycidae) at a pine forest in Pohang, Korea where infected pine trees had been cut down and fumigated. Twenty-seven M. alternatus were captured in cross-vane panel traps made of polyethylene terephthalate bottles and acrylic sheets. The results indicate that a high dose of 2-(undecyloxy)ethanol (700 mg per trap) is the most effective for attracting M. alternatus. The aggregation pheromone could be used to monitor the effectiveness of pest control measures as well as M. alternatus populations.