• Title/Summary/Keyword: 플라즈마 활성수

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Sterilization of Scoria Powder by Corona Discharge Plasma (코로나 방전 플라즈마를 이용한 화산암재 분말 살균)

  • Jo, Jin Oh;Lee, Ho Won;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.386-391
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    • 2014
  • Atmospheric-pressure nonthermal corona discharge plasma was applied to the sterilization of biologically contaminated scoria powder. Escherichia coli (E. coli) culture solution was uniformly sprayed throughout the scoria powder for artificial inoculation, which was well mixed to ensure uniformity of the batch. The effect of the key parameters such as discharge power, treatment time, type of gas and electrode distance on the sterilization efficiency was examined and discussed. The experimental results revealed that the plasma treatment was very effective for the sterilization of scoria powder; 5-min treatment at 15 W could sterilize more than 99.9% of E. coli inoculated into the scoria powder. Increasing the discharge power, treatment time or applied voltage led to an improvement in the sterilization efficiency. The effect of type of gas on the sterilization efficiency was in order of oxygen, synthetic air (20% oxygen) and nitrogen from high to low. The inactivation of E. coli under the influence of corona discharge plasma can be explained by cell membrane erosion or etching resulting from UV and reactive oxidizing species (oxygen radical, OH radical, ozone, etc.), and the destruction of E. coli cell membrane by the physical action of numerous corona streamers.

Study of Stabilization Process of PAN Precursor and its Characteristics Change by Plasma Treatment (플라즈마 처리 방법을 이용한 PAN 전구체 특성 변화 연구)

  • Kang, Hyo-Kyoung;Kim, Jung-Yeon;Kim, Hak-Yong;Choi, Yeong-Og
    • Composites Research
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    • v.34 no.1
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    • pp.23-29
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    • 2021
  • Commercialized carbon fiber obtained from polyacrylonitrile(PAN) precursor is subjected to oxidation stabilization at 180 to 300℃ in air atmosphere and carbonization process at 1600℃ or lower in inert gas atmosphere. Both of these processes use a lot of time and high energy, but are essential and important for producing high-performance carbon fibers. Therefore, in recent years, an alternative stabilization technology by being assisted with various other energy sources such as plasma, electron beam and microwave which can shorten the process time and lower energy consumption has been studied. In this study, the PAN precursor was stabilized by using plasma treatment and heat treatment continuously. The morphology, structural changes, thermal and physical properties were analyzed using Field emission scanning electron microscopy(FE-SEM), X-ray diffraction(XRD), Fourier transform infrared(FT-IR), Thermogravimetric analysis(TGA) and Favimat.

Electrical Discharge Plasma in a Porous Ceramic Membrane-supported Catalyst for the Decomposition of a Volatile Organic Compound (다공질 세라믹지지 촉매 상에서의 플라즈마 방전을 이용한 휘발성유기화합물의 분해)

  • Jo, Jin-Oh;Lee, Sang Baek;Jang, Dong Lyong;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.433-437
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    • 2013
  • Electrical discharge plasma created in a multi-channel porous ceramic membrane-supported catalyst was applied to the decomposition of a volatile organic compound (VOC). For the purpose of improving the oxidation capability, the ceramic membrane used as a low-pressure drop catalyst support was loaded with zinc oxide photocatalyst by the incipient wetness impregnation method. Alternating current-driven discharge plasma was created inside the porous ceramic membrane to produce reactive species such as radicals, ozone, ions and excited molecules available for the decomposition of VOC. As the voltage supplied to the reactor increased, the plasma discharge gradually propagated in the radial direction, creating an uniform plasma in the entire ceramic membrane above a certain voltage. Ethylene was used as a model VOC. The ethylene decomposition efficiency was examined with experimental variables such as the specific energy density, inlet ethylene concentration and zinc oxide loading. When compared at the identical energy density, the decomposition efficiency obtained with the zinc oxide-loaded ceramic membrane was substantially higher than that of the bare membrane case. Both nitrogen and oxygen played an important role in initiating the decomposition of ethylene. The rate of the decomposition is governed by the quantity of reactive species generated by the plasma, and a strong dependence of the decomposition efficiency on the initial concentration was observed.

Reduction of gate leakage current for AlGaN/GaN HEMT by ${N_2}O$ plasma (${N_2}O$ 플라즈마에 의한 AlGaN/GaN HEMT의 누설전류 감소)

  • Yang, Jeon-Wook
    • Journal of IKEEE
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    • v.11 no.4
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    • pp.152-157
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    • 2007
  • AlGaN/GaN high electron mobility transistors (HEMTs) were fabricated and the effect of ${N_2}O$ plasma on the electrical characteristics of the devices was investigated. The HEMT exposed to ${N_2}O$ plasma formed by 40 W of RF power in a chamber with pressure of 20 mTorr at a temperature of $200^{\circ}C$, exhibited a reduction of gate leakage current from 246 nA to 1.2 pA by 10 seconds treatment. The current between the two isolated active regions reduced from 3 uA to 7 nA and the sheet resistance of the active layer was lowered also. The variations of electrical characteristics for HEMT were occurred within a short time expose of 10 seconds and the successive expose did not influence on the improvements of gate leakage characteristics and conductivity of the active region. The reduced leakage current level was not varied by successive $SiO_2$ deposition and its removal. The transconductnace and drain current of AlGaN/GaN HEMTs were increased also by the expose to the ${N_2}O$ plasma.

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Efficacy of Hydrogen Peroxide on Root Rot Disease of Ginseng Sprouts (과산화수소를 이용한 새싹인삼의 뿌리썩음병 방제효과)

  • Jong-Seok, Song;Geum Ran, Ahn;Sunkyung, Jung
    • Research in Plant Disease
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    • v.28 no.4
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    • pp.204-208
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    • 2022
  • Hydrogen peroxide is an eco-friendly oxidizing agent, which has exhibited a broad spectrum of antimicrobial activity without adverse environmental impact. This study was conducted to investigate the antifungal effect of hydrogen peroxide treatment against Cylindrocarpon destructans, and consequently to evaluate its control efficacy against root rot disease of 2-year-old ginseng plants. Hydrogen peroxide treatment strongly inhibited the viability of C. destructans conidia in vitro. The hydrogen peroxide at a concentration of 300 mg/l significantly reduced disease infection of the ginseng root when treated to spore suspension (107 conidia/ml). Spraying with 300 mg/l of hydrogen peroxide reduced the root rot disease of the ginseng sprouts by 15% compared to the untreated control at 14 days after the inoculation. However, 300 mg/l of hydrogen peroxide delayed the emergence of ginseng plants during sprouting under aeroponic conditions. Further works need to be done to provide an acceptable control efficacy of hydrogen peroxide against the disease and its good safety to ginseng plants.

Helium dielectric barrier discharge-cold plasma treatment for microbiological safety and preservation of onion powder (유전체 방벽 방전 콜드 플라즈마 기술을 이용한 양파 분말 미생물 안전성 향상 및 품질 보존)

  • Won, Mee Yeon;Choi, Ha Young;Lee, Kwang Sik;Min, Sea Cheol
    • Korean Journal of Food Science and Technology
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    • v.48 no.5
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    • pp.486-491
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    • 2016
  • Efficacy of dielectric barrier discharge-cold plasma treatment (DBD-CPT) for microbial decontamination of onion powder was evaluated. Onion powder, inoculated with Escherichia coli O157:H7, Salmonella Enteritidis, or Listeria monocytogenes, was treated with helium DBD-CPT. DBD-CPT (9 kV, 20 min) inhibited E. coli O157:H7, S. Enteritidis, and L. monocytogenes by $1.4{\pm}0.5$, $2.3{\pm}0.3$, and $1.2{\pm}0.0log\;CFU/cm^2$, respectively. The inactivation levels of E. coli O157:H7, S. Enteritidis and L. monocytogenes increased by $2.2{\pm}0.1$, $2.5{\pm}0.1$ and $1.9{\pm}0.3log\;CFU/cm^2$, respectively, as water activity increased from 0.4 to 0.8, and increased by $2.3{\pm}0.4$, $2.1{\pm}0.1$ and $1.6{\pm}0.1log\;CFU/cm^2$, respectively, as the particle size increased from 0.3 to $1.0cm^2$. Neither the ascorbic acid and quercetin concentrations nor the color of onion powder was changed by DBD-CPT (p>0.05). These results demonstrate the potential for application of DBD-CPT in improving microbiological safety of onion powder while preserving the physicochemical properties.

Red-tide Prevention and Killing Treatment of Seaweed and Algae (적조방재와 해조류 사멸 처리)

  • Soh, Dea-Wha;Bai, Mingdong;Bai, Xiyao
    • Journal of the Speleological Society of Korea
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    • no.75
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    • pp.9-13
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    • 2006
  • 자유수산기는 단분자 제조공정으로 분자, 원자 층에서 가공되어 기타 활성입자와 함께 얻어지며, 20% 이상의 고 밀도 질량 비는 양산공정에 중요한 의미를 부여한다. 자유수산기가 선박안정수의 외래침입 생물과 적조처리 및 양식수체 정화에도 효과적인 새로운 처리기술로 선박 안정수에 포함되어 타 지역으로부터 옮겨지는 외래침입생물 처리 방안의 하나로, 강 전리방전 기술을 적용하여 고 밀집 산소와 물분자로부터 고농도 수사자유기(OH: hydroxyl radical)를 전리, 발생시켜서 활성입자를 신속히 확산시켜 비교적 낮은 수산기농도 하에서 유해성침입생물을 사멸 처리하는 환경 친화적 녹색 청정처리방법을 제안하였다.

Coastal Sea Red-tide Prevention and Killing Treatment of Seaweed and Algae (연안해역의 적조방제와 해조류 사멸 처리)

  • 소대화;백민동;백희요;선우택
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2004.05b
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    • pp.285-288
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    • 2004
  • 자유수산기는 단분자 제조공정으로 분자, 원자 충에서 가공되어 기타 활성입자와 함께 얻어지며, 20% 이상의 고 밀도 질량비는 양산공정에 중요한 의미를 부여한다. 자유수산기가 선박안정수의 외래침입생물과 적조처리 및 양식수체 정화에도 효과적인 새로운 처리기술로 선박 안정수에 포함되어 타 지역으로부터 옮겨지는 외래침입생물 처리 방안의 하나로, 강 전리방전 기술을 적용하여 고 밀집산소와 물분자로부터 고농도 수산자유기(OH: hydroxyl radical)를 전리, 발생시켜서 활성입자를 신속히 확산시켜 비교적 낮은 수산기농도 하에서 유해성침입생물을 사멸 처리하는 환경 친화적 녹색 청정처리방법을 제안하였다.

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High Concentrated Toluene Decomposition by Non-thermal Plasma-Photocatalytic (Mn-Ti-MCM-41) Hybrid System (상온 방전 플라즈마-광촉매(Mn-Ti-MCM-41) 복합 시스템에 놓인 고농도 톨루엔의 분해성능)

  • Ban, Ji-Young;Son, Yeon-Hee;Lee, Sung-Chul;Kang, Misook;Choung, Suk-Jin;Sung, Joon-Yong
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.413-421
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    • 2005
  • This study focused on the decomposition of toluene in a plasma-photocatalytic hybrid system. Hexagonally packed meso-structured Mn-titanosilicates (Mn-Ti-MCM-41), as the photocatalysts, have been prepared by the hydrothermal method. The physical properties of the photocatalysts were characterized using XRD, XPS, TEM, BET/ICP, and $NH_3$/Toluene-TPD. Experiments were carried out at the applied voltage of 9.0 kV and at room temperature of $20^{\circ}C$. In the plasma only system, the activity of the toluene decomposition was higher than that in the photocatalytic system. However, the amount of by-products, such as phenol, $C_2{\sim}C_4$ alkene, was also increased in the plasma only system. However, the by-products decreased remarkably in a plasma-photocatalytic hybrid system. When Mn5mol%-Ti-MCM-41 was used as a photocatalyst in a plasma-photocatalytic hybrid system, the $CO_2$ selectivity in products was increased dramatically compared to other catalysts. It was confirmed that a plasma-photocatalytic hybrid system was better for toluene decomposition compared to photocatalytic and plasma only systems.

High Density Planar Inductively Coupled Plasma Etching of GaAs in BCl$_3$-based Chemistries (BCl$_3$ 기반 가스를 이용한 GaAs의 고밀도 평판형 유도결합 플라즈마 식각)

  • ;;;;;;S.J. Pearton
    • Journal of Surface Science and Engineering
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    • v.36 no.5
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    • pp.418-422
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    • 2003
  • 평판형 유도결합 플라즈마 식각장비(inductively coupled plasma etcher)를 이용하여 각종 공정조건들에 따른 GaAs의 식각특성을 연구하였다. 공정변수들은 ICP 소스파워(0-500 W), RIE 척파워(0-150 W), 가스 종류($BCl_3$, $BCl_3$/Ar, $BCl_3$/Ne) 및 가스혼합비였다. $BCl_3$ 가스만을 이용하여 GaAs를 식각한 경우보다 25%의 Ar이나 Ne같은 불활성 기체를 혼합한 $15BCl_3$/5Ar, $15BCl_3$/5Ne 가스를 이용한 경우의 식각률이 더 우수한 것을 확인하였다. 그리고 50% 이하의 Ar이 혼합된 $BCl_3$/Ar의 경우는 높은 식각률 (>4,000 $\AA$/min)과 평탄한 표면(RMS roughness : <2 nm)을 얻을 수 있었지만 지나친 양(>50%)의 Ar의 혼합은 오히려 표면을 거칠게 하거나 식각률을 떨어뜨리는 결과를 가져왔다. 그리고 20 sccm $BCl_3$, 100 W RIE 척파워, 300 W ICP 소스파워, 공정압력이 7.5 mTorr인 조건에서의 GaAs의 식각결과는 아주 우수한 특성(식각률: ∼ 4,000, $\AA$/min, 우수한 수직측벽도: >$87^{\circ}$, 평탄한 표면: RMS roughness : ∼0.6 nm)을 나타내었다.