• Title/Summary/Keyword: 프로판/공기

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Soot Formation and Oxidation in Air-Diluted Propane Diffusion Flames under Elevated Pressures (압력조건에서 공기로 희석된 프로판 확산화염의 매연 생성과 산화 특성)

  • Bae, Seungman;Nam, Younwoo;Lee, Wonnam
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.267-268
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    • 2012
  • Soot formation and oxidation characteristics of air-diluted propane diffusion flames have been experimentally investigated under the elevated pressure conditions. PAH concentrations showed more pressure sensitive behavior comparing to soot volume fractions. The flame/soot temperatures in soot oxidation region were obtained using the MOLLIP technique. Under the complete soot oxidation environment, the flame/soot temperature is increased with pressure. The increased temperature could accelerate the soot oxidation process and then exothermic oxidation reaction, in turn, could further raise the flame/soot temperature, which would result in the enhancement of soot oxidation process.

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Flame Propagation Characteristics of Propane-Air Premixed Mixtures (프로판-공기 예혼합기의 화염전파 과정에 관한 연구)

  • Bae, Choong-Sik
    • Journal of the Korean Society of Combustion
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    • v.1 no.2
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    • pp.21-29
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    • 1996
  • Flame propagation characteristics of propane-air mixtures were experimentally investigated in constant-volume combustion chambers. Flame propagation process was observed as a function of mixture strength, initial mixture temperature and initial mixture pressure in quiescent mixtures. A cylindrical combustion chamber and a spherical combustion chamber contain a pair of parallel windows through which optical access into the chamber can be provided. Laser two beam deflection method was adopted to measure the local flame propagation, which gave information on the flame size and flame propagation speed. Pressure development was also measured by a piezoelectric pressure transducer to characterize combustion in quiescent mixtures. Burning velocity was calculated from flame propagation and pressure measurements. The effect of flow on flame propagation was also investigated under flowing mixture conditions. Laser two beam method was found to be feasible in measuring flame propagation of quiescent mixtures. Flame was observed to propagate faster with higher initial mixture temperature and lower initial pressure. Combustion duration was shortened in the highly turbulent flowing mixtures.

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A Study on the MESG of Flammable Ternary Gas Mixtures (3성분계 인화성 혼합가스의 MESG에 관한 연구)

  • Hwang, Kyungyong;Byeon, Junghwan;Rhee, Kyunam;Lee, Taeck-Kie
    • Journal of the Korean Institute of Gas
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    • v.20 no.3
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    • pp.30-37
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    • 2016
  • Electrical apparatuses for use in the presence of flammable gas atmospheres have to be specially designed to prevent them from igniting the explosive gas. Flameproof design implies that electrical components producing electrical sparks are contained in enclosures and withstand the maximum pressure of internal gas or vapours. In addition, any gaps in the enclosure wall have to designed in such a way that they will not transmit a gas explosion inside the enclosure to an explosive gas or vapours atmosphere outside it. In this study, we explained some of the most important physical mechanism of MESG(Maximum Experimental Safe Gap) that the jet of combustion products ejected through the flame gap to the external surroundings do not have an energy and temperature large enough to initiate an ignition of external gas or vapours. We measured the MESG and maximum explosion pressure of ternary gas mixtures(propane-acetylene-air) by the test method and procedure of IEC 60079-20-1:2010. As a result, the composition of propane gas that has lower explosive power than acetylene gas in the ternary gas mixtures makes greater effects on MESG and explosion pressure.

Performance of HFC152a, HFC134a and HC290 Mixtures as Alternative Refrigerants for HFC134a (HFC152a, HFC134a, 프로판을 포함한 자동차용 대체/보충 냉매의 성능)

  • Kang, Nam-Koo;Bae, Guen-Hwan;Park, Ki-Jung;Jung, Dong-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.6
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    • pp.383-391
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    • 2010
  • In this study, HFC152a, HFC134a/HFC152a and HC290/HFC134a/HFC152a mixtures are studied for the supplementary and alternative refrigerants for HFC134a used in automobile air-conditioners. Due to the high global warming potential of HFC134a, it has to be phased out in the long run. Thermodynamic performance of these refrigerants are measured in a bench tester of 3.5 kW capacity with an open type compressor under both summer and winter conditions. Test results show that the coefficient of performance (COP) and capacity of pure HFC152a and HFC134a/HFC152a mixture are 9.1~12% and 7% higher than those of HFC134a. As for the HC290/HFC134a/HFC152a, the COP is up to 9.5% higher than that of HFC134a with 1~2% of HC290 while that is up to 6.1% lower than that of HFC134a with 5% HC290. The capacity of the ternary mixture, however, is 8.6% higher than that of HFC134a at all compositions tested. The compressor discharge temperatures of all refrigerants tested are $6{\sim}10^{\circ}C$ higher than that of HFC134a. For all refrigerants, the amount of charge is reduced up to 32% due to the decrease in liquid density. Overall, these refrigerants provide good performance with reasonable energy savings with less environmental problem and thus can be used as long term alternatives for automobile air-conditioners.

Preparation of Asymmetric Membranes by Addition of Nonsolvent (비용매 첨가제를 이용한 비대칭막의 제조)

  • Kim, Nowon
    • Membrane Journal
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    • v.25 no.1
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    • pp.32-41
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    • 2015
  • High performance polysulfone microfiltration membranes with a high were successfully prepared by vapor induced phase separation (VIPS) coupled with non-solvent induced phase separation (NIPS) process. Asymmetric Membranes were prepared with PSF/DMF/PVP/PEG/DMSO/water mixed solutions and water/IPA coagulant. PSF, DMF, PVP, PEG, DMSO, water was used as a membrane polymer, a solvent, a hydrophilic polymer additive, a polar protic liquid polymer, a polar aprotic nonsolvent, and a polar protic nonsolvent in the casting solution, respectively. The addition of polar aprotic nonsolvents, and polar protic nonsolvents is a convenient and effective method to control membrane structure. In order to control the morphology of polymeric membranes, the spontaneous emulsification induced by drawing water vapor into the exposed casting solution surface has been used. Control of the internal morphology of polymeric membranes by using mixed coagulation solution such as water and IPA is discussed in the present work. The pure water permeability, pore size distribution, surface hydrophilicity and membrane morphology were investigated. Due to the addition of DMSO to casting solution, the mean pore size increased almost $0.2{\mu}m$ and the water flux increased about 1000-1800 LMH.

The Air-stripping Process Conjugated with the Ultrasonic Treatment to Remove TOC in Groundwater around the LPG Underground Storage Cavern (탈기법과 초음파 처리법을 연계한 LPG 지하공동저장소 주변 오염지하수 내 TOC 제거)

  • Han, Yikyeong;Jun, Seongchun;Kim, Danu;Jeon, Soyoung;Lee, Minhee
    • Economic and Environmental Geology
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    • v.55 no.5
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    • pp.511-519
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    • 2022
  • In order to develop an air-stripping based remediation process to remove the TOC (Total Organic Carbon) in groundwater around the underground LPG storage cavern, the laboratory scale experiments at various conditions (change of air injection volume and temperature, the application of ultrasonic treatment, etc.) for two types of groundwater (initial TOC concentration of 608 mg/L and 153 mg/L, respectively). From results of experiment, as the air injection rate for stripping into groundwater increased from 2 L/min to 11 L/min and as the air-stripping time increased from 1 hour to 24 hour, the TOC removal efficiency of air-stripping increased. However, the TOC concentration of treated groundwater was higher than the discharge tolerance limit (100 mg/L) even after 24 hour stripping at the maximum air injection rate of 11 L/min. The main compounds of the TOC in groundwater were identified as methanol and propane and the long stripping time (more than 24 hour) was needed to separate the methanol from groundwater because of the affinity between water and methanol. At 20℃ and 4 L/min of air injection, the TOC removal efficiency increased to 59.1% after 24 hour air-stripping. When the temperature of groundwater increased to 30℃ and 40℃, the TOC removal efficiency increased up to 80.0% and 82.8%, suggesting that more than 24 hour air-stripping at 40℃ is needed to lower the TOC concentration to below 100 mg/L and the additional TOC removal process as well as the air-stripping is necessary. When the temperature increased to 60℃ and the ultrasonic treatment was conjugated with the air-stripping, the TOC removal efficiency increased to 87.8% within 5 hour stripping and the final TOC concentration (72.4 mg/L) was satisfied with the TOC discharge tolerance limit. The TOC removal efficiency for groundwater having low TOC concentration (153 mg/L) also showed similar removal efficiency of 89.7% (the final TOC concentration: 18.9 mg/L). Results in this study supported that the air-stripping conjugated with the ultrasonic treatment could remove successfully the TOC in groundwater around the underground LPG strorage cavern.

Basic Study on Lift-off Characteristics of Non-Premixed Flames of Methane-Air Jet in a Tube (관 내부 메탄-공기 분류 비예혼합 화염의 부상 특성 기초 연구)

  • Kim, Go-Tae;Kim, Nam-Il
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.4
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    • pp.431-438
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    • 2011
  • Flame lift-off conditions determine the operating conditions of burners. It is known that a flame can be lifted when the Schmidt number (Sc), which is the ratio of the dynamic viscosity to the mass diffusivity, is greater than unity. In this study, the flame lift-off characteristics of non-premixed flames of propane (Sc > 1) and methane (Sc < 1) in a coaxial outer air tube were experimentally compared. The experimental results indicated that stable lifted flames could be obtained even when Sc < 1 in a confined air tube. On the basis of the results of a simple numerical analysis, it was confirmed that a new flame stabilization mechanism exists in the tube. A velocity field is preferentially developed upstream of the flame, and it results in a new stabilization condition. This result can be very useful in explaining the stabilization of the flames of ordinary burners in which a flame is produced in a confined space.

Effect of Ignition Delay Time on Autoignited Laminar Lifted Flames (자발화된 층류 부상화염에 대한 점화지연시간의 영향)

  • Choi, Byung-Chul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.10
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    • pp.1025-1031
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    • 2011
  • Autoignition characteristic is an important parameter for designing diesel or PCCI engines. In particular, diesel spray flames are lifted from the nozzle and the initial flame is formed by an autoignition phenomenon. The lifted nature of diesel spray flames influences soot formation, since air will be entrained into the spray core by the entrainment of air between the nozzle region and the lifted flame base. The objective of the present study was to identify the effect of heat loss on the ignition delay time by adopting a coflow jet as a model problem. Methane ($CH_4$), ethylene ($C_2H_4$), ethane ($C_2H_6$), propene ($C_3H_6$), propane ($C_3H_8$), and normal butane (n-$C_4H_{10}$) fuels were injected into high temperature air, and the liftoff height was measured experimentally. As the result, a correlation was determined between the liftoff height of the autoignited lifted flame and the ignition delay time considering the heat loss to the atmosphere.

Effects of the Gas Composition on Internal Oxidation Characteristics of Low Carbon Alloy Steel during Carburizing in Nitrogen-Propane-Air Atmospheres (질소-프로판-공기분위기에서 저탄소 합금강의 침탄시 내부산화 특성에 미치는 가스조성의 영향)

  • Roh, Y.S.;Kim, S.M.;Kim, Y.H.;Kim, H.K.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.4
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    • pp.53-60
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    • 1991
  • This study has been performed to investigate into the internal oxidation characteristics of low carbon steel with respect to the added amount of air in nitrogen-propane atmosphere after gas carburizing for various times at $930^{\circ}C$. The results obtained from the experiment are as follows ; (1) Optical micrographs have shown that the internal oxidation is unlikely to occur in the gas atmosphere without air and that oxidized zone in the outer surface layer is formed in the gas atmosphere with air revealing that the depth of oxidized zone increases with increasing the added amount of air. (2) The formation of internally oxidized zone in the outer surface layer has been found to be inhibited as Ni content increases, i. e, the amount of alloying element increases. (3) The depth of oxidation has been measured to increase with almost parabolically gas carburizing time of up to 6 hours.

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Visualization of luminescent radicals in the flame by image processing (영상처리에 의한 화염 발광 라디칼의 가시화)

  • 김경찬;김영민;정주영;김태권
    • Korean Journal of Optics and Photonics
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    • v.9 no.4
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    • pp.264-269
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    • 1998
  • The Measurement of concentration patterns for $C_2$, CH and OH radicals in the premixed propane-air flame could be managed through an image processing technique. This technique was applied to the three kinds of flames on a bunsen burner-mixtures of fuel to be lean, optimum and excessive respectively. The image processing system was complished by treating single wavelength flame images around the eac radical luminescence band, which was obtained by using a set of narrow band pass filters, an image intensifier, CCD and PC. It was possible to observe and predict the reaction zone and the concentration distribution of the radicals, Spatial distribution of each radicals in the raaction zone gave us enough informations to analyze the reaction mechanisms in $C_mH_n$ combustion process. According to this informations, the image of $C_2$ radical exists at front zone, following the images of CH and OH radicals at downstream.

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