• Title/Summary/Keyword: 퓨리에 변환 분광

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Noise Equivalent Differential Temperature of Passive FTIR Sensor System (수동형 퓨리에변환 적외선 분광기의 잡음등가온도지수)

  • Kang, Young-Il;Park, Byeong-Hwang;Choi, Myung-Jin;Hong, Dea-Sik;Choi, Soo;Kim, Dong-Hwan;Park, Do-Hyun
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.2
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    • pp.161-166
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    • 2011
  • The passive open-path Fourier-Transform-Infrared system was implemented for the toxic gas monitoring. Noise Equivalent Differential Temperature(NEDT) was investigated as a system performance evaluation figure and analyzed numerically with the designed parameters. Calculated NEDT was compared with the experimental value in the wavelength region of $700{\sim}1400cm^{-1}^$. The minimum detectable gas concentration was estimated from the obtained NEDT at the absorption wavelength of $SF_6$.

Construction and Measurement of Normal Spectral Emissivity Device using Fourier Transform Infrared Spectrometer (퓨리에 변환 적외선 분광기를 이용한 수직 분광 복사율 측정 장치의 제작과 측정)

  • Jeon, Sang-Ho;Yoo, Nam-Joon;Jo, Jae-Heung;Park, Chul-Woung;Park, Seung-Nam;Lee, Geun-Woo
    • Korean Journal of Optics and Photonics
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    • v.19 no.6
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    • pp.400-407
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    • 2008
  • An Instrument to measure normal spectral emissivity is built using a Fourier Transform-Infrared (FT-IR) spectrometer. The instrument is composed of four main parts, reference blackbody, sample furnace, optics system, and FT-IR spectrometer. Measurement ranges of temperature and wavelength are $200^{\circ}C{\sim}500^{\circ}C$ and $3.5{\mu}m{\sim}20{\mu}m$, respectively. Measured emissivity of the reference blackbody is greater than 0.9993 with combined relative uncertainty less than 0.69%, which can be considered an ideal blackbody. We studied the emissivity of opaque alumina, graphite, anodized aluminum, and steel (IMS 200). It is shown that emissivity increases with the roughness of the steel (IMS 200) surface.

Long Organic Cation-modified Perovskite Solar Cells with High Efficiency and Stability (알킬 사슬이 긴 유기 양이온이 도입된 고효율/고안정성 페로브스카이트 태양전지)

  • Jung, Minsu
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.78-82
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    • 2022
  • Inorganic-organic hybrid perovskite solar cells have demonstrated considerable improvements, reaching 25.5% of certified power conversion efficiency (PCE) in 2020 from 3.8% in 2009 comparable to silicon photovoltacis. However, there remains important concern on the stability of perovskite solar cells under environmental conditions that should be solved prior to commercialization. In order to overcome the problem, we have introduced a small amount of octylammonium iodide with longer alkyl chain than volatile methylammonium iodide into MAPbI3 perovskites. The presence of octylammonium into perovskites were confirmed using Fourier-transform infrared spectroscopy and UV-visible spectroscopy. Moreover, octylammonium-modified perovskite solar cells showed a PCE of 16.6% and enhanced moisture stability with an increased contact angle of 72.2° from 57.0°. This work demonstrated the importance of perovskite compositional engineering for improving efficiency and stability.

Image Fusion of High Resolution SAR and Optical Image Using High Frequency Information (고해상도 SAR와 광학영상의 고주파 정보를 이용한 다중센서 융합)

  • Byun, Young-Gi;Chae, Tae-Byeong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.30 no.1
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    • pp.75-86
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    • 2012
  • Synthetic Aperture Radar(SAR) imaging system is independent of solar illumination and weather conditions; however, SAR image is difficult to interpret as compared with optical images. It has been increased interest in multi-sensor fusion technique which can improve the interpretability of $SAR^{\circ\circ}$ images by fusing the spectral information from multispectral(MS) image. In this paper, a multi-sensor fusion method based on high-frequency extraction process using Fast Fourier Transform(FFT) and outlier elimination process is proposed, which maintain the spectral content of the original MS image while retaining the spatial detail of the high-resolution SAR image. We used TerraSAR-X which is constructed on the same X-band SAR system as KOMPSAT-5 and KOMPSAT-2 MS image as the test data set to evaluate the proposed method. In order to evaluate the efficiency of the proposed method, the fusion result was compared visually and quantitatively with the result obtained using existing fusion algorithms. The evaluation results showed that the proposed image fusion method achieved successful results in the fusion of SAR and MS image compared with the existing fusion algorithms.

Wear Characteristics of Diamond-Like Carbon Thin Film for Durability Enhancement of Ultra-precision Systems (초정밀 시스템의 내구성 향상을 위한 다이아몬드상 탄소 박막의 마멸특성에 관한 연구)

  • 박관우;나종주;김대은
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.467-470
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    • 2004
  • Diamond-Like Carbon (DLC) thin film is a semiconductor with high mechanical hardness, low friction coefficient, high chemical inertness, and optical transparency. DLC thin films have widespread applications as protective coatings and solid lubricant coatings in areas such as Hard Disk Drive (HDD) and Micro-Electro-Mechanical-Systems (MEMS). In this work, the wear characteristics of DLC thin films deposited on silicon substrates using a DC-magnetron sputtering system were analyzed. The wear tracks were measured with an Atomic Force Microscope (AFM). To identify the sp2 and sp3 hybridization of carbon bonds and other bonds Raman spectroscopy was used. The structural information of DLC thin films was obtained with Fourier transform infrared spectroscopy and wear tests were conducted by using a micro-pin-on-reciprocator tester. Results showed that the wear characteristics were dependent on the sputtering conditions. The wear rate could be correlated with the bonding state of the DLC thin film.

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고온고압처리에 따른 천연갈색다이아몬드의 광학특성분석

  • Seo, Jin-Gyo;An, Yong-Gil;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.52-52
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    • 2010
  • 본 연구에서 우리는 HPHT 처리 전 FT-IR spectrometer를 이용한 사전분석을 통해 type Ia brown 다이아몬드를 IaA, IaB, IaAB (A>B), IaAB (A=B), IaAB (A$1700-1800^{\circ}C$, 5 GPa에서 다이아몬드가 흑연화 되지 않는 범위 하에 HPHT처리를 시행하였다. 자외선-가시광선 분광분석기(UV-Vis Spectrometer, Shimadzu UV 3101PC)를 사용하여 350~800 nm에서의 가시광선 범위를 0.1nm의 분해능으로 투과(Transmittance) 모드로 측정하였고, 퓨리에 변환 적외선 분광분석기(FT-IR spectrometer, Jasco-4100)을 사용하여 $400{\sim}6000cm^{-1}$의 범위에서 $4cm^{-1}$ 의 분해능으로 흡수(Absorption) 모드로 측정한 후 HPHT 처리 전후를 비교 분석하였다. 또한 광루미네선스(Photoluminescence) 분석은 325 nm He-Cd laser를 광원으로 한(PL, Spectra-pro 2150i, Spectra-pro 2300i micro-spectrometer) 및 532 nm green laser를 광원으로 한(PL, SAS 2000)를 사용하여 각각 350~600 nm, 550~1100 nm의 범위에서 0.1nm step으로 측정하여 HPHT 처리전과 후를 비교 분석하였다. HPHT처리 후 모든 시료는 N3 center (415.4 nm), H4 center (496.4nm) 및 platelet와 연관된 ($1363\;cm^{-1}$)의 peak가 감소하였고, H3 center (503.2 nm)와 G-band가 증가하는 경향을 나타내었다. 또한 HPHT 처리 시 질소의 B집합보다 A집합이 더 감소하는 경향을 나타내었으며, A 또는 B집합의 파괴에서 발생된 질소 원자에 의해 질소의 interstitial center (594 nm)가 증가함을 알 수 있었다. HPHT 처리 후 모든 시료는 (N-V)- center가 생성됨을 확인 할 수 있었다. 결론적으로 본 연구를 통해 HPHT 처리를 통해 다이아몬드 내에 존재하는 질소결합관련 상태의 변화를 확인할 수 있었다.

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Preparation of electrostatic spray pyrolysis derived nano powder and hydroxyapatite forming ability (정전분무 열분해법에 의한 나노분말의 제조 및 하이드록시 아파타이트 형성능력 평가)

  • Lee, Young-Hwan;Jeon, Kyung-Ok;Jeon, Young-Sun;Lee, Ji-Chang;Hwang, Kyu-Seog
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.6
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    • pp.244-249
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    • 2006
  • Electrostatic spray pyrolysis, a novel fabrication technique, has been used in this study to prepare calcium phosphate nano powders. Final annealing was done at $400^{\circ}C$ for 30min in air. The hydroxyapatite - forming ability of the annealed powder has been evaluated in Eagle's minimum essential medium solution (MEM). X-ray diffraction analysis, field emission - scanning electron microscope, energy dispersive X-ray spectroscope, and Fourier transform infrared spectroscope were used to characterized the annealed powders after immersion in MEM. The powder with an amorphous structure induced hydroxyapatite formation on their surfaces after immersion fer 15 days.

Colorless and Transparent Polyimide Films from Poly(amic acid)s with Cross-linkable Anhydride End (가교 반응이 가능한 말단 무수물을 이용한 무색투명한 폴리이미드 필름)

  • Min, Ung-Ki;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.34 no.6
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    • pp.495-500
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    • 2010
  • Crosslinked PI films were synthesized from 4,4'-(hexafluoro isopropylidene)diphthalic anhydride (6FDA) and bis[4-(3-aminophenoxy) phenyl] sulfone(BAPS) with various ratios of the reactive monomer cis-4-cyclohexene-1,2-dicarboxylic anhydride(CDBA). We prepared crosslinked poly(amic acid) (PAA) using a 0.1 wt% Grubbs catalyst as a crosslinking agent. The crosslinked PAA was heat-treated at different temperatures to give PI films. The thermo-mechanical properties and optical transparency of the PI films were investigated. The thermal properties of the PI films were examined using Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry(DSC), thermogravimetric analysis(TGA), thermo-mechanical analysis(TMA), and universal tensile machine(UTM), and their optical transparencies were investigated using UV-vis. spectrophotometry. The thermomechanical properties of the PI films improved with increasing CDBA content. However, the optical transparency of the PI films decreased slightly with increasing CDBA content.

Matching Points Extraction Between Optical and TIR Images by Using SURF and Local Phase Correlation (SURF와 지역적 위상 상관도를 활용한 광학 및 열적외선 영상 간 정합쌍 추출)

  • Han, You Kyung;Choi, Jae Wan
    • Journal of Korean Society for Geospatial Information Science
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    • v.23 no.1
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    • pp.81-88
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    • 2015
  • Various satellite sensors having ranges of the visible, infrared, and thermal wavelengths have been launched due to the improvement of hardware technologies of satellite sensors development. According to the development of satellite sensors with various wavelength ranges, the fusion and integration of multisensor images are proceeded. Image matching process is an essential step for the application of multisensor images. Some algorithms, such as SIFT and SURF, have been proposed to co-register satellite images. However, when the existing algorithms are applied to extract matching points between optical and thermal images, high accuracy of co-registration might not be guaranteed because these images have difference spectral and spatial characteristics. In this paper, location of control points in a reference image is extracted by SURF, and then, location of their corresponding pairs is estimated from the correlation of the local similarity. In the case of local similarity, phase correlation method, which is based on fourier transformation, is applied. In the experiments by simulated, Landsat-8, and ASTER datasets, the proposed algorithm could extract reliable matching points compared to the existing SURF-based method.

A DESIGN STUDY OF THB 400MHZ WIDE-BAND DIGITAL AUTOCORRELATION SPECTROMETER (400MHz 광대역 디지털 자기상관분광기 설계연구)

  • 이창훈;김광동;한석태;김태성;최한규;변도영;구본철
    • Journal of Astronomy and Space Sciences
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    • v.19 no.4
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    • pp.327-340
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    • 2002
  • In this paper, we performed the design study of a wide-band digital autocorrelation spectrometer for the observation study of an extra-galaxy's spectral lines and the survey research of the special radio sources in field of the radio astronomy observational research. The autocorrelation spectrometer designed in this paper can be used to their spectrometer of any system because this spectrometer has a wide dynamic power and frequency range properties. In this system we use the aliasing sampling method to minimize the band loss. For the output signal of the correlator we can increase the signal processing speed using by a special DSP chip, the integration and the FFT using hardware, so this spectrometer can support the newest developed technique for the radio astronomy observation so called “On the fly” method.