• Title/Summary/Keyword: 표면 침투

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Effect of Al Addition on the Surface Nitrogen Permeation Treatment of 13%Cr Stainless Steels (13%Cr 스테인리스강의 표면 질소침투처리에 미치는 Al첨가의 영향)

  • Yoon, S.S.;Kim, K.D.;Lee, H.W.;Kang, C.Y.;Sung, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.3
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    • pp.221-230
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    • 1999
  • The surface nitrogen permeation of Al alloyed 0.14%C-13%Cr stainless steels was investigated after heat treating at $1050^{\circ}C{\sim}1150^{\circ}C$ in the nitrogen gas atmosphere. The strong affinity between Al and nitrogen permeates the nitrogen through the interior of the steels. Two precipitates of round type and needle type are observed at the surface layer. These precipitates mainly consist of AlN containing plenty of aluminum. The surface layer of 0.53%Al alloyed specimen shows ferrite phase, while the surface layers of 1.65%Al and 2.27%Al alloyed specimens appear ${\gamma}$ plus ${\alpha}$ phases. The depth of nitrogen permeation depends upon the Al content and microstructure of the matrix. The 1.65%Al alloyed specimen representing ${\alpha}+{\gamma}$ matrix phases at the nitrogen permeation temperature shows the maximum case depth in this experiment. Although the surface hardness increases by raising the Al content of the specimen owing to the increase of nitride precipitation density, the nitride precipitation deteriorates the corrosion resistance in the solution of HCl, $H_2SO_4$, and $FeCl_3$.

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Preparation and Properties Enhancement of Epoxy Resin Employing Poly(amic acid) (PAA) (Poly(amic acid) (PAA)를 함유한 에폭시 수지의 제조 및 물성 향상)

  • 이용택;배성호;박병천
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.254-262
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    • 2001
  • Epoxy resin based upon the N,N'-diglycidylaniline which is widely used in optic, electronic and composite material. We modified this epoxy resin with poly(amic acid) (PAA) that is a precursor of polyimide. To improve the mechanical property we controlled PAA content and imidization ratio. PI-modified epoxy blends were prepared for the formation of IPN structure. The possible reaction in the epoxy resin/PAA blends were investigated by FT-IR and inherent viscosity techniques. Thermal properties are measured by TGA, DSC, and TMA. Mechanical properties are measured by UTM and impact test machine. Morphology is investigated by SEM. Thermal stability improved with increasing the content of PAA in blends. As the content of PAA increases in blend, the glass transition temperature and thermal expansion coefficient decreases. Increasing impact strengths in J/m in the range of 920∼2412 were observed in blends. The PAA segment may act as a toughening agent in the epoxy networks, thus contributing the impact strength improvement of the blends.

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Estimation of Service Life for Expressway Bridge Subjected to Chloride Ingress from De-icer (동절기 제설제 사용에 대한 고속도로 교량의 내구수명 평가)

  • Lee, Honam;Jeon, Chanki;Kim, Juho;Shim, Jaeyeong;Jeon, Inkyu
    • Journal of the Society of Disaster Information
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    • v.11 no.4
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    • pp.548-555
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    • 2015
  • This paper aims to estimate the service life of the target bridge structures subjected to chloride ingress from de-icer, which is used for safety of vehicles in winter, by investigating the chloride ingress into concrete. In this study, the 10-year-old bridge structures were investigated by measuring the chloride along the depth from the exposed surface to derive the surface chloride concentration and the diffusion coefficient for the prediction of service life. The service life of each measured point on the structures were estimated with the surface chloride concentration and the diffusion coefficient by using Life-365 software. As a result, it was estimated for all measured points to have over 100-year service life. Furthermore, the diffusion coefficient and the service life from the measured data were compared to another method calculated with the concrete mix, considering the time dependency of diffusion coefficient.

Development of Biomimetic Scaffold for Tissue Engineering (조직공학을 위한 생체모사용 스캐폴드 개발)

  • Park, Su-A;Lee, Jun-Hee;Kim, Wan-Doo
    • Elastomers and Composites
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    • v.44 no.2
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    • pp.106-111
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    • 2009
  • Tissue engineering is a research field for artificial substitutes to improve or replace biological functions. Scaffolds play a important role in tissue engineering. Scaffold porosity and pore size provide adequate space, nutrient transportation and cell penetration throughout the scaffold structure. Scaffold structure is directly related to fabrication methods. This review will introduce the current technique of 3D scaffold fabrication for tissue engineering. The conventional technique for scaffold fabrication includes salt leaching, gas foaming, fiber bonding, phase seperation, melt moulding, and freeze drying. These conventional scaffold fabrication has the limitations of cell penetration and interconnectivity. In this paper, we will present the solid freeform fabrication (SFF) such as stereolithography (SLA), selective laser sintering (SLS), and fused deposition modeling (FDM), and 3D printing (3DP).

A STUDY ON THE RESIN IMPREGNATION AND SHEAR BOND STRENGTH BY VARIOUS DENTIN CONDITIONERS (수종 상아질 표면처리제에 의한 레진 침투 및 전단결합강도에 관한 연구)

  • Lee, Kwang-Won;Lee, Myung-Jong
    • Restorative Dentistry and Endodontics
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    • v.15 no.1
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    • pp.201-216
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    • 1990
  • A variety of surface pre-treatments have been advocated to prepare the dentin prior to placement of a bonding agent. The purpose of this study was to evaluate the effect of various dentin conditioners upon the degree of resin impregnation to the dentinal tubules and the shear bond strength of a new dentinal bonding agent (Scotchbond 2) used in conjunction with a visible light cured composite (Silux). The healthy eighty human molars extracted due to periodontal or orthodontic reasons were used and randomly divided into five groups. All the grinded dentin surfaces were conditioned with 3% $H_2O_2$, Cavity Cleanser (Columbus/Bayer), Dentin Conditioner (GC Inter. Corp.), Scotchprep (3M Co.) according to the manufacturer's directions. The specimens were then demineralized in 10% HCl for 20 sec. and 24 hrs. in order to observe the resin tags in Hitachi X-450 scanning electron microscope at 25KV. Also, shear strengths were obtained using an Instron Testing Machine with a cross head speed of 1 mm/min. The following results were obtained ; 1. In group treating with Dentin Conditioner and Scotchprep, the resin strings were formed on most of the surfaces and penetrated more than $50{\mu}m$ into the tubules. 2. The inner surface of resin treated with Cavity Cleanser, indicating the resin strings formed partly and penetrated about in depth of $30{\mu}m$. 3. In control and experimental group treated with 3% $H_2O_2$, the resin tags were not formed, if any, penetrated shortly. 4. Shear bond strengths in groups treating with Dentin Conditioner and Scotchprep were statistically significant increase than with 3% $H_2O_2$. (P<0.01). 5. The Scotchprep treatment group was significantly higher in shear strength than groups treated with no conditioning and Cavity Cleanser.(P<0.01) 6. Shear bond strengths evaluated were gradually increase in proportion to the tag length of resin impregnation.

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Morphological aspects of white-rot degraded oak wood by Trametes versicolor (Trametes versicolor에 의한 상수리나무의 분해형태)

  • Yoo, Tae-Bang;Yoon, Min-Ho;Choi, Woo-Young;Lee, Jong-Shin
    • Korean Journal of Agricultural Science
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    • v.28 no.2
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    • pp.125-131
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    • 2001
  • Trametes versicolor(CV5) selected as a white-rot fungus with strong lignin degrading activity, in the previous paper, was investigated on a properties of degradation of wood lignin. Lignins of hardwoods, especially oak(Querous acutissima carruth) an paulownia (Paulownia coreana Uyeki) were considerably delignified by the CV5, however, softwoods used in this experiment were not delignified. Bavendamm's reaction was positive with several phenols on agar plates for the confirmation of a phenoloxidase secreted Through the morphologies of decayed wood chip observed with the aid of scanning electron microscopy, it was found that the hypha of CV5 penetrated the ray cells and vessels caused separation of the wood cellulose.

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The Kinetics of Montmorillonite Expansion in the Treatment with Hexadecyltrimethylammonium (HDTMA와 반응하는 몬모릴로나이트의 팽창 속도론)

  • Lee Seung Yeop;Cho Won Jin
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.299-307
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    • 2004
  • Surfactant adsorption by two montmorillonite types with different interlayer cations of Ca and Na was characterized by examining the time dependence of surfactant behavior on the clay surfaces. Surfactants with different micelle concentration were conducted in our experiment to observe a nonequilibrium activity of cationic surfactant on the clay over reaction periods ranging from 0.1 min to 11 days. As compared with Ca-montmorillonite (SAz), a more active intrusion of surfactant molecules into the interlayers was found in Na-montmorillonite (SWy). During a short 'initiation' stage, the basal spacing of SWy montmorillonite increased rapidly with logarithmic time. For SAz montmorillonite, however, the abrupt basal spacing increase occurred at the later stage of the reaction. From the result, the difference in the adsorption behavior exhibited by the two montmorillonite types partly results from their intrinsic nature, that is, inorganic cations originally existing on the clay surfaces. Additionally, the micelle concentration of surfactants affects the development of organo-montmorillonite, especially, in the intercalant formation and stabilization under nonequilibrium.

Durability Performances of Concrete Produced with Recycled Bio-Polymer Based on Sargassum Honeri (괭생이모자반 기반의 자원순환형 바이오 폴리머를 혼입한 콘크리트의 내구성능)

  • Lee, Byung-Jae;Lee, Sun-Mok;Hyun, Jung-Hwan;Kim, Yun-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.445-451
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    • 2019
  • In this study, we evaluated the durability of concrete produced with recycled polymer that could replace synthetic polymer, which is the main raw material of bridge deck concrete pavement. As a result of the slump and air content test, the requirements of the Korea Highway Corporation Standard were satisfied with all mixing conditions. The slump was lowered when incorporating the recycled bio-polymer, compared to other mix proportions concrete. In contrast, the compressive strength was increased by 6.3~24.4% when the recycled bio-polymer was mixed, compared to the concrete produced with synthetic polymer. It should be noted that the compressive strength was lowered when synthetic polymer was added to concrete mixture. Durability test results showed the best durability when incorporating synthetic polymer. The durability of concrete also increased as the amount of recycled bio-polymer increased, however, the impact was slightly smaller than that of synthetic polymer.

A Study on the Estimation for the Flow Coefficient of Elevator Shaft (엘리베이터 샤프트의 유량계수 산정에 관한 연구)

  • Kim, Hak-Joong
    • Journal of the Society of Disaster Information
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    • v.8 no.2
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    • pp.148-157
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    • 2012
  • Recently, evacuation safety of building residents becomes the major concern, as the building has been higher and more complicated. Many high-rise multi use buildings are under construction in Korea. Required evacuation time using stairway is longer in high-rise buildings, moreover it is impossible for the disabled to evacuate by using stairway. For this reason the study on the effectiveness of using elevator for evacuation is being progressed. Elevator shaft flow coefficient is the major factor for the calculation of elevator piston effect. The results of this study can be used for the study of elevator piston effect as basic data. The flow coefficient simulation was performed using FLUENT, commercial CFD program. As a result of the flow coefficient simulation, the coefficient is 0.88 considering the safety factor. This result is verified that the result of experimental study, 0.86 is conservative.

Study on an Evaluation of Remote Control Torch Performance to reduce CO2 Welding Defects (CO2 용접결함 감소를 위한 원격 제어 토치 성능 평가 연구)

  • Kim, Jeong-Hyeok;Oh, Seck-Hyeog;Lee, Hae-Gil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.10
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    • pp.6282-6288
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    • 2014
  • $CO_2$ welding is used widely in the field. On the other hand, welding defects occur when welders cannot adjust the current and voltage needed for welding and have to stop working to adjust the current and voltage, causing sudden cooling down of the welding structure inside a vehicle or tank where the control panel is invisible or when work site is far. This study used three types of existing $CO_2$ welders. This also applied SS400 rolled steel for welding structural purposes for remote control torch welding, perform a welding test through v-groove butt welding with a remote control torch and existing $CO_2$ welding torch, conducted visual inspection on the appearance of a welded top bead. In addition, the appearance quality of the welding part was monitored mainly through penetrant testing and a bending test to evaluate the welding defect reduction and the effect on the performance and compatibility by replacing the existing welder.