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An Investigation of the Current Squeezing Effect through Measurement and Calculation of the Approach Curve in Scanning Ion Conductivity Microscopy (Scanning Ion Conductivity Microscopy의 Approach Curve에 대한 측정 및 계산을 통한 Current Squeezing 효과의 고찰)

  • Young-Seo Kim;Young-Jun Cho;Han-Kyun Shin;Hyun Park;Jung Han Kim;Hyo-Jong Lee
    • Journal of the Microelectronics and Packaging Society
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    • v.31 no.2
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    • pp.54-62
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    • 2024
  • SICM (Scanning Ion Conductivity Microscopy) is a technique for measuring surface topography in an environment where electrochemical reactions occur, by detecting changes in ion conductivity as a nanopipette tip approaches the sample. This study includes an investigation of the current response curve, known as the approach curve, according to the distance between the tip and the sample. First, a simulation analysis was conducted on the approach curves. Based on the simulation results, then, several measuring experiments were conducted concurrently to analyze the difference between the simulated and measured approach curves. The simulation analysis confirms that the current squeezing effect occurs as the distance between the tip and the sample approaches half the inner radius of the tip. However, through the calculations, the decrease in current density due to the simple reduction in ion channels was found to be much smaller compared to the current squeezing effect measured through actual experiments. This suggests that ion conductivity in nano-scale narrow channels does not simply follow the Nernst-Einstein relationship based on the diffusion coefficients, but also takes into account the fluidic hydrodynamic resistance at the interface created by the tip and the sample. It is expected that SICM can be combined with SECM (Scanning Electrochemical Microscopy) to overcome the limitations of SECM through consecutive measurement of the two techniques, thereby to strengthen the analysis of electrochemical surface reactivity. This could potentially provide groundbreaking help in understanding the local catalytic reactions in electroless plating and the behaviors of organic additives in electroplating for various kinds of patterns used in semiconductor damascene processes and packaging processes.

Effects of Edged Curve Angle of Rotary Blade on Entwining Spreaded Rice Straw in Paddy (볏짚 시용(施用) 답(畓)의 Rotary 경운시(耕耘時) 날의 궤적(軌跡) 진입각(進入角)이 볏짚 감김에 미치는 영향(影響))

  • Yi, Woon Young;Kim, Soung Rai
    • Korean Journal of Agricultural Science
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    • v.13 no.1
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    • pp.103-112
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    • 1986
  • This study was carried out to prevent the entwining of rice straw on rotary shaft and blade where rice straw was spreaded on paddy field as an organic source before rotary tilling. The rotary tillage was conducted in the paddy field having the soil moisture contents of 30%, 39%, 59% in dry basis and spreaded rice straw (450kg/10a) of 30cm, 45cm, 90cm length with the edged curve angles of rotary blade of $30^{\circ}$, $40^{\circ}$, $50^{\circ}$, $55^{\circ}$ at Yuseung area. And the test were performed on the plot which has width of 30cm and 5cm length and the quantity of entwined rice straw was analized. The test results were summarized as the followings. 1. Entwining phenomenon of rice straw was decreased as the blade edged curve angle increased. The edged curve angle of rotary blade must be determind by considering the characteristics of soil cutting resistance, tilling torque and entwining phenomenon of rice straw. But according to the entwining phenomenon of rice straw only, the edged curve angle of rotary blade should be bigger than $55^{\circ}$ for design. 2. Amount of entwining rice straw was minimized when soil moisture contents was 30 percent (d. b.). It would be better that rotary tillage is performed when soil moisture contents is lower than 30 percent in dry basis. 3. Amount of entwining rice straw was minimized when the length of rice straw was 30cm with $55^{\circ}$ edged curve angle. Therefore, it would be better to chop rice straw as 30cm. 4. Entwining phenomenon of rice straw was decreased as the forward speed decreased. To decrease the entwining rice straw, rotary tillage should be done with forward fist gear (0.35m/s).

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Packaging Technology for the Optical Fiber Bragg Grating Multiplexed Sensors (광섬유 브래그 격자 다중화 센서 패키징 기술에 관한 연구)

  • Lee, Sang Mae
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.4
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    • pp.23-29
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    • 2017
  • The packaged optical fiber Bragg grating sensors which were networked by multiplexing the Bragg grating sensors with WDM technology were investigated in application for the structural health monitoring of the marine trestle structure transporting the ship. The optical fiber Bragg grating sensor was packaged in a cylindrical shape made of aluminum tubes. Furthermore, after the packaged optical fiber sensor was inserted in polymeric tube, the epoxy was filled inside the tube so that the sensor has resistance and durability against sea water. The packaged optical fiber sensor component was investigated under 0.2 MPa of hydraulic pressure and was found to be robust. The number and location of Bragg gratings attached at the trestle were determined where the trestle was subject to high displacement obtained by the finite element simulation. Strain of the part in the trestle being subjected to the maximum load was analyzed to be ${\sim}1000{\mu}{\varepsilon}$ and thus shift in Bragg wavelength of the sensor caused by the maximum load of the trestle was found to be ~1,200 pm. According to results of the finite element analysis, the Bragg wavelength spacings of the sensors were determined to have 3~5 nm without overlapping of grating wavelengths between sensors when the trestle was under loads and thus 50 of the grating sensors with each module consisting of 5 sensors could be networked within 150 nm optical window at 1550 nm wavelength of the Bragg wavelength interrogator. Shifts in Bragg wavelength of the 5 packaged optical fiber sensors attached at the mock trestle unit were well interrogated by the grating interrogator which used the optical fiber loop mirror, and the maximum strain rate was measured to be about $235.650{\mu}{\varepsilon}$. The modelling result of the sensor packaging and networking was in good agreements with experimental result each other.

A Study on a Quantitative Method in Estimating Forest Effects for Streamflow Regulation (II) - Mainly Dealing with Application of Coefficient for Slope Roughness - (삼림이수기능(森林理水機能)의 정량적(定量的) 평가방법(平價方法)에 관한 연구(硏究)(II) - 조도계수(粗度係數)의 응용(應用)을 중심(中心)으로 -)

  • Lee, Heon Ho
    • Journal of Korean Society of Forest Science
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    • v.81 no.4
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    • pp.337-345
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    • 1992
  • In this research, a kinematic wave model was applied for the runoff analysis, Regulation of streamflow was estimated by the calibration of roughness coefficient as a parameter. The data analyzed were obtained from Ananomiya and Shirasaka experimental basins at Tokyo University Forest in Aichi. Estimation methods and characteristics of roughness coefficient as a evaluation method of hydrological function of forest are summarized as follows ; 1. Roughness coefficient($N_s$) indicates the resistance of hillslope to the flowing water of surface runoff. There exists an hypothesis that resistance of hillslope to flowing water increase with the growth forest and development of the $A_o$ layer. 2. Roughness coefficient($N_s$) was estimated by the parameter when the stream direct runoff was calculated by using the kinematic wave. 3. Secular change of '$N_s$' in ananomiya has a curve which has an upper limit and increases exponentially near the limit. The curve quickly increased from 1935 to 1945 when results of afforestation for erosion control were thought to be effective. On the other hand, slight increase of '$N_s$' in Shirasaka indicates that there was not such a big change in the surface of soil layer. 4. The increase of '$N_s$' was related with decrease of direct runoff and increase of base flow. It was recognized that the rate of direct runoff decreased with the improvement of forest physiognomy and the rate of base flow was increased. But absolute value of water runoff per one storm decreased in chronological order.

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Assessment of the permanent canine bone support after secondary bone graft In UCLP patients (편측성 순구개열 환자에서 이차 골이식후 맹출된 영구 견치의 치조골 지지도에 관한 연구)

  • Park, Ki-Tae
    • The korean journal of orthodontics
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    • v.31 no.6 s.89
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    • pp.601-610
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    • 2001
  • The purpose of this retrospective study was to evaluate the level oi alveolar bone support of the erupted Permanent canine through the reconstructed cleft region compared to the contralateral canine on the non-cleft side. This study was limited to children with complete unilateral cleft lip and palate who underwent secondary alveolar iliac bone gvaft and the apices of the erupted canine roots were closed at the time of evaluation. With these criteria the study included 21 children whose average age at the time of bone graft reconstruction was 9.8 years, with a minimum of 12.4 years of age at the time of the evaluation. The study was limited to the use of iliac cancellous bone as the autograft material for reconstruction of the alveolar cleft. Cranial bone graft and other autogenous bone sources were excluded. The periapical radiographs were used to evaluate alveolar bone level of each canine. The percentages of root supported by the bone were established by dividing the amount of root covered with the bone by the anatomic root length. The canine oi the non-cleft side was used as an internal control and the canine on the cleft side was used as an experimental. There was a statistically significant difference in the alveolar bone support ratio between the control ($92.9\%$) and experimental canines ($8.7\%$). An average of $95\%$ level of alveolar bone support was achieved for the experimental canine in comparison to the control canine. Neither the presence of lateral incisor, nor the stage of root development of the canine at the time of the bone graft appeared to have affected the alveolar bone support ratio of the canine after the secondary bone graft.

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Design of Truck Escape Ramps (자동차 긴급 피난 차선의 계획 설계)

  • 구본충
    • Journal of the Korean Professional Engineers Association
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    • v.28 no.4
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    • pp.54-75
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    • 1995
  • This synthesis has been prepared from a review of literature on Truck Escape Ramps technology and a survey of current practice by state department of transportation. Their locations have been determined usually from a combination of accident experience and en-gineering judgement, but new tools are emerging that can identify needs and sites without waiting for catastrophic accidents to happen. The Grade Severity Rating Systems holds promise in this regard. Design Procedures for truck excape ramps continue to evolve. Gravel arrester beds are clearly the preferred choice across the country Rounded aggregate, uniformly graded in the approximate size range of 13 to 18mm. Tech-nical publications typically have dassified TER types as paved gravity, sandpile, and ar-rester bed ramps. The design speed for vehicle entry into the ramp in critical to the deter-mination of ramp length. An escape ramp should be designed for a minimum entry speed of 130km/hr, a 145km/hr design being preferred. The ramps should be straight and their angle to the roadway align-ment should be as possible. The grade of truck escape ramps show the adjustment of ramp design to local topography, such as the tradeoff of ramp length against earthwork requirements. A width of 9 to 12m would more safety acommodate two or more outof con-trol vehicles. Reguarding comments on the most effective material, most respondents cited their own specification or referred to single graded, rounded pea gravel. The consensus essentially Is that single graded, well -rounded gravel is the most desirable material for use in arrester beds. The arrester beds should be constructed with a minimum aggregate depth of 30cm. Successful ramps have used depths between 30 and 90cm.

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고무의 가황(加黃) 및 열전도론(熱傳導論) (3(三))

  • Heo, Dong-Seop;Gwon, Dong-Yong
    • Elastomers and Composites
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    • v.10 no.2
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    • pp.136-156
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    • 1975
  • 고무는 불량열전도체(不良熱傳導體)이며 두께가 두꺼우면 내부(內部)가 적정온도수준(適正溫度水準)에 이르기 전까지 가황시간(加黃時間)이 길어진다. 가황온도(加黃溫度)가 상승(上昇)할수록 가황물(加黃物)의 물성(物性)은 열화(劣化)되는 경향(傾向이) 있다. 천연(天然)고무든지 합성(合成)고무든지 간(間)에 과가황(過加黃)에 대(對)한 저항성(抵抗性)이 나쁘므로 특(特)히 고온가황(高溫加黃)에 대(對)해 민감(敏感)하다. 이것은 고온(高溫)에서 단시간(短時間) 가황(加黃)일수록 가속(加速)된다. 평탄가황배합물(平坦加黃配合物)의 경우에서 보더라도 내부(內部)가 적절(適切)히 가황(加黃)되기도 전(前)에 외부(外部)는 과가황(過加黃)이 되는 수가 있다. 근래(近來) 발간(發刊)된 문헌(文獻)에서도 이러한 내용(內容)이 잘 설명(說明)이 되어 있는데 다른 각도(角度)에서 고찰(考察)해 볼것 같으면 정체시간(停滯時間)이 비교적(比較的) 길지 않는 한(限) 가황시간(加黃時間)은 정체시간(停滯時間)과 sheet 가황시간(加黃時間)과의 합(合)이라고 말할 수 있겠다. 예(例)를 들어 설명(說明)하자면 $130^{\circ}C(266^{\circ}F)$에서 정체시간(停滯時間)이 10분(分)이고 sheet 가황시간(加黃時間)이 20분(分)인 제품(製品)은 이 온도(溫度)에서 30분간(分間) 가황(加黃)해야 된다는 것이다. 온도계수(溫度係數)를 2라고 가정(假定)할 경우 $140^{\circ}C(284^{\circ}F)$에서의 가황시간(加黃時間)은 $30\times\frac{1}{2}=15$분(分)이 아니라 $20\times\frac{1}{2}+10=20$분(分)이 된다. 크기가 큰 제품(製品)은 보통(普通) 다음에 있는 여러 방법(方法)들 가운데 한 가지 또는 여러가지를 조합(組合)하여 가황(加黃)시킨다. a) 크기가 작은 것에 대한 것 보다 낮은 온도(溫度)에서 가황(加黃)한다. b) 침투가황-제품(浸透加黃-製品)을 가압하(加壓下)에 두고서 외부가황(外部加黃)은 단속(斷續)시키고 열(熱)이 중심(中心)으로 침투(浸透)하게 한다. c) 단계가황(段階加黃)-처음에는 저온(低溫)에서 시작(始作)하여 일정간격(一定間隔)을 두고 점차(漸次) 온도(溫度)를 상승(上昇)시켜 최종적(最終的)으로 가황온도(加黃溫度)까지 올린다. d) 가능(可能)하다면 metal base나 금형(金型)에서 고무를 증기가황(蒸氣加黃)시킬 경우에 있어서 속이 빈 축(軸)을 사용하여 내부(內部)로 부터 가열(加熱)하면 가황시간(加黃時間)이 단축(短縮)된다. e) 냉각중(冷却中)의 후가황(後加黃)-이것은 가열장치(加熱裝置)에서 끄집어낸 후 제품(製品)의 외부(外部)를 냉각(冷却)시키는 방법(方法)이다. 가열(加熱)된 제품(製品)이 쌓여 있거나 적절(適切)하게 냉각(冷却)되지 않을 때 가황(加黃)이 추가적(追加的)으로 되거나 과가황(過加黃)이 될 우려가 있는 제조공정(製造工程)에서는 흔히들 이 방법(方法)을 무시(無視)하고 있다. 여기서 강조(强調)해 두어야 할 것은 항상 제품(製品)의 외부(外部)를 완전(完全)히 가황(加黃)시킬 필요(必要)는 없다는 것이다. 다공성(多孔性)이나 기포생성(氣泡生成)을 조장(助長)하는 불량가황상태(不良加黃狀態)와 표면(表面)에서의 과가황상태간(過加黃狀態間)의 균형(均衡)을 취(取)해 줘야 하는데 물론(勿論) 이때는 가황시간(加黃時間)을 단축(短縮)시켜야 한다는 경제적(經濟的)인 측면(側面)도 아울러 고려(考慮)해야 한다. 이것은 고무기술자(技術者)가 당면(當面)해야할 과제(課題)에 속(屬)하며 바람직 한것은 본장(本章)의 내용(內容)이 여러 상황하(狀況下)에서 당면(當面)한 문제(問題)에 대(對)해 어떻게 대처(對處)해 야 할지를 모르는 여러 기술자(技術者)들에게 도움이 되었으면 하는 것이다.

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Improved Electrochemical Performance and Minimized Residual Li on LiNi0.6Co0.2Mn0.2O2 Active Material Using KCl (KCl을 사용한 LiNi0.6Co0.2Mn0.2O2계 양극활물질의 잔류리튬 저감 및 전기화학특성 개선)

  • Yoo, Gi-Won;Shin, Mi-Ra;Shin, Tae-Myung;Hong, Tae-Whan;Kim, Hong-kyeong
    • Journal of the Korean Electrochemical Society
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    • v.20 no.1
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    • pp.7-12
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    • 2017
  • Using a precursor of $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ as a starting material, a surface-modified cathode material was obtained by coating with KCl, where the added KCl reduces residual Li compounds such as $Li_2CO_3$ and LiOH, on the surface. The resulting electrochemical properties were investigated. The amounts of $Li_2CO_3$ and LiOH decreased from 8,464 ppm to 1,639 ppm and from 8,088 ppm to 6,287 ppm, respectively, with 1 wt% KCl added $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ that had been calcined at $800^{\circ}C$. X-ray diffraction results revealed that 1 wt% of KCl added $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ did not affect the parent structure but enhanced the development of hexagonal crystallites. Additionally, the charge transfer resistance ($R_{ct}$) decreased dramatically from $225{\Omega}$ to $99{\Omega}$, and the discharge capacity increased to 182.73mAh/g. Using atomic force microscopy, we observed that the surface area decreased by half because of the exothermic heat released by the Li residues. The reduced surface area protects the cathode material from reacting with the electrolyte and hinders the development of a solid electrolyte interphase (SEI) film on the surface of the oxide particles. Finally, we found that the introduction of KCl into $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ is a very effective method of enhancing the electrochemical properties of this active material by reducing the residual Li. To the best of our knowledge, this report is the first to demonstrate this phenomenon.

A Study on the Effect of O$_2$ annealing on Structural, Optical, and Electrical Characteristics of Undoped ZnO Thin Films Deposited by Magnetron Sputtering (산소 어닐링이 마그네 트론 스퍼터링으로 증착된 undoped ZnO박막의 구조적, 광학적, 전기적 특성에 미치는 영향에 대한 연구)

  • Yun, Eui-Jung;Park, Hyeong-Sik
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.7
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    • pp.7-14
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    • 2009
  • In this paper, the effects of annealing conditions on the structural ((002) intensity, FWHM, d-spacing, grain size, (002) peak position), optical (UV peak, UV peak position) and electrical properties (carrier concentrations, resistivity, mobility) of ZnO films were investigated. ZnO films were deposited onto SiO$_2$/si substrates by RF magnetron sputtering from a ZnO target. The substrate was not heated during deposition. ZnO films were annealed in temperature ranges of $500\sim650^{\circ}C$ in the O$_2$ flow for 5$\sim$20 min. The film average thicknesses were in the range of 291 nm. The surface morphologies and structures of the samples were characterize by SEM and XRD, respectively. The optical properties were evaluated by photoluminescence (PL) measurement at room temperature (RT) using a He-Cd 325 nm laser. As the annealing temperature and time vary, the following relations were also observed: (1) proportional relationships among UV intensity (002) intensity, and grain size exist, (2) UV intensity is inversely proportional to FWHM, (3) there is no special relationship between UV intensity and electron carrier concentrations, (4) d-spacing is inversely proportional to (002) peak position, (5) UV peak position in the range of 3.20$\sim$3.24 eV means that ZnO films have a n-type conductivity which was consistent with that obtained from the electrical property, (6) the optimal conditions for the best optical and structural characteristics were found to be oxygen fraction, (O$_2$/(O$_2$+Ar)) of 0.2, RF power of 240W, substrate temperature of RT, annealing condition of 600$^{\circ}C$ for 20 min, and sputtering pressure of 20 mTorr.

Evaluation of the Temperature Drop Effect and the Rutting Resistance of Moisture Retaining-Porous Asphalt Pavement Using Accelerated Pavement Testing (포장가속시험을 이용한 보수형 배수성 포장의 온도저감 효과 및 소성변형 저항특성 연구)

  • Kwak, Byoung-Seok;Suh, Young-Chan;Song, Chul-Young;Kim, Ju-Won
    • International Journal of Highway Engineering
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    • v.11 no.3
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    • pp.97-109
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    • 2009
  • One of the main causes of asphalt rutting is high temperature of the pavement. Nevertheless, there has been few research on lowering the pavement temperature for reducing rutting. This study investigated the performance characteristics of moisture-retaining porous asphalt pavement, which is known to have a temperature reducing effect. The purpose of this study is to quantify the temperature reducing effect of moisture-retaining porous asphalt pavement and its effect of reducing rutting through Accelerated Pavement Testing(APT). Additionally, the possibility of reducing the thickness of the pavement in comparison to general dense grade pavement by analyzing structural layer coefficient of moisture retaining pavement. A total of three test sections consisting of two moisture-retaining porous asphalt pavement sections and one general dense-grade porous asphalt pavement section were constructed for this study. Heating and spraying of water were carried out in a regular cycle. The loading condition was 8.2 ton of wheel load, the tire pressure of $7.03kgf/cm^2$, and the contact area of $610cm^2$. The result of this experiment revealed that the temperature reducing effect of the pavement was about $6.6{\sim}7.9^{\circ}C$(average of $7.4^{\circ}C$) for the middle layer and $7.9{\sim}9.8^{\circ}C$(average of $8.8^{\circ}C$) for surface course, resulting in a rutting reduction of 26% at the pavement surface. Additionally, the structural layer coefficient of moisture retaining pavement measured from a laboratory test was 0.173, about 1.2 times that of general dense grade pavement. The general dense-grade porous asphalt pavement test section exhibited rutting at all layers of surface course, middle layer, and base layer, while the test sections of moisture-retaining porous asphalt pavement manifested rutting mostly at surface course only.

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