• Title/Summary/Keyword: 표면 단열재

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Study on the hydrophobic modification of zirconia surface for organic-inorganic hybrid coatings (유-무기 하이브리드 코팅액 제조를 위한 지르코니아 표면의 소수화 개질 연구)

  • Lee, Soo;Moon, Sung Jin;Park, Jung Ju
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.260-270
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    • 2017
  • Zirconia has white color and physical, chemical stability, also using in high temperature materials and various industrial structural ceramics such as heat insulating materials and refractories due to their low thermal conductivity, excellent strength, toughness, and corrosion resistance. If hydrophobically modified zirconia is introduced into a hydrophobic acrylate coating solution, the hardness, chemical, electrical, and optical properties will be improved due to the better dispersibility of inorganic particle in organic coating media. Thus, we introduced $-CH_3$ group through silylation reaction using either trimethylchlorosilane(TMCS) or hexamethyldisilazane(HMDZ) on zirconia surface. The $Si-CH_3$ peaks derived from TMCS and HMDZ on hydrophobically modified zirconia surface was confirmed by FT-IR ATR spectroscopy, and introduction of silicon was confirmed by FE-SEM/EDS and ICP-AES. In addition, the sedimentation rate result in acrylate monomer of the modified zirconia showed the improved dispersibility. Comparison of the sizes of a pristine and the modified zirconia particles, which were clearly measured not by the normal microscope but by particle size analysis, provided a pulverizing was occurred by physical force during the silylation process. From the BET analysis data, the specific surface area of zirconia was approximately $18m^2/g$ and did not significantly change during modification process.

Effect of the Kind of Modified Bubble Sheets on the Temperature Profiles and Crack Reduction of the Concrete under Hot Weather (표면개량 버블시트 종류 변화가 서중환경 콘크리트의 온도 및 균열발생에 미치는 영향)

  • Lee, Sang-Woon;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.251-257
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    • 2018
  • There are various quality deteriorations of concrete such as plastic, drying shrinkage due to abrupt moisture evaporation, slump loss and cold joint under hot weather condition. To protect from above deteriorations, several kinds of modified bubble sheets have been applied to secure heat insulation performance. But, there is not enough application cases of bubble sheets at job site under hot weather condition. The objective of the paper is to investigate the temperature profile and crack occurrence of the concrete covered with five different kinds of surface curing sheets, which is placed under hot weather condition. Single layer transparent bubble sheet, white colored bubble sheet, aluminum metalizing bubble sheet and PE film are adopted for surface curing sheets. Test results indicated that application of aluminum metalizing bubble sheet had most favorable effect on the reduction of on temperature rise and on the crack reduction of concrete. But due to larger reflection of light by aluminum, it brings about visual pollution to the workers. Hence, the application of white colored bubble sheet can be the most desirable alternative to protect the concrete from hot weather in the field.

Evaluation of The Hygrothermal Performance by Wall Layer Component of Wooden Houses Using WUFI Simulation Program (WUFI 시뮬레이션 프로그램을 이용한 목조주택 벽체 레이어 구성에 따른 hygrothermal 성능 평가)

  • Kang, Yujin;Kim, Sumin
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.1
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    • pp.75-84
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    • 2016
  • Thermal performance of wooden houses used by building materials effectively contributing to building energy saving has been improved. However, the performance was decreased to the condensation and mould growth from exterior wall because the moisture control was difficult to high insulation and airtightness. Therefore, the hygrothermal performance of exterior wall, that selected 5 types of wooden houses, evaluated using the hygrothermal simulation program: heat and moisture behavior, condensation and mould growth risk. Wooden houses were selected Rural houses standard plans '10 and '14, $2^{{\prime}{\prime}}{\times}6^{{\prime}{\prime}}$ type, EIFS and wood-based passive house. And the wall A, B, C, D and E were determined by layer component of each wall. The U-value of exterior wall are 0.171, 0.172, 0.221, 0.150, $0.079W/m^2K$. The OSB absolute water content of the wall A and C was exceeds the reference value of 20%, and it was confirmed that condensation occur at insulation material inner surface through the condensation evaluation in the winter. The wall D and E showed excellent results with condensation and water content evaluation compared to others. However, mould growth risk assessment in all five types of wall had have risk. We were determined that hygrothermal performance difference of exterior wall occur the difference in the layer structure rather than in thermal performance.

Analysis of melt flows and remelting phenomena through numerical simulations during the kyropoulos sapphire single crystal growth (전산해석을 통한 키로플러스 사파이어 단결정 성장공정의 유동 및 remelting 현상 분석)

  • Kim, Jin Hyung;Park, Yong Ho;Lee, Young Cheol
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.3
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    • pp.129-134
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    • 2013
  • Sapphire wafers are used as an important substrate for the production of blue LED (light emitting diode) and the LED's performance largely depends on the quality of the sapphire single crystals. There are several crystal growth methods for sapphire crystals and Kyropoulos method is an efficient way to grow large diameter and high-quality sapphire single crystals with low dislocation density. During Kyropoulos growth, the convection of molten melt is largely influenced by the hot zone geometry such as crucible shape, heater and refractory arrangements. In this study, CFD (computational fluid dynamics) simulations were performed according to the bottom/side ratios (per unit of the crucible surface area) of heaters. And, based on the results of analysis, the molten alumina flows and remelting phenomena were analyzed.

A Study on the Visualization of Ice-formation Phenomena of Bath Water to Decide Maintenance Period of Gas Heater (가스히터 보수주기 결정을 위한 히터내부 열전달 매체액 결빙현상 가시화에 관한 연구)

  • Lee J. H.;Ha J. M.;Sung W. M.
    • Journal of the Korean Institute of Gas
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    • v.5 no.3 s.15
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    • pp.1-8
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    • 2001
  • This study was carried out for the purpose of determination of maintenance period and investigation of weak point due to freeze when the gas heater of KOGAS valve station Is not operated in winter season. 3-dimensional non-linear numerical simulation was conducted in order to predict the time and location which bath water in heater reaches to ice point. FLUENT V 5.0, commercial code, is used for thermal fluid flow analysis. We thought this was problem of heat conduction solving the energy equation and modeled gas heater by using the real geometry and scale for performing the 3-dimensional simulation. It was analyzed complex heat transfer phenomena considering convection due to air on surface, conduction in insulation material, natural convection of liquid in heater and heat loss through the pipe.

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Dinosaur Tracksite at Jeori, Geumseongmyeon, Euiseonggun, Gyeongsangbukdo, Korea(National Monument No. 373) - Occurrences, Significance in Natural History, and Preservation Plan - (경북 의성군 금성면 제오리 공룡발자국화석 산지(천연기념물 제373호) - 산상, 자연사적 가치 및 보존 방안 -)

  • Paik, In Sung;Kim, Hyun Joo;Kang, Hee Cheol;Lim, Jong-Deock
    • Korean Journal of Heritage: History & Science
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    • v.46 no.1
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    • pp.268-289
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    • 2013
  • The Dinosaur tracksite at Jeori, Geumseongmyeon, Euiseonggun, Gyeongsangbukdo, Korea (National Monument No. 373) has been studied in the aspects of location, stratigraphy, sedimentology, fossil occurrence, unique geological records, literature, significance in natural history, preservation, and management. On the basis of these features, the Jeori tracksite has been assessed semiquantitavely. The Jeori tracksite occurs in the Sagok Formation (Albian) of the Euiseong sub-basin, and over 300 footprints forming 12 sauropod trackways, 10 ornithopod trackways, and 1 theropod trackways are preserved in this tracksite. The track-bearing deposits consist of tabular-bedded medium- to fine-grained arkose with mudstone drape, interlaminated fine-grained sandstone to siltstone and mudstone, and shaly mudstone. The dinosaur tracks are preserved in the interlaminated fine-grained sandstone to siltstone and mudstone, and most of them are observed as underprints. The track-bearing deposits are interpreted as sheetflood deposits on the floodplain under a seasonal paleoclimatic condition with alternating of wetting and drying periods. Multiple tension fractures with NE strike were formed in the track-bearing bed, which resulted in that tracks seem to occur in several horizons. The significance in natural history of the tracksite can be summarized as follows: 1) the historical implication of the Jeori tracksite as the firstly designated National Monument of dinosaur fossil sites, 2) the high density of the occurrence of diverse footprints (over 300) within small area (about $1,600m^2$), and 3) the significance of the tension fractures associated with the track-bearing bed as geoeducational records for the understanding the development of fault. In order to share the value of the Jeori tracksite in the aspect of natural history with the community and public, the interpretive panel should be modified to include figures explaining paleoenvironment and tension fault development. In addition it is recommended that a brochure be published briefly explaining the tracksite and to educate the residents about the natural and social significance of the tracksite. For the safety of visitors it would be desirable for the road in front of the tracksite to be moved at least 10 m southward, which could mitigate the shaking of the track bed caused by traffic.

Safety evaluation of type B transport container for tritium storage vessel (B형 삼중수소 운반용기 안정성 평가)

  • Lee, Min-Soo;Paek, Seung-Woo;Kim, Kwang-Rag;Ahn, Do-Hee;Yim, Sung-Paal;Chung, Hong-Suk;Choi, Heui-Joo;Choi, Jeong-Won;Son, Soon-Hwan;Song, Kyu-Min
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.2
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    • pp.155-169
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    • 2007
  • A transport container for a 500 kCi tritium storage vessel was developed, which could be used for the transport of metal tritide from Wolsong TRF facility to a disposal site. The structural, thermal, shielding, and confinement analyses were performed for the container in a view of Type B. As a result of structural analysis, the developed container sustained its integrity under normal and accidental conditions. The maximum temperature increase of the inner storage vessel by radiation was evaluated at $134.8^{\circ}C at room temperature. In $800^{\circ}C$ fire test, The thermal barrier of container sustained the inner vessel at $405^{\circ}C after 30 min, which temperature was allowable for the container integrity since maximum design temperature of inner vessel was $550^{\circ}C. In the evaluation of the shielding, the activity of radiation was nearly zero on the outer surface of inner vessel. Consequently the transport container for a 500 kCi tritium was evaluated to pass all the safety tests including accidental condition, so it was concluded that the designed transport container is proper to be used.

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Effects of Freezing Rate and Storage Temperature on the Degree of Retrogradation, Texture and Microstructure of Cooked Rice (동결속도 및 저장온도가 취반된 쌀의 노화도, 조직감 및 미세구조에 미치는 영향)

  • Choi, Sung-Gil;Rhee, Chul
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.783-788
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    • 1995
  • Cooked rices were frozen at four different rates(3, 5, 7 and 12 hr) of maximum ice crystal formation zone and stored at $-20^{\circ}C\;and\;-70^{\circ}C$ for 3 months. Freezing rate, storage temperature and storage period all affected the degree of retrogradation of cooked rice. As the maximum ice crystal formation zone increased from 3 hrs to 12 hrs, the degree of retrogradation of cooked rice increased from 14.9% to 40.0%. Further retrogradation occurred during the freezing storage and cooked rice stored at $-20^{\circ}C$ retrograded faster than that held at $-70^{\circ}C$. The hardness and adhesiveness of frozen cooked rice thawed in $40^{\circ}C$ water were measured. Hardness of the frozen cooked rice was higher than that of non-frozen sample and was higher at lower freezing rate. However, the hardness of cooked rice decreased after 3 months of storage. On the other hand, the adhesiveness decreased during the freezing processing, and adhesiveness decreased more rapidly at a higher freezing rate. However, the adhesiveness of cooked rice increased after 3 months of the storage, and the level of decrease was higher at $-70^{\circ}C$ than at $-20^{\circ}C$. After 3 months of storage, ice crystal size of frozen cooked rice became larger by recrystalization than that of frozen sample prior to storage. Microstructure of cooked rice was damaged by ice crystal formation and its growth when observed by scanning electron microscope.

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Surrogate Models and Genetic Algorithm Application to Approximate Optimization of Discrete Design for A60 Class Deck Penetration Piece (A60 급 갑판 관통 관의 이산설계 근사최적화를 위한 대리모델과 유전자 알고리즘 응용)

  • Park, Woo Chang;Song, Chang Yong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.2
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    • pp.377-386
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    • 2021
  • The A60 class deck penetration piece is a fire-resistant system installed on a horizontal compartment to prevent flame spreading and protect lives in fire accidents in ships and offshore plants. This study deals with approximate optimization using discrete variables for the fire resistance design of an A60 class deck penetration piece using different surrogate models and a genetic algorithm. Transient heat transfer analysis was performed to evaluate the fire resistance design of the A60 class deck penetration piece. For the approximate optimization of the piece, the length, diameter, material type, and insulation density were applied to discrete design variables, and temperature, productivity, and cost constraints were considered. The approximate optimum design problem based on the surrogate models was formulated such that the discrete design variables were determined by minimizing the weight of the piece subjected to the constraints. The surrogate models used in the approximate optimization were the response surface model, Kriging model, and radial basis function-based neural network. The approximate optimization results were compared with the actual analysis results in terms of approximate accuracy. The radial basis function-based neural network showed the most accurate optimum design results for the fire resistance design of the A60 class deck penetration piece.

Characteristics of Zeolites (Zeolite의 특성)

  • Im, Goeng
    • The Journal of Natural Sciences
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    • v.6 no.1
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    • pp.103-108
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    • 1993
  • Zeolites were discovered as a natural mineral more than two hundred ago. In the beginning, the mineral was used as ion-exchange material and adsorbent. After the end of World War II , however, a variety of zeolites have become available in large amounts because of the establishment of low temperature synthesis and the discobery of natural zeolite deposits of sedimentary origin. Various uses of xeolite were developed utilizing the unique crystal strucrure and function of these minerals. In connection with this development remakable progress has also been made in basic stuides on the related geology and mineralogy, crystallization from sols and gels, structure, ion exchange, adsorption and cataiysis. As a result, zeolites, which had been known only as mineral specimens displayed in museums. established a firm position among the high-technology masterials with excellent functional capabilities.

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