• Title/Summary/Keyword: 폴리아미드

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최신 절연시스템과 내열특성에 대한 소고

  • 이복희;김정섭
    • 전기의세계
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    • v.35 no.4
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    • pp.254-258
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    • 1986
  • 최근 고분자재료의 눈부신 발전은 전기기기의 절연에도 많은 향상을 가져왔다. 전기기기의 절연재료로는 기계적, 전기적, 화학적 성능이 우수한 합성수지재료가 많이 쓰이고 있다. 전기절연재료를 대별하여 보면 박막재료와 함침재료로 나눌 수 있으며, 박막재료에는 운모, 실리콘고무, 폴리아미드필름, 폴리아미드클로즈 등이 있으며, 바니쉬류에는 내열성이 우수한 실리콘계바니쉬와 무용제함침재료가 많이 사용된다. 전기기기의 기본 구성재료이며 기기의 성능 향상과 소형화, 경량화에 중요한 인자로 작용하는 전기절연재료인 박막재료와 함침재료의 조화로 구성되는 절연시스템의 열열화와 내열수명에 영향을 미치는 절연의 신뢰성에 대하여 알아본다.

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The effect of blending condition on the ester-amide exchange reactions and their rheological properties of Poly(trimethylene terephthalate)/Polyamide 6 or 6,6 Blends (Poly(trimethylene terephthalate)/Polyamide 6 및 6,6의 용융블렌드시 블렌드조건에 따른 에스테르-아미드 교환반응 정도와 유변특성)

  • 이현주;김학성;임경율;김병철
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.183-186
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    • 2001
  • 폴리에스테르/폴리아미드의 블렌드는 두 고분자의 단점을 상호 보완할 수 있을 뿐만 아니라 조성비에 의해 원하는 물성을 부여할 수 있는 장점이 있다. 이들 블렌드 중에서 폴리(에틸렌 테레프탈레이트)(PET)/폴리아미드(PA)의 블렌드의 경우 일반적인 폴리에스테르계의 블렌드에서 일어나는 에스테르 교환반응과 마찬가지로 에스테르-아미드 교환반응이 일어나며 이를 이용하여 두 고분자간의 상용성을 향상시키려는 연구가 보고된 바 있다. (중략)

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Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin -(I) Physical Properties of Adhesives- (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능 향상 -(I) 접착제의 물성-)

  • Chun, Young-Sik;Hong, Young-Keun;Chung, Kyung-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.194-202
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    • 1996
  • Hot melt adhesive based on the polyamide resin was studied to improve the conventional hot melt adhesives such as ethylene-vinyl acetate which have inherent problems against creep and heat resistance. It was found that the terpolymer of nylons6, nylon66, and nylon12 or the nylon blend instead of nylon homopolymer was suitable base resin for hot melt adhesives, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. Also, the rheological properties of the polyamide based hot melt adhesive could be controlled by the incorporation of terpene resin, butyl benzyl phthalate, and paraffin wax. The results of melt viscosities and tensile properties of adhesive itself indicated that the optimum adhesion properties could be obtained through the blending of CM831/843P resins with weight ratio 75/25~50/50. The adhesion between steel and steel was tested by using lap shear geometry. It was found that the surface roughness of steel affected the adhesion strength.

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Performance Evaluation of Organic and Inorganic Fiber Reinforced Concrete in Tunnel Lining Structure (유·무기 섬유 혼입 터널 라이닝 콘크리트 부재의 성능 평가)

  • Lee, Jong-Eun;Kim, Tae-Won;Kim, Su-Man;Jeon, Joong-Kyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.3 s.55
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    • pp.110-118
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    • 2009
  • The tunnel structure is widely used for transportation in the mountain area. To reduce the duration of construction and thus the expense, a tunnel excavation is often performed simultaneously with a tunnel lining in in-situ. However, cracking of the tunnel lining may occur arising from the vibrating impact in the excavation process. The present study concerns the role of steel fiber and nylon fibers in tunnel lining concrete to reduce the vibrating impact. As a result it was found that both the nylon fiber and steel fiber improved the durability and physical properties of concrete.

A Study on the Polyamide Based Thermoplastic Composites for Fuel Cell Separators (연료전지 분리판용 폴리아미드계 복합체의 특성 연구)

  • Lee, Kwang-Yong;Kim, Jeong-Heon;Ryu, Sung-Hun
    • Elastomers and Composites
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    • v.43 no.4
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    • pp.253-258
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    • 2008
  • In this study polyamide 6,6 based thermoplastic composite with graphite and carbon black had been examined feasibility for separators of fuel cell which requires good mechanical and electrical properties with gas impermeability. The effects of molding pressure and filler content on the properties of the composite were investigated. Maximum flexural modulus was obtained about 80 wt% graphite, while electrical conductivity increased with graphite content. Flexural strength increased with molding pressure and tended to level-off from $400\;kgf/cm^2$. Molding pressure did not affect the electrical conductivity. The addition of carbon black enhanced the electrical conductivity of the composite. Mechanical properties were decreased under acidic condition.

Synthesis of Polyimides Derived from 2,2-Bis[4-(4-aminobenzoyl)phenoxy]hexafluoropropane and Aromatic Dianhydrides (2,2-Bis[4-(4-nitrobenzoyl)phenoxy]hexafluoropropane과 방향족 이무수물을 사용한 폴리이미드의 합성)

  • Park, Jung Hye;Ahn, Byung Hyun
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.50-55
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    • 2016
  • Aromatic diamines containing hexafluoroisopropylidene and ester moiety were synthesized from 4,4'-hexafluoroisopropylidene diphenol and nitrobenzoyl chloride. The reaction of aromatic diamines with hexafluoroisopropylidene phthalicdianhydride (6FDA) or pyromellitic dianhydride (PMDA) gave four kinds of poly(amic acid)s. Their inherent viscosities ranged from 0.196 to 0.346 dL/g. Poly(amic acid)s were converted to polyimides by thermal imidization. The glass transition temperatures ($T_g$) of polyimides were between 241 and $289^{\circ}C$. The 5% weight loss temperatures were recorded in the range of $430{\sim}492^{\circ}C$. The tensile strength of polyimide films were measured as 29.84~64.38 MPa.

Reactive Compatibilization of Amorphous Poly-${\alpha}$-olefins/Amorphous Polyamide Blends (무정형 알파-올레핀 고분자/무정형 폴리아미드 블렌드의 반응 상용화)

  • Yun, Deok-Woo;Choi, Mi-Ju;Hwang, Kyu-Hee;Kim, Geon-Seok;Lee, Kwang-Hee
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.490-495
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    • 2009
  • The reactive compatibilization of amorphous poly-${\alpha}$-olefins (APAO)/amorphous polyamide (aPA) blends was carried out using two kinds of reactive compatibilizers such as maleated polypropylene and ethylene-glycidyl methacrylate-methyl acrylate copolymer. The grafting reaction rates between aPA and the compatibilizers were examined using FT-IR, SEM and rheometer. The effect of the reactive compatibilization on the mechanical property of the blends was investigated with a universal testing machine. The adhesion strength of the blends including a hydrocarbon tackifier resin, C9 was also measured.

Miscibility and Mechanical Properties of Polycaprolactone-polyamide Block Copolymer/Poly(vinyl chloride) Blend (Polycaprolactone-폴리아미드 블록공중합체/Poly(vinyl chloride) 블렌드의 상용성과 기계적 성질)

  • 안소봉;이하용;정한모
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.128-132
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    • 2000
  • The miscibility between poly(vinyl chloride) (PVC) and polycaprolactone (PCL)-polyamide block copolymer whose content of PCL block is 62.7 wt%, was studied by differential scanning calorimetry. The PCL segment in the block copolymer and PVC has the miscibility showing single glass transition temperature (T$_{g}$). The miscible PVC molecule inhibited the crystallization of PCL segment, making an amorphous homogeneous phase of PCL and PVC segments at high PVC content. The blends had rubber elasticity at the temperature range between the T$_{g}$ of amorphous homogeneous phase of PCL and PVC segments and the melting temperature of polyamide segment, when both phases coexist.ist.

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A Experimental Study on the Flexural Behavior of Bundle Type Polyamide Fiber Reinforced Concrete (다발형 폴리아미드섬유 보강 콘크리트의 휨거동에 관한 실험적 연구)

  • Jeon, Chan Ki;Jeon, Joong Kyu
    • Journal of the Society of Disaster Information
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    • v.10 no.1
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    • pp.61-70
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    • 2014
  • Synthetic fiber reinforced concrete is applicable to many applications for construction material. In general, synthetic fibers have low tensile strength and elastic modulus, but they have many advantages such as high crack resistance, impact resistance, chemical resistance, flexural behavior and corrosion free in fiber reinforced concrete. Recently, fiber reinforced concrete with macro synthetic fibers has been used to improve performance of structures in tunnel shotcrete, precast segmental lining and bridge slab and precast concrete structures. This study investigated the influence of bundled type polyamide fiber reinforced concrete on the flexural behavior in accordance with ASTM C 1609 and KS F 2566 standards.