• Title/Summary/Keyword: 폴리머시멘트

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Properties of Latex Modified Concrete by Binder Content and Effect on Chloride Ion Diffusion (라텍스 개질 콘크리트(LMC)의 결합재량에 따른 배합 및 염화물 이온 확산 특성)

  • Park, Sung-Gi;Won, Jong-Pil;Park, Chan-Gi;Lee, Sang-Woo;Sung, Sang-Kyoung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.949-952
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    • 2008
  • The latex modified concrete(LMC) was adds latex in the plain concrete as the latex has increase the durability of concrete. But it is added in LMC manufacture, which is a high price compares with different material and there is a weak point where the construction expense is very high. So, this study are decided mix proportion from the scope where the security strong point of LMC is possible and reduced the material expense by control the latex contents. and these mix proportions are estimated the chloride ion diffusion. The results of study appear that it can reduced the latex content until the $5{\sim}10$% of cements, and these mixtures are very low chloride ion diffusion.

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Strength Properties of Bisphenol A-Type Epoxy-Modified Mortars under Various Curing Conditions (각종 양생조건에 따른 비스페놀 A형 에폭시수지 혼입 모르타르의 강도성상)

  • Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.55-59
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    • 2009
  • The epoxy resin without hardener can harden by a ring-opening reaction in the presence of the alkalies produced by the hydration of cement in epoxy-modified mortars and concretes. This paper investigates the effect of curing conditions on the strength improvement of polymer-modified mortars using bisphenol A-type epoxy resin without hardener. The polymer-modified mortars using epoxy resin are prepared with various polymer-cement ratios, and subjected to ideal, water, dry and heat cures. In the heat cure, the epoxy-modified mortars are sealed or unsealed with a PVDC (polyvinylidene chloride) film. The epoxy-modified mortars are tested for flexural and compressive strengths at desired curing methods. The microstructures of the epoxy-modified mortars are also observed by scanning electron microscope. The effects of curing conditions on the strength development of the epoxy-modified mortars are examined. From the test results, the marked effectiveness of the heat cure under the PVDC film sealing against the development of the strength of the epoxy-modified mortar without the hardener is recognized. The flexural and compressive strengths of 7-day-90℃ heat-cured, PVDC film-sealed epoxy-modified mortars without hardener reach 7 to 17MPa and 24 to 44MPa respectively, and are two to three times of Unmodified mortar. Such high strength development of the epoxy-modified mortars may be achieved by the dense microstructure formation by cement hydrates and the hardening of the epoxy resin in the mortars.

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Shell Powder Coating on the Surface of Concrete by Geopolymer Cement (지오폴리머 시멘트를 이용한 콘크리트 표면의 패각 분말 코팅)

  • Kim, Gab-Joong;Han, Hyun-Geun;Seo, Dong-Seok;Lee, Jong-Kook
    • Korean Journal of Materials Research
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    • v.20 no.1
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    • pp.1-6
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    • 2010
  • Geopolymer materials are attractive as inorganic binders due to their superior mechanical and eco-friendly properties. In the current study, geopolymer-based cement was prepared using aluminosilicate minerals from fly-ash with KOH as an alkaline-activator and $Na_2SiO_3$ as liquid glass. Then, calcium carbonate powder from a clam shell was mixed with the geopolymer and the mixture was coated on a concrete surface to provide points of attachment for environmental organisms to grow on the geopolymers. We investigated the effect of the shell powder grain size on the microstructure and bonding property of the geopolymers. A homogeneous geopolymer layer coated well on the concrete surface via aluminosilicate bonding, but the adhesiveness of the shell powder on the geopolymer cement was dependent on the grain size of the shell powder. Superior adhesive characteristics were shown in the shell powder of large grain size due to the deep penetration into the geopolymer by their large weight. This kind of coating can be applied to the adhesiveness of eco-materials on the surface of seaside or riverside blocks.

New Development of Eco-friendly cementitious Ceramic Tile Adhesive by Thick-Bed method for Polishing tile and Porcelain tile (폴리싱 및 포세린 타일 떠붙임용 시멘트계 친환경 타일접착제 개발)

  • Cho, Chang-Hwan;Lee, Duk-Yong;Lee, Jae-Min;Choi, Il-Joon;Eom, Joo-Il
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.62-63
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    • 2019
  • Currently, polymer-based tile cement (Thin-bed method) and epoxy adhesive (Thick-bed method) are mainly used as tile adhesive for polishing and porcelain. In the case of epoxy adhesive, there is a low economic efficiency, there is a problem that the work efficiency is reduced by mixing the resin and the hardener. In particular, the epoxy contains a bisphenol A and amine component, there is a risk of workable disease when a worker is exposed to odor and harmful gases generated in the epoxy adhesive for a long time. Against this background, it is necessary to analyze the hazards of using epoxy adhesives indoors, and develop cementitious high performance tile adhesive products with significantly lower hazards than epoxy adhesives.

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Analysis of the Cause of Waterleakage in Residential Apartment Underground Parking Ground and the Review of the Repare Methods (공동주택 지하주차장의 누수원인 분석 및 보수방안 검토)

  • Oh, Sang-Keun;Choi, Sung-Min;Song, Je-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.3
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    • pp.255-264
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    • 2014
  • This study analyzes the cause and the repairing method of water leak by parts of basement parking lot which is recorded to have a high defect frequency in apartment buildings. It has been assessed that the cause of water leakage on the first floor upper substrate is due to such factors as landscaping and weights. During construction or through other cases, it has been determined that cracks were produced in the apartment structure because the structure was weak and exposed to the effects of the substrate movement. The base floor and underground external walls are areas that are exposed to water pressure (uplife pressure), thus in normal cases the rear surface repair of the structure using sythetic rubberized polymer gel should be considered as an effective method. However, in cases where application of waterproofing layer is required in the structure due to high water pressure, using asystolic cement milk grout to form the waterproofing layer and applying water-swelling acrylic material into the cracked areas is considered to be highly effective.

Evaluation of Aging Characteristics of Selected PMA using HP-GPC (HP-GPC를 이용한 폴리머개질 아스팔트의 노화특성 분석)

  • Kim, Kwang-Woo;Doh, Young-Soo;Amerkhanian, Serj N.
    • International Journal of Highway Engineering
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    • v.6 no.2 s.20
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    • pp.15-24
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    • 2004
  • Oxidation causes increment of the quantity of large molecular size or LMS in asphalt and is a major reason for hardening of asphalt binder. An extended service life of pavement on a road is expected by reducing oxidation of binder. Oxidation of binder occurs during hot mixing with aggregates before placement on road and then during in-service after the asphalt pavement is constructed. Quantitative increase of LMS as result of aging after RTFO and PAV was analyzed based on the data from high-pressure gel-permeation chromatography (HP-GPC). Polymer modified asphalt (PMA) after RTFO procedure showed 20-30% increment in LMS and then after PAV procedure more than twice, although the percentage of increment was different according to asphalt brand and grade. The PMAs containing LDPE or SBS, which showed a great mechanical property improvement in previous studies, were selected for characterizing PMA aging In this study. Considerably reduced increment of LMS was observed from the PMA containing LDPE after RTFO and PAV procedures. The GPC result showing the binder with less LMS increment means that the asphalt while being mixed with LDPE was aged less during the aging treatment. The dispersed particle of LDPE in asphalt cement seems to disturb oxidative aging reaction and evaporation.

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Basic Properties of Polymer Cement Mortar with EVA Emulsion and Admixtures (EVA 에멀젼과 혼화재를 사용한 폴리머 시멘트 모르타르의 기초적 성질)

  • Jo, Young-Kug
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.6
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    • pp.53-60
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    • 2019
  • The purpose of this study is to evaluate the degree of improvement in strengths by mixing blast-furnace slag and fly ash in polymer cement mortar(PCM). The test specimens are prepared with EVA polymer dispersion, two types of Admixtures (blast-furnace slag and fly ash), five kinds of polymer-cement ratios (0, 5, 10, 15 and 20%), and six kinds of admixtures (0, 3, 5, 10, 15 and 20%). Plain cement mortar is also made for comparison. From the test results, the flowing of PCM is greatly improved with the mixing of the admixtures, and strengths of PCM compared to ordinary cement mortar are also improved due to a decrease in water cement ratio. In addition, the strength characteristics of PCM by admixtures are greatly improved in flexural strength with fly ash compared to other strengths. It is apparent that the optimum mix proportions with polymer-cement ratio of 10% or more, admixture contents 5 to 10% of flay ash for flexural strength improvement of EVA-cement mortar are recommended in this study.

Evaluation of the Exothermic Properties and Reproducibility of Concrete Containing Electro-conductive Materials (전기전도성 재료를 혼입한 콘크리트의 발열특성 및 재현성 평가)

  • Song, Dong-Geun;Cho, Hyeong-Kyu;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.25-34
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    • 2016
  • From 1990's, a study on the development of exothermic concrete, a concrete which electro-conductive material is mixed, has been proceeded. However, due to the difficulty of exothermic reproducibility of concrete specimen, the study has been unable to continuously carried out. Accordingly, this study was focused on developing an exothermic concrete for the purpose of snow-melting material. Cement paste and mortar specimens mixed with graphite, conductive metal powder and chemical admixture were made. The evaluation of exothermic performance and reproducibility was conducted under $-2^{\circ}C$ of low temperature. In addition, micro-chemical analysis was carried out to investigate a cause of exothermic reproducibility. As a test result, the specimen mixed with graphite and superplasticizer with air entrained showed the best exothermic performance and reproducibility. Through micro-chemical analysis, it is judged that polymer or methacrylic acid (MAA), the contents inside the superplasticizer with air entrained, gave exothermic reproducibility by generating the electrochemical reaction with graphite.

Numerical study on contact behavior of TSL (Thin Spray-on Liner) (접촉 거동을 고려한 TSL(Thin Spray-on Liner)의 수치해석 연구)

  • Lee, Chulho;Chang, Soo-Ho;Lee, Kicheol;Kim, Dongwook
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.17 no.6
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    • pp.665-674
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    • 2015
  • A TSL (Thin Spray-on Liner) which consists of polymers has a higher initial strength, faster construction time and higher waterproofing performance than the conventional cementitious shotcrete. Main supporting mechanism of TSL is the adhesion and tensile strength which is distinct from the conventional shotcrete. Even though highly in demand due to its outstanding characteristics, TSL is not yet well-known support material. In this study, to evaluate contact behavior of TSL, numerical analysis was performed with comparing result from laboratory tests. From the analysis, cohesive behavior at the contact surface between TSL and rock can be evaluated by using combination of cohesive and the damage model. In addition, results show that the cohesive stiffness controled slope between force and displacement, the fracture energy controled level of force at the contact.

Analysis of Mechanical Properties and Micro structure of Fly Ash Based Alkali-activated Mortar (플라이애쉬 기반(基盤) 알칼리 활성(活性) 모르타르의 역학적(力學的) 특성(特性) 및 미세구조(微細構造) 분석(分析))

  • Ryu, Gum-Sung;Koh, Kyung-Taek;Chung, Young-Soo
    • Resources Recycling
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    • v.21 no.3
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    • pp.28-38
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    • 2012
  • The purpose of this paper is to develop the alkali-activated concrete which uses 100% fly ash as a binder without any cement. The compressive strength of the mortar was examined depending on the chemical change in alkali-activator through SEM and SEM/EDS observations and the XRD analysis. It was found from the test that the higher molar concentration induced the greater effect on the initial strength, and that $Si^{4+}$ and $Al^{3+}$ were eluted relative to the compressive strength of mortar. In addition, it was confirmed that Al and Si were determined to be most influential ingredients on the microstructural development of the mortar, and that the different ingredient of the activator was almost no change in solidity from the XRD analysis.