• Title/Summary/Keyword: 포졸란 반응

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Pozzolanic Properties of Coal Bottom Ash (화력발전소 바닥재의 포졸란 특성)

  • Han, Gi-Chun;Cho, Hee-Chan;Kim, Kwan-Ho;Kim, Jung-Ah;Ahn, Ji-Whan
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.155-158
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    • 2004
  • 본 연구에서는 공냉(空冷)된 화력발전소 바닥재의 입도분포, 화학조성, 광물상 등 기초 특성과 압축강도비에 의해 포졸란 반응성을 측정하였다. 바닥재의 주요 성분은 $SiO_2$, $Al_2O_3,\;Fe_2O_3$로 이들의 합계가 91.2wt.%였으며, 주요 광물상은 mullite, quartz, cristobalite, tridymite, hematie 등이었다. 입도별 화학조성 변동은 거의 없었으나, 입도가 커짐에 따라 $SiO_2$는 quartz에서 cristobalite로 존재하는 비율이 증가하였다. 분쇄된 바닥재(blame 비표면적 $7,540cm^2/g$)의 양생 28일에서의 활성도 지수는 101을 나타내었다.

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An Experimental Study on the Pozzolan Reaction of discarded Bentonite by the Cooling Method after Heat Treatment (소성가공한 폐 벤토나이트 분말의 냉각방법에 따른 포졸란 반응성에 관한 실험적 연구)

  • Kim, Hyo-Yeul;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.3
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    • pp.139-146
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    • 2002
  • As the bentonite is main material to prevent from collapse of drilling hole at underground excavation works, it is increased using quantity on construction industry day by day. But, the discarded bentonite that is over using at underground excavation works is caused various environmental trouble as soil and water pollution est. This study aims to propose a foundamental report for pozzolan reaction of discarded Bentonite powder by heat-treatment and cooling as concrete mineral admixture. To find out pozzolan reaction ability of discarded Bentonite powder by indirect cooling & cooling using of water after heat-treatment, the experiments are excuted Phenolphtalein test, setting test, pH test and the analysis by X-ray diffractor. As a result of this study, discarded Bentonite powder can be utilized as concrete mineral admixture by heat-treatment and especially, pozzolan reaction ability of discarded Bentonite powder is superior to the situation of 50$0^{\circ}C$~$700^{\circ}C$, 60min.

Experimental Study on the Properties of Concrete by the Kinds of Admixture and the Replacement Ratios of Activated Hwangtoh (혼화재 종류 및 활성황토 대체율별 콘크리트의 공학적 특성에 관한 실험적 연구)

  • 최희용;김무한;김문한;황혜주;최성우
    • Journal of the Korea Concrete Institute
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    • v.13 no.2
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    • pp.123-129
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    • 2001
  • Pozzolan is to improve the strength and the durability of concrete as a result of the pozzolanic reaction, Broadly speaking, pozzolanic materials can be artificial materials, such as slica fume and fly ash, and natural material, such as rice husk ash, clay, volcanic ash, clayish pozzolan. Hwangtoh is a mineral which belongs to a group of matakaolin, especially halloysite, and the main elements is SiO$_2$, Al$_2$O$_3$, Fe$_2$O$_3$. The purpose of this study is to examine the application of Hwangtoh for the concrete admixtures, the composition of this study is shown as follows. Chapter I is analysis for properties of concrete as the kinds of admixture, and Chapter H is analysis for properties of concrete as the replacement ratio of activated Hwangtoh. As a result of this study, Hwangtoh is found to have high practical use as pozzolanic material, and the pertinent range of replacement ratios of Hwangtoh on cement are 10∼20 %.

The Degree of Hydration and Mechanical Properties of High Volume Fly Ash Cement (하이볼륨 플라이애시 시멘트의 수화도 및 역학적 특성)

  • Cha, Soo-Won;Choi, Young-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.95-102
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    • 2022
  • Recently, there has been a growing interest in reducing greenhouse gases in all industrial fields. In the construction industry, studies have been conducted for the use of high-volume fly ash concrete to replace cement with fly ash. Quantitative measurements of cement hydration and fly ash reactivity enable a clear understanding of the strength development mechanism of high-volume fly ash concrete. It is very difficult to describe the reactivity in a simple way because the hydration and pozzolanic reactions of cement paste containing fly ash are very complex and the composition of the hydration product cannot be accurately determined. This study investigated the hydration and mechanical properties of high volume fly ash (HVFA) cement according to the substitution rate of fly ash (FA). The hydration degree of cement and the reactivity of FA were evaluated through the selective dissolution method and the non-evaporable water content of the paste according to age. In addition, compressive strength was measured using HVFA mortar specimens according to age. As a result of the experiment, as the substitution rate of fly ash increased, the hydration degree of cement increased, but the reactivity of FA decreased.

Effect of the Fineness of Fly Ash on the Compressive Strength (플라이애시 입도가 압축강도에 미치는 영향)

  • Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Ahn
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.313-319
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    • 2017
  • In general, various factors such as grain size, chemical composition, amorphous amount, amorphous Si and Al content of fly ash affect the reaction with cement. In this study, we investigate the effect of fly ash particle characteristics on compressive strength. The standard sand was pulverized to a particle size similar to that of fly ash and the compressive strength was measured by blending with the cement as in fly. Using the measured compressive strength results, strength enhancement by cement hydration reaction and strength enhancement by particle filling effect were confirmed. Strength increment by pozzolanic reaction of fly ash was calculated by using the compressive strength results of mortar substituted with standard powder. As a result of comparison between compressive strengths and the particle characteristics of fly ash, the blaine showed a weak correlation with the compressive strength and the PI(Pozzolanic Index) showed good correlation with the 10% penetration diameter(D10) and the 50% Respectively. Therefore, it is expected that PI will be a good means to evaluate the fly ash characteristics together with the chemical characteristics of fly ash.

Evaluation for Fundamental Properties of Concrete mixed with Pyroclastic Flow Deposit (화쇄류 퇴적물을 혼입한 콘크리트의 기초특성 평가)

  • Choi, Hyeong-Gil;Kim, Gyu-Yong;Noguchi, Takafumi
    • Journal of the Korea Concrete Institute
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    • v.28 no.1
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    • pp.49-57
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    • 2016
  • The aim of this study was to investigate the fundamental properties of pyroclastic flow deposit (PFD), and evaluate the fresh and strength properties of concrete mixed with PFD by indoor tests. The fresh properties, strength properties, shrinkage properties, and durability of the concrete mixed with PFD were also evaluated by outdoor plant tests. the harmful alkali-silica reaction did not occur by mixing concrete with PFD. ages. Moreover, no difficulty was found to be associated with concrete manufacture in the plant because no change in air contents and noticeable slump loss occurred by mixing concrete with PFD. The strength properties, shrinkage properties, and durability of the concrete mixed with PFD were also compared with those of normal concrete. With a suitable temperature control and curing method of concrete, the concrete mixed with PFD is considered to be useful in the construction material field.

Strength Characteristics of Low Cement Ratio Soil Stabilizer Using Industrial By-products (산업부산물을 이용한 저시멘트계 지반개량재의 강도 특성)

  • Cho Jin-Woo;Lee Yong-Soo;Yu Jun;Kim Sei-Ho
    • Journal of the Korean Geotechnical Society
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    • v.22 no.4
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    • pp.31-39
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    • 2006
  • An experimental investigation was carried out to evaluate the strength characteristics of low cement ratio soil stabilizer. The low cement ratio soil stabilizer has been developed by the replacement of certain part of cement with by-product pozzolanic materials such as blast furnace slag, fly ash, waste gypsum and by using activator. A series of unconfined compressive strength tests were performed to investigate and obtain high-strength composite soil stabilizer with large amounts of blast furnace slag and fly ash. Test results show that there were better properties when blast furnace slag, fly ash, waste gypsum, and activator were added in proper ratio. The replacement of certain part of cement with by-product pozzolanic materials improved the strength and pore structure properties.

A Study on the Application of Paper Fly Ash as Stabilization/Hardening Agent (지반개량재로서 제지회의 활용에 관한 연구)

  • Lee, Yong-An;Lee, Hong-Ju;Kim, You-Seong
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.2
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    • pp.23-33
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    • 2002
  • Examined a practical use possibility of paper fly ash that is industrial by-product as a stabilization/hardening agent. Performed unconfined compression test, scanning electron microscopy and pH analysis etc. for 100% paper fly ash-soil mixtures and each paper fly ash-soil mixtures that add cement as the second addition and sulfate component of small quantity for strength promotion and so on. In all cases, strength of admixtures increased according as curing time and mixing ratio increases but almost strength is revealed at mixing early and expressed maximum strength increase efficiency at mixing ratio 9% with raw soil. Compare with the case that use paper fly ash only, in case of cement amount 10~30% was included in paper fly ash, strength of admixtures increases two times and 40% was included, that increases from five to eight times.

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Effects of Limestone Powder and Silica Fume on the Hydration and Pozzolanic Reaction of High-Strength High-Volume GGBFS Blended Cement Mortars (고강도 고함량 고로슬래그 혼합 시멘트 모르터의 수화 및 포졸란 반응에 미치는 석회석 미분말과 실리카퓸의 영향)

  • Jeong, Ji-Yong;Jang, Seung-Yup;Choi, Young-Cheol;Jung, Sang-Hwa;Kim, Sung-Il
    • Journal of the Korea Concrete Institute
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    • v.27 no.2
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    • pp.127-136
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    • 2015
  • To evaluate the effects of limestone powder and silica fume on the properties of high-strength high-volume ground granulated blast-furnace slag (GGBFS) blended cement concrete, this study investigated the rheology, strength development, hydration and pozzolanic reaction characteristics, porosity and pore size distribution of high-strength mortars with the water-to-binder ratio of 20, 50 to 80% GGBFS, up to 20% limestone powder, and up to 10% silica fume. According to test results, compared with the Portland cement mixture, the high-volume GGBFS mixture had much higher flow due to the low surface friction of GGBFS particles and higher strength in the early age due to the accelerated cement hydration by increase of free water; however, because of too low water-to-binder ratio and cement content, and lack of calcium hydroxide content, the pozzolanic reactio cannot be activated and the long-term strength development was limited. Limestone powder did not affect the flowability, and also accelerate the early cement hydration. However, because its effect on the acceleration of cement hydration is not greater than that of GGBFS, and it does not have hydraulic reactivity unlikely to GGBFS, compressive strength was reduced proportional to the replacement ratio of limestone powder. Also, silica fume and very fine GGBFS lowered flow and strength by absorbing more free water required for cement hydration. Capillary porosities of GGBFS blended mortars were smaller than that of OPC mortar, but the effect of limestone powder on porosity was not noticeable, and silica fume increased porosity due to low degree of hydration. Nevertheless, it is confirmed that the addition of GGBFS and silica fume increases fine pores.