• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.483-486
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• 2008

본 연구에서는 디스크 이동식 열분해 실증 설비를 이용하여 폐타이어 열분해 반응을 수행하였고, 생성된 열분해 생성물들의 특성을 분석하였다. 폐타이어 열분해 반응은 약 $550^{\circ}C$에서 90분간 진행되었고, 반응 결과 Recovered Oil, Carbon Black, Non Condensing Gas(NC Gas)가 생성되었다. 폐타이어 열분해 생성물의 수율은 Recovered Oil $40{\sim}50%$, Carbon Black 30$\sim$35%, NC Gas 10$\sim$15%, Steel 10$\sim$15%로 나타났다. 폐타이어 열분해 반응 후 생성된 Recovered Oil은 비점 및 특성 분석 결과 상업용 중유와 비슷한 성질을 나타냈고, 폐타이어 열분해 반응의 또 다른 생성물인 Carbon Black은 특성 분석 결과 고정 탄소 비율이 낮은 반면 회분과 휘발분의 비율이 높아 상업용으로 사용하기 위해서는 적절한 정제 과정이 필요함을 알 수 있었다.열분해 과정 중에 생성된NC Gas는 GC/MS를 이용하여 성분 분석을 수행한 결과, $CO_2$, $CH_4$를 비롯하여 주로 탄화수소류로 이루어졌으며, 대부분이 연료 가스로 구성되어 있어 열분해 반응의 열원으로서 사용이 가능하였다.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.157-160
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• 2008

본 연구에서는 디스크 이동식 폐타이어 열분해 실증 설비(10톤/일)를 설계, 제작 그리고 시운전을 통하여 열분해 설비의 안정적인 연속 운전이 가능함을 확인하였다. 시운전 결과 반응기 내부 온도는 $500{\sim}600^{\circ}C$, 내부 압력은 $-80{\sim}-100mmHg$, 체류시간은 $60{\sim}90min$ 범위에서 안정적인 열분해가 일어났다. 또한 이번 과제 수행을 통해NC 가스의 연소기를 개발 적용하여 NC 가스의 열분해 열원으로 사용 가능성을 확인하였으며, NC 가스 연소 시 대기 측정을 통하여 규제치도 만족함을 확인할 수 있었다. 지금까지 나온 결과는 장기 연속 운전과 scale-up을 위한 기초 자료가 될 것이다.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2000.04a
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• pp.19-144
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• 2000

막대한 에너지원을 갖고 있는 고분자 폐기물은 열분해에 의하여 오일화가 가능하며 이 오일은 대체 연료유로서 사용이 가능하다. 그러나 이 연료유를 생산하기 위해서는 폐플라스틱 및 폐타이어의 경우는 공정을 서로 달리하여야 이용이 가능하며 생성유의 유질에서도 다소 차이가 있다. 올레핀계가 함유된 폐플라스틱을 열분해 오일화 하기 위해서는 분해 촉매를 사용하여야 하며 열분해유는 경유분과 d사한 성상을 갖고 있으며 폐타이어의 열분해유는 유황성분 및 BTX 분을 상당량 함유하고 있어서 경유분과는 다소 다른 성상을 갖고 있다. 또한 폐타이어 및 폐플라스틱의 열분해 기술이 사용화되기 위해서는 열분해시 발생하는 Coking 문제 극복 및 시스템에 대한 설계기술이 뒷받침되어야 한다.

• Elastomers and Composites
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• v.34 no.4
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• pp.350-359
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• 1999

Conversion and oil-yield of a used automotive tire sample in supercritical decomposition and extraction for three solvents such as water, 28% ammoina solution and ammonia, were compared. Supercritical extraction with ammonia gave the highest conversion and oil-yield at the same temperature and pressure. In this paper, supercritical ammonia was used as major solvent and tetralin acting as hydrogen-donor, was used as cosolvent. As the amount of tetralin increased, oil-yield was Increased. When a tire sample was extracted by supercritical ammonia, oil-yield was 48.8% at $280^{\circ}C$, 22.3MPa. But when the weight ratio of tetralin to tire sample (weight of tetralin/weight of tire sample) was 5, oil-yield was 61.2% at $280^{\circ}C$ and 22.3 MPa. These phenomena indicate that as radicals produced in supercritical decomposition become stable, the polymerization and the second decomposition of products may be inhibited. Supercritical extraction of a tire sample swollen by tetralin gave high oil-yield although the amount of tetralin was a little.

• Journal of Energy Engineering
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• v.26 no.3
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• pp.97-104
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• 2017

In this study, waste tire rubbers were pyrolyzed in a lab-scale pyrolysis plant equipped with a fluidized bed reactor in a temperature ranges of $450-650^{\circ}C$. The main object of this work is to investigate the properties of pyrolysis oil with reaction temperatures and the behavior of sulfur in the products when waste polypropylene was added for co-pyrolysis. The maximum yield of oil was about 52wt.% at the reaction temperature of $456^{\circ}C$. From GC-MS analysis, the pyrolysis oils consisted mainly of limonene, toluene, xylene, styrene, trimethylbenzene, methylnaphthalenes and some heteroatom(sulfur and nitrogen)-containing compounds. The addition of waste polypropylene resulted in decrease in sulfur contents of the pyrolysis oils.

• Journal of Biosystems Engineering
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• v.25 no.6
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• pp.481-488
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• 2000

This study was initiated in order to find alternative fuel substituting for light oil the most common fuel for heating greenhouse. The tire oil used in this research was produced by pyrolysis process, one of the final products besides steel string and carbon black in which waste tires as a form of chopped pieces broken by shredding machine are heated up to 200~30$0^{\circ}C$ with maximum restraining of oxygen supply. In order to justify light oil equivalent qualities in tire oil combustion characteristics were defined in the way of comparing kinetic viscosities in the wide range of temperature flame sizes and exhaust gas components in the various combustion conditions. We found that kinetic viscosity of tire oil was lower than light oil by 1 to 2 cSt in the temperature range showing better flowing mobility in the fuel line of the burner and no significant difference in flame size between the two oils in the all combustion treatments. However much more NO and SO$_2$ were detected from the exhaust gases of tire oil than light oil combustions. In fact tire oil contains more nitrogen and total sulfur, by 25 times and 40 times respectively than light oil according to the composition analysis. Tolerable limit for SO$_2$discharge amount defined by the national air pollution standards is under 540ppm so tire oil combustion satisfies the requirement though. It is desirable if sulfur and nitrogen filtering process shall be added in the tire oil production line. Except the exhaust gas components all greenhouse heating qualities of tire oil including hot air temperature are very identical to those of light oil.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.5
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• pp.577-583
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• 2017

A series of microwave waste tire pyrolysis experiments were conducted using a lab-scale batch reactor to delineate the effects of microwave ouput power on the pyrolysis behavior of waste tire. As results of experiments, it was found that as the microwave output power was increased from 1.22 kW/kg to 2.26 kW/kg, the reaction temperature and oil yield increased significantly and the required time and microwave power consumption decreased remarkably, respectively. With increased power consumption, the content of the fixed carbon of pyrolysis residue increased.

• Resources Recycling
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• v.4 no.4
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• pp.16-21
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• 1995

When waste t~re/~vastmz otor oil is pyrolyzed. most of them hecome gaseous produds. and thc remaining onc, whascwelght is ahout in% oi the waste Ore, is pyrolyced residue mnstly composcd oi ca~bnn black A rescsrcll was canicrl nut loutilize lhe pyralyred residue of waste tnelwuste lnotol 011 us retnin~cing agent of asphall concrete, bescd on iolelg~r lesearchrepurl. This shows thal the properlies ol asphall concrele ~nclud~cd~ugl ah~l~tyre, sistance to Tear. temperature-v~scusilysusceptil,ilily u e g reatly improved when lhe pellellrcd hrln aI carlmn hlack usmg petroleum o ~als a hinder Iar ihe pellels isused with asphalt. The surface of the pyralyred resirh~ei s covned by ocl film and thla lnakes good comllatibllity with asphallIn order lo ulilk pyrolyzed residue as a reinforcing agenl oi lhe itsphalt concrete, various tests such as Marshnll tcsi, wheeltracking, and revelhng test has been carried out a1 KLER, Ko~ea I-lighway Coo~poration, and TCMO. Tcst lcsults satirry KSslandard, show "npmvements an the dynam~cs tab~l~lzym, d incrcase reslslance to wear at cold telnpelatule Invrsligadon wascarlied oul to sludg the possibility of soil pallul~on when pyrolyzed residue is used as a tzmioicing agenl. E~pcrimentalresulls show the rcsidue contained in thc asphall docs not cause cnv~ranma~lparlo blems.e cnv~ranma~lparlo blems.

• Resources Recycling
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• v.4 no.4
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• pp.12-15
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• 1995

In this paper, some representative waste tire pyrolysis were investigated together with the analysis of the problems associated with the commercialization of various waste tire treatment technologies. Also, R & D results on recovering the oil from the pyrolysis of waste tires, when waste oil was used as a heating medium, were summarized in this study. Experimental results show that the present pyrolysis process has both lower pyrolytic temperature and higher pyrolysis rate than usual one and that the quality of the product oil and residue obtained was relatively even with large availability.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.6-10
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• 2012

The main objective of this work was studying the influence of paraffin oil(PO) on the adhesion properties at low temperature in styrene-butadiene-styrene(SBS) copolymer and crumb rubber(CR) modified asphalt. The temperature susceptibility of SBS/CR asphalt and PO/SBS/CR/asphalt blends were measured by penetration and softening point. Adhesion properties at low temperature and dispersion of modifiers in PO/SBS/CR/asphalt blends were evaluated by universal test machine and florescence microscopy, respectively. The adhesion properties of PO/SBS/CR/asphalt blends at low temperature increased in the proportion of SBS contents with both 5 and 10 wt % of paraffin oil. Results showed that the maximum tensile adhesion strength and toughness energy at $-20^{\circ}C$ were obtained when PO and SBS contents were 10 wt % and 6 wt %, respectively. The addition of PO is effective for enhancing the flexibility of SBS/CR/asphalt blends and leads to the increase of toughness at low temperature.