• Resources Recycling
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• v.8 no.1
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• pp.18-22
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• 1999

In order to utilize incineration fly ash of industrial wastes as resources, we present the recovery and separation of metals included in the fly ash by leaching with aqueous solution A great quantity of Cu, Pb, and Zn as well as a small amount oftoxic heavy metals are contained in the leach liquor of the fly ash, and the concentration of the ingredients of the fly ash depends on the industrial wastes which are fed into incinerators. In this paper, sequential Ieachiog operations are conducted using $H_2O$, $H_2SO_4$, $(NH_4)_2CO_3$ and NaOH as Icachants. Water soluble copper salt was leached by $H_2O$, Zn and Pb were separated by the NaOH leach liquor, and water insoluble copper was selectively leached as chelate ion with the $(NH_4)_2CO_3$ leach liquor of the third Ieaehant. Results show that the reduction percent of the fly ash in the leaching steps using $H_2O$, $H_2SO_4$, and $(NH_4)_2CO_3$ is 77%, and the other leaching procedures lose the weight of fly ash by above 60%.

• Resources Recycling
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• v.10 no.4
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• pp.48-57
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• 2001

The main consistent materials and main elements of the bottom ash in municipal solid waste incineration ash according to particle size were investigated and the environmental hazards were considered by investigating the content of dioxin and heavy metals in bottom ash and the concentration of heavy metals in its leachate. The main materials of bottom ash are glasses, ceramics, scraps of iron. As the particle size increases, their percentage weight also increases and their percentage weight was over 70% in 4 mesh~25 mm particle size fraction. The main elements of bottom ash are CaO, $SiO_2$, $Fe_2$$O_3$,$ A1_2$$O_3$and the content of CaO decreases and the content of $SiO_2$increases as particle size increases. The heavy metals accumulate in small particle size fraction. The concentration of heavy metals in each leachate by domestic leaching test is almost similar. As the aging period is prolonged, pH of bottom ash lowers gradually and the leached concentration of Cu and Pb diminishes.

• Clean Technology
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• v.22 no.1
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• pp.1-8
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• 2016

Rapid growth in nanotechnology promise novel benefits through the exploitation of their unique industrial applications. However, as increasing of production amount of nanomaterials, their unintentional exposure to the environment has been caused. Therefore, there is a need for effective management of nanowaste to the sustainable nanotechnology. One possible endpoint at the environmental exposure scenario for nanowaste treatment is incineration. Although a few study on the incineration of nanomaterials was reported, pioneering researchers found that although it is possible to incinerate nanowaste without releasing nanoparticles into the atmosphere, the residues (bottom ash or slag) with nanomaterials eventually end up in landfills. Though there are still many questions to understand the fate of nanomaterials in incinerator, firstly we have to study whether nanowaste treatment via incineration is safe to human and environment.

• Applied Chemistry for Engineering
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• v.17 no.2
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• pp.163-169
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• 2006

A Life Cycle Assessment (LCA) study was carried out to identify and improve the environmental aspects associated with the present incineration system of spent Li-ion batteries (LIBs) in Korea. The environmental impact associated with the landfill of the incineration ash was also assessed in this study, while so far it was excluded in most studies. It was found out that the $CO_{2}$ emission from the electricity generation as well as the incineration process and heavy metals emissions to air and water accounted for about 90% of total environmental impacts. In particular, the effect of the emission of heavy metals were dominant. In oder to improve the current incineration system environmentally, it is needed to incinerate the wastes like spent LIBs which contained relatively high portion of heavy metals separately from other combustible wastes. On the other hand, the effect of the landfill of ash after incineration was insignificant since the ash from the incineration process was chemically stable.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.1
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• pp.111-116
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• 2010

The treatment of heavy metal, in the waste ash from incinerator and mine solid waste, by using alkali-soluble acrylic copolymer emulsion, that is effective in the absorption of heavy metal has been studied. It seemed that alkali soluble acrylic copolymer emulsion was very effective in the absorption of Hg, Pb, Cd and Cu in this test. Also, eco-friendly thixotropic grout, using alkali soluble acrylic copolymer emulsion, that is effective in the absorption of heavy metal, for the recycling of waste ash from incinerator and mine solid waste has been tested. It was observed that waste ash could be used as a raw material of eco-friendly thixotropic grout mortar due to the effectiveness of alkali soluble acrylic copolymer emulsion in the fixation of heavy metals including $Cr^{6+}$ from waste ash in this test.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.05a
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• pp.617-620
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• 2003

열분해를 이용한 폐기물의 처리가 여러 유해물질을 저감시킬 수 있다는 기대감으로 국내에서도 열분해를 이용한 폐기물 처리 관련 연구가 많이 진행되고 있다. 아울러 폐기물을 열분해 한 후에 산소를 공급하여 가스화와 동시에 잔재를 용융시키는 열분해 가스화 용융이나 예열공기와 혼합하여 고온으로 연소시키면서 잔재를 용융하는 열분해 연소 용융 등의 방식이 개발되면서 다이옥신과 소각재의 발생을 차단하는, 환경적으로는 제로 에미션(zero-emission)에 근접하는 기술에 대한 관심도 높아지고 있다.(중략)

• Journal of Industrial Technology
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• v.21 no.B
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• pp.45-49
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• 2001

Many cities and provinces are rapidly depleting landfill spaces. As the result, some municities have adopted to incinerate their municipal solid waste(MSW). The motive behind the choice is that incineration significantly reduces the volume of solid waste in need of disposal, destroys the harmful organic compounds that are present in MSW, and provides an attractive source of alternative energy. Conclusively, the generation of MSW ash is expected to increse in the furture. However, disposing the MSW ash in landfills may not always be an environmentally or an economically feasible solution. This paper addresses the various issues associated with MSW ash and its possible use in construction applications.

• Analytical Science and Technology
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• v.19 no.1
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• pp.86-95
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• 2006

This study was carried out to estimate leaching characteristics of incineration residues from municipal solid waste incinerators, and determine organic compounds in raw ash, leaching water and leaching residue. A total of 44 organic compounds, which were analyzed by GC/MSD and identified by wiley library search, were contained in bottom ashes. A total of 17 organic compounds were contained in fly ashes. Bottom ash and fly ash were found to contain a wide range of organic compounds such as aliphatic compounds and aromatic compounds. Organic compounds such as Ethenylbenzene, Benzaldehyde, 1-Phenyl-Ethanone and 1,4-Benzenedicarboxylic acid dimethyl ester were detected in raw ash, leaching water and residues (from bottom ash). Organic compounds such as Naphthalene, Dodecane, 1,2,3,5-Tetrachlorobenzene, Tetradecane, Hexadecane and Pentachlorobenzene were detected in raw ash, leaching water and residues (from fly ash). Through the leaching characteristics of incineration residue, it was represented that the open dumping of incineration residue can contaminate the soil and undergroundwater. In order to prevent environmental contamination that derived from extremely toxic substances in the incineration residues, it is particularly important that the incineration residues should be treated before disposal the incineration residues. Further study and proper management about leaching characteristics of organic compounds might be required.

• Resources Recycling
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• v.17 no.1
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• pp.3-11
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• 2008

The treatment of domestic municipal solid waste has inclined to incineration process instead of disposal in landfills. So, the amount of ash generated by incineration of municipal solid waste is gradually increased. The incineration ash divides into bottom ash and fly ash. The bottom ash which accounts for about 90% of the incineration ash consists of ceramics, glasses and metals. And it can be used as the recycling product by the stabilization process. For example, the bottom ash is used as secondary building material or for other similar purposes such as road sub-bases and noise barrier in USA, Europe and Japan. But, the stabilization-treatment technique of bottom ash sti11leaves much to be desired in Korea. Thus, the domestic study of recycling about bottom ash must be improved through investigation about the chemical property and technique of stabilization.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.05a
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• pp.523-526
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• 2003

본 연구센터에서는 폐기물의 무해화 처리 및 합성가스 제조를 통한 에너지화를 목적으로 가스화용융시스템의 개발을 진행 중에 있다. 현재까지 개발된 가스화용융시스템은 분류층(Entrained bed) 방식의 가스화용융로를 핵심장치로 하고 있으며, 폐유, 중질잔사유, 액상슬러리등의 액상폐기물과 건조하수슬러지, 소각재등의 입자상 폐기물을 대상으로 개발되었다.(중략)