• Title/Summary/Keyword: 팽창성 혼화재

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Self-Healing Investigation of Bisphenol F-Type Epoxy-Modified Mortars with Expansive Admixtures Under Outdoor Exposure Conditions (환경조건에 따른 팽창성 혼화재 및 비스페놀 F형 에폭시수지 병용 모르타르의 자기치유 검토)

  • Park, Seung-Min;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.22-23
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    • 2017
  • The purpose of this study is to ascertain self-healing function on microcracks in bisphenol F-type epoxy-modified mortars using expansive admixtures. The specimens are prepared with various polymer-binder ratios of 0, 5, 10, 20%, expansive admixture contents of 0% and 10%, a sodium carbonate content of 0.25%, and subjected to exposure conditions of CR1, CR2, CR3 and CR4. The specimens are tested for self-healing effect, porosity and FE-SEM analysis. As a result, self-healing effects of bisphenol F-type EPMMs with expansive admixtures are visible in all of the outdoor exposure conditions. In particular, exposure conditions of CR3 and CR4 are most noticeable. And the porosity of EPMMs is reduced with an increase in the polymer-binder ratio, and is considerably smaller than that of unmodified mortar.

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Drying Shrinkage and Pore Structure of Self-Healing Epoxy-Modified Mortars Using Expansive Admixtures (팽창성 혼화재를 병용한 에폭시수지 혼입 자기치유 모르타르의 건조수축 및 세공구조)

  • Ham, Seong-Min;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.166-167
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    • 2015
  • The purpose of this study is to examine the effect on drying shrinkage of self-healing epoxy-modified mortars(EPMMs) using expansive admixtures. The EPMMs are prepared with polymer-binder ratios of 0 and 10%, and tested for drying shrinkage and pore structure analysis. As a result, regardless of the expansion and swelling agent content, the drying shrinkage of the EPMMs is remarkably decreased than that of unmodified mortars. Also, the pore size distribution of the EPMMs is moved to smaller size in comparison with unmodified mortars. In this study, the EPMM with expansive agent 7.5% and swelling agent 2.5% is recommended as a optimal mix proportion for reduction of drying shrinkage.

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Influence of Mineral Admixtures on the Resistance to Sulfuric Acid and Sulfate Attack in Concrete (콘크리트의 황산 및 황산염 침투 저항성에 미치는 광물질 혼화재의 영향)

  • Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.219-228
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    • 2010
  • It has been well known that concrete structures exposed to acid and sulfate environments such as sewer, sewage and wastewater, soil, groundwater, and seawater etc. show significant decrease in their durability due to chemical attack. Such deleterious acid and sulfate attacks lead to expansion and cracking in concrete, and thus, eventually result in damage to concrete matrix by forming expansive hydration products due to the reaction between portland cement hydration products and acid and sulfate ions. Objectives of this experimental research are to investigate the effect of mineral admixtures on the resistance to acid and sulfate attack in concrete and to suggest high-resistance concrete mix against acid and sulfate attack. For this purpose, concretes specimens with three types of cement (ordinary portland cement (OPC), binary blended cement (BBC), and ternary blended cement (TBC) composed of different types and proportions of admixtures) were prepared at water-biner ratios of 32% and 43%. The concrete specimens were immersed in fresh water, 5% sulfuric acid, 10% sodium sulfate, and 10% magnesium sulfate solutions for 28, 56, 91, 182, and 365 days, respectively. To evaluate the resistance to acid and sulfate for concrete specimens, visual appearance changes were observed and compressive strength ratios and mass change ratios were measured. It was observed from the test results that the resistance against sulfuric acid and sodium sulfate solutions of the concretes containing mineral admixtures were much better than that of OPC concrete, but in the case of magnesium sulfate solution the concretes containing mineral admixtures was less resistant than OPC concrete due to formation of magnesium silicate hydrate (M-S-H) which is non-cementitious.

Preventive Measures on Alkali-Silica Reaction of Crushed Stones (쇄석 골재의 알칼리-실리카 반응 방지 대책)

  • Jun Ssang-Sun;Lee Hyo-Min;Seo Ki-Young;Hwang Jin-Yeon;Jin Chi-Sub
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.129-137
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    • 2005
  • In Korea, due to the insufficiency of natural aggregates and increasing needs of crushed stones, it is necessary to examine the alkali-silica reaction of the crushed stones. The reaction produces an alkali-silica reaction gel which can imbibe pore solution and swell to generate cracks that are visible In affected concrete. In general, crushed stones are tested by petrograptuc examination, chemical method and mortar-bar method, but the most reliable method Is mortar-bar test. This study tested alkali-silica reactivity of crushed stones of various rock types using ASTM C 227 and C 1260, and compared the results of two test methods. This study also analyzed effects of particle size and grading of reactive aggregate on alkali-silica reaction expansion of mortar-bar. The effectiveness of mineral admixtures to reduce detrimental expansion caused by alkali-silica reaction was investigated through the ASTM C 1260 method. The mineral admixtures used were nv ash, silica fume, metakaolin and ground granulated blast furnace slag. The replacement ratios of 0, 5, 10, 15, 25 and $35\%$ were commonly applied for all the mineral admixtures and the replacement ratios of 45 and $55\%$ were additional applied for the admixtures that could maintain workability. The results indicate that replacement ratios of $25\%$ for ay ash, $10\%$ for silica fume, $25\%$ for metakaolin or $35\%$ for ground granulated blast furnace slag were most effective to reduce alkali-silica reaction expansion under the experimental conditions.

A Study on the Properties of High Performance Concrete Using CSA Expansive Additives and Inorganic Admixtures (CSA계 팽창재 및 무기질 혼화재를 이용한 고성능 콘크리트의 특성에 관한 연구)

  • Han, Cheon-Goo;Bahn, Ho-Yong;Jun, Byung-Chea;Hong, Sang-Hee
    • Magazine of the Korea Concrete Institute
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    • v.11 no.1
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    • pp.141-148
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    • 1999
  • Recently, high performance concrete developed has a good quality at fresh and hardened state, but high binder contents results in spending much money on manufacturing and many cracks by drying and autogenous shrinkage, Therefore, in this paper, not only prevention of cracks caused by drying and autogenous shrinkage, but improvement of quality and accomplishment of economy by applying F.A(fly ash), S.F(silica fume) and CSA(calcium sulfa aluminate) expansive additives as an inorganic admixtures in W/B 35% are discussed. According to the experimental results, when 5% of CSA expansive additives and 15:5(F.A:S.F)are replaced at unit cement content, high performance concrete with both good fluidity at fresh state and high compressive strength, compensation of drying and autogenous shrinkage at hardened state are accomplished.

Effects of Admixtures in Properties of Polymer Cement Mortar for Concrete Repair (혼화재료가 보수용 폴리머 시멘트 모르타르의 성질에 미치는 영향)

  • Song, Hyung-Soo;Lee, Chin-Yong;Min, Chang-Shik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.1
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    • pp.85-94
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    • 2007
  • The EVA polymer is used as a modifier in the repair mortar, which contains various admixtures and mineral admixtures. It has been reported that the effect of polymer in cement mortar by the cement-polymer ratio only, but effect of admixtures over the polymer mortar was unknown. In this study, the fresh and mechanical properties of polymer cement mortar influenced by the range of admixtures(CSA expansive addictive, CSA accelerator, gypsum, silica fume) ratio were investigated.

Fundamental Properties of Fly ash Concrete Containing Lightly Burnt MgO Powder (저온 소성한 MgO 분말을 함유한 플라이애시 콘크리트의 기본 물성)

  • Choi, Seul-Woo;Jang, Bong-Seok;Lee, Kwang-Myong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.2
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    • pp.475-481
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    • 2013
  • Although the lightly burnt MgO at $850{\sim}1000^{\circ}C$ has expansibility, it does not lead to unsound concrete. The expansion of MgO could compensate for shrinkage of concrete for a long-term, because the hydration of MgO occurs at a slow pace. Recently, the study and application of mineral admixture such as fly ash and blast furnace slag have increased for the hydration heat reduction, durability improvement, and reducing $CO_2$ emission in the construction industry. Thus, it is necessary to research on the concrete that contains both a mineral admixture and MgO as an expansion agent. This study investigates fundamental properties of fly ash concrete with lightly burnt MgO through various experiments. The adiabatic temperature test results showed that the fly ash concrete with MgO of the 5% replacement ratio had the slower pace of the temperature rise and the lower final temperature than the fly ash concrete. The influences of MgO on long-term compressive strength varied depending on water-binder ratio, and the long-term length change test results indicated the expansion effects of the FA concrete containing MgO.

Development of Rural Road Pavement Technology Using Cement Stabilizer (시멘트계 고화재를 활용한 농어촌도로 포장공법 개발)

  • Oh, Young-In;Kong, Gil-Yong;Kim, Seung-Wook
    • International Journal of Highway Engineering
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    • v.9 no.4
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    • pp.171-184
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    • 2007
  • Chemical admixture stabilization has been extensively used in both shallow and deep stabilization in order to improve inherent properties of the soil such as strength and deformation behavior. An increment in strength, a reduction in compressibility, an improvement of the swelling or squeezing characteristics and increasing the durability of soil are the main aims of the admixtures for soil stabilization. Recently, the various advanced cement stabilizer mixing technique was developed. Advanced cement stabilizer mixing technique is environmentally-friendly and has an excellent mixing property and outstanding mixing speed. In this study, to develop the rural road pavement technology using cement stabilizer, compaction and unconfined compression test were performed with various mixing ratio and two types of soil(clay and silty soil). And the freezing/thaw test and bending strength test performed to develop suitable cement stabilizer material for stabilization of rural road. Based on the test results, the liquid types of cement stabilizer material and silty soil mixture are most suitable for rural road construction and although the mixing ratio is low, cement stabilizer mixture is effective for durability of rural road surface layer.

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Strength Characteristics on High Strength Concrete against Sulfate Attack (황산염의 침해를 받는 고강도 콘크리트의 강도특성과 물성변화)

  • Park, Young-Shik;Suh, Jin-Kook;Lee, Jae-Hoon;Shin, Young-Shik
    • Magazine of the Korea Concrete Institute
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    • v.10 no.5
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    • pp.117-128
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    • 1998
  • 화학적으로 유해한 환경에 놓인 콘크리트 구조물은 필연적으로 그 기능이 악화되므로 혼화재를 포함한 고강도 콘크리트 또는 혼화재 그 자체가 화학물질에 오염된 환경하에서 어떤 변화를 일으키는가에 대한 연구의 필요성이 점점 증대되고 있다. 따라서 본 논문에서는 건설현장에서 가장 흔히 사용되는 보통강도 콘크리트와 실리카-흄을 포함한 포틀랜드시멘트 경화체인 고강도 콘크리트가 황산염의 침해를 받는 경우에 일어나는 강도특성과 물성변화를 조사하기 위하여 담수와 함께 황산나트륨, 황산마근네슘, 황산나트륨과 황산마그네슘의 혼합용액 등 여러종류의 황산염 용액에 실리카-흄을 사용한 고강도 콘크리트, 낮은 물-시멘트 비의 고강도 콘크리트, 보통강도의 콘크리트 등의 시험체들을 270일간 침지시켜 침지시간에 따른 압축강도 변화와 실리카-흄의 첨가량에 따른 압축강도 변화, 그리고 실리카-흄의 첨가량에 따른 선형팽창량 및 중량변화등에 관한 실험을 수행하였다. 이에 대한 실험결과를 토대로 실리카-흄을 사용한 고강도 콘크리트에 황산염이 미치는 영향을 분석하여 고강도 콘크리트의 실용성을 극대화하기 위한 방안에 대하여 고찰해보았다. 그 결과 실리카-흄을 포함한 고강도 콘크리트는 황산나트륨의 침해에 대해서는 강한 저항성을 나타내지만 황산마그네슘에 대해서는 심각한 침해를 일으키는 것으로 나타났으므로 황산마그네슘에 노출될 우려가 있는 콘크리트 구조물에 고강도를 발현하기 위하여 실리카-흄을 사용하는 것은 구조적으로 큰 문제가 발생할 것으로 사료된다.