• Title/Summary/Keyword: 토양화학

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Investigation on Soil Contamination and Its Remediation System in the Vicinity of Some Metalliferous Mines in Korea (국내 일부 금속광산 주변의 토양오염 조사와 광해방지시스템 연구)

  • 정명채;전효택;안주성
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1997.05a
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    • pp.17-20
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    • 1997
  • 이 연구에서는 국내에 산재되어 있는 금속광산들에 대한 토양환경오염을 조사하고 적절한 환경처리를 위한 기초자료를 제공하기 위하여 대표적인 연-아연광산, 동광산 및 금-은광산을 대상으로 As. Cd, Cu, Pb, Zn 등의 오염규모와 분산정도를 규명하고자 하였다. 연구대상지역으로 삼보 연-아연강산, 달성 동-텅스텐광산 그리고 구봉, 삼광, 금왕 금-은광산을 선정하여 이들 광산 주변에서 토양을 채취하여 화학분석을 실시하였다. 그리고 연속추출법을 이용하여 토양중에 존재하는 중금속의 존재형태를 규명하였으며 화학분해방법에 따른 중금속의 추출정도를 고찰하기 위하여 강산을 이용한 분해방법과 토양환경보전법에 제시된 방법을 비교하였다. 화학분석 결과, 삼보광산 주변의 상부토양 (0-15cm 심도)에서는 평균 11.8 $\mu\textrm{g}$/g Cd, 208 $\mu\textrm{g}$/g Cu, 2,700 $\mu\textrm{g}$/g Pb, 8,300 $\mu\textrm{g}$/g Zn이 검출되었으며 일부 농경지에서는 토양환경보전법의 우려기준을 초과하는 중금속이 검출되어 광산활동에 의한 토양오염이 심각함이 조사되었다. 달성광산 주변 토양에서도 다량의 중금속이 검출되었으며 (평균 4.4 $\mu\textrm{g}$/g Cd, 1,950 $\mu\textrm{g}$/g Cu, 1,030 $\mu\textrm{g}$/g Pb, 419 $\mu\textrm{g}$/g Zn) 특히 As (평균 2,500 $\mu\textrm{g}$/g)의 오염이 심각하였다. 그리고 대표적인 금은광산인 구봉, 삼광 및 금왕광산에서는 광미와 선광장 주변에서 다량의 중금속과 As가 검출되었다. 이 연구 결과, 이들 점오염원에 대한 오염정도가 심각하므로 이를 적절하게 처리할 수 있는 오염복구사업이 실시되어야할 것으로 판단된다.

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Geochemical Contamination Assessment and Distribution Property Investigation of Heavy Metals, Arsenic, and Antimony Vicinity of Abandoned Mine (폐광산 인근지역에서 중금속, 비소, 안티모니의 지구화학적 오염도 평가 및 분산 특성 조사)

  • Han-Gyum Kim;Bum-Jun Kim;Myoung-Soo Ko
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.717-726
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    • 2022
  • This study was conducted to assess the geochemical contamination degree of As, Cd, Cu, Pb, Sb, and Zn in the soil and water samples from an abandoned gold mine. Enrichment Factor (EF), Geoaccumulation Index (Igeo), and Pollution Load Index (PLI) were carried out to assess the geochemical contamination degree of the soil samples. Variations of sulfate and heavy metals concentration in water samples were determined to identify the geochemical distribution with respect to the distance from the mine tailing dam. Geochemical pollution indices indicated significant contaminated with As, Cd, Pb, and Zn in the soil samples that areas close to the mine tailing dam, while, Sb showed similar indices in all soil samples. These results indicated that the As, Cd, Pb, and Zn dispersion has occurred via anthropogenic sources, such as mining activities. In terms of water samples, anomalies in the concentrations of As, Cd, Zn, and SO42- was determined at specific area, in addition, the concentrations of the elements gradually decreased with distance. This result implies the heavy metals distribution in water has carried out by the weathering of sulfide minerals in the mine tailing and soil. The study area has been conducted the remediation of contaminated soil in the past, however, the geochemical dispersion of heavy metals was supposed to be occurred from the potential contamination source. Therefore, continuous monitoring of the soil and water is necessary after the completion of remediation.

오키나와현의 토양유실 현황과 저감대책

  • 정상옥
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.41 no.6
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    • pp.6-12
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    • 1999
  • 오키나와 지방의 심각한 문제가 되고 있는 토양유실에 대하여 알아보았다. 먼저 오키나와의 자연적 사회적 현황을 소개하였으며, 이어서 오키나와 지방의 토양유출 현황과 토양유출 저감방법에 대하여 소개하였다. 농지에서의 토양유실 저감기법으로는 물리적, 화학적, 영농관리실행 등으로 구분할 수 있으며, 개발현장에서의 토양유출 저감공법으로는 표토보호공, 유출억제공, 탁수처리공, 확산처리공으로 구분할 수 있다. 오키나와 지방에서는 농지와 개발사업지역에서 토양유출을 방지하기 위하여 최선의 노력을 경주하고 있다. 우리 나라에서도 토양보전을 위하여 노력하여야 할 것이며 특히 토양유실이 심각한 북한의 토양보전공법에 대하여 많은 관심과 투자가 필요할 것으로 사료된다.

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Effect of Pig Slurry Fertigation on Soil Chemical Properties and Yield of Tomato (Lycopersicon esculentum Mill.) (돈분 액비 관비가 토마토의 수량 및 토양화학성에 미치는 영향)

  • Park, Jin-Myeon;Lim, Tae-Jun;Kang, Seok-Boem;Lee, In-Bok;Kang, Yun-Im
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.610-615
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    • 2010
  • This study was conducted to evaluate fertigation effects of pig slurry (PS) and chemical fertilizer (CF) in tomato by analyzing the growth and yield, nutrient content and uptake, nutrient use efficiency, and soil characteristics in greenhouse cultivation. The treatments compared were; no-fertilizer, two different levels of PS (26 mg $L^{-1}$ and 52 mg $L^{-1}$), and a control treatment of chemical fertilizer. There was no significant difference in growth and yield between PS and CF treatments. however, yield reduction was observed in PS 26 mg $L^{-1}$ treatment. The N-utilization efficiency in CF treatment was similar to that of PS 52 mg $L^{-1}$ treatment. Nutrient utilization efficiency decreased in order of potassium (K), nitrogen (N), phosphate (P) with 29.2~43.3% in K, 15.8~36.7% in N, and 3.0~6.3% in P. In soil chemical characteristics, soil pH in PS treatment was higher than in CF treatment. In contrast, nitrate content in soil was higher in CF treatment than in PS treatment. The content of exchangeable K in soil was higher in PS and CF 52 mg $L^{-1}$ treatments. There was no significant difference in exchangeable Ca and Mg among those treatments. Therefore, it can be concluded that chemical fertilizers can be substituted by PS based on soil chemical analysis in tomato fertigation culture.

Comparison of the Heavy Metal Analysis in Soil Samples by Bench-Top ED-XRF and Field-Portable XRF (Bench-Top ED-XRF 및 휴대용 XRF를 이용한 토양 시료 중의 중금속 비교 분석)

  • Choi, Soo-Jung;Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.22 no.4
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    • pp.293-301
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    • 2009
  • As a basic research for development of the domestic field-portable XRF spectrometer, we discussed the analytical results of bench-top ED-XRF and field-portable XRF method for polluted heavy metals such as Cr, As, Se, Hg, Pb, Cd in soil samples. To obtain the best performance of the XRF spectrometer, the instrumental parameters of X-ray tube-voltage and measurement time were optimized for 6 heavy-metal elements in soil using certified reference material. The quantitative analysis of Cr, As, Se, Hg, Pb, Cd concentration in certified reference materials and soil samples were compared by empirical method and fundamental parameter method.

Monitoring on Chemical Properties of Bench Marked Upland Soils in Korea (우리나라 밭 토양(土壤) 화학적(化學的) 특성(特性))

  • Jung, Beung-Gan;Choi, Jeong-Weon;Yoon, Jung-Hui;Kim, Yoo-Hak;Yun, Eul-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.5
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    • pp.326-332
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    • 2001
  • To investigate a fertility status of upland soil, the soil were sampled at 854 sites chosen in consideration of areal distribution percent on the basis of topography and were analyzed on pH, organic mater, available phosphorus ($P_2O_5$), exchangeable potassium and calcium and magnesium. The content of soil chemical properties showed pH 5.6, organic mater $24g\;kg^{-1}$, available $P_2O_5$ $577mg\;kg^{-1}$, exchangeable potassium and calcium and magnesium were 0.85, 4.5, $1.4cmol^+kg^{-1}$, respectively. The distribution percent of soil samples within the optimum range for cropping were 13.4% for pH, 46.7% for organic matter. 27.4% for available $P_2O_5$, 10.7, 15.8, 18.3% for exchangeable potassium and calcium and magnesium, respectively. In chronological changes of soil properties, exchangeable calcium and magnesium were ignorable ; pH was slightly decreased ; organic matter was slightly increased ; available $P_2O_5$ and exchangeable potassium were greatly increased.

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Changes in Chemical Properties and Fauna of Plastic Film House Soil by Application of Chemical Fertilizer and Composted Pig Manure (시설재배지에서 화학비료와 돈분 퇴비시용에 따른 토양의 화학성 및 생물상 변화)

  • Kwak, Han-Kang;Seong, Ki-Seog;Lee, Nam-Jong;Lee, Sang-Beom;Han, Min-Su;Roh, Kee-An
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.5
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    • pp.304-310
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    • 2003
  • Effects of different amounts of fertilizer and manure application on changes of chemical and biological properties of soil were studied in plastic film house. Application amount of fertilizer was determined on the basis of soil test, standard application rate, and conventional rate of farmers. Lettuce in the first and second seasons and spinach in the third season were cultivated. Crop yields were highest in the plot fertilized on the basis of soil test during the three crop seasons. In the third crop season, spinach yield was lower in conventional plot applied with larger amount of pig manure compost than any other treatment. Organic matter, available phosphorus, and exchangeable potassium were accumulated in soil of the conventional plot with successive cropping. There was no difference in the abundance of soil invertebrates among the treatments, but soil enzyme activity was highest in the conventional plot.

매립장 주변 대수층 매질특성과 수질의 상관관계 연구

  • O In-Suk;Go Gyeong-Seok;Gu Min-Ho;An Ju-Seong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.387-390
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    • 2006
  • 매립장주변의 대수층 특성과 수리지화학적 특성과의 상관관계 분석은 매립장 환경 위해 요인을 평가하는데 중요한 역할을 하며 이를 위해 생활쓰레기 매립장인 금산 매립장을 대상으로 연구를 수행하였다. 대수층 매질 특성을 파악하기 위해 토양시료를 채취하여 중금속 성분 및 pH, 전기전도도, 용존유기탄소, 양이온교환능력, 유기물함량, 토양 입도분석을 수행하였고, 수리지화학적 특성 파악을 위해 수질검층 및 지하수 시료를 분석하여 매립지역의 수직 및 수평적인 분포 특성을 파악하였다. 대수층의 토양특성과 지하수 수질특성의 비교분석 결과 침출수 집수정을 기점으로 침출수의 영향을 받은 관측정의 전기전도도(EC) 측정값이 배경 지하수에 비해 상대적으로 높은 값을 보여 주었다. 입도분석 결과 상부 표토에 가까운 50cm 이내의 토양은 농경의 영향으로 심부보다 상대적으로 실트질 토양이 많고 이보다. 심부의 토양은 사질 토양으로 되어 있었다. 이러한 투수성이 좋은 사질 토양은 지하수의 이동을 비교적 쉽게 유도하기 때문에 매립장으로부터 침출수가 누출되었을 때 지하수 흐름을 따라 빠르게 이동할 수 있는 통로로 작용될 것으로 판단된다.

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Long-term Composting and Fertilization Impact on Dehydrogenase-producing Bacteria and Dehydrogenase Activity in Rice Paddy Soil (동일비료 장기연용 논토양의 탈수소효소 생성균과 효소활성)

  • Suh, Jang-Sun;Kim, Su-Jung;Noh, Hyung-Jun;Kwon, Jang-Sik;Jung, Won-Kyo
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.4
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    • pp.229-233
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    • 2007
  • A long-term rice paddy field, which is located in the National Institute of Crop Science (Suwon city, Korea) has been managed for studying of fertilization and composting impact on paddy soil fertility since 1954. The objective of this research was to evaluate soil quality through dehydrogenase analysis in long-term paddy soil treatment plots, such as control, N fertilization (N), NPK fertilization (NPK), and rice straw compost with NPK (CNPK). Dehydrogenase-producing bacterial population developing red-colored triphenyl formazan (TPF) was highly correlated to the dehydrogenase activity in rice paddy soils sampled prior to waterlog. The dehydrogenase-producing bacterial population and dehydrogenase activity was comparatively high in plots of NPK, and CNPK, which organic matter content was relatively high.

Effect of Swine Liquid Manure on Soil Chemical Properties and Growth of Rice (Oryza sativa L.) (양돈분뇨 발효액비 시용이 토양 화학성과 벼 (Oryza sativa L.) 생육에 미치는 영향)

  • Lee, Kyu-Hoi;Yoo, Jae-Hong;Park, Eun-Ju;Jung, Yeong-In;Tipayno, S.C.;Shagol, C.C.;Sa, Tong-Min
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.945-953
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    • 2010
  • This study was conducted to evaluate the effect of swine liquid manure (SLM) on rice grown in Yeonggwang-gun in 2008. The treatments consisted of SLM and chemical fertilizer (CF) based on the recommended amount of nitrogen (11 kg N $10a^{-1}$). The Total N content of the SLM used was 2,881 mg $L^{-1}$. Plant height at the early stage of growth and tiller number were not significantly different between plots applied with swine liquid manure and those with chemical fertilizer in all areas. Plant height at the later stage of growth, lodging and yield were not significantly different between plots applied with swine liquid manure and those with chemical fertilizer in three areas (Baeksu, Gunnam, Beopseong). Plant height at the later stage of growth, as well as lodging were higher in SLM plots than in chemically fertilized plots in Yeonggwang and Yeomsan. However, grain yield was lower in SLM plots than in chemically fertilized plots in these areas. Soil organic matter content and exchangeable cations increased in the swine liquid manure applied plots. Moreover, heavy metal content did not increase in the plots treated with swine liquid manure. Further research to determine the suitable rate of swine liquid manure is needed to reduce lodging damage and to increase the yield and quality of rice.