• Journal of Soil and Groundwater Environment
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• v.9 no.4
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• pp.15-23
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• 2004

Deicer operations provide traffic safety during winter driving conditions in urban areas. Using large quantities of de-icing chemicals (i.e., $CaCl_2$ and NaCl) can cause serious environmental problems and may change behaviors of heavy metals in roadside sediments, resulting in an increase in mobilization of heavy metals due to complexation of heavy metals with chloride ions. To examine effect of de-icing salt concentration on the leaching behaviors and mobility of heavy metals (cadmium, zinc, copper, lead, arsenic, nickel, chromium, cobalt, manganese, and iron), leaching experiments were conducted on roadside sediments collected from Seoul city using de-icing salt solutions having various concentrations (0.01-5.0M). Results indicate that zinc, copper, and manganese in roadside sediments were easily mobilized, whereas chromium and cobalt remain strongly fixed. The zinc, copper and manganese concentrations measured in the leaching experiments were relatively high. De-icing salts can cause a decrease in partitioning between adsorbed (or precipitated) and dissolved metals, resulting in an increase in concentrations of dissolved metals in salt laden snowmelt. As a result, run-off water quality can be degraded. The de-icing salt applied on the road surface also lead to infiltration and contamination of heavy metal to groundwater.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.166-170
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• 2006

본 연구에서는 폐광산 주변에 산재되어 있는 광미/광폐석을 처리하기 위하여 고형화 실증 실험을 수행하였다. 고형화 공정에서 흔히 사용하는 포틀랜드 시멘트와 MSG-E, MSG-N을 고화제로 사용하였으며 현장 광미 및 광폐석을 대상으로 고화체를 양생하고 고화체의 압축강도 및 중금속 용출 정도를 측정하였다. 고화체의 물리/화학적 특성을 비교하기 위해 광미/고화제 비율, 배합수/고화제 비율 그리고 고화체 양생기간을 실험인자로 설정하였다. 실험 결과 광미/고화제의 비율 1:1 만을 고려하더라도 중금속 용출의 급격한 감소가 이루어지는 것을 확인할 수 있었으며 광미/고화제의 비율을 3:1 이하로 유지시키는 경우, 고화체의 압축강도가 현행 폐기물 관리법(20조 관련)에서 규정하고 있는 차단형 매립시설 내부막의 압축강도 기준인 $0.21kgf/mm^2$ 보다 높은 것으로 나타났다. 다양한 pH를 갖는 수용액에 대하여 시간에 따른 고화체의 중금속 용출률을 측정한 결과, 수용액의 pH가 1과 13인 강산/강염기 용액에서 일부 중금속의 용출 농도가 지하수 생활용수 기준치를 초과하였으나, pH와 3 - 11인 경우에는 중금속 용출률이 급격히 감소하여 모두 기준치 이하를 나타내었다. 또한, pH가 1과 13인 수용액의 경우에도 고화체와 반응하는 시간이 증가할수록 고화체의 buffering 효과에 의해 수용액의 pH가 감소하였다. 이러한 결과는 현장에서 접촉수의 pH가 강산이나 강염기라 하여도, 고화체의 buffering 효과에 의해 시간이 지남에 따라 수용액의 pH가 낮아져 고화체로부터의 중금속 용출은 매우 감소할 것임을 의미한다.ss of an active application defined using the model. The technique is developed in a platform- and language-independent way, and it is algorithmic and can be automated by computer program. We give an example dealing with network auction to illustrate the use of the model and the verification technique.품으로 내부 온도분포를 측정하였으며, 유한차분법 프로그램으로 대류열전달계수를 결정하였다. 대류열전달계수는 792에서 2,107 W/m$^2$로 분석되었다. 대류열전달 계수는 액상식품과의 상대속도가 증가함에 따라서 증가하였고, 점도가 증가함에 따라서는 감소하였다.ce of precision/recall of 90.99%/92.52%, and 93.39%/93.41% respectively. 의한 변성에 부분적으로 보호 작용을 나타 낼 것으로 추정된다.경(製麴72時間頃)의 활성(活性)은 보리쌀국(麴), 밀가루국(麴), 찹쌀국(麴), 고구마국(麴)의 순이었다.험 결과 오전용 사료는 관행적인 산란계 배합사료에서 Ca공급제를 제외한 것을 급여하고, 오후용 사료는 Ca공급제를 3배 첨가한 T2처리로 15:00~16:00시에 교체급여를 하면 사료섭취량 감소와 사료비 절감면에서 바람직할 것으로 사료되며, 고에너지-고단백질-저Ca의 분말사료와 저에너지-저단백질-고Ca의 펠렛사료를 혼합급여하면 산란계의 사료

• Analytical Science and Technology
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• v.19 no.1
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• pp.86-95
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• 2006

This study was carried out to estimate leaching characteristics of incineration residues from municipal solid waste incinerators, and determine organic compounds in raw ash, leaching water and leaching residue. A total of 44 organic compounds, which were analyzed by GC/MSD and identified by wiley library search, were contained in bottom ashes. A total of 17 organic compounds were contained in fly ashes. Bottom ash and fly ash were found to contain a wide range of organic compounds such as aliphatic compounds and aromatic compounds. Organic compounds such as Ethenylbenzene, Benzaldehyde, 1-Phenyl-Ethanone and 1,4-Benzenedicarboxylic acid dimethyl ester were detected in raw ash, leaching water and residues (from bottom ash). Organic compounds such as Naphthalene, Dodecane, 1,2,3,5-Tetrachlorobenzene, Tetradecane, Hexadecane and Pentachlorobenzene were detected in raw ash, leaching water and residues (from fly ash). Through the leaching characteristics of incineration residue, it was represented that the open dumping of incineration residue can contaminate the soil and undergroundwater. In order to prevent environmental contamination that derived from extremely toxic substances in the incineration residues, it is particularly important that the incineration residues should be treated before disposal the incineration residues. Further study and proper management about leaching characteristics of organic compounds might be required.

• Magazine of the Korean Society of Agricultural Engineers
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• v.40 no.4
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• pp.77-84
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• 1998

Adsorption and leaching characteristics of the artificial soils produced from water and wastewater treatment sludges were examined. The batch adsorption test and TCLP leaching test were used, and constituents of interest were heavy metals and nutrients. As, Cr, Cu, Pb, and Cd were analyzed for metals, and nitrogen and phosphorus were analyzed for nutrients. All the artificial soils showed strong adsorption and low leaching for the heavy metals, which implies that the artificial soils may not be hazardous to the environment due to heavy metals and even they can be utilized effectively to remove metals in solution like mine and industrial wastewaters. This is quite promising result because in most case heavy metals are the most concern in the application of sludge product to the farmland. For the nutrients, generally, artificial soils showed high adsorption and low leaching except artificial soil from wastewater sludge produced by low temperature firing. The artificial soils produced from water treatment sludge were active in adsorbing nutrients and showed low leaching that they can be practically used to remove nutrients in advanced treatment process of the wastewater. The artificial soils produced from wastewater treatment sludge were less active in adsorbing nutrients and showed high teaching. However, they could be used usefully if applied properly to the plant growing because of their fertilizing effect. Based on the test results, overall, the artificial soils were thought to be not hazardous to the environment and they could be more useful if applied properly.

• The Korean Journal of Pesticide Science
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• v.9 no.1
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• pp.60-69
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• 2005

The herbicide molinate has been detected with high frequency in the main river during the growing season in Korea. To elucidate the exposure of molinate in agricultural environment, the persistence and the degradation characteristics of molinate were investigated in paddy ecosystems. The half-lives of molinate were 4.1 days with soil aquatic system, and 4.2 days in only aquatic system. Initial dissipation rate of molinate in water was greater with soil aquatic system than that of only aquatic system. Photolysis of molinate was occurred about 31.0% of molinate treated in pure water, when irradiated at 5,530 $J/cm^2$ by the xenon lamp, but its hydrolysis was stable. For the accelerated photolysis of molinate in aqueous solution, several photosensitizers were screened, showing that the hydroperoxide($H_2O_2$) and acetone were prominent among the chemical tested. When hydroperoxide and zinkoxide(ZnO) were used as photosensitizer, their photolysis were accelerated greater than 98% and 58% in aqueous solution, respectively. Elution rate of molinate as granular formulations in aqueous system was more than 90% in 30 hour at $35^{\circ}C$. Molinate concentration pattern in paddy water was rapidly decrease from treatment till 7 days in paddy rice field and its half-lives were 3.7 days($Y=1.9258{\times}e^{-0.1865X}$(r=-0.9402)).

• Economic and Environmental Geology
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• v.36 no.6
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• pp.469-480
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• 2003

Laboratory leaching experiment study carried out to estimate a extent of heavy metals that could be leached out when acid rain(pH 5.0-3.0) and strong acidic solution(pH 2.5-1.0) reacted with tailings and contaminated soils from abandoned metal mines. In slightly to moderately acid conditions(pH 5.0-3.0), As, Pb and Zn dissolutions became significantly increased with decreased pH in tailing, while dissolution of these elements was very limited in contaminated soil. These results suggested that moderately acid rainwater leaches Pb, As and Zn from the tailings, while these elements would remain fixed in contaminated soil. In the pH range of 2.5-1.0(strongly acid condition), Zn, Cd and Cu concentrations of leachate rapidly increased with decreased pH in contaminated soil, while Pb, As and Co dissolutions became importantly increased in tailings. The experimental solubility of Zn. Cd and Cu was very low even at very low pH values(up to pH 1), except for CY4(Cheongyang mine). These can result from an incomplete dissolution or the presence of less soluble mineral phases. So, the solubility of heavy metals depends not only on the pH values of leachate but also on the speciation of metals associated with contaminated soils and tailings. The relative mobility of each element within failings at the pH 5.0-3.0 of the reaction solution was in the order of Pb>Zn>Cd>Co=Cu>As. In case of pH 2.5-1.0 of the reaction solution, the relative mobility of each element within contaminated soils and tailings were in the order of Zn＞Cd>Cu>Co>Pb=As for contaminated soils, and Pb>Zn>Cd>hs>Co>Cu for tailings. The obtained results could be useful for assessing the environmental effects and setting up the restoration plan in the areas.

• Journal of Ginseng Research
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• v.32 no.4
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• pp.357-381
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• 2008

REEs of ginsengs(2, 3, 4 years) from the granite, phyllite and shale areas, Keumsan, are analysed and compared with the their soils. In the weathered soils, high element contents are shown in the LREE of the granite and in the HREE of the phyllite. The granite dominantly show positive correlation relationships. In the field soils, the phyllite are high while the granite are low. Relationships of the contents and correlation relationships can be explained with mineral assemblages and contents within soils, and their solubilities. In the host rocks, high contents are found in the LREE of the granite and HREE of the phyllite. The rocks dominantly show positive relationships. In the ginseng, high contents are shown in the 2 year for the shale and granite, and the 4 year for the phyllite. Element pairs mainly show positive relationships. Comparing of the same ages, the granite are mainly high. In the ratios between the soils and the ginsengs, differences of the several hundred to ten times are found, but dominantly, of the several hundred times in the shale and phyllite, and of the several ten times in the granite. The differences are big in the 3 year, and small in all REE of the 2 year from the shale and granite. while, in the phyllite, big in the LREE of the 2 year and HREE of the 3 year. Based on the absorption of the leachate by the ginsengs within soils, contents and correlation relationships of the ginsengs from the different soils can be explained with mineral assemblages, solubilities of the constitutional minerals and phyio-chemical affects influenced on the solubility. Of the three different soils, the ginsengs of the granites are chemically more similar to their soils.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.378-381
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• 2002

금정산지역의 수리적인 특성을 파악하기 위하여 27개 지하수 공을 대상으로 순간충격시험(주입, 인양시험)을 실시하였다. 순간충격시험자료는 C-B-P법, Hvorslev법, Bouwer & Rice법을 이용하여 분석하였으며, 분석을 위해서는 AQTESOLV(Version 3.01) 소프트웨어를 이용하였다. 또한, 자료의 해석을 위해서 시추자료와 연관하여 해석하였으며, 이때 시추시 용출심도와 수리전도도와의 관련성 분석으로 dummy의 충격과 심도의 관련성을 고찰해 보았다. 순간충격시험 분석결과 얻어진 수리전도도는 7.69E-8 ~ 2.30E-5m/sec를 보인다.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.2
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• pp.161-166
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• 2021

This study was on leaching test(KSLT) of the aggregate for the products to evaluate the characteristics of contaminants and the possibility of contamination arising from the aggregate. On the basis pH, conductivity, turbidity, TN, TP, COD and heavy metal contents in the aggregate increased as the particle size of the aggregate was smaller. The pH appeared to be 9.9~11.4 which is relatively higher than soil, however, heavy metal has investigated within the 1 region's standard value of soil pollution standards. From the leaching test, there is strong indication that the risk of pollution due to elution of pollutants gets higher with the smaller grain size. Especially conductivity and turbidity are the potential water pollution source and recycled aggregates of 10mm or less could be a potential pollution source since it could elute soluble matters and suspended solid, but there is no proper management standard for them. As a result of evaluating water pollution possibility of the aggregate, the pH displayed in items with a very high possibility of contamination, TN and TP did in item with a low possibility of contamination and on the other hand the heavy metals did in item with a very low possibility of contamination.

• Proceedings of the Plant Resources Society of Korea Conference
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• 2003.04a
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• pp.79-82
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• 2003

대부분의 신 간척지 논은 점토 함량이 적은 반면 미사 함량이 많고 토양 콜로이드의 분산제 역할을 하는 Na함량이 높기 때문에 이러한 토양은 입단화가 저해되고 투수성이 불량해 진다. 이러한 투수와 더불어 다량의 SiO$_2$, F$_2$, MR, MgO 등이 하층으로 용출되어 투수성과 통기성을 저하시키고 간척지 토양의 토양 물리화학적 불량에 의한 저수확답의 원인의 되어 벼의 재배가 어렵고 생산성이 낮아 경제성을 기대하기 어렵다. (김, 1992 : 고건, 1988 ;단야, 1983 ; 전중등, 1974). 따라서 본 실험에서는 토양의 염분농도차이가 토양화학성과 수량에 미치는 영향을 검토하여 간척지 토양의 경제성을 높이는데 기초자료로 활용코자 시험한 결과는 다음과 같다. 1. 출수기는 0.1%의 염분농도 토양은 8월15일, 0.4%의 염분농도 토양은 8월 20일, 0.8%의 염분 농도 토양은 8월 25일로서 0.1%의 염분농도 토양이 가장 빨랐다. 2. 쌀수량은 토양의 염분농도가 0.1%로 낮은 토양이 599kg/10a로 가장 많았고, 다음으로는 0,4%의 염분농도 토양이 568kg/10a이었고 0.8%의 염분농도 토양은 446kg/10a로 가장 낮았으며 쌀수량 구성요소 역시 같은 경향으로 0.1%의 염분농도 토양에서 가장 우수하였고 다음으로는 0.4%, 0.8%순으로 나타났었다. 3. 쌀수량과 토양의 이화학적 특성간의 상관에서는 pH와는 부의 상관, 유기물, 인산, 질소, 가리, 칼슘, 마그네슘의 함량간에는 정의상관이있다. 4. 전남광양만 간척지에서 쌀수량과 수량 구성요소면에서 볼때에 적합한 토양의 염분농도는 0.1%이라고 사료된다.