• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2001.09a
• /
• pp.239-243
• /
• 2001

대수층에서 오염물질의 이동은 대류, 확산, 흡착 등의 물리화학적 현상에 영향을 받는다. 지하수 유동과 오염 물질 운송에 관련된 분석은 지하수 자원의 관리와 평가, 복원사업에 필요한 요소이다. 본 연구의 목적은 사질대수층에서의 2차원 plume 모니터링을 통하여 오염운의 관측치와 모사치를 비교하므로써 종분산지수와 종/횡분산지수비를 결정하는 것이다. 실내 자유면 대수층 실험에서 MT3D를 이용한 case study로부터 추정된 종분산지수는 0.4 cm였으며 횡/종분산지수비는 1/5로 나타났다.

• Journal of Soil and Groundwater Environment
• /
• v.8 no.4
• /
• pp.53-63
• /
• 2003

Objectives of this research were to fractionate heavy metals in soil samples in the upper Okdong River basin and to assess the potential pollution index of each metal fraction. Soil samples were collected from the cultivated land soils and analyzed for physical and chemical properties. pH of cultivated soils ranged from 5.2 to 7.6. Contents of total kelhaldal nitrogen and loss on ignition were in the ranges of 0.6∼2.5%, and 1.9∼12.9%, respectively. Heavy metals in the cultivated land soils were higher in the abandoned closed coal mine near field soils than those in the paddy soils. Total concentrations of metals in the cultivated land soils were in the orders of Zn > Pb > Ni > Cu > Cd, exceed the corrective action level of the Soil Environment Conservation Law and higher than the naturals were abundance levels reported from uncontaminated cultivated land soils. Mobile fractions of metals were relatively small compared to the total concentrations. Soil Pollution Assesment Index (SPAI) values of each fraction of metals were leveled from Non polluted to Moderately polluted based on total concentrations. SPAI values of mobil fractions were lower than those of immobile fractions. Results on metal fractions and SPAI values of the cultivated land soils indicate that field soils samples were contaminated with heavy metals and had potential to cause a detrimental effects on plants. A prompt countermeasure to prevent field soils in the abandoned closed coal mine near fields are urgently needed.

• Economic and Environmental Geology
• /
• v.55 no.6
• /
• pp.717-726
• /
• 2022

This study was conducted to assess the geochemical contamination degree of As, Cd, Cu, Pb, Sb, and Zn in the soil and water samples from an abandoned gold mine. Enrichment Factor (EF), Geoaccumulation Index (Igeo), and Pollution Load Index (PLI) were carried out to assess the geochemical contamination degree of the soil samples. Variations of sulfate and heavy metals concentration in water samples were determined to identify the geochemical distribution with respect to the distance from the mine tailing dam. Geochemical pollution indices indicated significant contaminated with As, Cd, Pb, and Zn in the soil samples that areas close to the mine tailing dam, while, Sb showed similar indices in all soil samples. These results indicated that the As, Cd, Pb, and Zn dispersion has occurred via anthropogenic sources, such as mining activities. In terms of water samples, anomalies in the concentrations of As, Cd, Zn, and SO₄^2- was determined at specific area, in addition, the concentrations of the elements gradually decreased with distance. This result implies the heavy metals distribution in water has carried out by the weathering of sulfide minerals in the mine tailing and soil. The study area has been conducted the remediation of contaminated soil in the past, however, the geochemical dispersion of heavy metals was supposed to be occurred from the potential contamination source. Therefore, continuous monitoring of the soil and water is necessary after the completion of remediation.

• Economic and Environmental Geology
• /
• v.40 no.1 s.182
• /
• pp.15-28
• /
• 2007

The study is for contaminations of major, rare earth and trace elements of the farmland soils from the Boeunjeil mine area. The results are compared with the soils of Chungjoo, Deokpyeong, Boeun and Chubu areas. Fe and S contents of the contaminated area are high relative to those from the uncontaminated areas, Chungjoo and Boeun areas. Trace elements of the contaminated area are high relative to those from uncontaminated area, Chunajoo, Deokpyeong, Boeun and Chubu areas. The trace elements ares divided into Cd, Ni, Sr, U, V, Zn and As, Co, Cu, Mo, Pb, Sb, based on these dispersion and correlation. Two groups show the positive correlation. Enrichment factor of potentially toxic elements from contaminated area is >5 value, but <4 value in the uncontaminated area. In the geoaccumulation index of the minor elements, the contaminated area has >1 value and the uncontaminated area has <1 value except Mn. Enrichment index of potentially toxic elements(As, Cd, Co, Cu, Ni, U, Zn) ranges from 0.3 to 87.0 in the contaminated area and from 0.4 to 3.9 in the uncontaminated area. Overall results show that the high contents of farmland soils for the elements(Fe, S, As, Cd, Co, Cu, Ni, U, Zn) indicate the contamination by coal-related activities.

• Proceedings of the KSEEG Conference
• /
• 2000.04a
• /
• pp.63-65
• /
• 2000

• Journal of Soil and Groundwater Environment
• /
• v.12 no.6
• /
• pp.78-91
• /
• 2007

The groundwater chemistry is heavily influenced by land use. This study has investigated the groundwater quality and contamination characteristic associated with land use. Contamination index ($C_d$) was estimated for evaluating and areal distribution of groundwater contamination degree. Groundwater samples collected from 216 locations in the study area show great variability in chemical composition. Electrical conductance ranges from 100 to $31,360\;{\mu}S/cm$. The pH values are between 4.6 (acidic) and 8.57 (weak alkaline). The water types predominantly represent the $Ca-HCO_3$ and $Ca-Na-HCO_3$ types, whereas, in the residential and business areas, the water type is shifted to (Na, Ca)-Cl type with rich concentration of Cl. The $C_d$ values of the study area range from 1.1 to 117.6 with a mean of 9.56.

• Korean Journal of Environmental Agriculture
• /
• v.21 no.1
• /
• pp.7-16
• /
• 2002

Contamination of groundwater by agrochemicals used in the regional-scale Is now a major environmental problem, and this is especially true for Cheju island where virtually all potable water is from groundwater. The objective of this study was to assess leaching potential of eight pesticides in soils of citrus orchards using groundwater ubiquity score (GUS), retardation factor (RF) and attenuation factor (AF). Considering GUS estimated in 30 citrus orchard soils, metribuzin and metolachlor were classified as leacher, alachlor in volcanic ash soils and linuron in non-volcanic soils were classified as leacher, but chlorothalonil and chlorpyrifos were classified as non-leacher. For RF values, metribuzin was classified to be mobile in soils of low organic carbon, metolachlor and alachlor were classified to be moderately immobile in most soils, but linuron, diuron, diniconazole, chlorothalonil and chlorpyrifos were all classified to be very immobile. For AF values, diniconazole, chlorothalonil, and chlorpyrifos were classified to be very unlikely leachable in all of the soils, metribuzin was classified to be likely leachable, and metolahclor, alachlor, linuron and diuron were classified to be leachable only in non-volcanic soils. Although there were some variations in the relative potential of teachability of pesticides estimated with the three different indices, the ranking was essentially determined on the base of the intrinsic properties of the chemicals and environmental properties. Among the eight pesticides, metribuzin, metolachlor, and alachlor, which have high water solubility and low $K_{oc}$ values, have a significant leaching potential especially in non-volcanic ash soils of low organic carbon. But diniconazole, chlorothalonil, and chlorpyrifos, which have low water solubility and high $K_{oc}$ values, were classified to be very immobile in all of the soils. Therefore, to lower the possibility of pesticide contamination of the groundwater in Cheju island, those pesticides which have high water solubility and low $K_{oc}$ values should be used with care in soils of low organic carbon including non-volcanic ash soils.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2004.04a
• /
• pp.362-365
• /
• 2004

토양오염의 확산과정중의 서로 다른 지질적 기반위에 놓인 토양에 대한 침투특성과 4단계 이상의 장력을 적용하여 침투율을 산정하였다. 장력과 침투율과는 지수함수로 비선형 회귀시켜서 산정하였으며, 단지 몇단계의 장력만으로 구하여진 값보다 더 많은 불포화대수리특성과 신뢰성있는 포화수리전도도를 제공할 수 있을 것이다. 구하여진 침투율은 토양분석결과를 비교했을 경우 점토함량이 적은 시료에서 적게나오는 경향이 있고, sand가 많은 토양의 경우 높게 산정되었다.

• Journal of Korea Soil Environment Society
• /
• v.4 no.2
• /
• pp.175-183
• /
• 1999

Mine tailings, field soils, and paddy soils around Jingok abandoned mine were analyzed In order to investigate their pollution levels of heavy metals and cyanide. The average contents of As, Cd, Cu. Hg. Pb, Zn, and CN￣in mine tailings were 3.94$\times$$10^3$, 14.3, 266, 6.13, 4.07$\times$$10^3$, 2.51$\times$$10^3$, and 1.19mg/kg, respectively. The pollution indices calculated by the tolerance level of Kloke were 32~58 and the pH values were slightly acidic in mine tailings. In the field and paddy soils of Jingok abandoned mine area except for soils nearby mine tailings, concentrations of the heavy metals were less than standards of soil pollution of agricultural area in the environmental protection law.

• Economic and Environmental Geology
• /
• v.53 no.6
• /
• pp.743-753
• /
• 2020

This study analyzed heavy metal concentration, mineral composition, and spectral characteristics of heavy metal contaminated soil samples of cropland and rice field located in downstream of abandoned Okdong coal mine. X-ray fluorescence analysis detected heavy metal elements including cadmium, copper, arsenic, lead, zinc and nickel in the soils. Both cropland and rice field samples were severely contaminated with arsenic showing higher concentration over the concerned standard. The pollution index of cropland samples was higher than that of rice field samples. X-ray powder diffraction analysis identified that the mineral composition of cropland and rice field samples is similar with quartz, calcite, kaolinite, illite, smectite, magnetite and hematite. The range of organic matter content were more widely distributed in cropland samples. The spectral analysis showed that the reflectance spectra and the absorption features of cropland and rice field samples were alike. The absorption features that appeared near 490nm and 900nm were attributed to the ferric iron, and clay minerals such as kaolinite and smectite caused the absorption features at 1410nm, 1910nm and 2200nm. The reflectance of the soil spectral decreased with an increase in organic content. The absorption depths of both types of soil samples decreased with higher organic matter content at 490nm and 1916nm as well as higher heavy metal concentration.