• Title/Summary/Keyword: 토양오염물질

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Nondestructive Deterioration Diagnosis for the Former Ore Dressing Plant in the Yongwha Mine of Registered Cultural Property No. 255 (등록문화재 제255호 영양 구 용화광산 선광장의 비파괴 훼손도 진단)

  • Chun, Yu Gun;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.28 no.3
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    • pp.235-245
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    • 2012
  • Nondestructive deterioration diagnosis has been carried out for the former ore dressing plant of the Yongwha mine in Yeongyang (Registered Cultural Property No. 255). Deterioration rates about organic contaminant and soil of the upper part (7 to 13 layer) indicate higher than the lower part (1 to 6 layer) of the ore dressing plants. By contrast, deterioration rates such as crack, break out and discoloration of the lower part indicate very higher than the upper part. It is estimated that the plants of the lower part that mechanical and chemical process had been done for flotation were damaged severely by physicochemical weathering with reaction of concrete and chemical solution. As results of ultrasonic velocity measurement, average p-wave velocity of plants were measured 2,462m/s (compressive strength $529kgf/cm^2$). As for the analytical results of surface contaminants and soil compositions using P-XRF, they were identical with major elements (Cu, Zn, Pb, Fe and As) of ore minerals from the Yongwha mine. Therefore, the ore dressing plant should be treated by phytoremediation with conservation because heavy metals could impinged upon plants and natural environment.

Effect of of Sulfur dioxide gas on Soybean Plant (대두(大豆)에 대(對)한 아황산가스의 영향(影響))

  • Kim, B.Y.;Han, K.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.11 no.2
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    • pp.105-112
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    • 1979
  • A study was carried out to examine the effects of sulfur dioxide gas on soybean plants; at two concentrations(0.2mg/l and 0.5mg/l) and in different fumigation periods, The grain yield of soybeans, sulfur and chlorophyll contents in leaves, and ratios of destroyed leaf were investigated, 1) At the concentration of $SO_2$ 0.5mg/l, a) The yield decrease were 52% and 76.4% at 5 minutes and one houre fumigation period respectively, b) The sulfur contents in leaves were positively correlated with fumigation period and yield decrease, however the water soluble sulfur was superior than the total sulfur in correlation coefficient. 2) At the concentration of $SO_2$ 0.2mg/l; a) The most severe destruction of leaves were observed at noon exposure (10:00-11:00 O'clock) and no visible damage was observed at night exposure (22:00-23:00) b) The sulfur contents in leaves and stems were the highest at noon exposure and the lowest at evening exposure (18:00-19:00 O'clock) chlorophyll contents were the highest at night exposure but, the lowest at noon exposure, c) The ratio of destroyed leaf was positively correlated with the sulfur content of leaves, but negatively correlated with chlorophyll contents. d) Absorbance spectra of chlorophyll in the chlorolast were greatly decreased at noon exposure but slightly decreased at night exposure. The decrease of absorbance spectra was mainly at $456m{\mu}$ and $663m{\mu}$.

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A Review on Alkalinity Analysis Methods Suitable for Korean Groundwater (우리나라 지하수에 적합한 알칼리도 분석법에 대한 고찰)

  • Kim, Kangjoo;Hamm, Se-Yeong;Kim, Rak-Hyeon;Kim, Hyunkoo
    • Economic and Environmental Geology
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    • v.51 no.6
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    • pp.509-520
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    • 2018
  • Alkalinity is one of the basic variables, which determine geochemical characteristics of natural waters and participate in processes changing concentrations of various contaminants either directly or indirectly. However, not a few laboratories and researchers of Korea still use alkalinity-measurement methods not appropriate for groundwaters, and which becomes one of the major reasons for the poor ion balance errors of the geochemical analysis. This study was performed to review alkalinity-measurement methods, to discuss their advantages and disadvantages, and, thus, to help researchers and analytical specialists in analyzing alkalinity of groundwaters. The pH-titration-curve-inflection-point (PTC-IP) methods, which finds the alkalinity end point from the inflection point of the pH titration curve are revealed to be most accurate. Gran titration technique among them are likely to be most appropriate for accurate estimation of titrant volume to the end point. In contrast, other titration methods such as pH indicator method and pre-selected pH method, which are still commonly being used, are likely to cause erroneous results especially for groundwaters of low ionic strength and alkalinity.

Analysis of Relationship between Spatial Distribution of Land Use and Water Quality in Agricultural Reservoirs (토지이용의 공간적 분포와 농업용저수지 수질 간의 상관분석)

  • Lee, Sae-Bom;Yoon, Chun-Gyeong;Jung, Kwang-Wook;Jang, Jae-Ho;Jeon, Ji-Hong
    • Korean Journal of Ecology and Environment
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    • v.40 no.3
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    • pp.481-488
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    • 2007
  • This study covers the relationship between land use and water quality items. The kinds of land used in this study were almost agricultural areas with paddy fields and mountains. We set up zones at intervals of 200 m along 48 watersheds all over the country. The analysis showed high relationship between the water quality and the land use specially on the areas in the 400 m radius from the stream so that the areas needed to have strict managements. In the cases of residential area and upland, the positive correlation had a tendency to be lower when they were farther away from the stream. It depended on the increase of rainfall during July and August which affected on the water quality of reservoirs. The correlation analysis of paddy fields resulted in negative relationship, which indicated that paddy fields did not have negative effect on the quality of the stream. Through adequate irrigation and Management, paddy fields may be led to have positive effect on the quality of the reservoirs. In the case of forest, it also resulted in negative correlation so it was concerned as a positive factor which helped to improve water quality. Furthermore more than 00% of the land used in this study is comprised of forest so that it would have a positive effect on the reservoir management.

Effects of Fertilization Methods on the Growth and Physiological Characteristics of $Larix$ $kaempferi$ Seedlings in the Container Nursery System (시비처리 방법에 따른 낙엽송 용기묘의 생장 및 생리 특성)

  • Cho, Min-Seok;Lee, Soo-Won;Park, Byung-Bae
    • Journal of Bio-Environment Control
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    • v.21 no.1
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    • pp.57-65
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    • 2012
  • Fertilization is essential to seedling production in nursery culture, but excessive fertilization can contaminate surface and ground water around the nursery. The objective of this study was to find optimal fertilization practice of container seedling production for reducing soil and water contamination around the nursery without compromising seedling quality. This study was conducted to investigate chemical properties of the growth medium, growth performance, chlorophyll fluorescence, and chlorophyll contents of larch ($Larix$ $kaempferi$) growing under three different fertilization treatments (Constant rate, Three stage rate, and Exponential rate fertilization). Root collar diameter and height of larch were not significantly different among treatments even though the nutrient supply of the exponential treatment was half that of the constant and three stage treatments. Chemical properties of the growth medium showed the same trends as root collar diameter and height. The total biomass and seedling quality index (SQI) were higher at Constant than at other treatments, but both SQI of Constant and Exponential were not significantly different. Photochemical efficiency and chlorophyll contents were lower at Exponential than at other treatments, but not significantly different among treatments. Therefore, Exponential fertilization which is 50% fertilizer of other treatments would maximize seedling growth and minimize nutrient loss.

Groundwater Quality in Gyeongnam Region Using Groundwater Quality Monitoring Data: Characteristics According to Depth and Geological Features by Background Water Quality Exclusive Monitoring Network (지하수수질측정망 자료를 활용한 경남지역 지하수 수질: 배경수질전용측정망에 의한 심도·지질별 특성)

  • Cha, Suyeon;Seo, Yang Gon
    • Clean Technology
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    • v.26 no.1
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    • pp.39-54
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    • 2020
  • This study analyzed the groundwater quality according to the depth and geological features in Gyeongsangnam-do area using groundwater quality monitoring network data to grasp the groundwater quality characteristics and to provide basic data for policy making on efficient groundwater management. Five hundred and three data sets were acquired from background water quality exclusive monitoring network in soil groundwater information system for five years (2013 ~ 2017). Except for the total coliforms and tracer items such as mercury, phenol, and others, the parameters of water quality were significant or very significant, depending on depth and geological features. As the depth got deeper, the average value of pH and electrical conductivity increased; water temperature, dissolved oxygen, oxide reduction potential, arsenic, total coliforms, and turbidity decreased; and total unfit rate for drinking water standards was lower. It was found that the sum of the positive and negative ions was the highest in the clastic sedimentary rock and the lowest in metamorphic rock. The total unfit rate for drinking water standards was the highest for metamorphic rocks, followed by clastic sedimentary rock and unconsolidated sediments and, finally, intrusive igneous rock with the lowest penetration. The Na-Cl water type, which indicated the possibility of contamination by external pollutants, appeared only at some points in shallow depths and in clastic sedimentary rocks.

Anaerobic dechlorinating enrichment culture on tetrachloroethene (PCE) (PCE 탈염소화를 위한 혐기성배양)

  • Kim, Byung-Hyuk;Baek, Kyung-Hwa;Sung, Youl-Boong;Choi, Gang-Kook;Cho, Dae-Hyun;Oh, Hee-Mock;Kim, Hee-Sik
    • Proceedings of KOSOMES biannual meeting
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    • 2007.11a
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    • pp.185-185
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    • 2007
  • Starting at the beginning q the 20th century, increasing amounts of tetrach1oroethene (PCE) and trichloroethene (TCE)were manufactured due to the extensive use of these compounds in industry, in the military, and in private households, mainly as nonflammable solvents. This widespread use, along with careless handling and storage, are among the most serious contaminants of soil, sediment and groundwater. Highly chlorinated ethenes are typically not degraded through oxygenation by aerobic bacteria Since complete reductive dechlorination of PCE and TCE to ethene (ETH) has been observed in anaerobic enrichment culture, anaerobic dehalorespiring bacteria have received increased attention in the last decade. Under anaerobic conditions, these compounds con be reductively dehalogenated to less-chlorinated ethenes or innocuous ethene by microorganism through dehalorespiration. We have been studying anaerobic enrichment culture which used lactate as the electron donor for reductive dechlorination of PCE to ETH the anaerobic mixed microbial culture was enriched from the sediment sample taken from site contaminated with PCE. PCE was consistently and completely converted to ethene. In addition, the accumulation of intermediate products such as 1,2-ds-dichloroethene (cis-DCE) and vinyl chloride (VC) was observed in the anaerobic mixed microbial culture. the established dechlorinating enrichment culture was analyzed by DGGE using primers specific to DefrJ1ococcoides 16S rRNA gene sequences. In conclusion, we established the PCE dechlorinating enrichment culture and confirmed the existence of Dehalococcoides in an enrichment culture.

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Analyzing Characteristic of Deterioration Status for Stone Properties in the Tae-Jo Geonwolleung of the Royal Tombs of the Joseon Dynasty (조선왕릉 태조 건원릉 내 석물의 훼손 특성 분석)

  • Lee, Mi Hye;Lee, Myeong Seong;Chun, Yu Gun;Lee, Tae Jong
    • Korean Journal of Heritage: History & Science
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    • v.48 no.4
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    • pp.62-73
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    • 2015
  • The Tae-Jo Geonwolleung is the tomb of the first king Tae-Jo of the Joseon Dynasty in the complex of the Royal Tombs of the Joseon Dynasty which is listed in World Heritage, and it contains various types of stone properties. The material of the stone properties consist of a single type of medium-grained biotite granite, however, each properties have different intensity and types in deterioration phenomena according to their locations and purposes. The major deterioration types of the stones are analyzed as physical decomposition and biodeterioration. The exfoliation, breaking-out and granular decomposition are widespread types of the deterioration throughout the entire burial mound stone properties and surrounding stone properties. On the other hands, the colonization of mosses and plants, and contamination by foreign materials are found more frequent in the burial mound stone properties as these stones are in contact with the soil of the tomb mound and moisture in the soil helped biodeterioration. It is suggested that anti-biology treatment and physical reinforcement are applied to the deteriorated stones to prevent further damage on the stone components of the tomb.

Identifying sources of heavy metal contamination in stream sediments using machine learning classifiers (기계학습 분류모델을 이용한 하천퇴적물의 중금속 오염원 식별)

  • Min Jeong Ban;Sangwook Shin;Dong Hoon Lee;Jeong-Gyu Kim;Hosik Lee;Young Kim;Jeong-Hun Park;ShunHwa Lee;Seon-Young Kim;Joo-Hyon Kang
    • Journal of Wetlands Research
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    • v.25 no.4
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    • pp.306-314
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    • 2023
  • Stream sediments are an important component of water quality management because they are receptors of various pollutants such as heavy metals and organic matters emitted from upland sources and can be secondary pollution sources, adversely affecting water environment. To effectively manage the stream sediments, identification of primary sources of sediment contamination and source-associated control strategies will be required. We evaluated the performance of machine learning models in identifying primary sources of sediment contamination based on the physico-chemical properties of stream sediments. A total of 356 stream sediment data sets of 18 quality parameters including 10 heavy metal species(Cd, Cu, Pb, Ni, As, Zn, Cr, Hg, Li, and Al), 3 soil parameters(clay, silt, and sand fractions), and 5 water quality parameters(water content, loss on ignition, total organic carbon, total nitrogen, and total phosphorous) were collected near abandoned metal mines and industrial complexes across the four major river basins in Korea. Two machine learning algorithms, linear discriminant analysis (LDA) and support vector machine (SVM) classifiers were used to classify the sediments into four cases of different combinations of the sampling period and locations (i.e., mine in dry season, mine in wet season, industrial complex in dry season, and industrial complex in wet season). Both models showed good performance in the classification, with SVM outperformed LDA; the accuracy values of LDA and SVM were 79.5% and 88.1%, respectively. An SVM ensemble model was used for multi-label classification of the multiple contamination sources inlcuding landuses in the upland areas within 1 km radius from the sampling sites. The results showed that the multi-label classifier was comparable performance with sinlgle-label SVM in classifying mines and industrial complexes, but was less accurate in classifying dominant land uses (50~60%). The poor performance of the multi-label SVM is likely due to the overfitting caused by small data sets compared to the complexity of the model. A larger data set might increase the performance of the machine learning models in identifying contamination sources.

The Characteristics of Heavy Metal Accumulations in Feral Pigeon (Columba livia) Feathers for Environmental Monitoring (환경모니터링을 위한 집비둘기 깃털의 중금속 축적특성 연구)

  • Lee, Jangho;Lee, Jongchun;Lee, Sang Hee;Kim, Myungjin;Lee, Eugene;Han, Areum;Shim, Kyuyoung
    • Journal of Environmental Impact Assessment
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    • v.23 no.6
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    • pp.492-504
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    • 2014
  • Feral pigeon (Columba livia) has been known as a good indicator for accumulations of chemical pollutants in urban areas. However, it is against the animal rights to kill the indicator species in order to monitor pollutants accumulations in wild birds. Eggs and feathers of birds, therefore, have been used as non-invasive monitoring materials. Even though eggs are a good indicator for accumulations of lipophilic pollutants, but unsuitable for some heavy metals such as lead and cadmium because bird's ovary builds a sort of barrier to inhibit higher accumulations of some heavy metals in the eggs. Therefore, feathers instead of eggs have been used as a non-invasive indicator for accumulations of heavy metals. However, there are few studies of heavy metal accumulations of feral pigeon in Korea. In this study, we characterized the characteristics of heavy metal accumulations of feathers in relation to internal organs (bloods, viscera and bones) in feral pigeons between two sites (Hangang Park representing urban area and Hampyeong Park for rural area). The samples from the Hangang Park showed significantly higher lead (Pb) concentrations in the blood, liver and bone than those from Hampyeong Park. The Pb concentration in the feathers was also significantly higher at Hangang Park than at Hampyeong Park. The analytical result for the breast, wing and tail feathers, and the internal organs (blood, lung, liver, kidney and bone) indicated that the Pb concentrations in the feathers were significantly positively correlated with the levels in the kidney and bone. Overall, feathers of feral pigeon may be candidate for bioindicator to monitor for Pb accumulations in urban areas.