• Title/Summary/Keyword: 토양오염기준

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Mercury Contents of Paddy Soil in Korea and its Uptake to Rice Plant (우리나라 논 토양 중 수은함량과 벼 흡수이행)

  • Park, Sang-Won;Yang, Ju-Seok;Kim, Jin-Kyoung;Park, Byung-Jun;Kim, Won-Il;Choi, Ju-Hyeon;Kwon, Oh-Kyung;Ryu, Gab-Hee
    • Journal of Food Hygiene and Safety
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    • v.23 no.1
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    • pp.6-14
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    • 2008
  • Objective of this study was to investigate the residual levels of mercury (Hg) in soil for "Top-rice" area and its uptake into rice plant for making sure food safety as compared to "Top-rice" & common rice produced from 2005 to 2006. Hg was analyzed with the direct mercury analyzer (DMA 80, Milestone, Italy), which implements the US/EPA method 7473. The average concentration of Hg in paddy soil was 0.031 mg/kg, which was below at 1/25-1/65 fold of the threshold levels (concern level 4 mg/kg, action level 10 mg/kg) for soil contamination designated by "The Soil Environment Conservation Law" in Korea. The maximum residue level (MRLs) for Hg residue in the polished rice is not designated in Korea. Therefore, Hg contents in the polished rice of "Top-rice" brand and common rice were compared to other country's criteria. Hg contents in the polished rice of "Top-rice" brand was 0.0018 mg/kg, which was lower at 1/10-1/30 fold than the MRLs, 0.02 mg/kg of China criteria and 0.05 mg/kg of Taiwan criteria, respectively. Hg were 0.02788, 0.00896, 0.00182, 0.00189, 0.00166, 0.00452 and 0.00145 mg/kg in soil, rice straw, unhulled rice, rice hulls, brown rice, rice bran, and polished rice produced in 2006 "Top-rice" area, respectively. For the ratio of Hg as compared to Hg contents in soil, there were 0.321 of rice straw ${\gg}$ 0.162 of rice bran ${\gg}$ 0.068 of rice hulls > 0.065 of unhulled rice > 0.060 of brown rice> 0.052 of polished rice. And, the slope of Hg uptakes was steeped as following order; rice straw ${\gg}$ rice bran ${\gg}$ rice hulls > unhulled rice > brown rice > polished rice. It means that the more slope steeped was the more uptakes. For the distribution of Hg uptaken, there was 83.8% into rice straw, and 16.2% into unhulled rice, 2.8% into rice hulls, 12.4% into brown rice, 3.5% into rice bran and 9.7% into polished rice. Consequently, it was appeared that the Hg contamination in the polished rice should not be worried in Korea.

Nitrogen Losses During Animal Manure Management : A review (가축분뇨관리 과정 중 손실되는 질소 : A review)

  • Choi, Dong-Yoon;Song, Jun-Ik;Park, Kyu-Hyun;Khan, Modabber A.;Ahn, Heekwon
    • Journal of Animal Environmental Science
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    • v.18 no.sup
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    • pp.73-80
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    • 2012
  • Nitrogen included in animal manure can be used as organic fertilizer if it is treated properly but it may cause serious air and water pollution without proper management. Significant amount of nitrogen losses happen in the form of ammonia when the manure staying in animal house and storage facilities and being composted and applied to the field. In order to maximize the manure nitrogen utilization, it is important to understand the mechanisms of nitrogen loss during the diverse manure handling and treatment procedures. The plant available nitrogen portion of total nitrogen in excreted manure was evaluated based on animal type, animal manure collection system, manure treatment process, and application method. About 27% of nitrogen included in excreted pig manure could be plant available if it is applied to the filed after composting process. The plant available nitrogen portion varies from 29% (surface application) to 54% (solid injection) based on application method of digestated piggery slurry. Plant can use 18% of manure nitrogen if the composted cattle and poultry manure applied to the field using surface application method. Manure treatment and application methods need to be carefully selected to control and utilize the manure nitrogen properly.

Study on Applying of Unsteady Analysis in ToSS(Total Sewer Operation and Management System) for Optimal Management of Sewer System (하수관망 최적관리를 위한 통합하수관거 시스템의 부정류 해석적용에 대한 연구)

  • Choi, Gye-Woon;Lee, Ho-Sun;Jho, Hyung-Guen
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.1148-1153
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    • 2005
  • 하수관거는 국민의 정맥이라고 할 수 있을 정도로 도시의 환경관리와 치수, 쾌적한 환경조성에 있어서 매우 중요한 시설이며 그 규모가 광범위하고 복잡한 네트워크로 구성되어 있다. 이러한 하수관망을 통해 이송되는 물은 지저분하고 냄새가 심하기 때문에 지하에 관의 형태로 대부분 시공되어 왔으며, 상수관망처럼 압력관이 아니라 대부분 중력에 의한 이송방식을 채택하고 있어 문제 발생 시 원인파악과 대처를 힘들게 하는 요인을 가지고 있다. 특히 하수관거의 관리 소홀은 곧바로 토양오염과 인근 환경오염으로 직결되며 장기적으로는 상수를 오염시키는 요인으로 작용하므로 체계적인 방법과 장기적인 안목을 가지고 명확한 분석을 시행할 수 있는 시스템을 가지고 최적으로 유지관리 되어야 한다. 최근 들어 이러한 하수도 시설을 효율적으로 관리 및 개선하기 위해 대도시를 중심으로 근거 조사와 정비 사업이 활발히 시행되고 있다. 그러나, 사업효과를 검증하거나 관로의 유지관리를 위하여 국내 실정에 맞지 않는 외국하수관망 흐름 해석 프로그램을 그대로 사용하고 있고 정확한 해석이 이루어지지 않고 있어 효율적인 유지관리가 어렵다. 이와 같은 문제점을 해결하기 위하여 하수관망해석이나 하수관망 정비시 필요한 불명수산정이 가능하고 국내실정에 맞는 프로그램 개발이 시급한 실정이며, 아울러 프로그램을 효율적 운영하고 관리하는 제어관리 기술을 개발, 진행하고 있다. 본 논문에서는 개발된 프로그램의 부정류 해석 기능을 활용하여 대상구역의 해석을 실시하여 기존분석방법의 I/I결과와 비교하였으며 최적관리를 위한 방안을 제시하였다.준편차가 증가하고 있음을 알 수 있다. 본 연구에서는 상용 CFD모형인 FLOW-3D를 계획 중인 하수처리장의 침전지 유입부 설계에 적용하였으며 저류벽의 위치와 폭, 유공정류벽의 유공율에 따른 유입하수의 분배효과를 분석하였다. 실험을 수행하여 보다 정밀한 공식으로 개선할 수 있었다.$10,924m^3/s$ 및 $10,075m^3/s$로서 실험 I의 $2,757m^3/s$에 비해 통수능이 많이 개선되었음을 알 수 있다.함을 알 수 있다. 상수관로 설계 기준에서는 관로내 수압을 $1.5\~4.0kg/cm^2$으로 나타내고 있는데 $6kg/cm^2$보다 과수압을 나타내는 경우가 $100\%$로 밸브를 개방하였을 때보다 $60\%,\;80\%$ 개방하였을 때가 더 빈번히 발생하고 있으므로 대상지역의 밸브 개폐는 $100\%$ 개방하는 것이 선계기준에 적합한 것으로 나타났다. 밸브 개폐에 따른 수압 변화를 모의한 결과 밸브 개폐도를 적절히 유지하여 필요수량의 확보 및 누수방지대책에 활용할 수 있을 것으로 판단된다.8R(mm)(r^2=0.84)$로 지수적으로 증가하는 경향을 나타내었다. 유거수량은 토성별로 양토를 1.0으로 기준할 때 사양토가 0.86으로 가장 작았고, 식양토 1.09, 식토 1.15로 평가되어 침투수에 비해 토성별 차이가 크게 나타났다. 이는 토성이 세립질일 수록 유거수의 저항이 작기 때문으로 생각된다. 경사에 따라서는

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Hydrogeochemistry and Statistical Analysis of Water Quality for Small Potable Water Supply System in Nonsan Area (논산지역 마을상수도 수질의 수리지화학 및 통계 분석)

  • Ko, Kyung-Seok;Ahn, Joo-Sung;Suk, Hee-Jun;Lee, Jin-Soo;Kim, Hyeong-Soo
    • Journal of Soil and Groundwater Environment
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    • v.13 no.6
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    • pp.72-84
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    • 2008
  • This study was carried out to provide proper management plans for small portable water supply system in the Nonsan area through water quality monitoring, hydrogeochemical investigation and multivariate statistical analyses. Nonsan area is a typical rural area heavily depending on small water supply system for portable usage. Geology of the area is composed of granite dominantly along with metasedimentary rocks, gneiss and volcanic rocks. The monitoring results of small portable water supply system showed that 13-21% of groundwaters have exceeded the groundwater standard for drinking water, which is 5 to 8 times higher than the results from the whole country survey (2.5% in average). The major components exceeding the standard limits are nitrate-nitrogen, turbidity, total coliform, bacteria, fluoride and arsenic. High nitrate contamination observed at southern and northern parts of the study area seems to be caused by cultivation practices such as greenhouses. Although Ca and $HCO_3$ are dominant species in groundwater, concentrations of Na, Cl and $NO_3$ have increased at the granitic area indicating anthropogenic contamination. The groundwaters are divided into 2 groups, granite and metasedimentary rock/gneiss areas, with the second principal component presenting anthropogenic pollution by cultivation and residence from the principal components analysis. The discriminant analysis, with an error of 5.56% between initial classification and prediction on geology, can explain more clearly the geochemical characteristics of groundwaters by geology than the principal components analysis. Based on the obtained results, it is considered that the multivariate statistical analysis can be used as an effective method to analyze the integrated hydrogeochemical characteristics and to clearly discriminate variations of the groundwater quality. The research results of small potable water supply system in the study area showed that the groundwater chemistry is determined by the mixed influence of land use, soil properties, and topography which are controlled by geology. To properly control and manage small water supply systems for central and local governments, it is recommended to construct a total database system for groundwater environment including geology, land use, and topography.

Experimental Study on the pH of Recycled Aggregate (순환골재의 pH에 관한 실험적 연구)

  • Kim, Dae-Bong;Kim, Jong-Hwan;Park, Je-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.1
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    • pp.62-67
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    • 2016
  • This study provides basic materials about setting pH standard of recycle aggregate by analysing pH change from elution time, type of solvent and ratio of solvent with existing experiment methods about recycle aggregate. Also it has purpose of evaluating impact of recycle aggregate outflow's pH on actual environment by building a model that is similar to condition of recycling recycle aggregates. pH of recycle aggregates seemed to not change a lot by time with each experimental method. To evaluate degree of generation by recycle aggregates in natural state, natural water with distilled water seemed be useful to use as solvent. Also it was possible to confirm that there is a difference between actual pollution in natural state by only pH of recycle aggregates.

Decomposition characteristics of pollutants by time dependent variation of livestock carcass leachate (매몰지 침출수의 경시변화에 따른 오염물질 분해특성)

  • Kim, Yong Jun;Kang, Young Yeul;Hwang, Dong Gun;Jeon, Tae Wan;Shin, Sun Kyoung
    • Analytical Science and Technology
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    • v.30 no.6
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    • pp.338-347
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    • 2017
  • The purpose of this study is to investigation of the decomposition characteristics in a pilot-scale burial site of livestock in three kinds of typical soils in Korea: sandy loam soil, clay loam soil, and sandy soil. In this study, we confirmed that most of the animals in the condition were decomposed within three years as mentioned in the "Livestock burial regional environmental research guidelines." We also determined that the decomposition rate of dead cows was higher than that of dead pigs, and that the biodegradation rate depends on the soil types in the following order: sandy soil > clay loam soil > sandy loam soil. The various external environment factors, such as temperature, moisture, pH, earthiness, nutrient, and the burial depth, should be managed properly for appropriate decomposition of dead animals.

Quantification of kerosene and Diesel in Mixed Petroleum Fuels for Environmental Sample Characterization (다종유류 오염 환경매체에서의 유류 분리.정량에 관한 연구(I) - 등유, 경유 정량을 중심으로 -)

  • 이군택;이민효
    • Journal of Korea Soil Environment Society
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    • v.5 no.2
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    • pp.23-31
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    • 2000
  • The objective of this study was to develop an effective separation and quantification method for kerosene and diesel in a mixed petroleum fuel (gasoline, kerosene, and diesel) contaminated environmental samples. This investigation was directed to prove the hypothesis that if the source of petroleum fuels were identical, the peak-area ratios of a reference n-alkane to other n-alkane peaks should be a constant even at the different concentrations. In addition, experimental recovery rates were determined to select the reference peaks of kerosene and diesel for peak area ratio measurements. The experimental results showed that the peak area ratios were constant among the samples having different concentrations when the ratios were calculated from areas of $C_{l3}$, $C_{l4}$, and $C_{15}$ peaks for kerosene and $C_{l6}$ and $C_{l7}$ peak for diesel as reference n-alkane peaks. The recovery rates were evaluated by comparing the relative peak area ratios of each reference peaks after making pairs of the kerosene and diesel reference peaks in the samples contained a known amount of gasoline, kerosene, and diesel. The recovery rates(%) Were 107.0$_{{\pm}20.6}$/86.6/ sub $\pm$15.9/ for kerosene- $C_{13}$/diesel- $C_{16}$, 99.6$\pm$$_{17.2}$/86.6$_{{\pm}15.9}$ for kerosene- $C_{14}$/diesel- $C_{16}$, 73.9/$\pm$14.4//86.6$_{{\pm}sub 15.9}$ for kerosene- $C_{15}$ /diesel- $C_{16}$, 109.4$_{{pm}0.8}$/75.9$_{{pm}4.7}$ for kerosene- $C_{13}$/diesel- $C_{17}$, 107.4$_{{pm}7.9}$/75.9$_{{pm}4.7}$ for kerosene- $C_{14}$/diesel- $C_{17}$, and 95.7$_{{pm}4.6}$ /75.9/$\pm$14.6//75.9$_{{pm$}4.7}$ for kerosene- $C_{15}$ /diesel- $C_{17.}$ The above experimental results confirm that all of the reference peak pairs of kerosene and diesel are applicable to the quantitative analysis for the mixed fuel contaminated samples, but the kerosene- $C_{15}$ /diesel- $C_{l7}$ peaks are recommended since the pair has a lower standard deviation than the other pairs.s..s.s.s..s..s.s.s.s.s.

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Application Effect of Organic Fertilizer and Chemical Fertilizer on the Watermelon Growth and Soil Chemical Properties in Greenhouse (유기질비료와 화학비료의 시용수준에 따른 시설수박 생육과 토양화학성의 변화)

  • Uhm, Mi-Jeong;Noh, Jae-Jong;Chon, Hyong-Gwon;Kwon, Sung-Whan;Song, Young-Ju
    • Korean Journal of Environmental Agriculture
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    • v.31 no.1
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    • pp.1-8
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    • 2012
  • BACKGROUND: Organic fertilizers in watermelon cultivation are widely used to supply nutrient and organic matter. This study was conducted to investigate the effects of application rate of organic fertilizer on the watermelon growth and soil chemical properties in greenhouse METHODS AND RESULTS: The organic fertilizers used in this experiment were mixed expeller cake (MEC) and mixed organic fertilizer (MOF). The treatments were conducted with 4 levels (1.0 N, 0.7 N, 0.5 N and 0.3 N) on the basis of soil testing nitrogen fertilization (STNF) using MEC or MOF as the basal dressing, and using chemical fertilizers (CF) as the additional dressing on the rest of STNF. These fertilizations were compared to CF 1.0 N (0.3 N as the basal and 0.7 N as the additional dressing) and non fertilization (NF). The leaf area of watermelon in treatment 0.5 N and 0.3 N using MEC or MOF was similar to CF treatment. The absorbed nutrient amounts by leaf, weight and sugar contents of fruit in the 0.5 N and 0.3 N treatments were higher than other treatments. In 0.5 N and 0.3 N treatments using MEC or MOF on the basis of STNF, soil chemical properties such as electrical conductivity (EC), available $P_2O_5$ and exchangeable K concentrations after experiment showed tendency to decreasing or similar level before experiment. CONCLUSION(s): These results suggest that the MEC or MOF application as the basal dressing at the 30~50% level of STNF and CF application as the additional dressing on the rest of STNF be best to maintain adequate nutrient of soil and to increase marketable yield for watermelon.

Heavy Metal Contamination in Roadside Sediments within the Watershed of the Hoidong Reservoir in Busan City (부산시 회동저수지 집수분지 내 주요 도로변 퇴적물의 중금속 오염 평가)

  • Youm Seung-Jun;Lee Pyeong-Koo;Yeon Kyu-Hun;Kang Min-Ju
    • Economic and Environmental Geology
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    • v.38 no.3 s.172
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    • pp.247-260
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    • 2005
  • Extractable concentrations (0.1 N & 1.0 N HCI) of heavy metals in roadside sediments are lower than guidelines for soil recommended by Ministry of Environment. Heavy traffic areas (such as No. 7 national road) show high contents of heavy metals, especially, at curved areas, gully pot, crackdown areas on overspeed, pedestrian crossing etc. Fine fractions $(<63\;{\mu}m)$ of roadside sediments have the highest concentrations of heavy metals, but mass loadings of heavy metal are determined by coarse fractions $(>100{\mu}m)$, due to washing out of fine fraction sediment by runoff water. Proper treatment facilities are needed to control the inflow of fine roadside sediments from No. 7 national road and bridge such as Hanmul bridge.

Miryang River Duration Variation Analysis Study Using SWAT Model (SWAT 모형을 이용한 밀양강본류 유황변동 분석연구)

  • Choi, Young-Don;Shin, Hyun-Suk;Kang, Doo-Kee;Kang, Sun-Koo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.137-141
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    • 2007
  • 우리나라는 지역적 특성상 여름철에 강수량이 편중되어 있어 계절별로 하천유량의 편차가 매우 크게 나타나고 있다. 또한 계속되는 도시화와 산업화로 인하여 하천에서 다양한 형태의 취수와 이용이 이루어지고, 국민들의 수질향상 등에 대한 기대가 커짐에 따라 하천유량에 대한 양적 질적 요구가 증대되고 있다. 이에 효율적인 수자원운영을 위하여 다양한 형태의 수자원확보가 이루어지고 있으며, 이중 가장 대표적인 댐을 이용하여 운영에 따른 하류 하천에서의 유황개선효과에 대해서 유역 장기분포모의 모형 중 하나인 SWAT모형을 밀양강유역에 적용하여 일 유출량 모의를 수행하였다. 모형의 구축은 $2000{\sim}2005$년의 밀양강유역 기상자료를 활용하였으며, 건교부에서 운영하는 Wamis를 이용하여 DEM, 토지이용도, 토양도를 취득하였다. 또한 밀양댐, 운문댐 유입량과 밀양2지점의 측정유량을 이용하여, SWAT의 다양한 매개변수 중 SOL_AWC, ESCO, CH_K등을 수정하여 Calibration을 실시하였으며, 밀양강유역 오염총량지점인 밀양A지점과 밀양B지점의 측정유량을 이용하여 Validation을 실시하였다. 그 결과, 댐의 경우 0.9이상의 선형상관관계를 나타내었으며, 오염총량지점의 경우 0.6이상의 선형상관관계를 나타내어 모형의 적용성이 양호함을 알 수 있었다. 과거 39년간의 강수량자료를 이용, 구축된 모형의 유역모의운영을 통해 밀양강 유역의 밀양댐과 운문댐이 있음으로 해서, 댐이 없는 경우와 비교, 하류 지점별 유황개선에 어느 정도 효과가 있는지 댐의 순기능에 대한 정량적인 분석을 수행하였다. 또한 댐별 방류량을 변동하여 하류 주요지점에 미치는 유황개선효과를 정량화하였다. 마지막으로 댐의 효율을 최대화한 하류확보가능하천유지유량을 월별평균량으로 산정하였다. 이는 향후 오염총량제 기준유량 및 환경용수의 법제화를 통한 하천유지용수의 증가시 비구조적 대책의 공급가능 최대량으로 활용가능할 것으로 사료된다.

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