• Title/Summary/Keyword: 탈유리화

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A Petrological Study of the Mudeungsan Tuff Focused on Cheonwangbong and Anyangsan (천왕봉과 안양산을 중심으로 한 무등산응회암의 암석학적 연구)

  • Jung, Woochul;Kil, Youngwoo;Huh, Min
    • The Journal of the Petrological Society of Korea
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    • v.23 no.4
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    • pp.325-336
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    • 2014
  • Even though Mesozoic Mudeungsan tuff, located within Neungju Basin, has been named several rock names, it should be named as Mudeungsan tuff due to several evidences, such as fiamme, welded texture and rock fragments in the Mudeungsan tuff. Volcanic eruption boundary between the Cheonwangbong and Anyangsan areas is not clear, but petrochemical and mineral chemical evidences with different ages indicate clear petrological boundary between Cheonwangbong and Anyangsan. The Mudeungsan tuffs from Cheonwangbong and Anyangsan is welded crystal tuff with dacitic composition and were generated from cogenetic calc-alkaline magma in the volcanic arc environment. Geochemical events indicate that magma beneath Cheonwangbong was seems to have been evolved from the magma beneath Anyangsan due to fractional crystallization dominated by plagioclase.

Inhibitory Effects of Soyasaponins on Antigen-induced Degranulation in RBL-2H3 Cells (Soyasaponin의 RBL-2H3 세포에서 탈과립화 억제 효과)

  • Yang, Seung Hwan;Lee, Jung A;Lee, Jae Yeon;Ahn, Eun-Kyung;Shin, Tai-Sun;Tsukamoto, Chigen;Chung, Gyuhwa;Suh, Joo-Won
    • Journal of Applied Biological Chemistry
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    • v.58 no.3
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    • pp.287-290
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    • 2015
  • Soyasaponins are glycosylated, which gives rise to a wide diversity of structures and functions. We evaluated for inhibitory effects of 4 soyasaponins on antigen-induced degranulation in RBL-2H3 Cells. 4 soyasaponins had shown dose-dependently inhibited histamine and ${\beta}$-hexosaminidase.

Tephra Origin of Goryeri Archaeological Site, Milyang Area, Korea (밀양 고례리 화산 유리물질 기원 해석)

  • 김주용;양동윤;박영철
    • The Korean Journal of Quaternary Research
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    • v.13 no.1
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    • pp.35-43
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    • 1999
  • Goryeri archaeological site is located in the upstream valley of the Danjang River. The basement rocks of the area are composed of the Cretaceous to Palaeogene biotite granite (KbGr), acidic dyke (Kad), Milyang Andesite (Kma) and Jyunggagsan Formation. Among them Milyang Andesite and Jyunggagsan Formation are prevailed in archaeological site and they are composed of reddish brown tuffaceous shale, sandstone and conglomerate, with intercalations of acidic tuffs and lapilli tuffs. The purpose of this research is not only to compare REE pattern of the soil-sedimentary deposits with those of surrounding rocks, but also to identify vitric tephra in the soil-sedimentary deposits derived from the andesite, acidic tuff and lapilii tuff, in order to illucidate the provenance of the vitric tephra. The rare earth element(REE) of the soils and sedimentary deposits results in the same REE pattern with those analyzed from the surrounding basement rocks. This indicates that the soils and sedimentary deposits are originated from the surrounding basement rocks, most probably from the andesite and lapilli tuff. In addition, vitric tephra were identified both in the Quaternary in-situ weathered soils and sedimentary deposits (PMU-13 and PMU-17), and in the weathered surrounding lapilli tuff. These vitric tephra are considered to be different from those of Japanese AT(Aira Tanzawa) -tephra. The latter is predominant with clean, platty, bubble-walled and Y-shaped vitrics, while the former is conspicuous with those shapes of large and diverse size and devitrified, as well as having secondarily bubbled-surfaces reflecting surface weathering. The size of vitric fragments in the Goryeri site is about 300${\mu}{\textrm}{m}$ and large in size in compasion to 150${\mu}{\textrm}{m}$ of Japanese AT-Tephra. The interim results of the research are contradictary to the explanations based on a series of AT-tephra researches carried by Japanese scholar. In short, the vitric materials of the Goryeri archaeological site are most probably originated from the weathering products of the surrounding basement rocks, and are different from the AT-tephra in their size, shape and devitrification properties. Thus it is highly recommended to have a further comprehensive research which is more emphasized the magmatic genesis of these vitric tephra in addition to the external shape and morphology.

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Hybrid Affine Registration Using Intensity Similarity and Feature Similarity for Pathology Detection

  • June-Sik Kim;Ho-Sung Kim;Jong-Min Lee;Jae-Seok Kim;In-Young Kim;Sun I. Kim
    • Journal of Biomedical Engineering Research
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    • v.23 no.1
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    • pp.39-47
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    • 2002
  • The objective of this study is to provide a Precise form of spatial normalization with affine transformation. The quantitative comparison of the brain architecture across different subjects requires a common coordinate system. For the common coordinate system, not only global brain but also a local region of interest should be spatially normalized. Registration using mutual information generally matches the whose brain well. However. a region of interest may not be normalized compared to the feature-based methods with the landmarks. The hybrid method of this Paper utilizes feature information of the local region as well as intensity similarity. Central gray nuclei of a brain including copus callosum, which is used for feature in Schizophrenia detection, is appropriately normalized by the hybrid method. In the results section. our method is compared with mutual information only method and Talairach mapping with schizophrenia Patients. and is shown how it accurately normalizes feature .

Immobilization of ATP on Bovine $\beta$- Caseins by Using Transglutaminase (효소법에 의한 ATP의 Bovine $\beta$-Casein에의 고정화)

  • 윤세억;박선영김명곤
    • KSBB Journal
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    • v.5 no.3
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    • pp.241-246
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    • 1990
  • ATP analogs were immobilized or bovine caseins by the action of transglutaminase. The ATP analogs immobilized on the caseins were enzymatically active and interconverten by kinases. The immobilized ATP was dephosphorylated to the corresponding ADP by hexokinase and rephosphorylated to the ATP in solid form by acetate kinase. Under the conditions chosen, about 55% of the immobilized ATP was dephosphorylated and about 80% of the resulted ADP was rephosphorylated. Bovine $\beta$-casein was more useful than $\alpha$sf-casein as a carrier and C8-substituted ATP analognwas more effective than N6-substituted one in immobilization. Michaelis constant of C8-substituted ATP analog immobilized on $\beta$-casein was similar to that of free form of ATP and that of ATP analog. The immobilized ATP was much more stable than free ATP and its analog, while maximum velocity was reduced to 37% of the free ATP analog. The immobilized ATP was recovered almost completely by calcium precipitation.

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Electronic Structure and Si L2,3-edge X-ray Raman Scattering Spectra for SiO2 Polymorphs: Insights from Quantum Chemical Calculations (양자화학계산을 이용한 SiO2 동질이상의 전자 구조와 Si L2,3-edge X-선 라만 산란 스펙트럼 분석)

  • Kim, Yong-Hyun;Yi, Yoo Soo;Lee, Sung Keun
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.1
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    • pp.1-10
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    • 2020
  • The atomic structures of silicate liquids at high pressure provide insights into the transport properties including thermal conductivities or elemental partitioning behavior between rocks and magmas in Earth's interior. Whereas the local electronic structure around silicon may vary with the arrangement of the nearby oxygens, the detailed nature of such relationship remains to be established. Here, we explored the atomic origin of the pressure-induced changes in the electronic structure around silicon by calculating the partial electronic density of states and L3-edge X-ray absorption spectra of SiO2 polymorphs. The result showed that the Si PDOS at the conduction band varies with the crystal structure and local atomic environments. Particularly, d-orbital showed the distinct features at 108 and 130 eV upon the changes in the coordination number of Si. Calculated Si XAS spectra showed features due to the s,d-orbitals at the conduction band and varied similarly with those observed in s,d-orbitals upon changes in the crystal structures. The calculated Si XAS spectrum for α-quartz was analogous to the experimental Si XRS spectrum for SiO2 glass, implying the overall similarities in the local atomic environments around the Si. The edge energies at the center of gravity of XAS spectra were closely related to the Si-O distance, thus showing the systematic changes upon densification. Current results suggest that the Si L2,3-edge XRS, sensitive probe of the Si-O distance, would be useful in unveiling the densification mechanism of silicate glasses and melts at high pressure.

Antibacterial Activity by Chitosan Derivatives with Quaternary Ammonium Salt (4차 암모늄기를 가진 키토산 유도체의 항균성)

  • Kim, C.H.;Choi, Y.S.;Choi, K.S.
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.1020-1026
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    • 1996
  • Chitosan is the deacetylation product of chitin. Chitosan was converted to N-alkyl chitosan derivatives using proper aldehyde having different alkyl chains, then chitosan derivatives with quaternary ammonium salt were producted by quaternization with methyl iodide. Their antibacterial activities aganst S. aureus(ATCC 6538P) and E. coli (ATCC 14339), gram-positive bacteria and gram-negative bacteria, respectively, as introduced alkyl length were evaluated by shake flask method using colony count. The antibacteiral activity was found to be increased as alkyl chains. hydrophobic goups. These antibacterial agents were more active against S. aureus than E. coli. It may be due to the different of structure of cytoplasmic membrane.

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A Study on Prediction of Cryptocurrency Price using News Articles and Machine learning (뉴스기사와 머신러닝을 활용한 암호화폐 가격 변화 예측에 관한 연구)

  • Choe, Uk-Cheol;Koo, Jahwan;Kim, Ungmo
    • Proceedings of the Korea Information Processing Society Conference
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    • 2022.05a
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    • pp.448-451
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    • 2022
  • 주식과 암호화폐 거래는 매매방식에 있어서 유사한 점이 있지만 기업의 사업분야, 자본금, 순이익 등의 경영현황과 미래가치에 영향을 많이 받는 주식과는 다르게 암호화폐는 실물 실체가 없으며 탈중앙화, 전산화된 데이터를 기반으로 하며 심리적인 요소가 크게 작용하여 단기적인 변동이 클 수 있다. 본 연구에서는 이러한 암호화폐 거래의 특성을 활용하여 특정 암호화폐에 관련된 뉴스기사들을 수집하고 그 암호화폐의 가격 변화 데이터와 연관되어 가격예측 딥러닝 모델을 생성하고 해당 암호화폐에 대한 신규 뉴스기사가 발생되었을 때 이를 이용하여 매수, 매도, 관망 등과 같은 매매 정보를 예측 적용할 수 있게 하였다. 첫째, 뉴스 기사에서 언급한 암호화폐를 매수, 매도, 관망 중 어느 편이 좋을 것인지 추천하는 알고리즘을 구현하였고, 둘째, 매수 이후 매매 차익을 위한 매도 시점이나 매도 이후 저가매수에 유리한 시점을 제안하는 알고리즘을 구현하였다. 또한, 실시간 뉴스기사 수집 및 예측한 매매 판단에 따라 매매 자동화 시스템을 구현하여 수익률을 직접 확인함으로써 그 유효성을 검증하였다.

Preparation and Characterization of Low Molecular Weight Water Soluble Chitosan Gene Carrier Fractioned according to Molecular Weight (저분자량 수용성 키토산이 분급화된 유전자 전달체의 제조 및 특성)

  • Jang, Min-Ja;Kim, Dong-Gon;Jeong, Young-Il;Jang, Mi-Kyeong;Nah, Jae-Woon
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.555-561
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    • 2007
  • To obtain low molecular weight water soluble chitosan (LMWSC) with various molecular weights, chitosan oligosaccharides (COS) with lactic acid was separated by using ultrafilteration technique and LMWSC with a free amine group was prepared by the novel salts-removal method. The characterization of LMWSC removed the lactic acid and degree of deacetylation (DDA) were identified by FT-IR and $^1H-NMR$ spectra. Polydispersity index (PDI) was $1.278{\sim}1.499$, which indicates a relatively molecular weight distribution. To identify the potential as a gene carrier, we confirmed the transfection efficiency of COS fractioned according to molecular weight successfully and the salt-removed LMWSC using 293T cell. Also, LMWSC derivatives prepared for improvement transfection efficiency were evaluated using Balb/C mice.

Petrological Study on the Spherulitic Rhyolite in the Jangsan Area, Busan (부산 장산 지역의 구과상(球課狀) 유문암에 대한 암석학적 연구)

  • Park, Sumi;Yun, Sung-Hyo
    • The Journal of the Petrological Society of Korea
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    • v.22 no.3
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    • pp.219-233
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    • 2013
  • Spherulitic rhyolite occur as part of ring dyke which showing a vertical flowage of $60^{\circ}{\sim}90^{\circ}$, of the Jangsan cauldron was studied. The spherulites range in diameter from a few millimeters to 2.8 centimeters or more, and average 5~10 millimeters. It belongs to radiated simple spherulite type. They consist of a core of moderate brown dense material encased by a thin crust, a few millimeters thick at most of white grey material. The spherulites frequently have a radiating fibrous structure, which are thought to have formed as a consequence of rapid mineral growth caused by very fast cooling of the dykes in shallow depth near the surface. EPMA examination of the concentric-zoned core of spherulites show that they are mainly composed of cryptocrystalline-fibrous intergrowth of silica minerals and alkali feldspars which have $SiO_2$ 82% or more, $Al_2O_3$ 7~10%, $Na_2O+K_2O$ less than 8%. The feldspar compositions of the spherulites lie essentially within the sanidine field. XRD examination show that spherulites are mainly composed of quartz, sanidine, albite with minor mica, kaolinite and chlorite. According to X-ray mapping, the spherulites are enriched in $SiO_2$ in the core and partly enriched $Na_2O$ or $K_2O$, $Al_2O_3$ in the shell that reflect in compositional zoning with increasing spherulitic devitrification. The feathery and non-equant crystal shapes of spherulites from rhyolite dyke of Jangsan cauldron suggest that they may have formed during the rapid cooling of dyke under the static state, or faster velocity of devitrification from glassy materials than movement velocity of the magma intrusion. The spherulitic rhyolite originated from high-silica(75.4~75.7 wt.%) rhyolite magma.