• Journal of the Korean Wood Science and Technology
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• v.30 no.4
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• pp.33-40
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• 2002

This research was to investigate the adsorption characteristics of charcoals of major Korean wood species (thinned trees) and wood-based materials. As carbonization time and temperature increased, methylene-blue adsorption (MBA) of charcoals of thinned trees and wood-based materials increased. Pinus koraiensis charcoal showed the highest MBA. MBA of softwoods was higher than that of hardwoods. There was a negative correlation between air-dried specific gravity before carbonization and MBA of carbonized thinned trees. The MBA of wood-based materials showed similar value, but wood-based materials in MBA was lower than thinned woods. Surface area and total pore volume of thinned trees and wood-based materials increased as carbonization temperature increased. The species showing highest MBA appeared to have the highest surface area at the carbonization temperature of 600℃ as well. There was a positive correlation between surface area, total pore volume and MBA of charcoals. The charcoal of wood-based materials generally exhibited micro pores.

• Journal of Welding and Joining
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• v.15 no.1
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• pp.101-108
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• 1997

In repaired weldment of ASTM A-470 class 8 high pressure stream turbine rotor steel, creep rupture life was studied in relation with carbide morphology. Carbides were identified using carbide extraction replica method. A retired rotor has molybdenum rich carbide $M_2C$, lndacochea vanadium rich carbide $M_4C_3$, and chromium rich carbides $M_{23}C_6$and $M_7C_3$. Weldments ruptured at ICHAZ showed that some of carbides have been transformed into spherical types of coarsened carbides at ruptured area. Those carbides were revealed as molybdenum rich $M_6C$ carbide and they provided cavitation sites due to molybdenum depletion around $(M_6C)$ carbide. However coarsened $M_6C$ and $M_{23}C_6$ carbides were observed at ruptured area in case of ruptured at CGHAZ.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05b
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• pp.72-77
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• 1998

액체금속로 노심재료로 사용되고 있는 HT9강의 열처리에 따른 미세조직 변화를 관찰하였다. 열간압연상태에서의 조직은 마르덴사이트, $\delta$-페라이트, 잔류 오스테나이트, 그리고 탄화물로 이루어져 있다. 잔류 오스테나이트는 austenitization하여도 그 함량은 감소하지만 완전히 제거되지는 않았으나, tempering후에는 잔류하지 않았다. 오스테나이트 입자크기는 austenitization 온도가 증가함에 따라 성장하여 11005$^{\circ}C$에서는 약 42$\mu\textrm{m}$였다. Austenitization 온도 증가에 따라 탄화물의 평균 크기 및 평균 면적 분율은 크게 감소하고 있었다. 50$0^{\circ}C$에서 tempering한 경우에는 Fe-rich 탄화물이 석출하였으나, tempering 온도가 증가하면 Cr-rich M$_2$$_3$C$_{6}$ 탄화물이 석출하고 있었다. Austenitization 상태에서는 100$0^{\circ}C$ 까지는 탄화물의 분해가 일어나 경도값이 증가하나 100$0^{\circ}C$ 이상에서는 일정한 경도값을 나타내었다. Tempering한 시편에서는 탄화물의 석출과 전위의 회복으로 인해 tempering 온도가 증가함에 따라 경도값이 급격히 감소하였다.

• Proceedings of the Korean Nuclear Society Conference
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• 1995.05b
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• pp.689-694
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• 1995

원자력용 316LN 스테인레스강의 입계탄화물 석출거동에 미치는 질소 및 Ti, B의 미량원소 영향을 시차열분석기(DSC)와 투과전자현미경(TEM)을 이용하여 관찰하였으며, 이들 결과와 예민화 특성과의 관계성을 분석하였다. Ti과 B의 첨가는 316LN 강의 탄화물 석출온도를 높이며, 탄화물 석출에 필요한 활성화에너지 값은 미첨가강에 비해 높았다. TEM/EDX 분석결과, 예민화된 316 LN 강은 M$_{23}$C$_{6}$ 탄화물이 입계에 석출되며 입계에서 Cr 고같층이 관찰되었다. 반면 Ti 및 B 첨가강은 7$50^{\circ}C$, 20시간 열처리 조건에서도 거의 입계석출물이 존재하지 않았으며 일부 소량 존재하는 입계 석출물은 EDX 분석결과 Mo-rich 상인 Laves 상으로 분석되었다. DSC와 TEM 분석 결과는 Oxalic 시험 및 Modified Strauss 시험에 의한 입계 부시시험결과와 잘 일치하였고, Ti 및 B의 첨가는 Cr의 확산을 저지시켜 입계탄화물의 석출 및 성장을 저지하는 역할을 하며, 316LN 강의 예민화 특성을 양호하게 하였다.

• Korean Journal of Materials Research
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• v.8 no.7
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• pp.607-612
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• 1998

다합금계백주철의 성분원소인 Cr, V, Mo 및 W 의 첨가량을 변화시켜 응고조직을 관찰하였다. MC탄화물은 초정 austenite dendrite 내에 괴상 및 구상으로 M7C3탄화물은 intercellular boundary에 꽃형태 또는 bar 형태로, 그리고 M2C 탄화물은 M7C3탄화물과 마찬가지로 intercellular boundary에 침상으로 정출하였다. 기지조직은 주방상태에서 pealite 또는 (pearlite + austenite)의 혼합조직으로 구성되어 있었으며, 또한 EPMA 분석결과 MC탄화물은 V, M7C3 탄화물은 Cr 그리고 M2C탄화물은 Mo 및 W가 주성분으로 되어 있음을 알 수 있었다. 냉각곡선을 측정한 결과 액상에서 MC, M7C3, M2C 순으로 공정반응이 일어나고 있었으며 또한 X-선 회절시험을 통해 각 탄화물의 회절 peak를 관찰하였는바 응고조직의 사진과 잘 일치하고 있음을 알 수 있었다.

• Journal of the Korean Wood Science and Technology
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• v.33 no.3 s.131
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• pp.45-52
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• 2005

This research was performed to evaluate adsorption behavior of woody charcoals obtained from wood powder, fiber and bark of spruce (Abies sibirica Ledeb). The wood materials were carbonized at various temperatures for 1 hour using experimental rotary kiln without any inert gas. The adsorption capacity of iodine and toluene, specific surface area and removal efficiency of acetic acid and ammonia gas of those charcoals were measured. The higher was the temperature for carbonization, the lower yields of charcoals were. Ash content of bark charcoal was higher than that of wood powder charcoal or fiber charcoal. Elemental analysis of woody charcoal revealed that the content of carbon was gradually lincreased as carbonization temperature was higher. When carbonization temperature was higher, adsorption capacity of woody charcoals for iodine was much improved. Wood powder charcoal and fiber charcoal were more effective for iodine adsorption rather than bark charcoal. Capacity of toluene adsorption was the highest in the charcoal of $600^{\circ}C$. Charcoals produced at high temperature efficiently removed acetic acid gas, while charcoals carbonized at low temperature such as $400^{\circ}C$ were proper to remove ammonia gas. This difference may be explained that the acidity of charcoals depends on the carbonization temperature: charcoals of low temperature indicate acidic property, while those of high temperature turned to alkaline.

• Resources Recycling
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• v.23 no.5
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• pp.28-35
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• 2014

The basic properties of cow and chicken manure such as proximate analysis and element analysis were estimated and the comparison to energy characteristics of carbonization residue between cow and chicken manure was evaluated. The optimum carbonization condition of cow and chicken manure was decided by total heating value of carbonization residue which was expressed by multiplying low heating value by yield. The optimum carbonization conditions for carbonization time and temperature can be decided by 15 min, and $350^{\circ}C$ for chicken manure, and 20 min, and $300^{\circ}C$ for cow manure. At the optimum carbonization conditions, low heating values for the carbonization residue of cow and chicken manure are evaluated by 4,378kcal/kg, and 3,462kcal/kg, respectively. The residues of cow manure were satisfied with the standard of solid fuel product. However, the residue of chicken should be improved by materials changes to be used as a renewable energy source.

• Korean Journal of Environmental Agriculture
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• v.35 no.3
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• pp.159-165
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• 2016

BACKGROUND: Carbonized biomass is increasingly used as a tool of soil carbon sequestration. The objective of this study was to evaluate soil carbon storage to application of carbonized biomass derived from pear tree pruning.METHODS AND RESULTS: The carbonized biomass was a mobile pyrolyzer with field scale, which a reactor was operated about 400~500℃ for 5 hours. The treatments were consisted of a control without input of carbonized biomass and two levels of carbonized biomass inputs as 6.06 Mg/ha, C-1 and 12.12 Mg/ha, C-2. It was shown that the soil carbon pools were 49.3 Mg/ha for C-1, 57.8 Mg/ha for C-2 and 40.1 Mg/ha for the control after experimental periods. The contents of accumulated soil carbon pool were significantly (P < 0.001) increased with enhancing the carbonized biomass input amount. The slopes (1.496) of the regression equations are suggested that carbon storage from the soil was increased about 0.1496 Mg/ha with every 100 kg/ha of carbonized biomass input amount.CONCLUSION: Our results suggest that application of carbonized biomass would be increased the soil carbon contents due to a highly stable C-matrix of carbonized biomass. More long-term studies are needed to be proved how long does carbon stay in orchard soils.

• Journal of the Korean Wood Science and Technology
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• v.34 no.3
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• pp.15-21
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• 2006

The objective of this research is to develop the technique for carbonization of wood pellet and analyze a possibility for the utilization of carbonized wood pellet. The properties of wood pellet charcoals, such as density, yield, elemental composition, higher heating value, and methyleneblue adsorption, were analyzed. Wood pellet was made of sawdust of Hyunsasi-poplar, Japanese larch, Korean pine, Korean red pine, and Jolcharn-oak (serrate oak), respectively. The high density charcoal ($0.5{\sim}0.7g/cm^3$) was yielded from densified wood pellet. The carbon contents and calorific values of wood pellet charcoals were increased with the increase of carbonization temperature. The methyleneblue adsorptivity of wood pellet charcoal was similar to that of wood charcoal.

• KSBB Journal
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• v.20 no.1 s.90
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• pp.50-54
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• 2005

Tar is often produced during the carbonization of cellulose that limits the formation fibrous structure of the carbonized sample. This problem was reduced by applying a high temperature $(up\;to\;800{\circ}C)$ during carbonization process. Alternatively, dry cellulose was immersed in toluene and ultrasonicated prior to carbonization. In both cases, complete fibrous structures were not achieved. The formation of tar was reduced by the heat treatment of cellulose in the presence of HCI vapor before carbonization process. Such treatment before carbonization yielded mostly the fibrous structures of the carbonized sample as evident from SEM analysis. Similar results were found when the cellulose was subjected to a heat treatment in an inert condition followed by the removal of tar by the oxidation process prior to the carbonization.