• Composites Research
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• v.26 no.2
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• pp.141-145
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• 2013

The mode II interlaminar fracture toughness was evaluated for CFRP laminates with different types of nonwoven tissues and the source of increased mode II interlaminar fracture toughness was examined by SEM analysis in this paper. The interlaminar fracture toughness in mode II is obtained by an end notched flexure test. The experiment is performed using three types of non-woven tissues: 8 $g/m^2$ of carbon tissue, 10 $g/m^2$ of glass tissue, and 8 $g/m^2$ of polyester tissue. On the basis of the specimen with no non-woven tissue, interlaminar fracture toughness on mode II at specimens inserted with non-woven carbon and glass tissues and polyester tissues increases as much as 166.5% and 137.1% and 157.4% respectively. The results show that mode II interlaminar fracture toughness of CFRP laminates inserted with nonwoven tissues increased due to the fiber bridging, fiber breakage, and hackle etc. by SEM analysis.

• Composites Research
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• v.23 no.6
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• pp.1-6
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• 2010

The electrical conductivity of carbon-fiber reinforced plastics (CFRP's) has been improved by indium-tin oxide (ITO) nano-particle coating on carbon fibers for the purpose of lightning strike protection of composite fuselage skins. ITO nano-particles were coated on the surface of carbon fibers by spraying the colloidal suspension with 10~40% ITO content. The electrical conductivity of the CFRP has been increased more than three times after ITO coating, comparable to or higher than that of B-787 composite fuselage skins with metal wire-meshes on the outer surface, without sacrificing the tensile property due to the existence of nano-particles at fiber-matrix interface. The damage area by the simulated lightning strike was also verified for different materials and conditions by using ultrasonic C-scan image. As the electrical conductivity of 40% nano-ITO coated sample surpass that of the B-787 sample, the damage area by lightning strike also appeared comparable to that of the materials currently employed for composite fuselage construction.

• Composites Research
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• v.12 no.4
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• pp.55-61
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• 1999

Interfacial shear strength (IFSS) of poly(arylene ether phosphine oxide) (PEPO) coated carbon fibers was evaluated via microdroplet test and compared with results obtained from carbon fibers coated with poly(arylene ether sulfone) (PES), Udel$^{\circledR}$ P-1700 and Ultem$^{\circledR}$ 1000. Interfacial adhesion between thermoplastics and uncoated carbon fibers was also measured in order to understand the adheion mechanism. PEPO coated carbon fibers showed the highest IFSS, followed by PES, Udel and Ultem coated fibers. A similar trend was observed for thermoplastic/uncoated fibers. SEM analysis indicated that only PEPO coated fiber exhibited cohesie failure in the vinylester resin, while others showed failure at or near the interface of polymer coating and vinylester resin. The enhanced interfacial adhesion by PEPO coating could be attributed to the strong interaction of P = 0 moiety to the fiber as well as to the vinylester resin.

• Composites Research
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• v.32 no.6
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• pp.342-348
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• 2019

Development of flame retarding polymer based materials has been studied actively due to the increase in use of polymers. The post treatment of manufactured fibers or the introduction of flame retardant into fibers is representative method for the way to improve the flame retardancy. Among the polymers, polyacrylonitrile (PAN), which is a precursor of carbon fiber, has been widely used for clothes. Due to low flame retardancy of PAN fiber (LOI value: 17~18%), the improvement of flame retardancy of PAN fiber is needed. In this review paper, we report preparation methods for the fabrication of post-treated (oxidization or chemical reaction) flame-retarding PAN fibers and composites composed of PAN and organic/inorganic materials (SiO₂, 2D materials or CNT).

• Polymer(Korea)
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• v.25 no.2
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• pp.293-301
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• 2001

Electrically conductive carbon fiber/high density polyethylene (CF/HDPE) composite films were fabricated by new method, so called electron-ion technology (EIT) and the effects of CF epoxy sizing on the volumetric resistivity. tensile strength and interphase properties of the films were investigated. While epoxy sizing increased conductivity of composite films resulting from enhanced tunneling effect it reduced interphase adhesion between CF and HDPE because polar epoxy sizing and nonpolar HDPE are incompatible. Consequently epoxy sized CF(CF(S)) caused significant reduction in the volumetric resisitivity and tensile strength of composite films when compared with unsized CF(CF(U)). Epoxy sizing reduced nucleating efficiency of CF(S), therefore CF(S)/HDPE composite films showed nonuniform transcrystalline layer when compared with CF(U)/HDPE composite films.

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.476-482
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• 2013

In this work, the effects of electrochemical oxidation of carbon fiber surfaces on mechanical interfacial properties of carbon fibers-reinforced polarized-polypropylene matrix composites were studied with various current densities during the treatments. Surface properties of the fibers before and after treatments were observed by SEM, AFM, XPS, and contact angle measurements. Mechanical interfacial properties of the composites were measured in terms of critical stress intensity factor ($K_{IC}$). From the results it was found that $O_{1s}$ peaks of the fiber surfaces were strengthened after electrochemical oxidation which led to the enhancement of surface free energy of the fiber, resulting in good mechanical performance of the composites. It can be concluded that electrochemical oxidation of the carbon fiber surfaces can control the interfacial adhesion between the carbon fibers and polarized-polypropylene in this composites system.

• Magazine of the Korea Concrete Institute
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• v.10 no.5
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• pp.109-115
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• 1998

철근콘크리트 구조물이 과소설계되어 있거나 과다 하중이 작용하게 되면 그 구조물의 구조성능을 파악하여 보수.보강을 시행하게 된다. 최근에 가장 맣이 사용되는 보수.보강 재료로는 특히 휨내력을 보강하는데 탄소섬유를 들 수 있다. 탄소섬유쉬트는 내열성과 내호염성에 있어서 회재가 발생할 경우 보강재료로서 충분한 성능을 가지고 있다. 그러나 이를 접착시키는데 사용되는 에폭시는 유기계 물질로서 화재시 유독가스가 발생하고 내열성능도 30$0^{\circ}C$정도에도 지탱하기 어려워 화재 발생이 가능한 구조물에 사용하기 어렵다. 이 연구에서는 무기계 폴리머 복합재료로 접착된 탄소섬유를 고온(약 800~100$0^{\circ}C$, 1시간)으로 가열한 후 가열된 섬유판의 인장, 휨 전단내력을 검토하여 내열성능을 파악하고 이 섬유쉬트로 보강한 철근콘크리트 부재의 휨 성능을 실험적으로 규명하여 화재의 위험이 있는 구조물에 구조적인 보강재료로 사용이 가능한가를 검토하였다. 연구 결과, 개발된 무기계 폴리머 복합체는 인장강도, 휨강도 및 접착강도가 유기계 접착제와 유사하게 나타났고 800~100$0^{\circ}C$ 정도로 1시간 가열한 이후에도 상온 시험체 휨내력과 전단내력의 63%, 33% 정도를 유지하여 화재의 위험이 있는 부위에도 사용이 가능한 것으로 판단되었다.

• Composites Research
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• v.27 no.2
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• pp.52-58
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• 2014

Short fiber reinforced composites manufactured by injection molding have diverse fiber orientations variable with measuring positions even in the same specimen, which is caused by the flow induced fiber orientation. Fiber orientations considerably affect the mechanical and thermal properties of final composite products. In this study, fiber orientation of injection molded carbon fiber reinforced PA6/PPO composite was measured at several points of the specimen by optical microscopy analysis and the corresponding izod impact strength, coefficients of thermal expansion (CTE) were also measured to investigate the influence of local fiber orientation on the mechanical and thermal properties. Izod impact strength where fiber was perpendicular to the direction of crack propagation was higher than where fiber was parallel to the direction, which could be explained be the impact resistance reinforcing mechanism by fiber orientation. CTE was also lower where fiber was parallel to the measurement direction of CTE than where fiber was perpendicular to the direction, which could be also explained by the dimensional stability mechanism by fiber orientation.

• Composites Research
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• v.28 no.4
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• pp.239-243
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• 2015

Recent studies regarding the properties of carbon nanotubes (CNT) have made remarkable progress in CNT fibers research. However no CNT fibers showed the properties of CNTs because CNTs in fibers have weak interfacial bonding with low shear modulus in the pristine form. Thus, it is upmost interest to develop and employ post-production treatments to the CNT fibers that would potentially improve their properties. In this study, post-treatments resulted in improvement of strength of CNT fibers up to 40%.

• Polymer(Korea)
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• v.25 no.2
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• pp.218-225
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• 2001

The electroless plating of a metallic nickel on PAN-based carbon fiber surfaces was carried out to improve mechanical interfacial properties of the carbon fiber/epoxy resin composites which were unidirectionally fabricated by a prepregging method. In this work, the influence of Ni-P alloy concentration showing brittle-to-ductile transition was investigated on interlaminar shear strength (ILSS) and impact strength of the composites. The surface properties of carbon fibers were also measured by X-ray photoelectron spectroscopy (XPS). As the result, the $O_{ls}$ /$O_{ls}$ ratio or Ni and P amounts were increased with increasing electroless nickel plating time but the ILSS were not significantly improved. However, the impact properties was significantly improved in the presence of Ni-P alloy in the carbon fiber surface, resulting in an increase of the ductility of the composites.