• Applied Chemistry for Engineering
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• 제27권3호
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• pp.285-290
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• 2016

To improve properties of epoxy composites, surfaces of the illite and carbon nanotube (CNT) were treated by fluorine gas. The fluorinated illite and CNT were then characterized by X-ray photoelectron microscopy (XPS) and the mechanical and thermal properties of their composites were evaluated. The tensile and impact strengths and thermal stability of the composites increased upto about 59%, 18% and 124%, respectively compared to those of the neat epoxy. Improvements of mechanical and thermal properties in the composites were attributed that the fluorination of illite and carbon nanotube helps to enhance the dispersion in epoxy resin and interfacial interaction between them.

• Polymer(Korea)
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• 제39권1호
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• pp.114-121
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• 2015

Mutli-walled carbon nanotubes (MWCNTs) were surface-modified by a hydrofluoric acid solution to remove impurities and improve interfacial bonding and dispersion of nanotubes in an epoxy matrix. The crystallinity on the surface of treated MWCNTs was investigated by X-ray photoelectron spectroscopy and Raman spectroscopy. The mechanical properties were characterized by tensile test, and the enhancement of mechanical properties of the modified MWCNTs/epoxy composites was indicated by a 33% increase in tensile strength. The electromagnetic interference shielding effectiveness (EMI-SE) of modified MWCNTs/epoxy composites was improved with an increase in concentration of hydrofluoric solution, and EMI-SE showed the maximum increase with 25% HF. However, mechanical and EMI-SE properties didn't show further increase with over 50% HF concentration because the properties of MWCNTs were influenced by degradation of crystallinity and intrinsic properties of MWCNTs. The mechanical and electrical property enhancements of the polymer composites are attributed to the modification of MWCNTs which improve crystallinity of MWCNTs and dispersion in the epoxy resin.

• Composites Research
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• 제17권6호
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• pp.1-7
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• 2004

The studies of particulate reinforced composites have been conducted for many years. The nanocomposites to be studied vigorously in recent years are one of them. We fabricated and studied multi-walled carbon nanotube(MWNT)/epoxy composites which may be useful as matrix for continuous fiber-reinforced composites. We investigated tensile properties of MWNT/epoxy composites as a function of MWNT concentration, which were prepared by the fabrication method established in this study. Tensile stiffness and strength increased 19% at 0.5 wt% and 12% at 0.2 wt%, respectively. We observed the reaggregation phenomenon of MWNTS during curing, which should be controlled to obtain higher tensile properties.

• Composites Research
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• 제24권5호
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• pp.34-38
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• 2011

Carbon nanotubes (CNTs) have been widely investigated as reinforcements of CNT/polymer nanocomposites to enhance mechanical and electrical properties of polymer matrices since their discovery in the early 90's. Furthermore, the number of studies about incorporating CNTs into carbon fiber reinforced plastics (CFRP) to reinforce their polymer matrices is increasing recently. In this study, single-walled carbon nanotubes (SWNT) were dispersed in epoxy with 0.2 wt.% and 0.5 wt.%. Then, the SWNT/epoxy mixtures were processed to carbon fiber composites by a vacuum assisted resin transfer molding (VARTM) and a wet lay up method. The processed composite samples were tested for the interlaminar shear strength (ILSS). The relationship between the interlaminar shear strengths and processing, and the reinforcement mechanism of carbon nanotubes were investigated. CNT/epoxy nanocomposite specimens showed the increased tensile properties. However, the ILSS of carbon fiber composites was not enhanced by reinforcing the matrix with CNTs because of processing issues caused by increased viscosity of the matrix due to addition of CNTs particularly for a VARTM method.

• Composites Research
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• 제17권3호
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• pp.38-44
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• 2004

The electromagnetic interference (EMI) shielding is very essential for commercial and military purposes. We fabricated multi-walled carbon nanotube (MWNT)/epoxy composites and studied the electromagnetic characteristics of the composites before we study the characteristics of MWNT-added glass fiber-reinforced composites. After setting up the fabrication process, we measured the permittivity of MWNT/epoxy composites with process variables and MWNT concentrations in X-band (8.2GHz~12.4GHz). We also observed re-aggregation phenomenon of MWNTs and investigated its effect on the permittivity. The permittivity of the composites was influenced by the degree of dispersion of MWNTs and increased almost linearly as MWNT concentration increases.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 한국추진공학회 2000년도 제14회 학술강연논문집
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• pp.37-37
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• 2000

복합재료는 높은 무게비 강도 및 강성뿐만 아니라 우수한 재료 특성 때문에 경량화와 구조적 안전성이 요구되는 항공기의 구조재로서 사용이 증대되고 있다. 소형 민용항공기는 구조적 안전성과 함께 제작과 정비, 유지보수의 용이성이 중요시된다. 본 연구에서는 복합재료를 구조재로 사용하였을 때의 성능변화와 경량화 등을 검토하기 위하여 기존의 알루미늄 합금을 이용하여 설계된 소형 프로펠러 경항공기 날개의 구조재로서 복합재료를 사용하여 재설계하였다. 날개의 기본 구조는 스킨, 스파, 웹으로 구성된 상자형 단면으로 설계하였으며 날개의 구조재로서 탄소/에폭시를 사용하여 상용 유한요소해석코드인 NISAII를 이용하여 굽힘, 좌굴 등의 응력해석을 수행하였고 기존 설계된 날개와의 성능비교를 위하여 알루미늄 합금으로 설계된 날개를 모델링하여 해석한 결과와 비교하였다. 비교결과 구조재로 탄소/에폭시를 사용하여 설계된 날개가 무게비 성능면에서 더 우수함을 확인하였다.

• Composites Research
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• 제21권6호
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• pp.1-7
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• 2008

The main objective of this study is to investigate the effect of salt water on the mechanical properties of a high modulus carbon-epoxy composite. Specimens were made of a carbon-epoxy composite UPN139B of SK Chemical and tested under inplane tension and shear after 0, 1, 3, 6, 9, and 12 months immersion in 3.5% salt water. Acceleration technique such as temperature elevation was not used. The tensile strengths and modulli in fiber and matrix direction did not show any remarkable degradation until 12 months immersion. In contrast to the tensile properties, shear strength and modulus started to gradually decrease up to about 10% of values of dry specimens after 12 months immersion. It was confirmed through the test that the material UPN139B can be an effective material for the shell structures in salt water to resist against the external pressure buckling because of the high fiber directional modulus and corrosion resistance.

• Transactions of the Korean Society of Mechanical Engineers A
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• 제37권5호
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• pp.657-664
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• 2013

By using shear mixing and ultrasonication, we fabricated specimens of well-dispersed multi-walled carbon nanotube composites. To confirm the proper dispersion of the filler, we used scanning electron microscopy images for quantitative evaluation and a tensile test for qualitative assessment. Furthermore, the coefficients of thermal expansion of several specimens having different filler contents were calculated from the measured thermal strains and temperatures of the specimens. Based on the microscopy images of the well-dispersed fillers and the small deviations in the measurements of the tensile strength and stiffness, we confirmed the proper dispersion of nanotubes in the epoxy. As the filler contents were increased, the values of tensile strength increased from 58.33 to 68.81 MPa, and those of stiffness increased from 2.93 to 3.27 GPa. At the same time, the coefficients of thermal expansion decreased. This implies better thermal stability of the specimen.

• Composites Research
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• 제25권6호
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• pp.191-197
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• 2012

In this paper, the penetration behavior of carbon/epoxy composite laminates subjected to high velocity projectile impact was studied by numerical simulation. The composite laminates made of carbon/epoxy with $[45/0/-45/90]_{ns}$ stacking sequence and the spherical steel impactor were three-dimensionally modeled. The ply numbers of 16 and 24 and the impact velocities in the range of 140-250 m/s were considered. The analysis was performed using an explicit finite element code LS-DYNA. The residual velocity and the amount of damage were predicted and compared to the experimental results.

• Journal of the Korean Society for Railway
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• 제13권3호
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• pp.271-277
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• 2010

In this paper, a numerical model for a Kevlar/Epoxy and Carbon-Kevlar/Epoxy tube used as an energy absorbing component has been developed and then results have been verified through experiment. The 2D shell element and Chang-Chang failure criterion of LS-DYNA that is commercial explicit FE code was used. Mechanical material properties for the model were obtained by material testing in advance. The numerical results were compared with quasi-static test results under axial compressive loading at 10mm/min. From the results, in the case of the Kevlar/Epoxy tube, load-crushed displacement curves were very close to the experiments and SEA (specific energy absorption) shows a good agreement with experimental one within less than 6%. However, the Carbon-Kevlar/Epoxy tube shows some differences with the experimental results.