• Title/Summary/Keyword: 탄산화양생

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An Experimental Study on Carbonation Induction in Paste with CO2 Reactive Cement (CO2 반응경화 시멘트를 혼입한 페이스트의 탄산화 양생에 관한 실험적 연구)

  • Kim, Young-Jin;Ryu, Dong-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.79-80
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    • 2023
  • After the Second Industrial Revolution, as global warming caused by environmental issues has intensified, the CO2 emissions from the cement industry have become an urgent challenge. Therefore, this study aimed to reduce and utilize CO2 emissions by using CO2-reducing Calcium Silicate Cement.

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Effect of Mixed Ratios of Ground Improvement Material using Microorganisms on the Strength of Sands (미생물을 활용한 지반개량제의 혼합비율에 따른 사질토의 강도개선 효과)

  • Park, Kyung-Ho;Kim, Daehyeon
    • Journal of the Korean Geosynthetics Society
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    • v.14 no.2
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    • pp.1-9
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    • 2015
  • In this study, the objective of the study is to evaluate the effect of calcium carbonate powder, produced by the microbial reactions, on the strength of soft ground (sand). To analyze the cementation effects of calcium carbonate powder produced by microbial reactions on the strength of the sand, six different types of specimens (untreated, calcium carbonate, cement, carbonate+cement (1:9, 3:7, 5:5)) were made. The specimen were tested after curing (7 and 28 days). Uniaxial compressive strengths were measured on $D5cm{\times}H10cm$ specimens. Based on the test results, as both the weight ratio and the curing period increase, calcium carbonate, cement, and calcium carbonate+cement specimens showed an increase in the strength. In addition, compared with the strength of the specimen with cement, the strengths of the specimens with mixing ratios of 1:9, 3:7, and 5:5 (carbonate : cement) were found to be 93.5~95.8%, 825.%, 65.2~70.6%.

Resistance to Freezing and Thawing of Concrete Subjected to Carbonation (탄산화를 받은 콘크리트의 동결융해 저항성)

  • Lee, Seung-Tae;Park, Kwang-Pil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.623-631
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    • 2018
  • In this study, the degree of deterioration of concrete was investigated in the laboratory under conditions of carbonation and freeze-thaw cycling, which are the major causes of the deterioration of its performance. In this test, the carbonated concrete was subjected to combined freeze-thaw deterioration tests for up to 300 cycles, and its dynamic elastic modulus and compressive strength were measured. The evaluation of the effect of the water-binder ratio on normal concrete subjected to combined carbonization and freezing-thawing showed that its resistibility against such combined deterioration decreased more rapidly in the concrete with a water-binder ratio of 55 % compared with that having a water-binder ratio of 35 %. In the case where the concrete was blended with a mineral admixture consisting of fly ash and blast furnace slag at the same water-binder ratio, it showed an increase of its resistibility against combined deterioration.

Carbonation Behavior Evaluation of OPC Concrete Considering Effect of Aging and Loading Conditions (재령 및 하중효과를 고려한 OPC 콘크리트의 탄산화 거동 평가)

  • Hwang, Sang-Hyeon;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.122-129
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    • 2019
  • The movement of deterioration agents such as a chloride ion, etc. in concrete varies with loading conditions and micro-structure developed by age effect. In this paper, the carbonation behavior by accelerated carbonation test is evaluated considering curing periods(28 days, 91 days, and 365 days) and loading conditions. Carbonation velocity coefficients are obtained referred to KS F 2584. In the control case without loading condition, carbonation velocity coefficient of 91 days decreases to 50.0 % level and that of 365 days decreases to 44.8 % level than that of 28 days curing condition. In 28 curing days, carbonation velocity coefficients changed level of 103.9 ~ 108.8 % in tensile region and 91.9~104.6 % in compressive region by loading conditions. Carbonation velocity coefficients in the 30 % and 60 % tensile loading case at 28 days decreases to 47.3 % and 52.5 % level compared to control case after 1 year. Furthermore, 45.8 % and 44.9 % level of carbonation velocity coefficients are evaluated for 30 % and 60 % compressive loading conditions compared to control case after 1 year. Carbonation velocity coefficient decreases in the 30 % compressive loading level due to effective pore compaction and it increases afterwards due to micro-cracking. In the tensile loading condition, unlike the behavior of compressive region, it linearly increases with increasing loading level.

An Experimental Study on the Moisture Rate of Concrete and Spalling Resistance Measure for Impact of Concrete Moisture Rate on Spalling (콘크리트의 함수율과 폭렬발생에 미치는 영향에 따른 폭렬 방지 대책에 관한 연구)

  • Seo, Yoon-Jeong;Kim, Dong-Jun;Kwon, Young-Jin
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2010.04a
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    • pp.340-345
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    • 2010
  • 국내의 건축물은 강한 내력을 갖기 위해 사용되는 HSC빈도가 점진적 증가하고 있으며, HSC로 시공되어진 건축구조물에서의 화재 발생시 폭렬현상의 문제점이 대두되고 있다. 이에 국내외에서 폭렬현상에 대한 연구들이 진행되었고, 이를 통해 폭렬현상에 원인을 알게 되어 이를 토대로 폭렬 방지 방안을 세웠다. 이에 따라 폭렬현상의 원인 중 합수율이 있으며, 이는 콘크리트가 함유하고 있는 수분으로 고온시에 팽창하여 폭렬현상의 매커니즘이 형성된다. 또한 이러한 함수율이 폭렬 발생에 미치는 영향을 크게 하는 요인으로 탄산화와 양생방법이 있다. 우선 탄산화는 반응을 일으킬 경우, 생성물이 공극을 채워 고온시 팽창된 수분이 외부로 나가는 것을 방해하여 수증기압을 축적시키고, 양생방법에 따라 함수율이 달라지게 되어 고온시 팽창될 수분의 양을 결정하게 된다. 특히, 함수율에 의해 발생되는 폭렬을 방지하기 위해 고강도 콘크리트 내부의 수분을 제거하는 강제건조를 하거나 팽창된 수분이 빠져나갈 곳을 만들기 위해 고온에서 녹는 PP섬유를 사용해 공극을 만들어주는 방법이 있다. 따라서 본 연구는 HSC의 폭렬현상방지 대책을 위한 기초자료를 제시하고자 한다.

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Performance Based Evaluation of Concrete Carbonation from Climate Change Effect on Curing Conditions of Wind Speed and Sunlight Exposure Time (기후변화의 풍속과 일조시간 양생조건에 따른 콘크리트 탄산화 성능중심평가)

  • Kim, Tae-Kyun;Shin, Jae-Ho;Choi, Seung-Jai;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.5
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    • pp.45-55
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    • 2015
  • Currently, extreme weather events such as super typhoon, extreme snowfall, and heat wave are frequently occurring all over the world by natural and human caused factors. After industrial growth in the 1970s, earth's temperature has risen sharply. due to greenhouse effect. Global warming can be attributed to gases emitted from using fossil fuel such as average carbon dioxide, perfluorocarbons, nitrous oxide, and methane. Especially, carbon dioxide has the highest composition of about 90%. in the fossile fuel usage emitted gas. Concrete has excellent durability as a building material climate change. However, due to various of physical and chemical environmental effect such as conditions during its curing process, the performance degradation may occur. Carbon dioxide in the atmosphere causes steel corrosion and durability decreases by lowering the alkalinity of concrete. Therefore, in this study, concrete durability performance with respect to carbonation from curing conditions change due to wind speed and sunshine exposure time. Concrete carbonation experiment are performed. using wind speed (0, 2, 4, 6) m/s and sunlight exposure time (2, 4, 6, 8) hrs. Also, performance based evaluation through the satisfaction curve based on the carbonation depth and carbonation rate test results are performed.

Properties of non-cement mortars with small addition of alkali activator using fly ash and fused waste slag (석탄회 및 용융폐기물 슬래그에 소량의 알칼리 활성화제를 첨가한 무시멘트 모르타르의 특성)

  • Kim, Yootaek;Lee, Kyongwoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.257-262
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    • 2015
  • Recently the world wide efforts reduce occurrence of $CO_2$; global warming main reason. The aim of this study is to improve recycling rate of the fly ash (FA) and fused waste slag (FWS) from the power plant and to carbonate under supercritical condition ($40^{\circ}C$, $80kgf/cm^2$ pressure, 60 min) for $CO_2$ fixation. Specimens of mortar with various mixing ratios of FA, FWS (from 100:0 to 20:80 in 5 steps of 20 % reduction each time), distilled water and 3 M NaOH alkali activators were prepared. As a result, the proportion of weight change ratio increases with CaO content, to 12 % after carbonation under the supercritical condition. There is difference of compressive strength between the carbonated and the alkali activator mortar specimens. The stabilization of $CO_2$ fixation through carbonation which could confirm the applicability of the eco-friendly materials without loss of compressive strength.

Properties of Cement Paste Containing High Volume γ-C2S and MgO Subjected to CO2 Curing (γ-C2S 및 MgO를 다량 혼입한 시멘트 페이스트의 CO2 양생유무에 따른 특성변화)

  • Sung, Myung-Jin;Cho, Hyeong-Kyu;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.3
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    • pp.281-289
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    • 2015
  • Carbonation of concrete causes reduction of pH and subsequently causes steel corrosion for reinforced concrete structure. However, for plain concrete structure or PC product, it can lead to a decrease in porosity, high density, improvement of concrete, shrinkage-compensation. Recently, based on this theory, research of $CO_2$ curing effect has been performed, but it was mainly focused on its effects on compressive strength using only ordinary portland cement. Researches on $CO_2$ curing effect for concrete containing $CO_2$ reactive materials such as ${\gamma}-C_2S$, MgO haven't been investigated. Therefore, this study has performed experiments under water-binder ratio 40%, and the replacement ratios of ${\gamma}-C_2S$ and MgO were 90%. Micro-chemical analysis, measurement of compressive strength according to admixtures and $CO_2$ curing were investigated. Results from this study revealed that higher strength was measured in case of $CO_2$ curing compared with none $CO_2$ curing for plain specimen indicating difference between 1.08 and 1.26 times, in case of ${\gamma}-C_2S$ 90, MgO 90 specimen, incorporating high volume replaced as much as 90%, it was proven that when applying $CO_2$ curing, higher strength which has difference between 14.56 and 45.7 times, and between 6.5 and 10.37 times was measured for each specimen compared to none $CO_2$ curing. Through micro-chemical analysis, massive amount of $CaCO_3$, $MgCO_3$ and decrease of porosity were appeared.

Development of Soil Binder Using Plant Extracts (식물추출액을 이용한 지반 고결제 개발)

  • Park, Sung-Sik;Choi, Sun-Gyu;Nam, In-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.28 no.3
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    • pp.67-75
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    • 2012
  • This paper presents an environment-friendly sand cementation method by precipitating calcium carbonate using plant extracts. The plant extracts contain urease like $Sporosarcina$ $pasteurii$, which can decompose urea into carbonate ion and ammonium ion. It can cause cementation within sand particles where carbonate ions decomposed from urea combine with calcium ions dissolved from calcium chloride or calcium hydroxide to form calcium carbonate. Plant extracts, urea and calcium chloride or calcium hydroxide were blended and then mixed with Nakdong River sand. The mixed sand was compacted into a cylindrical specimen and cured for 3 days at room temperature ($18^{\circ}C$). Unconfined compression test, SEM and XRD analyses were carried out to evaluate three levels of urea concentration and two different calcium sources. As urea concentration increased, the unconfined compressive strength increased up to 10 times those without plant extracts because calcium carbonate precipitated more, regardless of calcium source. It was also found that the strength of specimen using calcium chloride was higher than that of specimen using calcium hydroxide.