• Journal of the Korea Concrete Institute
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• v.28 no.6
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• pp.647-653
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• 2016

In the paper, durability performance in FA (Fly Ash) blended concrete is evaluated considering replacement of FA with TDFA (Tire Derived Fuel Ash) from 3.0% to 12%. TDFA is a byproduct from combustion process in thermal power plant, where chopped rubber is mixed for boiling efficiency. This is the 1st study on application of TDFA to concrete as mineral admixture. For the work, concrete samples containing 0.5 of w/b (water to binder) ratio and 20% replacement ratio of FA are prepared. With replacing FA with TDFA to 12%, durability performance is evaluated regarding compressive strength, carbonation, chloride diffusion, and porosity. The results of compressive strength, carbonation, and porosity tests show reasonable improvement in durability performance to 12% replacement of TDFA. In particular, clear decreasing diffusion coefficient is observed with increasing TDFA replacement due to its packing effect. Concrete containing TDFA can be effective for durability improvement when workability is satisfied in mixing stage.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.4
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• pp.111-119
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• 2016

Rebound hammer test, SonReb method and concrete core test are most useful testing methods for estimate the concrete compressive strength of deteriorated concrete structures. But the accuracy of the NDE results on the existing structures could be reduced by the effects of the uncertainty of nondestructive test methods, material effects by aging and carbonation, and mechanical damage by drilling of core. In this study, empirical procedure for verifying the in-situ compressive strength of concrete is suggested through the probabilistic analysis on the 268 data of rebound and ultra-pulse velocity and core strengths obtained from 106 bridges. To enhance the accuracy of predicted concrete strength, the coefficients of core strength, and surface hardness caused by ageing or carbonation was adopted. From the results, the proposed equation by KISTEC and the estimation procedures proposed by authors is reliable than previously suggested equation and correction coefficient.

• Journal of the Korean Institute of Gas
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• v.21 no.3
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• pp.39-45
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• 2017

The LNG storage tank as core facility of LNG industry is mainly composed of the inner tank of nikel 9% steel and the outer tank of prestressed concrete. To respond proactively increased risk of structure performance deterioration due to fatigue of the inner tank and durability reduction of the outer tank, life evaluation program for LNG storage tank is needed. In this study, life evaluation program for LNG storage tank was developed to assess fatigue of the inner tank and durability(carbonation and chloride attack) of the outer tank. By defining the main three scenarios in the inner tank, the fatigue life analysis is conducted from structural analysis and Miner's damage rule. Carbonation progress of the outer tank is predicted according to thickness of cover concrete by using carbon dioxide contents and data of penetration depth. To consider a variety of input conditions and a reliability in results of chloride attack, the evaluation of choride attack for the outer tank is constructed through Life-365 program of open source.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.458-466
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• 2023

Structures in our surroundings deteriorate over time due to environmental and chemical factors, resulting in a decrease in their performance. The primary causes of degradation in concrete structures are carbonation, salt damage, and freeze-thaw cycles. Various maintenance methods exist to address these degradation issues. However, research and technological development for existing maintenance methods have been ongoing, but the accuracy and effectiveness of repair materials and techniques have not been extensively validated. Therefore, in this study, we conducted a material performance evaluation of various manufacturers' repair materials. Based on this evaluation, we applied corrosion inhibitors and epoxy, which are the methods most closely related to crack repair, to assess the durability performance against carbonation, salt damage, and freeze-thaw cycles. The results show approximately a two-fold performance improvement against carbonation and salt damage, and a 5% enhancement in repair performance against freeze-thaw cycles. Thus, it is considered effective in preventing rebar corrosion when appropriate maintenance is carried out according to environmental and chemical factors during structural repairs.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.4
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• pp.302-308
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• 2000

Stable amorphous calcium carbonate were synthesized from the serial work for the synthetic conditions such as concentration of solution, reaction temperature, aging time and pH of mother liquor. By using this as a precusor, calcite, aragonite and vaterite crystal particles were obtained in the water from adequate crystallization conditions. Furthermore, characterization for flourescence were performed by using crystals which were crystallized from the Sn dopped amorphous calcium carbonate. Calcite showed the most intensive emission and the center of emission wavelength was 464 nm with pure blue color. Calcite is expected to be used as phosphor for flourescent lamp because the maximum emission intensity was obtained from the excitation with 255 nm wavelength.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.49-50
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• 2021

However, in the case of concrete, there is a concern that carbonation may proceed due to environmental factors. However, in the case of concrete, there is a concern that carbonation may proceed due to environmental factors. Research is steadily underway to prevent carbonation because carbonation decreases durability and increases the risk from disasters. However, there are many cases in which studies related to carbonation have been conducted only with materials in the same space. Therefore, in this study, FT-IR was used to analyze the difference in carbonation components by structural parts of old buildings. As a result, it was confirmed that there was a difference in peak values for each structural part of the building. The difference in peak values was determined to indicate differences in components, so the level of carbonation progress was different, and it is believed that differentiated repair and reinforcement methods will be needed depending on the structure.

• Journal of the Korean Chemical Society
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• v.41 no.10
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• pp.535-540
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• 1997

Potassium carbonate reacts with silicon tetrachloride to form trichlorosilyloxy carbonylchloride which reacts subsequently with another molecule of silicon tetrachloride leading to phosgene eventually in chlorinated solvents. This in situ generated trichlorosilyloxy carbonylchloride or phosgene were found to be very effective for the chlorination of a wide variety of alcohols to the corresponding chlorides. Primary, secondary and benzylic alcohols were converted into corresponding chlorides when treated with silicon tetrachloride in the presence of potassium carbonate at room temperature.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.3
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• pp.198-205
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• 2014

The present paper investigates the leaching property of coal fly ash (FA) using distilled water as solvent and its performance of mineral carbonation. The highest leaching efficiency is obtained at 100 min after leaching begins and the overall leaching efficiencies of Ca and Na via five consecutive leachings were calculated to be 25.37% and 7.40%, respectively. In addition, because $Ca(OH)_2$ produced during the leaching reacts with $SiO_2$ which is the major component of FA, the Pozzolanic reaction may occur and thus reduces leaching efficiency. Total carbonation capacity of FA by absorbing $CO_2$ into FA leachates is 6.08 mg $CO_2/g$ FA and the contribution of alkali substances such as Ca, Na, Mg and K to this value is calculated to be 5.19 mg $CO_2/g$ FA. Carbonation efficiencies of Ca and Na based on leachates are 85.62% and 77.70%, respectively. On the other hand, the ratios of Ca and Na in raw FA to participate in carbonation are calculated to be 9.04% and 5.26%, respectively.

• Journal of the Korea Concrete Institute
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• v.15 no.6
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• pp.778-784
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• 2003

The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion of carbon dioxide reached the steady-state within about five hours after exposure. The diffusion coefficient increases with the increase of water-cement ratio and decreases with the increase of relative humidity at the same water-cement ratio. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger than that of concrete or mortar. The experimental study of carbon dioxide diffusivity in this study will allow more realistic assessment of carbonation depth in concrete structures.

• Journal of the Korea Concrete Institute
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• v.15 no.3
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• pp.443-453
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• 2003

The diffusivity of carbon dioxide in concrete is very important in that it directly affects the degree of carbonation in concrete structures. The purpose of the present study is to explore the diffusivity of carbon dioxide and to derive a realistic equation to estimate the diffusion coefficient of carbon dioxide in concrete. For this purpose, several series of concrete specimens have been tested. Major test variables were the water-cement ratios. The total porosities and the diffusion coefficients of carbon dioxide were measured for the specimens. The present study indicates that the measured porosities agree well with the calculated ones. The effects of porosity and relative humidity on the diffusion coefficient of carbon dioxide were examined. A prediction equation to estimate the diffusion coefficient of carbon dioxide was derived and proposed in this study. The proposed equation shows reasonably good correlation with test data on the $CO_2$ diffusion coefficient of concrete